2006 journal article

Molecularly asymmetric triblock copolymers as a single-molecule route to ordered bidisperse polymer brushes

LANGMUIR, 22(15), 6465–6468.

By: S. Smith n, M. Hamersky n, M. Bowman n, K. Rasmussen n & R. Spontak n

TL;DR: The conditions signaling the formation of bidisperse brushes in ordered block copolymers are investigated as an A(2) block is progressively grown onto an A (1)B diblock copolymer to form a series of molecularly asymmetric, isomorphic A(1)BA( 2) triblockCopolymers. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2006 journal article

Selectivity- and size-induced segregation of molecular and nanoscale species in microphase-ordered triblock copolymers

NANO LETTERS, 6(9), 2115–2120.

By: R. Spontak n, R. Shankar n, M. Bowman n, A. Krishnan n, M. Hamersky n, J. Samseth n, M. Bockstaller n, K. Rasmussen n

TL;DR: A self-consistent field theoretical approach is used to quantitatively evaluate the segregation and interfacial excess of low-molar-mass and nanoscale species in ordered triblock copolymers as functions of block selectivity and inclusion size, and the predictions are found to agree with the morphology observed in a model triblockCopolymer/nanoparticle composite, demonstrating the generality of this approach. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

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