Cheng-Ping Yu

Works (2)

Updated: July 5th, 2023 15:34

2018 article

Elucidating the Reaction Pathway of Decarboxylation-Assisted Olefination Catalyzed by a Mononuclear Non-Heme Iron Enzyme

Yu, C.-P., Tang, Y., Cha, L., Milikisiyants, S., Smirnova, T. I., Smirnov, A. I., … Chang, W.-chen. (2018, October 30). Journal of the American Chemical Society, Vol. 140, pp. 15190–15193.

By: C. Yu n, Y. Tang *, L. Cha n , S. Milikisiyants n, T. Smirnova n , A. Smirnov n , Y. Guo *, W. Chang n 

Contributors: C. Yu n, Y. Tang *, L. Cha n , S. Milikisiyants n, T. Smirnova n , A. Smirnov n , Y. Guo *, W. Chang n 

MeSH headings : Alkenes / chemistry; Alkenes / metabolism; Biocatalysis; Decarboxylation; Molecular Structure; Nonheme Iron Proteins / metabolism
topics (OpenAlex): Metal-Catalyzed Oxygenation Mechanisms; Microbial Natural Products and Biosynthesis
TL;DR: Experimental observations imply that a pathway involving an initial C-H activation followed by a benzylic carbocation species or by electron transfer coupled β-scission is likely utilized to complete C═C bond formation. (via Semantic Scholar)
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Sources: Web Of Science, ORCID, NC State University Libraries
Added: December 10, 2018

2018 article

Mechanistic Investigation of Oxidative Decarboxylation Catalyzed by Two Iron(II)- and 2-Oxoglutarate-Dependent Enzymes

Huang, J.-L., Tang, Y., Yu, C.-P., Sanyal, D., Jia, X., Liu, X., … Chang, W.-chen. (2018, February 27). Biochemistry, Vol. 57, pp. 1838–1841.

By: J. Huang  n, Y. Tang *, C. Yu n, D. Sanyal n, X. Jia  n, X. Liu *, Y. Guo *, W. Chang n 

Contributors: J. Huang  n, Y. Tang *, C. Yu n, D. Sanyal n, X. Jia  n, X. Liu *, Y. Guo *, W. Chang n 

MeSH headings : Carboxy-Lyases / chemistry; Catalysis; Iron / chemistry; Ketoglutaric Acids / chemistry
topics (OpenAlex): Metal-Catalyzed Oxygenation Mechanisms; Synthesis and Catalytic Reactions
TL;DR: It is proposed that both IsnB and AmbI3 initiate stereoselective olefination via a benzylic C-H bond activation by an Fe(IV)-oxo intermediate, and the reaction likely proceeds through a radical- or carbocation-induced decarboxylation to complete C═C bond installation. (via Semantic Scholar)
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Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

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