@article{lemercier_pierce_2016, title={Thiohydroximic acids: Versatile reagents for organic synthesis}, volume={27}, number={2}, journal={Synlett}, author={Lemercier, B. C. and Pierce, J. G.}, year={2016}, pages={181–189} } @article{lemercier_pierce_2015, title={Synthesis of 1,4,2-Oxathiazoles via Oxidative Cyclization of Thiohydroximic Acids}, volume={17}, ISSN={["1523-7052"]}, DOI={10.1021/acs.orglett.5b02256}, abstractNote={An oxidative formation of 1,4,2-oxathiazoles from readily available thiohydroximic acids is reported. A variety of alkyl, aryl, and heteroaryl substituents are well tolerated for both the thiohydroximic acid and activating fragments, and the reaction has been demonstrated on gram-scale. This reaction represents the only method currently available to prepare a diverse set of oxathiazoles and expands the chemistry of C-H oxidation via appended N-OH functional groups. Finally, we also demonstrate the rapid preparation of a 1,4,2-oxathiazole analog of an anticancer lead molecule.}, number={18}, journal={ORGANIC LETTERS}, author={Lemercier, Berenice C. and Pierce, Joshua G.}, year={2015}, month={Sep}, pages={4542–4545} } @article{lemercier_pierce_2014, title={Synthesis of Thiazolines by Copper Catalyzed Aminobromination of Thiohydroximic Acids}, volume={16}, ISSN={["1523-7052"]}, DOI={10.1021/ol500588v}, abstractNote={A copper catalyzed aminobromination of alkene tethered thiohydroximic acids is described, providing a rapid approach to unnatural thiazoline scaffolds not readily available via existing methods. Moderate to high yields of bromothiazolines are obtained with alkyl- and aryl-substituted thiohydroximic acid building blocks containing mono-, di-, and trisubstituted alkenes. The reaction provides high levels of 5-exo selectivity, and terminally monosubstituted alkenes result in predominant syn-diastereoselectivity.}, number={7}, journal={ORGANIC LETTERS}, author={Lemercier, Berenice C. and Pierce, Joshua G.}, year={2014}, month={Apr}, pages={2074–2076} } @article{lemercier_pierce_2014, title={Synthesis of Thiohydroxamic Acids and Thiohydroximic Acid Derivatives}, volume={79}, ISSN={["0022-3263"]}, DOI={10.1021/jo500080x}, abstractNote={An improved and expanded preparation of thiohydroxamic acids is reported along with a one-pot conversion of these compounds to novel thiohydroximic acid derivatives. A variety of aryl, heteroaryl, and alkyl substituents are well tolerated to provide a rapid approach to alkene-functionalized thiohydroximic acids that serve as potentially useful building blocks for organic synthesis.}, number={5}, journal={JOURNAL OF ORGANIC CHEMISTRY}, author={Lemercier, Berenice C. and Pierce, Joshua G.}, year={2014}, month={Mar}, pages={2321–2330} }