@article{mohamed_elzeny_samuel_xu_malliakas_picard_pham_miller_hogan_space_et al._2024, title={Turning Normal to Abnormal: Reversing CO<sub>2</sub>/C2-Hydrocarbon Selectivity in HKUST-1}, volume={1}, ISSN={["1616-3028"]}, DOI={10.1002/adfm.202312280}, abstractNote={Abstract}, journal={ADVANCED FUNCTIONAL MATERIALS}, author={Mohamed, Mona H. and Elzeny, Islam and Samuel, Joshua and Xu, Wenqian and Malliakas, Christos D. and Picard, Yoosuf N. and Pham, Tony and Miller, Lenore and Hogan, Adam and Space, Brian and et al.}, year={2024}, month={Jan} }
 @article{forrest_pham_chen_jiang_madden_franz_hogan_zaworotko_space_2021, title={Tuning the Selectivity between C2H2 and CO2 in Molecular Porous Materials}, volume={37}, ISSN={["0743-7463"]}, DOI={10.1021/acs.langmuir.1c02009}, abstractNote={A combined experimental and theoretical study of C2H2 and CO2 adsorption and separation was performed in two isostructural molecular porous materials (MPMs): MPM-1-Cl ([Cu2(adenine)4Cl2]Cl2) and MPM-1-TIFSIX ([Cu2(adenine)4(TiF6)2]). It was revealed that MPM-1-Cl displayed higher low-pressure uptake, isosteric heat of adsorption (Qst), and selectivity for C2H2 than CO2, whereas the opposite was observed for MPM-1-TIFSIX. While MPM-1-Cl contains only one type of accessible channel, which has a greater preference toward C2H2, MPM-1-TIFSIX contains three distinct accessible channels, one of which is a confined region between two large channels that represents the primary binding site for both adsorbates. According to molecular simulations, the initial adsorption site in MPM-1-TIFSIX interacts more strongly with CO2 than C2H2, thus explaining the inversion of adsorbate selectivity relative to MPM-1-Cl.}, number={47}, journal={LANGMUIR}, author={Forrest, Katherine A. and Pham, Tony and Chen, Kai-Jie and Jiang, Xue and Madden, David G. and Franz, Douglas M. and Hogan, Adam and Zaworotko, Michael J. and Space, Brian}, year={2021}, month={Nov}, pages={13838–13845} }