@article{park_cruz_tiller_johnson_mittal_jameel_venditti_park_2022, title={Effect of ash in paper sludge on enzymatic hydrolysis}, volume={165}, ISSN={0961-9534}, url={http://dx.doi.org/10.1016/j.biombioe.2022.106567}, DOI={10.1016/j.biombioe.2022.106567}, abstractNote={The valorization of paper sludge is a high-potential process to develop renewable fuels and chemicals, which can be integrated with pulp and paper mills. Calcium carbonate is the main ash component in sludge, which plays a role in buffering pH and potentially lowering the conversion during enzymatic hydrolysis. Therefore, it is important to investigate the effect of ash on sugar yields and examine pH change to introduce efficient and economical enzymatic hydrolysis of sludge. Carbohydrate conversion was enhanced when the ash was removed by fractionation. On the other hand, the highest sugar recovery was obtained when the sludge contained 20% ash content. The pH change during enzymatic hydrolysis was influenced by ash and explained why sludge-derived hydrolysate showed lower carbohydrate conversion. Therefore, a high shear process with the increased acid amount is suggested to prohibit the negative effect of ash and enhance the accessibility of cellulase to fibers. This study highlights the feasibility of using wet waste streams generated by the paper industry.}, journal={Biomass and Bioenergy}, publisher={Elsevier BV}, author={Park, Hyeonji and Cruz, David and Tiller, Phoenix and Johnson, David K. and Mittal, Ashutosh and Jameel, Hasan and Venditti, Richard and Park, Sunkyu}, year={2022}, month={Oct}, pages={106567} } @misc{kropat_liao_park_salem_johnson_argyropoulos_2021, title={A Perspective of Lignin Processing and Utilization Technologies for Composites and Plastics with Emphasis on Technical and Market Trends}, volume={16}, ISSN={["1930-2126"]}, DOI={10.15376/biores.16.1.Kropat}, abstractNote={This effort is focused on work completed publicly and privately within academic research and industrial sectors on the utilization of lignin to produce thermosets, thermoplastics, foams, hydrogels, and rubbers. The size of the plastics market and the current and projected influence of lignin on it were evaluated. Further, an analysis of patent activity was employed to show the direction of and interest for lignin in these markets. The market trends documented in the literature, when coupled with detailed patent research, offer a new approach to evaluate potential markets and future directions. The analysis of the commercial market sizes of bioplastics and segmentation showed low penetration of actual lignin-based bioplastics. This exposed the contradiction between the abundance of technologies for lignin-based materials and their little practical use. In addition, this finding highlighted a severe gap between lignin research and development and the actual market.}, number={1}, journal={BIORESOURCES}, author={Kropat, Marcel and Liao, Mochen and Park, Hyeonji and Salem, Khandoker S. and Johnson, Shelly and Argyropoulos, Dimitris S.}, year={2021}, month={Feb}, pages={2084–2115} }