@article{alcoutlabi_lee_zhang_2015, title={Nanofiber-Based Membrane Separators for Lithium-ion Batteries}, volume={1718}, ISBN={["978-1-60511-695-2"]}, ISSN={["0272-9172"]}, url={https://publons.com/publon/26924678/}, DOI={10.1557/opl.2015.556}, abstractNote={Nanofiber-based membranes were prepared by two different methods for use as separators for Lithium-ion batteries (LIBs). In the first method, Electrospinning was used for the fabrication of Polyvinylidene fluoride PVDF nanofiber coatings on polyolefin microporous membrane separators to improve their electrolyte uptake and electrochemical performance. The nanofibercoated membrane separators show better electrolyte uptake and ionic conductivity than that for the uncoated membranes. In the second method, Forcespinning® (FS) was used to fabricate fibrous cellulose membranes as separators for LIBs. The cellulose fibrous membranes were made by the Forcespinning® of a cellulose acetate solution precursor followed by a subsequent alkaline hydrolysis treatment. The results show that the fibrous cellulose membrane-based separator exhibits high electrolyte uptake and good electrolyte/electrode wettability and therefore can be a good candidate for high performance and high safety LIB separators.}, journal={MULTIFUNCTIONAL POLYMERIC AND HYBRID MATERIALS}, publisher={Cambridge University Press (CUP)}, author={Alcoutlabi, Mataz and Lee, Hun and Zhang, Xiangwu}, year={2015}, pages={157–161} }
 @misc{lee_yanilmaz_toprakci_fu_zhang_2014, title={A review of recent developments in membrane separators for rechargeable lithium-ion batteries}, volume={7}, ISSN={["1754-5706"]}, url={https://publons.com/publon/674379/}, DOI={10.1039/c4ee01432d}, abstractNote={In this paper, the recent developments and the characteristics of membrane separators for lithium-ion batteries are reviewed. In recent years, there have been intensive efforts to develop advanced battery separators for rechargeable lithium-ion batteries for different applications such as portable electronics, electric vehicles, and energy storage for power grids. The separator is a critical component of lithium-ion batteries since it provides a physical barrier between the positive and negative electrodes in order to prevent electrical short circuits. The separator also serves as the electrolyte reservoir for the transport of ions during the charging and discharging cycles of a battery. The performance of lithium-ion batteries is greatly affected by the materials and structure of the separators. This paper introduces the requirements of battery separators and the structure and properties of five important types of membrane separators which are microporous membranes, modified microporous membranes, non-woven mats, composite membranes and electrolyte membranes. Each separator type has inherent advantages and disadvantages which influence the performance of lithium-ion batteries. The structures, characteristics, manufacturing, modification, and performance of separators are described in this review paper. The outlook and future directions in this research field are also given.}, number={12}, journal={ENERGY & ENVIRONMENTAL SCIENCE}, publisher={Royal Society of Chemistry (RSC)}, author={Lee, Hun and Yanilmaz, Meltem and Toprakci, Ozan and Fu, Kun and Zhang, Xiangwu}, year={2014}, pages={3857–3886} }
 @article{li_xu_yao_xue_yanilmaz_lee_zhang_2014, title={Coaxial electrospun Si/C-C core-shell composite nanofibers as binder-free anodes for lithium-ion batteries}, volume={258}, ISSN={["1872-7689"]}, url={https://publons.com/publon/11754002/}, DOI={10.1016/j.ssi.2014.02.003}, abstractNote={Si/C–C core–shell nanofiber structure was designed by dual nozzle coaxial electrospinning and subsequent carbonization. This core–shell nanofiber structure has Si/C composite as the core and carbon as the shell. Used as an anode in lithium-ion batteries, the carbon shell can help buffer the large volume expansion/contraction of the Si/C core during charge/discharge and restrain the capacity fading caused by the mechanical failure of the active material. Results showed that after 50 cycles, the discharge capacity of Si/C–C core–shell composite nanofibers was 63% higher than that of Si/C composite nanofibers and the capacity retention increased from 48.6 to 72.4%. It is, therefore, demonstrated that Si/C–C core–shell composite nanofibers are promising anode material with large reversible capacity and good cycling stability.}, journal={SOLID STATE IONICS}, author={Li, Ying and Xu, Guanjie and Yao, Yingfang and Xue, Leigang and Yanilmaz, Meltem and Lee, Hun and Zhang, Xiangwu}, year={2014}, month={May}, pages={67–73} }
 @article{lee_alcoutlabi_toprakci_xu_watson_zhang_2014, title={Preparation and characterization of electrospun nanofiber-coated membrane separators for lithium-ion batteries}, volume={18}, ISSN={["1433-0768"]}, url={https://publons.com/publon/674382/}, DOI={10.1007/s10008-014-2501-4}, number={9}, journal={JOURNAL OF SOLID STATE ELECTROCHEMISTRY}, publisher={Springer Nature}, author={Lee, Hun and Alcoutlabi, Mataz and Toprakci, Ozan and Xu, Guanjie and Watson, Jill V. and Zhang, Xiangwu}, year={2014}, month={Sep}, pages={2451–2458} }
 @article{fu_xue_yildiz_li_lee_li_xu_zhou_bradford_zhang_et al._2013, title={Effect of CVD carbon coatings on Si@CNF composite as anode for lithium-ion batteries}, volume={2}, ISSN={["2211-3282"]}, url={https://publons.com/publon/7178363/}, DOI={10.1016/j.nanoen.2013.03.019}, abstractNote={Lithium-ion battery (LIB) anodes with high capacity and binder free structure were synthesized from carbon nanofibers that contained silicon nanoparticles (Si@CNF). The particle filled nonwoven structures were produced by an electrospinning and subsequent carbonization process. Pristine Si@CNF composites had Si nanoparticles exposed on the fiber surface. As produced, the Si nanoparticles could become detached from the nanofiber surface during cycling, causing severe structural damage and capacity loss. In order to prevent Si from detaching from the nanofiber surface, the Si@CNF composite was then treated with a thermal chemical vapor deposition (CVD) technique to make Si completely coated with a carbon matrix. The carbon coated Si@CNF (Si@CNF-C) composites were synthesized with different Si contents (10, 30, and 50 wt%) for different CVD treatment times (30, 60, and 90 min). It was found that the initial coulombic efficiency of Si@CNF-C could be increased via the amorphous carbon by stabilizing solid-electrolyte-interface (SEI) formation on surface. The capacity and cyclic stability were improved by the CVD carbon coating, especially for the 30 wt% Si@CNF-C composite with 90 min CVD coating, a CVD amorphous carbon coating of less than 1% by weight on Si@CNF composites contributed to more than 200% improvement in cycling performance. Results indicate that the CVD carbon coating is an effective approach to improve the electrochemical properties of Si@CNF composites making this a potential route to obtain high-energy density anode materials for LIBs.}, number={5}, journal={NANO ENERGY}, author={Fu, K. and Xue, L. G. and Yildiz, O. and Li, S. L. and Lee, H. and Li, Y. and Xu, G. J. and Zhou, L. and Bradford, P. D. and Zhang, Xiangwu and et al.}, year={2013}, month={Sep}, pages={976–986} }
 @article{lee_alcoutlabi_watson_zhang_2013, title={Electrospun nanofiber-coated separator membranes for lithium-ion rechargeable batteries}, volume={129}, ISSN={["1097-4628"]}, url={https://publons.com/publon/7178362/}, DOI={10.1002/app.38894}, abstractNote={Nanofiber-coated composite membranes were prepared by electrospinning polyvinylidene fluoride-co-chlorotrifluoroethylene (PVDF-co-CTFE) and PVDF-co-CTFE/polyvinylidene fluoride-co-hexafluoropropylene (PVDF-co-HFP) onto six different Celgard® microporous battery separator membranes. Application of a PVDF-based copolymer nanofiber coating onto the surface of the battery separator membrane provides a method for improving the electrolyte absorption of the separator and the separator-electrode adhesion. Peel tests showed that both PVDF-co-CTFE and PVDF-co-CTFE/PVDF-co-HFP nanofiber coatings have comparable adhesion to the membrane substrates. Electrolyte uptake capacity was investigated by soaking the nanofiber-coated membranes in a liquid electrolyte solution. PVDF-co-CTFE and PVDF-co-CTFE/PVDF-co-HFP nanofiber-coated membranes exhibited higher electrolyte uptake capacities than uncoated membranes. It was also found that PVDF-co-CTFE nanofiber-coated membranes have higher electrolyte uptakes than PVDF-co-CTFE/PVDF-co-HFP nanofiber-coated membranes due to the smaller diameters of PVDF-co-CTFE nanofibers and higher polarity of PVDF-co-CTFE. The separator–electrode adhesion properties were also investigated. Results showed PVDF-co-CTFE and PVDF-co-CTFE/PVDF-co-HFP nanofiber coatings improved the adhesion of all six membrane substrates to the electrode. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013}, number={4}, journal={JOURNAL OF APPLIED POLYMER SCIENCE}, author={Lee, Hun and Alcoutlabi, Mataz and Watson, Jill V. and Zhang, Xiangwu}, year={2013}, month={Aug}, pages={1939–1951} }
 @article{lu_li_zhang_xu_fu_lee_zhang_2013, title={Parameter study and characterization for polyacrylonitrile nanofibers fabricated via centrifugal spinning process}, volume={49}, ISSN={["1873-1945"]}, url={https://publons.com/publon/7178360/}, DOI={10.1016/j.eurpolymj.2013.09.017}, abstractNote={Electrospinning is currently the most popular method for producing polymer nanofibers. However, the low production rate and safety concern limit the practical use of electrospinning as a cost-effective nanofiber fabrication approach. Herein, we present a novel and simple centrifugal spinning technology that extrudes nanofibers from polymer solutions by using a high-speed rotary and perforated spinneret. Polyacrylonitrile (PAN) nanofibers were prepared by selectively varying parameters that can affect solution intrinsic properties and operational conditions. The resultant PAN nanofibers were characterized by SEM, and XRD. The correlation between fiber morphology and processing conditions was established. Results demonstrated that the fiber morphology can be easily manipulated by controlling the spinning parameters and the centrifugal spinning process is a facile approach for fabricating polymer nanofibers in a large-scale and low-cost fashion.}, number={12}, journal={EUROPEAN POLYMER JOURNAL}, author={Lu, Yao and Li, Ying and Zhang, Shu and Xu, Guanjie and Fu, Kun and Lee, Hun and Zhang, Xiangwu}, year={2013}, month={Dec}, pages={3834–3845} }
 @article{lee_alcoutlabi_watson_zhang_2013, title={Polyvinylidene fluoride-co-chlorotrifluoroethylene and polyvinylidene fluoride-co-hexafluoropropylene nanofiber-coated polypropylene microporous battery separator membranes}, volume={51}, ISSN={["0887-6266"]}, url={https://publons.com/publon/26924690/}, DOI={10.1002/polb.23216}, abstractNote={Nanofiber-coated polypropylene (PP) separator membranes were prepared by coating a Celgard ® microporous PP membrane with electrospun polyvinylidene fluoride-co-chlorotrifluoroethylene (PVDF-co-CTFE) and PVDF-co-CTFE/ polyvinylidene fluoride-co-hexafluoropropylene (PVDF-co-HFP) nanofibers. Three PVDF polymer solutions of varying compositions were used in the preparation of the nanofiber coatings. Two of the polymer solutions were PVDF-co-CTFE blends made using different types of PVDF-co-HFP copolymers. The PVDF-co-CTFE and PVDF-co-CTFE/PVDF-co-HFP blend nanofiber coatings have been found to have comparable adhesion to the PP microporous membrane substrate. The electrolyte uptakes and separator―electrode adhesion properties of nanofiber-coated membranes were evaluated. Both the electrolyte uptake and the separator―electrode adhesion were improved by the nanofiber coatings. The improvement in electrolyte update capacity is not only related to the gelation capability of the PVDF copolymer nanofibers, but also attributed to the increased porosity and capillary effect on nanofibrous structure of the electrospun nanofiber coatings. Enhancement of the separator― electrode adhesion was owing to the adhesion properties of the copolymer nanofiber coatings. Compared with the PVDF-co-CTFE/PVDF-co-HFP blend nanofiber coatings studied, the PVDF-co-CTFE coating was more effective in improving the electrolyte uptake and separator―electrode adhesion.}, number={5}, journal={JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS}, publisher={Wiley}, author={Lee, Hun and Alcoutlabi, Mataz and Watson, Jill V. and Zhang, Xiangwu}, year={2013}, month={Mar}, pages={349–357} }
 @article{alcoutlabi_lee_watson_zhang_2013, title={Preparation and properties of nanofiber-coated composite membranes as battery separators via electrospinning}, volume={48}, ISSN={["1573-4803"]}, url={https://publons.com/publon/7178345/}, DOI={10.1007/s10853-012-7064-0}, number={6}, journal={JOURNAL OF MATERIALS SCIENCE}, author={Alcoutlabi, Mataz and Lee, Hun and Watson, Jill V. and Zhang, Xiangwu}, year={2013}, month={Mar}, pages={2690–2700} }
 @article{toprakci_toprakci_li_ji_xue_lee_zhang_zhang_2013, title={Synthesis and characterization of xLi(2)MnO(3) center dot (1-x)LiMn1/3Ni1/3Co1/3O2 composite cathode materials for rechargeable lithium-ion batteries}, volume={241}, ISSN={["0378-7753"]}, url={https://publons.com/publon/674386/}, DOI={10.1016/j.jpowsour.2013.04.155}, abstractNote={Various xLi2MnO3·(1 − x)LiCo1/3Ni1/3Mn1/3O2 (x = 0.1, 0.2, 0.3, 0.4, and 0.5) cathode materials were prepared by the one-step sol–gel route. The structure of xLi2MnO3·(1 − x)LiCo1/3Ni1/3Mn1/3O2 composites was determined by X-ray diffraction analysis. The surface morphology and microstructure of xLi2MnO3·(1 − x)LiCo1/3Ni1/3Mn1/3O2 composites were characterized using scanning electron microscopy and transmission electron microscopy. Electrochemical performance of xLi2MnO3·(1 − x)LiCo1/3Ni1/3Mn1/3O2 composites was evaluated in terms of capacity, cycling performance and rate capability. Although the morphology and structure were found to be affected by the Li2MnO3 content, all composites showed an α-NaFeO2 structure with R3m space group. Electrochemical results showed that cells using 0.3Li2MnO3·0.7LiCo1/3Ni1/3Mn1/3O2 composites had good performance, in terms of large reversible capacity, prolonged cycling stability, and excellent rate capability.}, journal={JOURNAL OF POWER SOURCES}, publisher={Elsevier BV}, author={Toprakci, Ozan and Toprakci, Hatice A. K. and Li, Ying and Ji, Liwen and Xue, Leigang and Lee, Hun and Zhang, Shu and Zhang, Xiangwu}, year={2013}, month={Nov}, pages={522–528} }
 @article{shim_lee_lee_2013, title={The interaction of moving yarns with stationary surfaces}, volume={14}, number={1}, journal={Fibers and Polymers}, author={Shim, W. S. and Lee, H. and Lee, D. W.}, year={2013}, pages={164–171} }