Elon Ison

Nuruzzaman, M., Colella, B. M., Uzoewulu, C. P., Meo, A. E., Gross, E. J., Ishizawa, S., … Ohata, J. (2024, February 29). Hexafluoroisopropanol as a Bioconjugation Medium of Ultrafast, Tryptophan-Selective Catalysis. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Vol. 2. https://doi.org/10.1021/jacs.3c13447

Gouveia, L. R., & Ison, E. A. (2022). Well-Defined ENENES Re and Mn Complexes and Their Application in Catalysis: The Role of Potassium tert-Butoxide. ORGANOMETALLICS, 41(19), 2678–2687. https://doi.org/10.1021/acs.organomet.2c00261

Marshburn, R. D., Ashley, D. C., Curtin, G. M., Sultana, N., Liu, C., Vinueza, N. R., … Jakubikova, E. (2021, August 30). Are all charge-transfer parameters created equally? A study of functional dependence and excited-state charge-transfer quantification across two dye families. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, Vol. 8. https://doi.org/10.1039/d1cp03383b

Ison, E. A., & Tubb, J. L. (2021). Energy Decomposition Analysis of Lewis Acid/Base Adducts and Frustrated Lewis Pairs: The Use of E-Orb/E-Steric Ratios as a Reaction Parameter. INORGANIC CHEMISTRY, 60(18), 13797–13805. https://doi.org/10.1021/acs.inorgchem.1c00911

Davern, C. M., Lowe, B. D., Rosfi, A., Ison, E. A., & Proulx, C. (2021, May 10). Submonomer synthesis of peptoids containing trans-inducing N-imino- and N-alkylamino-glycines. CHEMICAL SCIENCE, Vol. 5. https://doi.org/10.1039/d1sc00717c

Guzmán Santiago, A. J., Brown, C. A., Sommer, R. D., & Ison, E. A. (2020). Identification of key functionalization species in the Cp*Ir(iii)-catalyzed-ortho halogenation of benzamides. Dalton Transactions, 49(45), 16166–16174. https://doi.org/10.1039/D0DT00565G

Brown, C. A., Abrahamse, M., & Ison, E. A. (2020). Re-Silane complexes as frustrated lewis pairs for catalytic hydrosilylation. DALTON TRANSACTIONS, 49(32), 11403–11411. https://doi.org/10.1039/d0dt02084b

Brown, C. A., Lilly, C. P., Lambic, N. S., Sommer, R. D., & Ison, E. A. (2020). Synthesis and Reactivity of Re(III) and Re(V) Fischer Carbenes. ORGANOMETALLICS, 39(3), 388–396. https://doi.org/10.1021/acs.organomet.9b00600

Lambić, N. S., Sommer, R. D., & Ison, E. A. (2020). Synthesis and reactivity of nitridorhenium complexes incorporating the mercaptoethylsulfide (SSS) ligand. Dalton Transactions, 49, 6127–6134. https://doi.org/10.1039/D0DT00631A

Ison, E. A. (2019). Toward N—N Bond Cleavage: Synthesis and Reactivity of Group 7 Dinitrogen Complexes. In Y. Nishibayashi (Ed.), Transition Metal‐Dinitrogen Complexes: Preparation and Reactivity (pp. 271–284). https://doi.org/10.1002/9783527344260.ch5

Lambic, N. S., Sommer, R. D., & Ison, E. A. (2018). High-valent nitridorhenium(V) complexes containing PNP ligands: implications of ligand flexibility. DALTON TRANSACTIONS, 47(3), 758–768. https://doi.org/10.1039/c7dt03615a

Perez, D. E., Smeltz, J. L., Sommer, R. D., Boyle, P. D., & Ison, E. (2017). Cationic rhenium ((III)) complexes: synthesis, characterization, and reactivity for hydrosilylation of aldehydes. Dalton Transactions (Cambridge, England : 2003), 46(14), 4609–4616. https://doi.org/10.1039/c7dt00271h

Lambic, N. S., Brown, C. A., Sommer, R. D., & Ison, E. A. (2017). Dramatic Increase in the Rate of Olefin Insertion by Coordination of Lewis Acids to the Oxo Ligand in Oxorhenium(V) Hydrides. ORGANOMETALLICS, 36(10), 2042–2051. https://doi.org/10.1021/acs.organomet.7b00291

Ison, A., Ison, E. A., & Perry, C. M. (2017). Oxorhenium Complexes for Catalytic Hydrosilylation and Hydrolytic Hydrogen Production: A Multiweek Advanced Laboratory Experiment for Undergraduate Students. Journal of Chemical Education, 94(6), 790–794. https://doi.org/10.1021/ACS.JCHEMED.6B00954

Lambic, N. S., Sommer, R. D., & Ison, E. A. (2017). Tuning Catalytic Activity in the Hydrogenation of Unactivated Olefins with Transition-Metal Oxos as the Lewis Base Component of Frustrated Lewis Pairs. ACS CATALYSIS, 7(2), 1170–1180. https://doi.org/10.1021/acscatal.6b03313

Robbins, L. K., Lilly, C. P., Sommer, R. D., & Ison, E. A. (2016). Effect of the Ancillary Ligand on the Mechanism for CO Migratory Insertion in High-Valent Oxorhenium Complexes. ORGANOMETALLICS, 35(20), 3530–3537. https://doi.org/10.1021/acs.organomet.6b00570

Lambic, N. S., Lilly, C. P., Sommer, R. D., & Ison, E. A. (2016). Mechanism for the Reaction of CO with Oxorhenium Hydrides: Migratory Insertion of CO into Rhenium Hydride and Formyl Bonds leads to Migration from Rhenium to the Oxo Ligand. ORGANOMETALLICS, 35(17), 3060–3068. https://doi.org/10.1021/acs.organomet.6b00591

Kerr, M. E., Ahmed, I., Gunay, A., Venditto, N. J., Zhu, F., Ison, E. A., & Emmert, M. H. (2016). Non-directed, carbonate-mediated C-H activation and aerobic C-H oxygenation with Cp*Ir catalysts. DALTON TRANSACTIONS, 45(24), 9942–9947. https://doi.org/10.1039/c6dt00234j

Frasco, D. A., Mukherjee, S., Sommer, R. D., Perry, C. M., Lambic, N. S., Abboud, K. A., … Ison, E. A. (2016). Nondirected C-H Activation of Arenes with Cp*Ir(III) Acetate Complexes: An Experimental and Computational Study. ORGANOMETALLICS, 35(15), 2435–2445. https://doi.org/10.1021/acs.organomet.6b00308

Frasco, D. A., Mukherjee, S., Sommer, R. D., Perry, C. M., Lambic, N. S., Abboud, K. A., … Ison, E. A. (2016). Nondirected C–H Activation of Arenes with Cp* Ir (III) Acetate Complexes: An Experimental and Computational Study. Organometallics, 35, 2435–2445. https://doi.org/https://doi.org/10.1021/acs.organomet.6b00308

Lambic, N. S., Lilly, C. P., Robbins, L. K., Sommer, R. D., & Ison, E. A. (2016). Reductive Carbonylation of Oxorhenium Hydrides Induced by Lewis Acids. ORGANOMETALLICS, 35(17), 2822–2829. https://doi.org/10.1021/acs.organomet.6b00393

Lambic, N. S., Sommer, R. D., & Ison, E. A. (2016). Transition-Metal Oxos as the Lewis Basic Component of Frustrated Lewis Pairs. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 138(14), 4832–4842. https://doi.org/10.1021/jacs.6b00705

Lehman, M. C., Pahls, D. R., Meredith, J. M., Sommer, R. D., Heinekey, D. M., Cundari, T. R., & Ison, E. A. (2015). Oxyfunctionalization with Cp*Ir-III(NHC)(Me)(CI) with O-2: Identification of a Rare Bimetallic Ir-IV mu-Oxo Intermediate. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 137(10), 3574–3584. https://doi.org/10.1021/ja512905t

Robbins, L. K., Lilly, C. P., Smeltz, J. L., Boyle, P. D., & Ison, E. A. (2015). Synthesis and Reactivity of Oxorhenium (V) Methyl, Benzyl, and Phenyl Complexes with CO: Implications for a Unique Mechanism for Migratory Insertion. Organometallics, 34(13), 3152–3158. https://doi.org/https://doi.org/10.1021/acs.organomet.5b00177

Robbins, L. K., Lilly, C. P., Smeltz, J. L., Boyle, P. D., & Ison, E. A. (2015). Synthesis and Reactivity of Oxorhenium(V) Methyl, Benzyl, and Phenyl Complexes with CO: Implications for a Unique Mechanism for Migratory Insertion. ORGANOMETALLICS, 34(13), 3152–3158. https://doi.org/10.1021/acs.organomet.5b00177

Frasco, D. A., Sommer, R. D., & Ison, E. A. (2015). ortho-C–H Activation of Thiobenzoic Acid: Synthesis, Characterization, and Reactivity of Iridium Thiobenzoate Complexes. Organometallics, 34(1), 275–279. https://doi.org/10.1021/om501115u

Lehman, M. C., Boyle, P. D., Sommer, R. D., & Ison, E. A. (2014). Oxyfunctionalization with Cp*Ir-III(NHC)(Me)L Complexes. ORGANOMETALLICS, 33(19), 5081–5084. https://doi.org/10.1021/om5007352

Frasco, D. A., Lilly, C. P., Boyle, P. D., & Ison, E. A. (2013). Cp*Ir-III-Catalyzed Oxidative Coupling of Benzoic Acids with Alkynes. ACS CATALYSIS, 3(10), 2421–2429. https://doi.org/10.1021/cs400656q

Lehman, M. C., Gary, J. B., Boyle, P. D., Sanford, M. S., & Ison, E. A. (2013). Effect of Solvent and Ancillary Ligands on the Catalytic H/D Exchange Reactivity of Cp*Ir-III(L) Complexes. ACS CATALYSIS, 3(10), 2304–2310. https://doi.org/10.1021/cs400420n

Liu, S., Senocak, A., Smeltz, J. L., Yang, L., Wegenhart, B., Yi, J., … Abu-Omar, M. M. (2013). Mechanism of MTO-Catalyzed Deoxydehydration of Diols to Alkenes Using Sacrificial Alcohols. ORGANOMETALLICS, 32(11), 3210–3219. https://doi.org/10.1021/om400127z

Smeltz, J. L., Lilly, C. P., Boyle, P. D., & Ison, E. A. (2013). The Electronic Nature of Terminal Oxo Ligands in Transition-Metal Complexes: Ambiphilic Reactivity of Oxorhenium Species. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 135(25), 9433–9441. https://doi.org/10.1021/ja401390v

Smeltz, J. L., Webster, C. E., & Ison, E. A. (2012). Computational Investigation of the Mechanism for the Activation of CO by Oxorhenium Complexes. ORGANOMETALLICS, 31(10), 4055–4062. https://doi.org/10.1021/om3003366

Smeltz, J. L., Boyle, P. D., & Ison, E. A. (2012). Role of Low-Valent Rhenium Species in Catalytic Hydrosilylation Reactions with Oxorhenium Catalysts. ORGANOMETALLICS, 31(17), 5994–5997. https://doi.org/10.1021/om300654q

Lilly, C. P., Boyle, P. D., & Ison, E. A. (2012). Synthesis of Oxorhenium Acetyl and Benzoyl Complexes Incorporating Diamidopyridine Ligands: Implications for the Mechanism of CO Insertion. ORGANOMETALLICS, 31(11), 4295–4301. https://doi.org/10.1021/om3002872

Ison, E. A., & Ison, A. (2012). Synthesis of Well-Defined Copper N-Heterocyclic Carbene Complexes and Their Use as Catalysts for a “Click Reaction”: A Multistep Experiment That Emphasizes the Role of Catalysis in Green Chemistry. Journal of Chemical Education, 89(12), 1575–1577. https://doi.org/10.1021/ed300243s

Engelman, K. L., Feng, Y., & Ison, E. A. (2011). C-H Bond Functionalization of Benzoic Acid: Catalytic Synthesis of 2-Hydroxy-6H-benzo[c]chromen-6-ones Using (Cp*IrCl2)(2). ORGANOMETALLICS, 30(17), 4572–4577. https://doi.org/10.1021/om200343b

Smeltz, J. L., Boyle, P. D., & Ison, E. A. (2011). Mechanism for the Activation of Carbon Monoxide via Oxorhenium Complexes. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 133(34), 13288–13291. https://doi.org/10.1021/ja205477w

Travia, N. E., Xu, Z., Keith, J. M., Ison, E. A., Fanwick, P. E., Hall, M. B., & Abu-Omar, M. M. (2011). Observation of Inductive Effects That Cause a Change in the Rate-Determining Step for the Conversion of Rhenium Azides to Imido Complexes. Inorganic Chemistry, 50(20), 10505–10514. https://doi.org/10.1021/ic2017853

Lilly, C. P., Boyle, P. D., & Ison, E. A. (2011). Synthesis and characterization of oxorhenium(V) diamido pyridine complexes that catalyze oxygen atom transfer reactions. DALTON TRANSACTIONS, 40(44), 11815–11821. https://doi.org/10.1039/c1dt11143d

Feng, Y., Jiang, B., Boyle, P. A., & Ison, E. A. (2010). Effect of Ancillary Ligands and Solvents on H/D Exchange Reactions Catalyzed by Cp*Ir Complexes. ORGANOMETALLICS, 29(13), 2857–2867. https://doi.org/10.1021/om100018x

Corbin, R. A., Ison, E. A., & Abu-Omar, M. M. (2009). Catalysis by cationic oxorhenium(v): hydrolysis and alcoholysis of organic silanes. Dalton Transactions, 15(15), 2850–2855. https://doi.org/10.1039/b822783g

Feng, Y., Aponte, J., Houseworth, P. J., Boyle, P. D., & Ison, E. A. (2009). Synthesis of Oxorhenium(V) Complexes with Diamido Amine Ancillary Ligands and Their Role in Oxygen Atom Transfer Catalysis. INORGANIC CHEMISTRY, 48(23), 11058–11066. https://doi.org/10.1021/ic901434u

Jiang, B., Feng, Y., & Ison, E. A. (2008). Mechanistic Investigations of the Iridium(III)-Catalyzed Aerobic Oxidation of Primary and Secondary Alcohols. Journal of the American Chemical Society, 130(44), 14462–14464. https://doi.org/10.1021/ja8049595

Ison, E. A., Cessarich, J. E., Travia, N. E., Fanwick, P. E., & Abu-Omar, M. M. (2007). Synthesis of Cationic Rhenium(VII) Oxo Imido Complexes and Their Tunability Towards Oxygen Atom Transfer. Journal of the American Chemical Society, 129(5), 1167–1178. https://doi.org/10.1021/ja065551p

Ison, E. A., Abboud, K. A., & Boncella, J. M. (2006). Synthesis and Reactivity of Molybdenum Imido Diamido Metallacyclopentenes and Metallacyclopentadienes and the Mechanism of Ethylene Exchange with Metallacyclopentane Complexes. Organometallics, 25(7), 1557–1564. https://doi.org/10.1021/om050280x

Ison, E. A., Cessarich, J. E., Du, G., Fanwick, P. E., & Abu-Omar, M. M. (2006). Synthesis of Cationic Oxorhenium Salen Complexes via μ-Oxo Abstraction and Their Activity in Catalytic Reductions. Inorganic Chemistry, 45(6), 2385–2387. https://doi.org/10.1021/ic0520768

Ison, E. A., Corbin, R. A., & Abu-Omar, M. M. (2005). Hydrogen Production from Hydrolytic Oxidation of Organosilanes Using a Cationic Oxorhenium Catalyst. Journal of the American Chemical Society, 127(34), 11938–11939. https://doi.org/10.1021/ja053860u

Ison, E. A., Trivedi, E. R., Corbin, R. A., & Abu-Omar, M. M. (2005). Mechanism for Reduction Catalysis by Metal Oxo:  Hydrosilation of Organic Carbonyl Groups Catalyzed by a Rhenium(V) Oxo Complex. Journal of the American Chemical Society, 127(44), 15374–15375. https://doi.org/10.1021/ja055704t

Ison, E. A., Ortiz, C. O., Abboud, K., & Boncella, J. M. (2005). Synthesis and Reactivity of Molybdenum(IV) Complexes with Alkyl and Aryl Isocyanides. Organometallics, 24(26), 6310–6318. https://doi.org/10.1021/om0502436

Ison, E. A., Abboud, K. A., Ghiviriga, I., & Boncella, J. M. (2004). Alkyl aluminum-Induced Diamide Transfer from Group 6 Imido Diamido Complexes. Organometallics, 23(5), 929–931. https://doi.org/10.1021/om034322y

Ison, E. A., Cameron, T. M., Abboud, K. A., & Boncella, J. M. (2004). Synthesis, Structure, and Dynamics of Molybdenum Imido Alkyne Complexes. Organometallics, 23(17), 4070–4076. https://doi.org/10.1021/om049942t