Dev Sanyal

Works (2)

Updated: July 5th, 2023 15:37

2018 journal article

Mechanistic Investigation of Oxidative Decarboxylation Catalyzed by Two Iron(II)- and 2-Oxoglutarate-Dependent Enzymes

BIOCHEMISTRY, 57(12), 1838–1841.

By: J. Huang n, Y. Tang *, C. Yu n, D. Sanyal n, X. Jia  n, X. Liu *, Y. Guo *, W. Chang n 

Contributors: J. Huang n, Y. Tang *, C. Yu n, D. Sanyal n, X. Jia  n, X. Liu *, Y. Guo *, W. Chang n 

MeSH headings : Carboxy-Lyases / chemistry; Catalysis; Iron / chemistry; Ketoglutaric Acids / chemistry
TL;DR: It is proposed that both IsnB and AmbI3 initiate stereoselective olefination via a benzylic C-H bond activation by an Fe(IV)-oxo intermediate, and the reaction likely proceeds through a radical- or carbocation-induced decarboxylation to complete C═C bond installation. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2017 journal article

In Vitro Stepwise Reconstitution of Amino Acid Derived Vinyl Isocyanide Biosynthesis: Detection of an Elusive Intermediate

ORGANIC LETTERS, 19(5), 1208–1211.

By: W. Chang n , D. Sanyal n, J. Huang n, K. Ittiamornkui, Q. Zhu * & X. Liu *

Contributors: W. Chang n , D. Sanyal n, J. Huang n, K. Ittiamornkul*, Q. Zhu * & X. Liu *

MeSH headings : Amino Acids; Cyanides / chemistry; Molecular Structure
TL;DR: Establishment of a tractable isonitrile synthase system (AmbI1 and AmbI2) paves the way to elucidate the enigmatic enzyme mechanism for isocyanide formation. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

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