Works (9)
Updated: August 28th, 2023 21:15
2021 journal article
Doubly Protective MOF-Photo-Fabrics: Facile Template-Free Synthesis of PCN-222-Textiles Enables Rapid Hydrolysis, Photo-Hydrolysis and Selective Oxidation of Multiple Chemical Warfare Agents and Simulants
CHEMISTRY-A EUROPEAN JOURNAL, 27(4), 1465–1472.
author keywords: chemical warfare agent; fabric; fiber; metal– organic frameworks; PCN-222
TL;DR:
This work reports the first metal-organic framework (MOF) fabric composite capable of both rapid catalytic hydrolysis and photo-oxidation of multiple chemical warfare agents (GD and HD) and their simulants and provides important new insights into the design of future materials and chemical systems to protect military, first-responders, and civilians upon exposure to complex chemical toxins.
(via Semantic Scholar)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: January 4, 2021
2021 review
Fibre-based composites from the integration of metal-organic frameworks and polymers
[Review of ]. NATURE REVIEWS MATERIALS, 6(7), 605–621.
Sources: Web Of Science, ORCID, NC State University Libraries
Added: April 12, 2021
2021 article
Freestanding Metal Organic Framework-Based Multifunctional Membranes Fabricated via Pseudomorphic Replication toward Liquid- and Gas-Hazards Abatement
Dai, Z., Pradeep, S., Zhu, J., Xie, W., Barton, H. F., Si, Y., … Parsons, G. N. (2021, October 24). ADVANCED MATERIALS INTERFACES, Vol. 10.
author keywords: Al-based metal-organic frameworks; freestanding MOF membrane; hazardous chemicals
Sources: Web Of Science, ORCID, NC State University Libraries
Added: November 1, 2021
2020 journal article
The Effect of Surface Hydroxylation on MOF Formation on ALD Metal Oxides: MOF-525 on TiO2/Polypropylene for Catalytic Hydrolysis of Chemical Warfare Agent Simulants
ACS APPLIED MATERIALS & INTERFACES, 12(13), 14690–14701.
TL;DR:
The mechanisms for MOF nucleation from metal oxide thin films are examined to explore why some metal oxide sources are better suited for one synthesis mechanism over another and whether the film serves as a nucleation promoter or may be converted directly to the MOF thin films.
(via Semantic Scholar)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: May 8, 2020
2019 journal article
Air, Water Vapor, and Aerosol Transport through Textiles with Surface Functional Coatings of Metal Oxides and Metal-Organic Frameworks
ACS APPLIED MATERIALS & INTERFACES, 11(27), 24683–24690.
author keywords: atomic layer deposition; metal-organic frameworks; aerosol transport; filtration; chemical/biological protection; breathable materials
TL;DR:
To better understand how MOFs can perform in future CB protective systems, atomic layer deposition (ALD) and solution deposition were used to modify nonwoven polypropylene and flame-resistant fabrics with HKUST-1 and UiO-66-NH2.
(via Semantic Scholar)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 5, 2019
2018 journal article
Solvothermal Synthesis of MIL-96 and UiO-66-NH2 on Atomic Layer Deposited Metal Oxide Coatings on Fiber Mats
JOVE-JOURNAL OF VISUALIZED EXPERIMENTS, 6(136).
author keywords: Chemistry; Issue 136; Metal-organic frameworks; atomic layer deposition; solvothermal
MeSH headings : Metals / chemistry; Oxides / chemistry
TL;DR:
A method of first coating fabrics with metal oxide films using atomic layer deposition (ALD) creates conformal films of controllable thickness on each fiber, while providing a more reactive surface for MOF nucleation.
(via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries
Added: October 16, 2018
2017 journal article
Intrinsic limitations of atomic layer deposition for pseudocapacitive metal oxides in porous electrochemical capacitor electrodes
JOURNAL OF MATERIALS CHEMISTRY A, 5(25), 13086–13097.
UN Sustainable Development Goal Categories
11. Sustainable Cities and Communities
(Web of Science)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018
2016 journal article
Diffusion of CO2 in Large Crystals of Cu-BTC MOF
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 138(36), 11449–11452.
Contributors: T. Tovar*, J. Zhao n, W. Nunn n, n, G. Peterson *, G. Parsons n , M. LeVan*
TL;DR:
A new reproducible procedure to synthesize millimeter-scale Cu- BTC single crystals using concentrated reactants and an acetic acid modulator is described, confirming the high quality of these Cu-BTC single crystals.
(via Semantic Scholar)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018
2016 journal article
Ultra-Fast Degradation of Chemical Warfare Agents Using MOF-Nanofiber Kebabs
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 55(42), 13224–13228.
Contributors: J. Zhao n, D. Lee n, R. Yaga*, M. Hall, n, I. Woodward n, C. Oldham n, H. Walls *, G. Peterson, G. Parsons n
author keywords: atomic layer deposition; chemical warfare agents; metal-organic frameworks; nanofibers; thin films
TL;DR:
The results therefore provide the earliest report of MOF-nanofiber textile composites capable of ultra-fast degradation of CWAs and exhibit excellent reactivity for detoxifying CWAs.
(via Semantic Scholar)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018
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