Understanding the electrospray ionization response factors of per- and poly-fluoroalkyl substances (PFAS)
Enders, J. R., O’Neill, G. M., Whitten, J. L., & Muddiman, D. C. (2021, July 21). Analytical and Bioanalytical Chemistry, Vol. 7.
author keywords: Electrospray ionization; PFAS; logP; Surface activity
topics (OpenAlex): Per- and polyfluoroalkyl substances research; Mass Spectrometry Techniques and Applications; Toxic Organic Pollutants Impact
TL;DR:
A method for predicting the behavior of individual PFAS compounds, including relative retention order in chromatography, is presented which is simply based on the number of fluorine atoms in the molecule as well as the class of the compound.
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