Works (14)
Updated: August 5th, 2023 21:15
2022 journal article
A Unified Approach to Decarboxylative Halogenation of (Hetero)aryl Carboxylic Acids
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 144(18), 8296–8305.
MeSH headings : Carboxylic Acids / chemistry; Catalysis; Copper / chemistry; Halogenation; Ligands
TL;DR:
This work reports a general catalytic method for direct decarboxylative halogenation of (hetero)aryl carboxylic acids via ligand-to-metal charge transfer that accommodates an exceptionally broad scope of substrates.
(via Semantic Scholar)
Sources: ORCID, Web Of Science, NC State University Libraries
Added: April 30, 2022
2022 article
Real-Time and In Situ Viscosity Monitoring in Industrial Adhesives Using Luminescent Cu(I) Phenanthroline Molecular Sensors
Dara, A., Mast, D. M., Razgoniaev, A. O., Hauke, C. E., Castellano, F. N., & Ostrowski, A. D. (2022, July 13). ACS APPLIED MATERIALS & INTERFACES, Vol. 7.
author keywords: viscosity sensing; materials sensing; real-time monitoring; Cu(I) sensors; mechanical property sensing
UN Sustainable Development Goal Categories
3. Good Health and Well-being
(Web of Science)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: July 14, 2022
2021 article
CsPbI3 Nanocrystals Go with the Flow: From Formation Mechanism to Continuous Nanomanufacturing
Antami, K., Bateni, F., Ramezani, M., Hauke, C. E., Castellano, F. N., & Abolhasani, M. (2021, November 21). ADVANCED FUNCTIONAL MATERIALS, Vol. 11.
author keywords: CsPbI; (3) nanocrystals; lead halide perovskites; microfluidics; nanomanufacturing; quantum dots
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy
(Web of Science; OpenAlex)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: November 22, 2021
2021 journal article
Next Generation Cuprous Phenanthroline MLCT Photosensitizer Featuring Cyclohexyl Substituents
INORGANIC CHEMISTRY, 60(12), 8394–8403.
TL;DR:
Electrochemical and static PL data illustrate that [Cu(dchtmp)2]PF6 is a potent photoreductant equal to or greater than all previously investigated homoleptic Cu(I) diimine complexes.
(via Semantic Scholar)
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy
(Web of Science)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: June 8, 2021
2020 journal article
Correction to “Direct Evidence of Visible Light-Induced Homolysis in Chlorobis(2,9-dimethyl-1,10-phenanthroline)copper(II)”
Correction to “Direct Evidence of Visible Light-Induced Homolysis in Chlorobis(2,9-dimethyl-1,10-phenanthroline)copper(II).” The Journal of Physical Chemistry Letters, 11(14), 5749–5749.
open access via pubs.acs.org (publisher PDF)
Source: ORCID
Added: December 15, 2020
2020 journal article
Direct Evidence of Visible Light-Induced Homolysis in Chlorobis(2,9-dimethyl-1,10-phenanthroline)copper(II)
The Journal of Physical Chemistry Letters, 11(13), 5345–5349.
TL;DR:
The combined results from static spectroscopic investigations and conventional photochemistry, ultrafast transient absorption, and electron paramagnetic resonance (EPR) spin trapping experiments, strongly support blue light induced Cu-Cl homolytic bond cleavage occurring in [Cu(dmp)2Cl]+ occurring in less than 100 femtoseconds.
(via Semantic Scholar)
Sources: Web Of Science, ORCID, NC State University Libraries, Crossref
Added: July 27, 2020
2020 journal article
Ligand-triplet migration in iridium(iii) cyclometalates featuring π-conjugated isocyanide ligands
Dalton Transactions, 49(29), 9995–10002.
TL;DR:
Variations in photophysical response are consistent with lowering the triplet ligand-centered (3LC) state of the arylisocyanide ligand as the π system was extended, confirmed by 77 K photoluminescence emission spectra and ultrafast transient absorption experiments.
(via Semantic Scholar)
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy
(Web of Science)
Sources: Web Of Science, ORCID, NC State University Libraries, Crossref
Added: August 17, 2020
2019 journal article
Understanding the Effects of Coordination and Self-Assembly on an Emissive Phenothiazine
Journal of the American Chemical Society, 141(8), 3717–3722.
MeSH headings : Coordination Complexes / chemical synthesis; Coordination Complexes / chemistry; Luminescence; Luminescent Agents / chemical synthesis; Luminescent Agents / chemistry; Molecular Structure; Phenothiazines / chemistry; Platinum / chemistry; Quantum Theory
TL;DR:
The self-assembly of a highly emissive platinum(II)-based metallacage is reported, which results in a 10-fold increase in quantum yield and a twist in the chromophore upon coordination of platinum or methylation on the pyridyl group, leading to intersystem crossing to a triplet state.
(via Semantic Scholar)
Source: ORCID
Added: January 18, 2022
2017 journal article
A Bis(dipyrrinato) Motif as a Building Block for Polynuclear Rhenium(I) Architectures
European Journal of Inorganic Chemistry, 2017(34), 4055–4060.
author keywords: Rhenium; X-ray diffraction; Polynuclear; Absorption; N ligands
Source: ORCID
Added: January 18, 2022
2017 journal article
Coordination-Driven Self-Assembly of Ruthenium Polypyridyl Nodes Resulting in Emergent Photophysical and Electrochemical Properties
Inorganic Chemistry, 57(7), 3587–3595.
TL;DR:
The use of the [Ru(bpy)2]2+ fragment as a 90° acceptor tecton (M) in coordination-driven self-assembly to synthesize a M4L4 metallacycle (L = 4,4'-bipyridine) and a M6L4 truncated tetrahedral cage [L = 2,4,6-tris(4-pyridyl)-1,3,5-triazine].
(via Semantic Scholar)
Source: ORCID
Added: January 18, 2022
2017 journal article
Increasing phosphorescent quantum yields and lifetimes of platinum-alkynyl complexes with extended conjugation
Dalton Transactions, 46(30), 9794–9800.
TL;DR:
Evidence is provided for stabilization of metallo-cumulene resonance forms whose increased rigidities manifest in the observed photophysical changes and the use of σ-donating N-heterocyclic carbenes to complete the Pt-coordination environment enhanced the quantum yield of phosphorescence.
(via Semantic Scholar)
Source: ORCID
Added: January 18, 2022
2017 journal article
Phosphorescent Decanuclear Bimetallic Pt6M4 (M = Zn, Fe) Tetrahedral Cages
Inorganic Chemistry, 56(8), 4258–4262.
TL;DR:
Both cages were fully characterized by NMR, electrospray ionization mass spectrometry, and single-crystal X-ray diffraction (SCXRD) and only the homochiral enantiomers are formed based on 1H NMR and SCXRD.
(via Semantic Scholar)
Source: ORCID
Added: January 18, 2022
2017 journal article
Photophysical Enhancement of Triplet Emitters by Coordination-Driven Self-Assembly
Chemistry - A European Journal, 23(19), 4532–4536.
author keywords: coordination-driven self-assembly; metallacycle; phosphorescence; photophysics; platinum
TL;DR:
The role of intersystem crossing from a deactivating process to one that delivers emissive triplet states was reversed and the quantum yields of organic fluorophores used as donors in coordination-driven self-assembly were improved.
(via Semantic Scholar)
Source: ORCID
Added: January 18, 2022
2015 journal article
A Suite of Tetraphenylethylene-Based Discrete Organoplatinum(II) Metallacycles: Controllable Structure and Stoichiometry, Aggregation-Induced Emission, and Nitroaromatics Sensing
Journal of the American Chemical Society, 137(48), 15276–15286.
TL;DR:
This work reports the preparation of a new family of discrete multi-TPE metallacycles in which two pendant phenyl rings of the TPE units remain unused as a structural element, representing novel AIE-active metal-organic materials based on supramolecular coordination complex platforms.
(via Semantic Scholar)
Source: ORCID
Added: January 18, 2022
Employment
Updated: February 13th, 2019 17:10
2019 - present
North Carolina State University Raleigh, NC, US
Post-Doctoral Research Scholar
Chemistry
2011 - 2014
Momentive Performance Materials Inc Tarrytown Waterford, NY, US
Product Development Technician
Research and Development
2008 - 2011
Albany Molecular Research Inc Albany, NY, US
Research Scientist I/II
Analytical Development
Education
Updated: February 13th, 2019 17:08
2014 - 2019
University at Buffalo - North Campus Amherst, NY, US
PhD
Chemistry
2004 - 2008
SUNY College of Environmental Science and Forestry Syracuse, NY, US
Bachelors of Science
Chemistry
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