@article{obijalska_pietrzak_constantinides_sommer_kaszynski_2023, title={"Super stable" Blatter radicals through ArLi addition: surprising chemistry of 7-(trifluoromethyl)benzo[e][1,2,4]triazine}, ISSN={["1364-548X"]}, DOI={10.1039/d3cc00832k}, abstractNote={Addition of PhLi to 7-(CF3)benzo[e][1,2,4]triazine at -78 °C gives the "super stable" Blatter radical in high yields, while above -5 °C two additional products are formed. XRD analysis revealed the formation of a "trimer" and a benzo[f][1,2,4]triazepine via a novel mechanism. The latter is formed from the anion generated from the isolated radical, which suggests its instability in organic batteries.}, journal={CHEMICAL COMMUNICATIONS}, author={Obijalska, Emilia and Pietrzak, Anna and Constantinides, Christos. P. P. and Sommer, Roger. D. D. and Kaszynski, Piotr}, year={2023}, month={Mar} }
 @article{constantinides_obijalska_kaszynski_2016, title={Access to 1,4-Dihydrobenzo[e][1,2,4]triazin-4-yl Derivatives}, volume={18}, ISSN={["1523-7052"]}, DOI={10.1021/acs.orglett.5b03528}, abstractNote={A simple, one-pot method for the preparation of 1-aryl-3-phenyl-1,4-dihydrobenzo[e][1,2,4]triazin-4-yl radicals by addition of aryllithium to the readily available 3-phenylbenzo[e][1,2,4]triazine followed by aerial oxidation is described. The intermediate anion is also trapped as an N-benzyloxycarbonyl derivative and purified prior to deprotection and oxidation to the radical. The method was demonstrated for nine (het)arenes, and the regioselectivity of nucleophilic addition to the benzo[e][1,2,4]triazine and trapping of the intermediate anion with electrophiles was assessed computationally.}, number={5}, journal={ORGANIC LETTERS}, author={Constantinides, Christos P. and Obijalska, Emilia and Kaszynski, Piotr}, year={2016}, month={Mar}, pages={916–919} }
 @misc{constantinides_koutentis_2016, title={Stable N- and N/S-rich heterocyclic radicals: Synthesis and applications}, volume={119}, journal={Heterocyclic chemistry in the 21st century: a tribute to alan katritzky}, author={Constantinides, C. P. and Koutentis, P. A.}, year={2016}, pages={173–207} }
 @article{kaszynski_constantinides_young_2016, title={The Planar Blatter Radical: Structural Chemistry of 1,4-Dihydrobenzo[e][1,2,4]triazin-4-yls}, volume={55}, ISSN={["1521-3773"]}, DOI={10.1002/anie.201605612}, abstractNote={Two planarized analogues of the prototypical Blatter radical (1), peri-annulated 1S and 1O , are demonstrated and provide a new platform for molecular and supramolecular engineering, and for tuning electronic and magnetic properties of the radical. Planarization of 1 results in bathochromic shift to the near-IR region, greater spin delocalization, and anodic shift of the reduction potential only for 1S . Magnetization studies revealed nearly ideal paramagnetic behavior at high temperatures for both radicals 1S and 1O with one-dimensional ferromagnetic interaction in the former (2J=14.4 cm(-1) ) and antiferromagnetic interactions in 1O at low temperatures.}, number={37}, journal={ANGEWANDTE CHEMIE-INTERNATIONAL EDITION}, author={Kaszynski, Piotr and Constantinides, Christos P. and Young, Victor G., Jr.}, year={2016}, month={Sep}, pages={11149–11152} }