Chelsea Marie Taliaferro

Works (5)

Updated: July 5th, 2023 15:34

2023 article

Excited state processes of dinuclear Pt(II) complexes bridged by 8-hydroxyquinoline

Kromer, S., Roy, S., Yarnell, J. E., Taliaferro, C. M., & Castellano, F. N. (2023, March 1). DALTON TRANSACTIONS, Vol. 3.

By: S. Kromer n, S. Roy n, J. Yarnell n, C. Taliaferro n & F. Castellano n 

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Added: March 7, 2023

2020 journal article

Photophysics and ultrafast processes in rhenium(i) diimine dicarbonyls

Dalton Transactions, 49(33), 11565–11576.

By: H. Atallah n , C. Taliaferro n, K. Wells n & F. Castellano n 

TL;DR: The MLCT excited state decay of this series of dicarbonyl molecules appears completely consistent with energy-gap law behavior, where the nonradiative decay rate constants increase logarithmically with decreasing excited state - ground state energy separation. (via Semantic Scholar)
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Added: September 14, 2020

2018 journal article

Bathophenanthroline Disulfonate Ligand-Induced Self-Assembly of Ir(III) Complexes in Water: An Intriguing Class of Photoluminescent Soft Materials

ACS Omega, 3(10), 14027–14038.

By: M. McGoorty n, A. Singh n, T. Deaton n, B. Peterson  n, C. Taliaferro n, Y. Yingling n , F. Castellano n 

Contributors: M. McGoorty n, A. Singh n, T. Deaton n, B. Peterson  n, C. Taliaferro n, Y. Yingling n , F. Castellano n 

TL;DR: A combination of nanoscale particle characterization techniques, static and dynamic photoluminescence spectroscopic studies, along with atomistic molecular dynamics simulations of these soft materials suggests the formation of small, heterogeneous nanoaggregate structures, wherein the sulfonated diimine ancillary ligand serves as a pro-aggregating subunit in all instances. (via Semantic Scholar)
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Added: November 26, 2018

2018 journal article

Excited-State Switching between Ligand-Centered and Charge Transfer Modulated by Metal–Carbon Bonds in Cyclopentadienyl Iridium Complexes

Inorganic Chemistry, 57(24), 15445–15461.

By: J. Deaton n, C. Taliaferro n, C. Pitman *, R. Czerwieniec *, E. Jakubikova n , A. Miller *, F. Castellano n 

TL;DR: Density functional theory calculations suggest that the lowest energy triplet states in these complexes are composed of a mixture of MLCT and ligand-to-ligand CT originating from both the Cp* and methyl or hydride ancillary ligands. (via Semantic Scholar)
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Added: January 7, 2019

2018 journal article

Ultrafast Dynamics of the Metal-to-Ligand Charge Transfer Excited States of Ir(III) Proteo and Deutero Dihydrides

The Journal of Physical Chemistry A, 122(18), 4430–4436.

By: C. Taliaferro n, E. Danilov n  & F. Castellano n 

TL;DR: The information presented here provides valuable insight for understanding the primary photophysical events and transient absorption and IR spectroscopic signatures likely to be encountered throughout metal hydride photochemistry. (via Semantic Scholar)
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Added: August 6, 2018

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