2013 journal article

Self-organized and cu-coordinated surface linear polymerization

Scientific Reports, 3.

By: Q. Li, J. Owens, C. Han, B. Sumpter, W. Lu, J. Bernholc, V. Meunier, P. Maksymovych, M. Fuentes-Cabrera, M. Pan

Source: NC State University Libraries
Added: August 6, 2018

2012 journal article

Electronic Control over Attachment and Self-Assembly of Alkyne Groups on Gold

ACS NANO, 6(10), 9267–9275.

author keywords: scanning tunneling microscopy; molecular reaction; self-assembly; 3D tethering
MeSH headings : Alkynes / chemistry; Crystallization / methods; Electroplating / methods; Gold / chemistry; Macromolecular Substances / chemistry; Materials Testing; Molecular Conformation; Nanostructures / chemistry; Nanostructures / ultrastructure; Particle Size; Surface Properties
TL;DR: A nonthermal, electron-induced approach to the self-assembly of phenylacetylene molecules on gold that allows for a previously unachievable attachment of the molecules to the surface through the alkyne group is demonstrated. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2011 journal article

Supramolecular Self-Assembly of pi-Conjugated Hydrocarbons via 2D Cooperative CH/pi Interaction

ACS NANO, 6(1), 566–572.

author keywords: phenylacetylene; self-assembly; STM; supramolecule; hydrogen bonding; magic cluster
MeSH headings : Carbon / chemistry; Computer Simulation; Hydrogen / chemistry; Hydrogen Bonding; Macromolecular Substances / chemistry; Models, Chemical; Models, Molecular; Nanostructures / chemistry; Nanostructures / ultrastructure; Particle Size; Surface Properties
TL;DR: It is shown that functionalizing a benzene molecule with an ethyne group introduces attractive interactions in a 2D geometry, which would otherwise be dominated by intermolecular repulsion, and enables supramolecular self-assembly. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

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