Synthesis of [NH4]MnCl2(OAc) and [NH4]2MnCl4(H2O)2 by Solvothermal Dehydration and Structure/Property Correlations in a One-Dimensional Antiferromagnet
Martin, J. D., Hess, R. F., & Boyle, P. D. (2004, April 15). Inorganic Chemistry, Vol. 43, pp. 3242–3247.
topics (OpenAlex): Magnetism in coordination complexes; Metal-Organic Frameworks: Synthesis and Applications; Lanthanide and Transition Metal Complexes
TL;DR:
The utility of the solvothermal dehydration strategy whereby superheated acetonitrile reacts with water of hydration to form ammonium acetate is demonstrated in the synthesis of [NH(4)]MnCl(2)(OAc), I, and [NH (4)](2)Mn Cl(4)(H( 2)O)(2), II, from MnCl( 2).4H(1)O.
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