@article{aneja_arya_rumsey_kim_bajwa_arkinson_semunegus_dickey_stefanski_todd_et al._2008, title={Characterizing ammonia emissions from swine farms in eastern North Carolina: Part 2 - Potential environmentally superior technologies for waste treatment}, volume={58}, ISSN={["2162-2906"]}, url={http://www.scopus.com/inward/record.url?eid=2-s2.0-53849100726&partnerID=MN8TOARS}, DOI={10.3155/1047-3289.58.9.1145}, abstractNote={Abstract The need for developing environmentally superior and sustainable solutions for managing the animal waste at commercial swine farms in eastern North Carolina has been recognized in recent years. Program OPEN (Odor, Pathogens, and Emissions of Nitrogen), funded by the North Carolina State University Animal and Poultry Waste Management Center (APWMC), was initiated and charged with the evaluation of potential environmentally superior technologies (ESTs) that have been developed and implemented at selected swine farms or facilities. The OPEN program has demonstrated the effectiveness of a new paradigm for policy-relevant environmental research related to North Carolina’s animal waste management programs. This new paradigm is based on a commitment to improve scientific understanding associated with a wide array of environmental issues (i.e., issues related to the movement of N from animal waste into air, water, and soil media; the transmission of odor and odorants; disease-transmitting vectors; and airborne pathogens). The primary focus of this paper is on emissions of ammonia (NH3) from some potential ESTs that were being evaluated at full-scale swine facilities. During 2-week-long periods in two different seasons (warm and cold), NH3 fluxes from water-holding structures and NH3 emissions from animal houses or barns were measured at six potential EST sites: (1) Barham farm—in-ground ambient temperature anaerobic digester/energy recovery/greenhouse vegetable production system; (2) BOC #93 farm—upflow biofiltration system—EKOKAN ; (3) Carrolls farm—aerobic blanket system—ISSUES-ABS; (4) Corbett #1 farm—solids separation/gasification for energy and ash recovery centralized system—BEST; (5) Corbett #2 farm—solid separation/reciprocating water technology—ReCip; and (6) Vestal farm—Recycling of Nutrient, Energy and Water System—ISSUES—RENEW. The ESTs were compared with similar measurements made at two conventional lagoon and spray technology (LST) farms (Moore farm and Stokes farm). A flow-through dynamic chamber system and two sets of open-path Fourier transform infrared (OP-FTIR) spectrometers measured NH3 fluxes continuously from water-holding structures and emissions from housing units at the EST and conventional LST sites. A statisticalobservational model for lagoon NH3 flux was developed using a multiple linear regression analysis of 15-min averaged NH3 flux data against the relevant environmental parameters measured at the two conventional farms during two different seasons of the year. This was used to compare the water-holding structures at ESTs with those from lagoons at conventional sites under similar environmental conditions. Percentage reductions in NH3 emissions from different components of each potential EST, as well as the whole farm on which the EST was located were evaluated from the estimated emissions from water-holding structures, barns, etc., all normalized by the appropriate nitrogen excretion rate at the potential EST farm, as well as from the appropriate conventional farm. This study showed that ammonia emissions were reduced by all but one potential EST for both experimental periods. However, on the basis of our evaluation results and analysis and available information in the scientific literature, the evaluated alternative technologies may require additional technical modifications to be qualified as unconditional ESTs relative to NH3 emissions reductions.}, number={9}, journal={JOURNAL OF THE AIR & WASTE MANAGEMENT ASSOCIATION}, author={Aneja, Viney P. and Arya, S. Pal and Rumsey, Ian C. and Kim, D. -S. and Bajwa, K. and Arkinson, H. L. and Semunegus, H. and Dickey, D. A. and Stefanski, L. A. and Todd, L. and et al.}, year={2008}, month={Sep}, pages={1145–1157} } @article{aneja_arya_kim_rumsey_arkinson_semunegus_bajwa_dickey_stefanski_todd_et al._2008, title={Characterizing ammonia emissions from swine farms in eastern north carolina: Part 1-conventional lagoon and spray technology for waste treatment}, volume={58}, ISSN={["1047-3289"]}, url={http://www.scopus.com/inward/record.url?eid=2-s2.0-53849107841&partnerID=MN8TOARS}, DOI={10.3155/1047-3289.58.9.1130}, abstractNote={Abstract Ammonia (NH3) fluxes from waste treatment lagoons and barns at two conventional swine farms in eastern North Carolina were measured. The waste treatment lagoon data were analyzed to elucidate the temporal (seasonal and diurnal) variability and to derive regression relationships between NH3 flux and lagoon temperature, pH and ammonium content of the lagoon, and the most relevant meteorological parameters. NH3 fluxes were measured at various sampling locations on the lagoons by a flow-through dynamic chamber system interfaced to an environmentally controlled mobile laboratory. Two sets of open-path Fourier transform infrared (FTIR) spectrometers were also used to measure NH3 concentrations for estimating NH3 emissions from the animal housing units (barns) at the lagoon and spray technology (LST) sites.Two different types of ventilation systems were used at the two farms. Moore farm used fan ventilation, and Stokes farm used natural ventilation. The early fall and winter season intensive measurement campaigns were conducted during September 9 to October 11, 2002 (lagoon temperature ranged from 21.2 to 33.6 °C) and January 6 to February 2, 2003 (lagoon temperature ranged from 1.7 to 12 °C), respectively. Significant differences in seasonal NH3 fluxes from the waste treatment lagoons were found at both farms. Typical diurnal variation of NH3 flux with its maximum value in the afternoon was observed during both experimental periods. Exponentially increasing flux with increasing surface lagoon temperature was observed, and a linear regression relationship between logarithm of NH3 flux and lagoon surface temperature (T l) was obtained. Correlations between lagoon NH3 flux and chemical parameters, such as pH, total Kjeldahl nitrogen (TKN), and total ammoniacal nitrogen (TAN) were found to be statistically insignificant or weak. In addition to lagoon surface temperature, the difference (D) between air temperature and the lagoon surface temperature was also found to influence the NH3 flux, especially when D > 0 (i.e., air hotter than lagoon). This hot-air effect is included in the statistical-observational model obtained in this study, which was used further in the companion study (Part II), to compare the emissions from potential environmental superior technologies to evaluate the effectiveness of each technology.}, number={9}, journal={JOURNAL OF THE AIR & WASTE MANAGEMENT ASSOCIATION}, author={Aneja, Viney P. and Arya, S. Pal and Kim, D. -S. and Rumsey, Ian C. and Arkinson, H. L. and Semunegus, H. and Bajwa, K. S. and Dickey, D. A. and Stefanski, L. A. and Todd, L. and et al.}, year={2008}, month={Sep}, pages={1130–1144} } @article{bajwa_arya_aneja_2008, title={Modeling studies of ammonia dispersion and dry deposition at some hog farms in North Carolina}, volume={58}, ISSN={["1047-3289"]}, url={http://www.scopus.com/inward/record.url?eid=2-s2.0-53849137372&partnerID=MN8TOARS}, DOI={10.3155/1047-3289.58.9.1198}, abstractNote={Abstract A modeling study was conducted on dispersion and dry deposition of ammonia taking one hog farm as a unit. The ammonia emissions used in this study were measured under our OPEN (Odor, Pathogens, and Emissions of Nitrogen) project over a waste lagoon and from hog barns. Meteorological data were also collected at the farm site. The actual layout of barns and lagoons on the farms was used to simulate dry deposition downwind of the farm. Dry deposition velocity, dispersion, and dry deposition of ammonia were studied over different seasons and under different stability conditions using the short-range dispersion/air quality model, AERMOD. Dry deposition velocities were highest under near-neutral conditions and lowest under stable conditions. The highest deposition at short range occurred under nighttime stable conditions and the lowest occurred during daytime unstable conditions. Significant differences in deposition over crop and grass surfaces were observed under stable conditions.}, number={9}, journal={JOURNAL OF THE AIR & WASTE MANAGEMENT ASSOCIATION}, author={Bajwa, Kanwardeep S. and Arya, S. Pal and Aneja, Viney P.}, year={2008}, month={Sep}, pages={1198–1207} } @article{aneja_arya_rumsey_kim_bajwa_williams_2008, title={Characterizing ammonia emissions from swine farms in eastern North Carolina: Reduction of emissions from water-holding structures at two candidate superior technologies for waste treatment}, volume={42}, ISSN={["1352-2310"]}, url={http://www.scopus.com/inward/record.url?eid=2-s2.0-41449117100&partnerID=MN8TOARS}, DOI={10.1016/j.atmosenv.2007.08.037}, abstractNote={Abstract Program OPEN (Odor, Pathogens, and Emissions of Nitrogen) was an integrated study of the emissions of ammonia (NH 3 ), odor and odorants, and pathogens from potential environmentally superior technologies (ESTs) for swine facilities in eastern North Carolina. This paper, as part of program OPEN, focuses on quantifying emissions of NH 3 from water-holding structures at two of the best ESTs and compares them with the projected emissions from two conventional lagoon and spray technologies (LSTs). The evaluated ESTs are: (1) Super Soils at Goshen Ridge; and (2) Environmental Technologies at Red Hill. The water-holding structures for these two ESTs contained no conventional anaerobic lagoon. A dynamic flow-through chamber was used to measure NH 3 fluxes from the water-holding structures at both the ESTs and at the conventional LST farms. In order to compare the emissions from the water-holding structures at the ESTs with those from the lagoons at the conventional sites under similar conditions, a statistical-observational model for lagoon NH 3 emissions was used. A mass-balance approach was used to quantify the emissions. All emissions were normalized by nitrogen-excretion rates. The percentage reductions relative to the conventional lagoons were calculated for the two ESTs. Results showed substantial reductions in NH 3 emissions at both ESTs. Super Soils had reductions of 94.7% for the warm season and 99.0% for the cool season. Environmental Technologies had slightly larger reductions of 99.4% and 99.98% for the cool and warm season, respectively. As a result of such large reductions in ammonia emissions, both technologies meet the criteria to be classified as ESTs for ammonia emissions.}, number={14}, journal={ATMOSPHERIC ENVIRONMENT}, author={Aneja, Viney P. and Arya, S. Pal and Rumsey, Ian C. and Kim, D-S. and Bajwa, K. S. and Williams, C. M.}, year={2008}, month={Apr}, pages={3291–3300} } @article{bajwa_aneja_arya_2006, title={Measurement and estimation of ammonia emissions from lagoon-atmosphere interface using a coupled mass transfer and chemical reactions model, and an equilibrium model}, volume={40}, ISSN={["1352-2310"]}, url={http://www.scopus.com/inward/record.url?eid=2-s2.0-33748805536&partnerID=MN8TOARS}, DOI={10.1016/j.atmosenv.2005.12.076}, abstractNote={Ammonia has recently gained importance for its increasing atmospheric concentrations and its role in the formation of aerosols. The anaerobic lagoon and spray method, commonly used for waste storage and disposal in confined animal feeding operations (CAFO), is a significant source of ammonia emissions. An accurate emission model for ammonia from aqueous surfaces can help in the development of emission factors. Data collected from field measurements made at hog waste lagoons in south eastern North Carolina, using the flow through dynamic chamber technique, were used to evaluate the Coupled mass transfer and Chemical reactions model and Equilibrium model developed by Aneja et al. [2001a. Measurement and modeling of ammonia emissions at waste treatment lagoon-Atmospheric Interface. Water, Air and Soil pollution: Focus 1, 177–188]. Sensitivity analysis shows that ammonia flux increases exponentially with lagoon temperature and pH, but a linear increase was observed with an increase in total ammoniacal nitrogen (TAN). Ammonia flux also shows a nonlinear increase with increasing wind speed. Observed ammonia fluxes were generally lower in the cold season than in the warm season when lagoon temperatures are higher. About 41% of the equilibrium model predictions and 43% of the Coupled model predictions are found to be within a factor of two of the observed fluxes. Several model performance statistics were used to evaluate the performance of the two models against the observed flux data. These indicate that the simpler Equilibrium model does as well as the Coupled model. The possible effects of the "artificial" environment within the chamber, which is different from that in the ambient atmospheric conditions above the open lagoon surface, on the measured fluxes are also recognized.}, number={SUPPL. 2}, journal={ATMOSPHERIC ENVIRONMENT}, author={Bajwa, Kanwardeep S. and Aneja, Viney P. and Arya, S. Pal}, year={2006}, pages={S275–S286} }