Tuning the Electronic Structure of Fe(II) Polypyridines via Donor Atom and Ligand Scaffold Modifications: A Computational Study
Bowman, D. N., Bondarev, A., Mukherjee, S., & Jakubikova, E. (2015, August 21). Inorganic Chemistry, Vol. 54, pp. 8786–8793.
topics (OpenAlex): Metal complexes synthesis and properties; Magnetism in coordination complexes; N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
TL;DR:
It is found that the ligand field strength in the Fe(II) polypyridines can be tuned by altering the donor atom identity, with C donor atoms providing the strongestligand field.
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