Works (51)

Updated: April 4th, 2024 07:16

2024 article

Hexafluoroisopropanol as a Bioconjugation Medium of Ultrafast, Tryptophan-Selective Catalysis

Nuruzzaman, M., Colella, B. M., Uzoewulu, C. P., Meo, A. E., Gross, E. J., Ishizawa, S., … Ohata, J. (2024, February 29). JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Vol. 2.

By: M. Nuruzzaman n, B. Colella n, C. Uzoewulu n, A. Meo n, E. Gross n, S. Ishizawa n, S. Sana*, H. Zhang* ...

Sources: Web Of Science, ORCID
Added: March 18, 2024

2022 journal article

Well-Defined ENENES Re and Mn Complexes and Their Application in Catalysis: The Role of Potassium tert-Butoxide

ORGANOMETALLICS, 41(19), 2678–2687.

By: L. Gouveia n & E. Ison n

UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, ORCID
Added: October 24, 2022

2021 article

Are all charge-transfer parameters created equally? A study of functional dependence and excited-state charge-transfer quantification across two dye families

Marshburn, R. D., Ashley, D. C., Curtin, G. M., Sultana, N., Liu, C., Vinueza, N. R., … Jakubikova, E. (2021, August 30). PHYSICAL CHEMISTRY CHEMICAL PHYSICS, Vol. 8.

By: R. Marshburn n, D. Ashley*, G. Curtin n, N. Sultana n, C. Liu n, N. Vinueza n, E. Ison n, E. Jakubikova n

TL;DR: A combined experimental and computational study of the excited-state electronic structure of twenty organic dyes obtained from the Max Weaver Dye Library at NCSU found that hybrid functionals with modest amounts of included Hartree-Fock exchange are the most effective at matching the experimentally determined λmax. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: September 20, 2021

2021 journal article

Energy Decomposition Analysis of Lewis Acid/Base Adducts and Frustrated Lewis Pairs: The Use of E-Orb/E-Steric Ratios as a Reaction Parameter

INORGANIC CHEMISTRY, 60(18), 13797–13805.

By: E. Ison n & J. Tubb n

TL;DR: Energy decomposition analyses on classical adducts and FLPs reveal that these species can be defined by the ratio (EOrb/ESteric) of covalent-to-noncovalent contributions to the total interaction energy, EInt, which suggests that similar NCIs are present in both transition-metal and main-group FLPs. (via Semantic Scholar)
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, ORCID
Added: October 12, 2021

2021 article

Submonomer synthesis of peptoids containing trans-inducing N-imino- and N-alkylamino-glycines

Davern, C. M., Lowe, B. D., Rosfi, A., Ison, E. A., & Proulx, C. (2021, May 10). CHEMICAL SCIENCE, Vol. 5.

By: C. Davern n, B. Lowe n, A. Rosfi n, E. Ison n & C. Proulx n

TL;DR: The use of hydrazones as a new type of submonomer in peptoid synthesis is described, giving access to peptoid monomers that are structure-inducing and favors the trans-amide bond geometry by NMR, X-ray crystallography, and computational analyses. (via Semantic Scholar)
Sources: Web Of Science, ORCID
Added: June 10, 2021

2020 journal article

Identification of key functionalization species in the Cp*Ir(iii)-catalyzed-ortho halogenation of benzamides

Dalton Transactions, 49(45), 16166–16174.

By: A. Guzmán Santiago n, C. Brown n, R. Sommer n & E. Ison n

Sources: Crossref, ORCID
Added: April 18, 2020

2020 journal article

Re-Silane complexes as frustrated lewis pairs for catalytic hydrosilylation

DALTON TRANSACTIONS, 49(32), 11403–11411.

By: C. Brown n, M. Abrahamse n & E. Ison n

TL;DR: By tuning the electrophilicity of the rhenium catalysts, conditions can be found that would enable the catalytic hydrosilylation of ketone and nitrile substrates that were unreactive in previously reported systems. (via Semantic Scholar)
Sources: Web Of Science, ORCID
Added: September 7, 2020

2020 journal article

Synthesis and Reactivity of Re(III) and Re(V) Fischer Carbenes

ORGANOMETALLICS, 39(3), 388–396.

By: C. Brown n, C. Lilly n, N. Lambic n, R. Sommer n & E. Ison n

Sources: Web Of Science, ORCID
Added: April 20, 2020

2020 journal article

Synthesis and reactivity of nitridorhenium complexes incorporating the mercaptoethylsulfide (SSS) ligand

Dalton Transactions, 49, 6127–6134.

By: N. Lambić n, R. Sommer n & E. Ison n

TL;DR: The lack of a significant steric profile on the SSS ligand combined with enhanced nucleophilicity of the nitrido group does not allow for the effective formation of frustrated Lewis pairs with these complexes and as a result these species are poor catalysts for the hydrogenation of unactivated olefins. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID
Added: April 24, 2020

2019 chapter

Toward N—N Bond Cleavage: Synthesis and Reactivity of Group 7 Dinitrogen Complexes

In Y. Nishibayashi (Ed.), Transition Metal‐Dinitrogen Complexes: Preparation and Reactivity (pp. 271–284).

By: E. Ison n

Ed(s): Y. Nishibayashi

Sources: NC State University Libraries, ORCID
Added: March 5, 2021

2018 journal article

High-valent nitridorhenium(V) complexes containing PNP ligands: implications of ligand flexibility

DALTON TRANSACTIONS, 47(3), 758–768.

By: N. Lambic n, R. Sommer n & E. Ison n

TL;DR: The addition of CO to isomer 3' is proposed to proceed with a similar mechanism to 2,6-dimethylphenyl isocyanide, and DFT (M06) calculations suggest that insertion of CNR into the Re-Me bond is inaccessible at room temperature. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: August 6, 2018

2017 journal article

Cationic rhenium ((III)) complexes: synthesis, characterization, and reactivity for hydrosilylation of aldehydes

Dalton Transactions (Cambridge, England : 2003), 46(14), 4609–4616.

By: D. Perez n, J. Smeltz n, R. Sommer n, P. Boyle n & E. Ison n

TL;DR: The catalytic efficiency for the hydrosilylation reaction of aldehydes using 4a has been demonstrated to be significantly more active than rhenium catalysts previously reported in the literature and the data suggest that electron-withdrawing substituents at the diamido amine ligand increase the catalysttic efficiency of the complexes. (via Semantic Scholar)
Sources: NC State University Libraries, ORCID
Added: August 6, 2018

2017 journal article

Dramatic Increase in the Rate of Olefin Insertion by Coordination of Lewis Acids to the Oxo Ligand in Oxorhenium(V) Hydrides

ORGANOMETALLICS, 36(10), 2042–2051.

By: N. Lambic n, C. Brown n, R. Sommer n & E. Ison n

Sources: Web Of Science, ORCID
Added: August 6, 2018

2017 journal article

Oxorhenium Complexes for Catalytic Hydrosilylation and Hydrolytic Hydrogen Production: A Multiweek Advanced Laboratory Experiment for Undergraduate Students

Journal of Chemical Education, 94(6), 790–794.

By: A. Ison n, E. Ison n & C. Perry n

author keywords: Upper-Division Undergraduate; Laboratory Instruction; Synthesis; Catalysis; Kinetics; NMR Spectroscopy; Organic Chemistry; Inorganic Chemistry; Communication/Writing
Sources: Crossref, ORCID
Added: February 24, 2020

2017 journal article

Tuning Catalytic Activity in the Hydrogenation of Unactivated Olefins with Transition-Metal Oxos as the Lewis Base Component of Frustrated Lewis Pairs

ACS CATALYSIS, 7(2), 1170–1180.

By: N. Lambic n, R. Sommer n & E. Ison n

author keywords: frustrated Lewis pairs; transition metal oxos; hydrogenation; olefins; catalytic tuning
Sources: Web Of Science, ORCID
Added: August 6, 2018

2016 journal article

Effect of the Ancillary Ligand on the Mechanism for CO Migratory Insertion in High-Valent Oxorhenium Complexes

ORGANOMETALLICS, 35(20), 3530–3537.

By: L. Robbins n, C. Lilly n, R. Sommer n & E. Ison n

UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: August 6, 2018

2016 journal article

Mechanism for the Reaction of CO with Oxorhenium Hydrides: Migratory Insertion of CO into Rhenium Hydride and Formyl Bonds leads to Migration from Rhenium to the Oxo Ligand

ORGANOMETALLICS, 35(17), 3060–3068.

By: N. Lambic n, C. Lilly n, R. Sommer n & E. Ison n

UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: August 6, 2018

2016 journal article

Non-directed, carbonate-mediated C-H activation and aerobic C-H oxygenation with Cp*Ir catalysts

DALTON TRANSACTIONS, 45(24), 9942–9947.

By: M. Kerr*, I. Ahmed*, A. Gunay*, N. Venditto*, F. Zhu*, E. Ison n, M. Emmert*

TL;DR: Based on these studies, Cp*Ir/carbonate systems are developed that catalyze the aerobic Csp(3)-H oxygenation of alkyl arenes, employing air as oxidant. (via Semantic Scholar)
Sources: Web Of Science, ORCID
Added: August 6, 2018

2016 journal article

Nondirected C-H Activation of Arenes with Cp*Ir(III) Acetate Complexes: An Experimental and Computational Study

ORGANOMETALLICS, 35(15), 2435–2445.

By: D. Frasco n, S. Mukherjee n, R. Sommer n, C. Perry n, N. Lambic n, K. Abboud*, E. Jakubikoya, E. Ison n

Sources: Web Of Science, ORCID
Added: August 6, 2018

2016 journal article

Nondirected C–H Activation of Arenes with Cp* Ir (III) Acetate Complexes: An Experimental and Computational Study

Organometallics, 35, 2435–2445.

By: D. Frasco n, S. Mukherjee n, R. Sommer n, C. Perry n, N. Lambic n, K. Abboud*, E. Jakubikova n, E. Ison n

Sources: NC State University Libraries, ORCID
Added: February 20, 2021

2016 journal article

Reductive Carbonylation of Oxorhenium Hydrides Induced by Lewis Acids

ORGANOMETALLICS, 35(17), 2822–2829.

By: N. Lambic n, C. Lilly n, L. Robbins n, R. Sommer n & E. Ison n

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID
Added: August 6, 2018

2016 journal article

Transition-Metal Oxos as the Lewis Basic Component of Frustrated Lewis Pairs

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 138(14), 4832–4842.

By: N. Lambic n, R. Sommer n & E. Ison n

TL;DR: It is demonstrated for the first time that the incorporation of a transition-metal oxo in a frustrated Lewis pair can have a synergistic effect and results in enhanced catalytic activity at olefin hydrogenation. (via Semantic Scholar)
Sources: Web Of Science, ORCID
Added: August 6, 2018

2015 journal article

Oxyfunctionalization with Cp*Ir-III(NHC)(Me)(CI) with O-2: Identification of a Rare Bimetallic Ir-IV mu-Oxo Intermediate

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 137(10), 3574–3584.

By: M. Lehman n, D. Pahls*, J. Meredith*, R. Sommer n, D. Heinekey*, T. Cundari*, E. Ison n

TL;DR: Isotope labeling studies confirmed the origin of the methyl group in the methanol product is the iridium-methyl bond in the [Cp*Ir(NHC)Me(CD2Cl2)][BAr(F)4] starting material, and DFT and MCSCF calculations reveal several important features of the electronic structure of 3. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: August 6, 2018

2015 journal article

Synthesis and Reactivity of Oxorhenium (V) Methyl, Benzyl, and Phenyl Complexes with CO: Implications for a Unique Mechanism for Migratory Insertion.

Organometallics, 34(13), 3152–3158.

By: L. Robbins n, C. Lilly n, J. Smeltz n, P. Boyle n & E. Ison n

Sources: NC State University Libraries, ORCID
Added: February 9, 2021

2015 journal article

Synthesis and Reactivity of Oxorhenium(V) Methyl, Benzyl, and Phenyl Complexes with CO: Implications for a Unique Mechanism for Migratory Insertion

ORGANOMETALLICS, 34(13), 3152–3158.

By: L. Robbins n, C. Lilly n, J. Smeltz n, P. Boyle n & E. Ison n

UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: August 6, 2018

2015 journal article

ortho-C–H Activation of Thiobenzoic Acid: Synthesis, Characterization, and Reactivity of Iridium Thiobenzoate Complexes

Organometallics, 34(1), 275–279.

By: D. Frasco n, R. Sommer n & E. Ison n

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID
Added: August 6, 2018

2014 journal article

Oxyfunctionalization with Cp*Ir-III(NHC)(Me)L Complexes

ORGANOMETALLICS, 33(19), 5081–5084.

By: M. Lehman n, P. Boyle n, R. Sommer n & E. Ison n

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID
Added: August 6, 2018

2013 journal article

Cp*Ir-III-Catalyzed Oxidative Coupling of Benzoic Acids with Alkynes

ACS CATALYSIS, 3(10), 2421–2429.

By: D. Frasco n, C. Lilly n, P. Boyle n & E. Ison n

author keywords: C-H functionalization; oxidative coupling; C-H activation; Cp*Ir-III; annulation
Sources: Web Of Science, ORCID
Added: August 6, 2018

2013 journal article

Effect of Solvent and Ancillary Ligands on the Catalytic H/D Exchange Reactivity of Cp*Ir-III(L) Complexes

ACS CATALYSIS, 3(10), 2304–2310.

By: M. Lehman n, J. Gary*, P. Boyle n, M. Sanford* & E. Ison n

author keywords: H/D exchange; C-H activation; C-H functionalization; Cp*Ir-III catalysts; kinetics; isotope effects
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID
Added: August 6, 2018

2013 journal article

Mechanism of MTO-Catalyzed Deoxydehydration of Diols to Alkenes Using Sacrificial Alcohols

ORGANOMETALLICS, 32(11), 3210–3219.

By: S. Liu*, A. Senocak*, J. Smeltz n, L. Yang*, B. Wegenhart*, J. Yi*, H. Kenttaemaa, E. Ison n, M. Abu-Omar*

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID
Added: August 6, 2018

2013 journal article

The Electronic Nature of Terminal Oxo Ligands in Transition-Metal Complexes: Ambiphilic Reactivity of Oxorhenium Species

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 135(25), 9433–9441.

By: J. Smeltz n, C. Lilly n, P. Boyle n & E. Ison n

TL;DR: These are the first examples of mono-oxo d(2) metal complexes in which the oxo ligand exhibits ambiphilic reactivity, and it is shown that stoichiometric reactions between 3 and triarylphosphine (PAr3) result in the formation of triaryl phosphine oxide (OPAr3). (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: August 6, 2018

2012 journal article

Computational Investigation of the Mechanism for the Activation of CO by Oxorhenium Complexes

ORGANOMETALLICS, 31(10), 4055–4062.

By: J. Smeltz n, C. Webster* & E. Ison n

UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: August 6, 2018

2012 journal article

Role of Low-Valent Rhenium Species in Catalytic Hydrosilylation Reactions with Oxorhenium Catalysts

ORGANOMETALLICS, 31(17), 5994–5997.

By: J. Smeltz n, P. Boyle n & E. Ison n

Sources: Web Of Science, ORCID
Added: August 6, 2018

2012 journal article

Synthesis of Oxorhenium Acetyl and Benzoyl Complexes Incorporating Diamidopyridine Ligands: Implications for the Mechanism of CO Insertion

ORGANOMETALLICS, 31(11), 4295–4301.

By: C. Lilly n, P. Boyle n & E. Ison n

UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, ORCID
Added: August 6, 2018

2012 journal article

Synthesis of Well-Defined Copper N-Heterocyclic Carbene Complexes and Their Use as Catalysts for a “Click Reaction”: A Multistep Experiment That Emphasizes the Role of Catalysis in Green Chemistry

Journal of Chemical Education, 89(12), 1575–1577.

By: E. Ison n & A. Ison n

author keywords: Upper-Division Undergraduate; Inorganic Chemistry; Laboratory Instruction; Organic Chemistry; Communication/Writing; Hands-On Learning/Manipulatives; Catalysis; Green Chemistry; Synthesis
UN Sustainable Development Goal Categories
Sources: Crossref, ORCID
Added: December 21, 2020

2011 journal article

C-H Bond Functionalization of Benzoic Acid: Catalytic Synthesis of 2-Hydroxy-6H-benzo[c]chromen-6-ones Using (Cp*IrCl2)(2)

ORGANOMETALLICS, 30(17), 4572–4577.

By: K. Engelman n, Y. Feng n & E. Ison n

Sources: Web Of Science, ORCID
Added: August 6, 2018

2011 journal article

Mechanism for the Activation of Carbon Monoxide via Oxorhenium Complexes

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 133(34), 13288–13291.

By: J. Smeltz n, P. Boyle n & E. Ison n

TL;DR: An unprecedented mechanism is proposed: CO is activated by theMetal oxo complex 1 and inserted into the rhenium-methyl bond to yield acyl complex 2, after which subsequent migration of the acyl ligand to the metal oxo ligand yields acetate complex 3. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: August 6, 2018

2011 journal article

Observation of Inductive Effects That Cause a Change in the Rate-Determining Step for the Conversion of Rhenium Azides to Imido Complexes

Inorganic Chemistry, 50(20), 10505–10514.

By: N. Travia*, Z. Xu*, J. Keith*, E. Ison*, P. Fanwick*, M. Hall*, M. Abu-Omar*

TL;DR: The Hammett linear free-energy relationship and the activation parameters support a change in the mechanism between electron-withdrawing and electron-donating aryl azide, and the barriers for these two steps are inverted in their order with respect to the Hammett σ values. (via Semantic Scholar)
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Crossref, ORCID
Added: February 24, 2020

2011 journal article

Synthesis and characterization of oxorhenium(V) diamido pyridine complexes that catalyze oxygen atom transfer reactions

DALTON TRANSACTIONS, 40(44), 11815–11821.

By: C. Lilly n, P. Boyle n & E. Ison n

TL;DR: The detailed syntheses of complexes 1-4 incorporating the diamido pyridine (DAP) ancillary ligand (2,6-bis((mesitylamino)methyl)pyridine) are described and shown to be effective catalysts for oxygen atom transfer (OAT) reactions of PyO to PPh(3). (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID
Added: August 6, 2018

2010 journal article

Effect of Ancillary Ligands and Solvents on H/D Exchange Reactions Catalyzed by Cp*Ir Complexes

ORGANOMETALLICS, 29(13), 2857–2867.

By: Y. Feng n, B. Jiang n, P. Boyle n & E. Ison n

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID
Added: August 6, 2018

2009 journal article

Catalysis by cationic oxorhenium(v): hydrolysis and alcoholysis of organic silanes

Dalton Transactions, 15(15), 2850–2855.

By: R. Corbin*, E. Ison* & M. Abu-Omar*

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Crossref, ORCID, Web Of Science
Added: February 24, 2020

2009 journal article

Synthesis of Oxorhenium(V) Complexes with Diamido Amine Ancillary Ligands and Their Role in Oxygen Atom Transfer Catalysis

INORGANIC CHEMISTRY, 48(23), 11058–11066.

By: Y. Feng n, J. Aponte n, P. Houseworth n, P. Boyle n & E. Ison n

MeSH headings : Amines / chemistry; Catalysis; Crystallography, X-Ray; Ligands; Models, Molecular; Molecular Structure; Organometallic Compounds / chemical synthesis; Organometallic Compounds / chemistry; Oxygen / chemistry; Rhenium / chemistry; Stereoisomerism
TL;DR: Although the Re(VII) intermediate could not be isolated, its activity in OAT reactions was probed by competition experiments with PPh(3) and four para-substituted triarylphosphines, suggesting that the OAT reaction in these five-coordinate complexes appears to be governed by isomerization of the starting complex. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: August 6, 2018

2008 journal article

Mechanistic Investigations of the Iridium(III)-Catalyzed Aerobic Oxidation of Primary and Secondary Alcohols

Journal of the American Chemical Society, 130(44), 14462–14464.

By: B. Jiang n, Y. Feng n & E. Ison n

TL;DR: A new mechanism for the Ir-catalyzed aerobic oxidation is presented that suggests that the transition metal maintains its +3 oxidation state throughout the entire catalytic cycle. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Crossref, ORCID, Web Of Science
Added: August 6, 2018

2007 journal article

Synthesis of Cationic Rhenium(VII) Oxo Imido Complexes and Their Tunability Towards Oxygen Atom Transfer

Journal of the American Chemical Society, 129(5), 1167–1178.

By: E. Ison*, J. Cessarich*, N. Travia*, P. Fanwick* & M. Abu-Omar*

TL;DR: Investigation of the mechanism suggests that the reactions of Re(V) with aryl azides proceed through an azido adduct similar to the group 5 complexes of Bergman and Cummins. (via Semantic Scholar)
Sources: Crossref, ORCID
Added: February 24, 2020

2006 journal article

Synthesis and Reactivity of Molybdenum Imido Diamido Metallacyclopentenes and Metallacyclopentadienes and the Mechanism of Ethylene Exchange with Metallacyclopentane Complexes

Organometallics, 25(7), 1557–1564.

By: E. Ison*, K. Abboud* & J. Boncella*

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Crossref, ORCID
Added: December 21, 2020

2006 journal article

Synthesis of Cationic Oxorhenium Salen Complexes via μ-Oxo Abstraction and Their Activity in Catalytic Reductions

Inorganic Chemistry, 45(6), 2385–2387.

By: E. Ison*, J. Cessarich*, G. Du*, P. Fanwick* & M. Abu-Omar*

TL;DR: Cationic oxorhenium salen complexes are prepared by the abstraction of bridging oxo ligands with [Et3Si][B(C6F5)4] and [Ph3C]; these complexes catalyze the reduction of 2-butanone with Et3SiH under ambient conditions. (via Semantic Scholar)
Sources: Crossref, ORCID
Added: August 28, 2020

2005 journal article

Hydrogen Production from Hydrolytic Oxidation of Organosilanes Using a Cationic Oxorhenium Catalyst

Journal of the American Chemical Society, 127(34), 11938–11939.

By: E. Ison*, R. Corbin* & M. Abu-Omar*

TL;DR: The novel application of a transition metal oxo complex, a cationic oxorhenium(V) oxazoline, in the production of molecular hydrogen (H2) from the catalytic hydrolytic oxidation of organosilanes is described. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Crossref, ORCID
Added: February 24, 2020

2005 journal article

Mechanism for Reduction Catalysis by Metal Oxo:  Hydrosilation of Organic Carbonyl Groups Catalyzed by a Rhenium(V) Oxo Complex

Journal of the American Chemical Society, 127(44), 15374–15375.

By: E. Ison*, E. Trivedi*, R. Corbin* & M. Abu-Omar*

TL;DR: The rhenium oxo complex catalyzes the hydrosilation of aldehydes and ketones under ambient temperature and atmosphere and a viable mechanism that is consistent with experimental findings, rate measurements, and kinetic isotope effects is proposed. (via Semantic Scholar)
Sources: Crossref, ORCID
Added: August 28, 2020

2005 journal article

Synthesis and Reactivity of Molybdenum(IV) Complexes with Alkyl and Aryl Isocyanides

Organometallics, 24(26), 6310–6318.

By: E. Ison*, C. Ortiz*, K. Abboud* & J. Boncella*

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Crossref, ORCID
Added: February 24, 2020

2004 journal article

Alkyl aluminum-Induced Diamide Transfer from Group 6 Imido Diamido Complexes

Organometallics, 23(5), 929–931.

By: E. Ison*, K. Abboud*, I. Ghiviriga* & J. Boncella*

Sources: Crossref, ORCID
Added: February 24, 2020

2004 journal article

Synthesis, Structure, and Dynamics of Molybdenum Imido Alkyne Complexes

Organometallics, 23(17), 4070–4076.

By: E. Ison*, T. Cameron*, K. Abboud* & J. Boncella*

Sources: Crossref, ORCID
Added: February 24, 2020

Employment

Updated: July 23rd, 2016 10:21

2006 - present

North Carolina State University Raleigh, NC, US
Associate Professor Chemistry

Education

Updated: July 23rd, 2016 10:20

1999 - 2004

University of Florida Gainesville, FL, US
PhD Chemistry

1994 - 1999

Kean University Union, NJ, US
BS Chemistry

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