Joseph DeSimone

Grundy, L. S., Shah, D. B., Nguyen, H. Q., Diederichsen, K. M., Celik, H., DeSimone, J. M., … Balsara, N. P. (2020). Impact of Frictional Interactions on Conductivity, Diffusion, and Transference Number in Ether- and Perfluoroether-Based Electrolytes. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 167(12). https://doi.org/10.1149/1945-7111/abb34e

Chintapalli, M., Timachova, K., Olson, K. R., Mecham, S. J., DeSimone, J. M., & Balsara, N. P. (2020). Lithium Salt Distribution and Thermodynamics in Electrolytes Based on Short Perfluoropolyether-block-Poly(ethylene oxide) Copolymers. MACROMOLECULES, 53(4), 1142–1153. https://doi.org/10.1021/acs.macromol.9b01637

Perry, J. L., Tian, S., Sengottuvel, N., Harrison, E. B., Gorentla, B. K., Kapadia, C. H., … Pecot, C. V. (2020). Pulmonary Delivery of Nanoparticle-Bound Toll-like Receptor 9 Agonist for the Treatment of Metastatic Lung Cancer. ACS NANO, 14(6), 7200–7215. https://doi.org/10.1021/acsnano.0c02207

Oh, H. J., Aboian, M. S., Yi, M. Y. J., Maslyn, J. A., Loo, W. S., Jiang, Xi, … Balsara, N. P. (2019). 3D Printed Absorber for Capturing Chemotherapy Drugs before They Spread through the Body. ACS CENTRAL SCIENCE, 5(3), 419–427. https://doi.org/10.1021/acscentsci.8b00700

Shah, D. B., Nguyen, H. Q., Grundy, L. S., Olson, K. R., Mecham, S. J., DeSimone, J. M., & Balsara, N. P. (2019). Difference between approximate and rigorously measured transference numbers in fluorinated electrolytes. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 21(15), 7857–7866. https://doi.org/10.1039/c9cp00216b

Kapadia, C. H., Tian, S., Perry, J. L., Luft, J. C., & Desimone, J. M. (2019). Role of Linker Length and Antigen Density in Nanoparticle Peptide Vaccine. ACS OMEGA, 4(3), 5547–5555. https://doi.org/10.1021/acsomega.8b03391

Bloomquist, C. J., Mecham, M. B., Paradzinsky, M. D., Janusziewicz, R., Warner, S. B., Luft, J. C., … DeSimone, J. M. (2018). Controlling release from 3D printed medical devices using CLIP and drug-loaded liquid resins. JOURNAL OF CONTROLLED RELEASE, 278, 9–23. https://doi.org/10.1016/j.jconrel.2018.03.026

Wilson, E. M., Luft, J. C., & DeSimone, J. M. (2018). Formulation of High-Performance Dry Powder Aerosols for Pulmonary Protein Delivery. PHARMACEUTICAL RESEARCH, 35(10). https://doi.org/10.1007/s11095-018-2452-z

Byrne, J. D., Jajja, M. R. N., Adrian T. O'Neill, Schorzman, A. N., Keeler, A. W., Luft, J. C., … Yeh, J. J. (2018). Impact of formulation on the iontophoretic delivery of the FOLFIRINOX regimen for the treatment of pancreatic cancer. CANCER CHEMOTHERAPY AND PHARMACOLOGY, 81(6), 991–998. https://doi.org/10.1007/s00280-018-3570-3

Coffman, J. E., Metz, S. W., Brackbill, A., Paul, M., Miley, M. J., DeSimone, J., … Tian, S. (2018). Optimization of Surface Display of DENV2 E Protein on a Nanoparticle to Induce Virus Specific Neutralizing Antibody Responses. BIOCONJUGATE CHEMISTRY, 29(5), 1544–1552. https://doi.org/10.1021/acs.bioconjchem.8b00090

Caudill, C. L., Perry, J. L., Tian, S., Luft, J. C., & DeSimone, J. M. (2018). Spatially controlled coating of continuous liquid interface production microneedles for transdermal protein delivery. JOURNAL OF CONTROLLED RELEASE, 284, 122–132. https://doi.org/10.1016/j.jconrel.2018.05.042

Byrne, J. D., Yeh, J. J., & DeSimone, J. M. (2018). [Review of Use of iontophoresis for the treatment of cancer]. JOURNAL OF CONTROLLED RELEASE, 284, 144–151. https://doi.org/10.1016/j.jconrel.2018.06.020

Min, Y., Roche, K. C., Tian, S., Eblan, M. J., McKinnon, K. P., Caster, J. M., … Wang, A. Z. (2017). Antigen-capturing nanoparticles improve the abscopal effect and cancer immunotherapy. NATURE NANOTECHNOLOGY, 12(9), 877-+. https://doi.org/10.1038/nnano.2017.113

Devaux, D., Villaluenga, I., Bhatt, M., Shah, D., Chen, X. C., Thelen, J. L., … Balsara, N. P. (2017). Crosslinked perfluoropolyether solid electrolytes for lithium ion transport. SOLID STATE IONICS, 310, 71–80. https://doi.org/10.1016/j.ssi.2017.08.007

Shah, D. B., Olson, K. R., Karny, A., Mecham, S. J., DeSimone, J. M., & Balsara, N. P. (2017). Effect of Anion Size on Conductivity and Transference Number of Perfluoroether Electrolytes with Lithium Salts. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 164(14), A3511–A3517. https://doi.org/10.1149/2.0301714jes

Chintapalli, M., Timachova, K., Olson, K. R., Banaszak, M., Thelen, J. L., Mecham, S. J., … Balsara, N. P. (2017). Incipient microphase separation in short chain perfluoropolyether-block-poly(ethylene oxide) copolymers. SOFT MATTER, 13(22), 4047–4056. https://doi.org/10.1039/c7sm00738h

Timachova, K., Chintapalli, M., Olson, K. R., Mecham, S. J., DeSimone, J. M., & Balsara, N. P. (2017). Mechanism of ion transport in perfluoropolyether electrolytes with a lithium salt. SOFT MATTER, 13(32), 5389–5396. https://doi.org/10.1039/c7sm00794a

Perry, J. L., Reuter, K. G., Luft, J. C., Pecot, C. V., Zamboni, W., & DeSimone, J. M. (2017). Mediating Passive Tumor Accumulation through Particle Size, Tumor Type, and Location. NANO LETTERS, 17(5), 2879–2886. https://doi.org/10.1021/acs.nanolett.7b00021

DeSimone, J. M. (2016). Co-opting Moore's law: Therapeutics, vaccines and interfacially active particles manufactured via PRINT®. Journal of Controlled Release, 240, 541–543. https://doi.org/10.1016/j.jconrel.2016.07.019

Devaux, D., Chang, Y. H., Villaluenga, I., Chen, X. C., Chintapalli, M., DeSimone, J. M., & Balsara, N. P. (2016). Conductivity of carbonate- and perfluoropolyether-based electrolytes in porous separators. JOURNAL OF POWER SOURCES, 323, 158–165. https://doi.org/10.1016/j.jpowsour.2016.05.039

Bowerman, C. J., Byrne, J. D., Chu, K. S., Schorzman, A. N., Keeler, A. W., Sherwood, C. A., … DeSimone, J. M. (2017). Docetaxel-Loaded PLGA Nanoparticles Improve Efficacy in Taxane-Resistant Triple-Negative Breast Cancer. NANO LETTERS, 17(1), 242–248. https://doi.org/10.1021/acs.nanolett.6b03971

Sambade, M., Deal, A., Schorzman, A., Luft, J. C., Bowerman, C., Chu, K., … Anders, C. K. (2016). Efficacy and pharmacokinetics of a modified acid-labile docetaxel-PRINT® nanoparticle formulation against non-small-cell lung cancer brain metastases. Nanomedicine, 11(15), 1947–1955. https://doi.org/10.2217/nnm-2016-0147

Byrne, J. D., Jajja, M. R. N., Schorzman, A. N., Keeler, A. W., Luft, J. C., Zamboni, W. C., … Yeh, J. J. (2016). Iontophoretic device delivery for the localized treatment of pancreatic ductal adenocarcinoma. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 113(8), 2200–2205. https://doi.org/10.1073/pnas.1600421113

Janusziewicz, R., Tumbleston, J. R., Quintanilla, A. L., Mecham, S. J., & DeSimone, J. M. (2016). Layerless fabrication with continuous liquid interface production. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 113(42), 11703–11708. https://doi.org/10.1073/pnas.1605271113

Olson, K. R., Wong, D. H. C., Chintapalli, M., Timachova, K., Janusziewicz, R., Daniel, W. F. M., … DeSimone, J. M. (2016). Liquid perfluoropolyether electrolytes with enhanced ionic conductivity for lithium battery applications. POLYMER, 100, 126–133. https://doi.org/10.1016/j.polymer.2016.08.020

Fromen, C. A., Rahhal, T. B., Robbins, G. R., Kai, M. P., Shen, T. W., Luft, J. C., & DeSimone, J. M. (2016). Nanoparticle surface charge impacts distribution, uptake and lymph node trafficking by pulmonary antigen-presenting cells. NANOMEDICINE-NANOTECHNOLOGY BIOLOGY AND MEDICINE, 12(3), 677–687. https://doi.org/10.1016/j.nano.2015.11.002

Rogers, J. A., & DeSimone, J. M. (2016). Novel materials. Proceedings of the National Academy of Sciences, 113(42), 11667–11669. https://doi.org/10.1073/pnas.1614927113

DeSimone, J. M., Mecham, S. J., & Farrell, C. L. (2016). Organic Polymer Chemistry in the Context of Novel Processes. ACS CENTRAL SCIENCE, 2(9), 588–597. https://doi.org/10.1021/acscentsci.6b00195

Metz, S. W., Tian, S., Hoekstra, G., Yi, X., Stone, M., Horvath, K., … Silva, A. M. (2016). Precisely Molded Nanoparticle Displaying DENV-E Proteins Induces Robust Serotype-Specific Neutralizing Antibody Responses. PLOS NEGLECTED TROPICAL DISEASES, 10(10). https://doi.org/10.1371/journal.pntd.0005071

Rahhal, T. B., Fromen, C. A., Wilson, E. M., Kai, M. P., Shen, T. W., Luft, J. C., & DeSimone, J. M. (2016). Pulmonary Delivery of Butyrylcholinesterase as a Model Protein to the Lung. MOLECULAR PHARMACEUTICS, 13(5), 1626–1635. https://doi.org/10.1021/acs.molpharmaceut.6b00066

Kapadia, C. H., Tian, S., Perry, J. L., Luft, J. C., & DeSimone, J. M. (2016). Reduction Sensitive PEG Hydrogels for Codelivery of Antigen and Adjuvant To Induce Potent CTLs. Molecular Pharmaceutics, 13(10), 3381–3394. https://doi.org/10.1021/acs.molpharmaceut.6b00288

Chintapalli, M., Timachova, K., Olson, K. R., Mecham, S. J., Devaux, D., DeSimone, J. M., & Balsara, N. P. (2016). Relationship between Conductivity, Ion Diffusion, and Transference Number in Perfluoropolyether Electrolytes. MACROMOLECULES, 49(9), 3508–3515. https://doi.org/10.1021/acs.macromol.6b00412

Johnson, A. R., Caudill, C. L., Tumbleston, J. R., Bloomquist, C. J., Moga, K. A., Ermoshkin, A., … DeSimone, J. M. (2016). Single-Step Fabrication of Computationally Designed Microneedles by Continuous Liquid Interface Production. PLOS ONE, 11(9). https://doi.org/10.1371/journal.pone.0162518

Roode, L. E., Brighton, H., Bo, T., Perry, J. L., Parrott, M. C., Kersey, F., … Davis, I. J. (2016). Subtumoral analysis of PRINT nanoparticle distribution reveals targeting variation based on cellular and particle properties. Nanomedicine: Nanotechnology, Biology and Medicine, 12(4), 1053–1062. https://doi.org/10.1016/j.nano.2015.12.382

Robbins, G. R., Roberts, R. A., Guo, H., Reuter, K., Shen, T., Sempowski, G. D., … Ting, J. P.-Y. (2015). Analysis of human innate immune responses to PRINT fabricated nanoparticles with cross validation using a humanized mouse model. Nanomedicine: Nanotechnology, Biology and Medicine, 11(3), 589–599. https://doi.org/10.1016/j.nano.2014.11.010

Phanse, Y., Dunphy, B. M., Perry, J. L., Airs, P. M., Paquette, C. C. H., Carlson, J. O., … Bartholomay, L. C. (2015). Biodistribution and Toxicity Studies of PRINT Hydrogel Nanoparticles in Mosquito Larvae and Cells. PLOS NEGLECTED TROPICAL DISEASES, 9(5). https://doi.org/10.1371/journal.pntd.0003735

Paquette, C. C. H., Phanse, Y., Perry, J. L., Sanchez-Vargas, I., Airs, P. M., Dunphy, B. M., … Beaty, B. J. (2015). Biodistribution and Trafficking of Hydrogel Nanoparticles in Adult Mosquitoes. PLOS NEGLECTED TROPICAL DISEASES, 9(5). https://doi.org/10.1371/journal.pntd.0003745

Perry, J. L., Kai, M. P., Reuter, K. G., Bowerman, C., Christopher Luft, J., & DeSimone, J. M. (2015). Calibration-Quality Cancer Nanotherapeutics. In Cancer Treatment and Research (pp. 275–291). https://doi.org/10.1007/978-3-319-16555-4_12

Villaluenga, I., Wujcik, K. H., Tong, W., Devaux, D., Wong, D. H. C., DeSimone, J. M., & Balsara, N. P. (2016). Compliant glass-polymer hybrid single ion-conducting electrolytes for lithium batteries. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 113(1), 52–57. https://doi.org/10.1073/pnas.1520394112

Tumbleston, J. R., Shirvanyants, D., Ermoshkin, N., Janusziewicz, R., Johnson, A. R., Kelly, D., … DeSimone, J. M. (2015). Continuous liquid interface production of 3D objects. SCIENCE, 347(6228), 1349–1352. https://doi.org/10.1126/science.aaa2397

Shen, T. W., Fromen, C. A., Kai, M. P., Luft, J. C., Rahhal, T. B., Robbins, G. R., & DeSimone, J. M. (2015). Distribution and Cellular Uptake of PEGylated Polymeric Particles in the Lung Towards Cell-Specific Targeted Delivery. Pharmaceutical Research, 32(10), 3248–3260. https://doi.org/10.1007/s11095-015-1701-7

Kai, M. P., Keeler, A. W., Perry, J. L., Reuter, K. G., Luft, J. C., Sara K. O'Neal, … DeSimone, J. M. (2015). Evaluation of drug loading, pharmacokinetic behavior, and toxicity of a cisplatin-containing hydrogel nanoparticle. JOURNAL OF CONTROLLED RELEASE, 204, 70–77. https://doi.org/10.1016/j.jconrel.2015.03.001

Byrne, J. D., Jajja, M. R. N., Adrian T. O'Neill, Bickford, L. R., Keeler, A. W., Hyder, N., … DeSimone, J. M. (2015). Local iontophoretic administration of cytotoxic therapies to solid tumors. SCIENCE TRANSLATIONAL MEDICINE, 7(273). https://doi.org/10.1126/scitranslmed.3009951

Kapadia, C. H., Perry, J. L., Tian, S., Luft, J. C., & DeSimone, J. M. (2015). Nanoparticulate immunotherapy for cancer. JOURNAL OF CONTROLLED RELEASE, 219, 167–180. https://doi.org/10.1016/j.jconrel.2015.09.062

Sharpe, R. J., Malinowski, J. T., Sorana, F., Luft, J. C., Bowerman, C. J., DeSimone, J. M., & Johnson, J. S. (2015). Preparation and biological evaluation of synthetic and polymer-encapsulated congeners of the antitumor agent pactamycin: Insight into functional group effects and biological activity. BIOORGANIC & MEDICINAL CHEMISTRY, 23(8), 1849–1857. https://doi.org/10.1016/j.bmc.2015.02.022

Mueller, S. N., Tian, S., & DeSimone, J. M. (2015). Rapid and Persistent Delivery of Antigen by Lymph Node Targeting PRINT Nanoparticle Vaccine Carrier To Promote Humoral Immunity. MOLECULAR PHARMACEUTICS, 12(5), 1356–1365. https://doi.org/10.1021/mp500589c

Ma, D., Tian, S., Baryza, J., Luft, J. C., & DeSimone, J. M. (2015). Reductively Responsive Hydrogel Nanoparticles with Uniform Size, Shape, and Tunable Composition for Systemic siRNA Delivery in Vivo. MOLECULAR PHARMACEUTICS, 12(10), 3518–3526. https://doi.org/10.1021/acs.molpharmaceut.5b00054

Reuter, K. G., Perry, J. L., Kim, D., Luft, J. C., Liu, R., & DeSimone, J. M. (2015). Targeted PRINT Hydrogels: The Role of Nanoparticle Size and Ligand Density on Cell Association, Biodistribution, and Tumor Accumulation. NANO LETTERS, 15(10), 6371–6378. https://doi.org/10.1021/acs.nanolett.5b01362

Roberts, R. A., Eitas, T. K., Byrne, J. D., Johnson, B. M., Short, P. J., McKinnon, K. P., … Ting, J. P. (2015). Towards programming immune tolerance through geometric manipulation of phosphatidylserine. BIOMATERIALS, 72, 1–10. https://doi.org/10.1016/j.biomaterials.2015.08.040

Kai, M. P., Brighton, H. E., Fromen, C. A., Shen, T. W., Luft, J. C., Luft, Y. E., … DeSimone, J. M. (2016). Tumor Presence Induces Global Immune Changes and Enhances Nanoparticle Clearance. ACS NANO, 10(1), 861–870. https://doi.org/10.1021/acsnano.5b05999

Finniss, M. C., Chu, K. S., Bowerman, C. J., Luft, J. C., Haroon, Z. A., & DeSimone, J. M. (2014). A versatile acid-labile linker for antibody-drug conjugates. MEDCHEMCOMM, 5(9), 1355–1358. https://doi.org/10.1039/c4md00150h

Fromen, C. A., Robbins, G. R., Shen, T. W., Kai, M. P., Ting, J. P. Y., & DeSimone, J. M. (2015). Controlled analysis of nanoparticle charge on mucosal and systemic antibody responses following pulmonary immunization. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 112(2), 488–493. https://doi.org/10.1073/pnas.1422923112

Chen, K., Xu, J., Luft, J. C., Tian, S., Raval, J. S., & DeSimone, J. M. (2014). Design of Asymmetric Particles Containing a Charged Interior and a Neutral Surface Charge: Comparative Study on in Vivo Circulation of Polyelectrolyte Microgels. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 136(28), 9947–9952. https://doi.org/10.1021/ja503939n

DeSimone, J. M., & Farrell, C. L. (2014, May 28). Driving Convergence with Human Diversity. SCIENCE TRANSLATIONAL MEDICINE, Vol. 6. https://doi.org/10.1126/scitranslmed.3004486

Gharpure, K. M., Chu, K. S., Bowerman, C., Miyake, T., Pradeep, S., Mangala, S., … Sood, A. K. (2014). Metronomic docetaxel in PRINT® nanoparticles and EZH2 silencing have synergistic antitumor effect in ovarian cancer. Molecular Cancer Therapeutics, 13(7), 1750–1757. https://doi.org/10.1158/1535-7163.MCT-13-0930

Wong, D. H. C., Thelen, J. L., Fu, Y., Devaux, D., Pandya, A. A., Battaglia, V. S., … DeSimone, J. M. (2014). Nonflammable perfluoropolyether-based electrolytes for lithium batteries. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 111(9), 3327–3331. https://doi.org/10.1073/pnas.1314615111

Chu, K. S., Finniss, M. C., Schorzman, A. N., Kuijer, J. L., Luft, J. C., Bowerman, C. J., … DeSimone, J. M. (2014). Particle Replication in Nonwetting Templates Nanoparticles with Tumor Selective Alkyl Silyl Ether Docetaxel Prodrug Reduces Toxicity. Nano Letters, 14(3), 1472–1476. https://doi.org/10.1021/nl4046558

Wong, D. H. C., Vitale, A., Devaux, D., Taylor, A., Pandya, A. A., Hallinan, D. T., … DeSimone, J. M. (2015). Phase Behavior and Electrochemical Characterization of Blends of Perfluoropolyether, Poly(ethylene glycol), and a Lithium Salt. CHEMISTRY OF MATERIALS, 27(2), 597–603. https://doi.org/10.1021/cm504228a

Roberts, R. A., Shen, T., Allen, I. C., Hasan, W., DeSimone, J. M., & Ting, J. P. Y. (2013). Analysis of the Murine Immune Response to Pulmonary Delivery of Precisely Fabricated Nano- and Microscale Particles. PLOS ONE, 8(4). https://doi.org/10.1371/journal.pone.0062115

Galloway, A. L., Murphy, A., DeSimone, J. M., Di, J., Herrmann, J. P., Hunter, M. E., … Hubby, B. (2013). Development of a nanoparticle-based influenza vaccine using the PRINT® technology. Nanomedicine: Nanotechnology, Biology and Medicine, 9(4), 523–531. https://doi.org/10.1016/j.nano.2012.11.001

Xu, J., Wong, D. H. C., Byrne, J. D., Chen, K., Bowerman, C., & DeSimone, J. M. (2013). [Review of Future of the Particle Replication in Nonwetting Templates (PRINT) Technology]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 52(26), 6580–6589. https://doi.org/10.1002/anie.201209145

Dunn, S. S., Byrne, J. D., Perry, J. L., Chen, K., & DeSimone, J. M. (2013). Generating Better Medicines for Cancer. ACS MACRO LETTERS, 2(5), 393–397. https://doi.org/10.1021/mz400116a

Jones, S. W., Roberts, R. A., Robbins, G. R., Perry, J. L., Kai, M. P., Chen, K., … Bear, J. E. (2013). Nanoparticle clearance is governed by Th1/Th2 immunity and strain background. JOURNAL OF CLINICAL INVESTIGATION, 123(7), 3061–3073. https://doi.org/10.1172/jci66895

Chu, K. S., Schorzman, A. N., Finniss, M. C., Bowerman, C. J., Peng, L., Luft, J. C., … DeSimone, J. M. (2013). Nanoparticle drug loading as a design parameter to improve docetaxel pharmacokinetics and efficacy. BIOMATERIALS, 34(33), 8424–8429. https://doi.org/10.1016/j.biomaterials.2013.07.038

Petrosko, S. H., Fromen, C. A., Auyeung, E., DeSimone, J. M., & Mirkin, C. A. (2013). Nanotechnology: An Enduring Bridge Between Engineering and Medicine. The Bridge: Linking Engineering and Society, 7–15.

Byrne, J. D., Hasan, W., Blake, S., Farrell, C., & DeSimone, J. (2013). PRINT Technology: A Versatile Platform for Novel Applications in Nanomedicine. In S. Yin & A. Wei (Eds.), Nanomaterials for Pharmaceutical Scientists. New York: Wiley.

Chu, K. S., Hasan, W., Rawal, S., Walsh, M. D., Enlow, E. M., Luft, J. C., … DeSimone, J. M. (2013). Plasma, tumor and tissue pharmacokinetics of Docetaxel delivered via nanoparticles of different sizes and shapes in mice bearing SKOV-3 human ovarian carcinoma xenograft. Nanomedicine: Nanotechnology, Biology and Medicine, 9(5), 686–693. https://doi.org/10.1016/j.nano.2012.11.008

Xu, J., Luft, J. C., Yi, X., Tian, S., Owens, G., Wang, J., … DeSimone, J. M. (2013). RNA Replicon Delivery via Lipid-Complexed PRINT Protein Particles. MOLECULAR PHARMACEUTICS, 10(9), 3366–3374. https://doi.org/10.1021/mp400190z

Moga, K. A., Bickford, L. R., Geil, R. D., Dunn, S. S., Pandya, A. A., Wang, Y., … DeSimone, J. M. (2013). Rapidly-Dissolvable Microneedle Patches Via a Highly Scalable and Reproducible Soft Lithography Approach. ADVANCED MATERIALS, 25(36), 5060–5066. https://doi.org/10.1002/adma.201300526

Morton, S. W., Herlihy, K. P., Shopsowitz, K. E., Deng, Z. J., Chu, K. S., Bowerman, C. J., … Hammond, P. T. (2013). Scalable Manufacture of Built-to-Order Nanomedicine: Spray-Assisted Layer-by-Layer Functionalization of PRINT Nanoparticles. ADVANCED MATERIALS, 25(34), 4707–4713. https://doi.org/10.1002/adma.201302025

Fromen, C. A., Shen, T. W., Larus, A. E., Mack, P., Maynor, B. W., Luft, J. C., & DeSimone, J. M. (2013). Synthesis and characterization of monodisperse uniformly shaped respirable aerosols. AICHE JOURNAL, 59(9), 3184–3194. https://doi.org/10.1002/aic.14157

DeSimone, J. M., Goodenough, J. B., Groves, J. T., & Bornscheuer, U. T. (2012). Chevreul Medal for Uwe T. Bornscheuer. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, Vol. 51, pp. 6563–6563. https://doi.org/10.1002/anie.201204166

Kersey, F. R., Merkel, T. J., Perry, J. L., Napier, M. E., & DeSimone, J. M. (2012). Effect of Aspect Ratio and Deformability on Nanoparticle Extravasation through Nanopores. LANGMUIR, 28(23), 8773–8781. https://doi.org/10.1021/la301279v

Wang, Y., Byrne, J. D., Napier, M. E., & DeSimone, J. M. (2012). [Review of Engineering nanomedicines using stimuli-responsive biomaterials]. ADVANCED DRUG DELIVERY REVIEWS, 64(11), 1021–1030. https://doi.org/10.1016/j.addr.2012.01.003

Parrott, M. C., Finniss, M., Luft, J. C., Pandya, A., Gullapalli, A., Napier, M. E., & Desimone, J. M. (2012). Incorporation and Controlled Release of Silyl Ether Prodrugs from PRINT Nanoparticles. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 134(18), 7978–7982. https://doi.org/10.1021/ja301710z

DeSimone, J. (2012). Interview: From traditional polymer science to nanomedicine: the interplay between disciplines to drive innovation. Nanomedicine, 7(8), 1125–1128. https://doi.org/10.2217/nnm.12.89

Chen, K., Merkel, T. J., Pandya, A., Napier, M. E., Luft, J. C., Daniel, W., … DeSimone, J. M. (2012). Low Modulus Biomimetic Microgel Particles with High Loading of Hemoglobin. BIOMACROMOLECULES, 13(9), 2748–2759. https://doi.org/10.1021/bm3007242

Perry, J. L., Reuter, K. G., Kai, M. P., Herlihy, K. P., Jones, S. W., Luft, J. C., … DeSimone, J. M. (2012). PEGylated PRINT Nanoparticles: The Impact of PEG Density on Protein Binding, Macrophage Association, Biodistribution, and Pharmacokinetics. NANO LETTERS, 12(10), 5304–5310. https://doi.org/10.1021/nl302638g

Dunn, S. S., Tian, S., Blake, S., Wang, J., Galloway, A. L., Murphy, A., … DeSimone, J. M. (2012). Reductively Responsive siRNA-Conjugated Hydrogel Nanoparticles for Gene Silencing. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 134(17), 7423–7430. https://doi.org/10.1021/ja300174v

Xu, J., Wang, J. J., Luft, J. C., Tian, S., Owens, G., Jr., Pandya, A. A., … DeSimone, J. M. (2012). Rendering Protein-Based Particles Transiently Insoluble for Therapeutic Applications. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 134(21), 8774–8777. https://doi.org/10.1021/ja302363r

Merkel, T. J., Chen, K., Jones, S. W., Pandya, A. A., Tian, S., Napier, M. E., … DeSimone, J. M. (2012). The effect of particle size on the biodistribution of low-modulus hydrogel PRINT particles. Journal of Controlled Release, 162(1), 37–44. https://doi.org/10.1016/j.jconrel.2012.06.009

Wang, Y., Finlay, J. A., Betts, D. E., Merkel, T. J., Luft, J. C., Callow, M. E., … DeSimone, J. M. (2011). Amphiphilic Co-networks with Moisture-Induced Surface Segregation for High-Performance Nonfouling Coatings. LANGMUIR, 27(17), 10365–10369. https://doi.org/10.1021/la202427z

Ko, D.-H., Tumbleston, J. R., Henderson, K. J., Euliss, L. E., DeSimone, J. M., Lopez, R., & Samulski, E. T. (2011). Biomimetic microlens array with antireflective “moth-eye” surface. Soft Matter, 7(14), 6404. https://doi.org/10.1039/c1sm05302g

Hasan, W., Chu, K., Gullapalli, A., Dunn, S. S., Enlow, E. M., Luft, J. C., … DeSimone, J. M. (2012). Delivery of Multiple siRNAs Using Lipid-Coated PLGA Nanoparticles for Treatment of Prostate Cancer. NANO LETTERS, 12(1), 287–292. https://doi.org/10.1021/nl2035354

Merkel, T. J., & DeSimone, J. M. (2011). Dodging Drug-Resistant Cancer with Diamonds. SCIENCE TRANSLATIONAL MEDICINE, 3(73). https://doi.org/10.1126/scitranslmed.3002137

Benhabbour, S. R., Luft, J. C., Kim, D., Jain, A., Wadhwa, S., Parrott, M. C., … Mumper, R. J. (2012). In vitro and in vivo assessment of targeting lipid-based nanoparticles to the epidermal growth factor-receptor (EGFR) using a novel Heptameric ZEGFR domain. Journal of Controlled Release, 158(1), 63–71. https://doi.org/10.1016/j.jconrel.2011.10.013

Wang, Y., Pitet, L. M., Finlay, J. A., Brewer, L. H., Cone, G., Betts, D. E., … DeSimone, J. M. (2011). Investigation of the role of hydrophilic chain length in amphiphilic perfluoropolyether/poly(ethylene glycol) networks: towards high-performance antifouling coatings. Biofouling, 27(10), 1139–1150. https://doi.org/10.1080/08927014.2011.629344

Wang, J., Byrne, J. D., Napier, M. E., & DeSimone, J. M. (2011). [Review of More Effective Nanomedicines through Particle Design]. SMALL, 7(14), 1919–1931. https://doi.org/10.1002/smll.201100442

Pillai, J. D., Dunn, S. S., Napier, M. E., & DeSimone, J. M. (2011). [Review of Novel Platforms for Vascular Carriers with Controlled Geometry]. IUBMB LIFE, 63(8), 596–606. https://doi.org/10.1002/iub.497

Perry, J. L., Herlihy, K. P., Napier, M. E., & DeSimone, J. M. (2011). PRINT: A Novel Platform Toward Shape and Size Specific Nanoparticle Theranostics. Accounts of Chemical Research, 44(10), 990–998. https://doi.org/10.1021/ar2000315

Wang, Y., Betts, D. E., Finlay, J. A., Brewer, L., Callow, M. E., Callow, J. A., … DeSimone, J. M. (2011). Photocurable Amphiphilic Perfluoropolyether/Poly(ethylene glycol) Networks for Fouling-Release Coatings. MACROMOLECULES, 44(4), 878–885. https://doi.org/10.1021/ma102271t

Enlow, E. M., Luft, J. C., Napier, M. E., & DeSimone, J. M. (2011). Potent Engineered PLGA Nanoparticles by Virtue of Exceptionally High Chemotherapeutic Loadings. NANO LETTERS, 11(2), 808–813. https://doi.org/10.1021/nl104117p

Parrott, M. C., & DeSimone, J. M. (2011). Relieving PEGylation. Nature Chemistry, 4(1), 13–14. https://doi.org/10.1038/nchem.1230

Brown, E., Zhang, H., Forman, N. A., Maynor, B. W., Betts, D. E., DeSimone, J. M., & Jaeger, H. M. (2011). Shear thickening and jamming in densely packed suspensions of different particle shapes. Physical Review E, 84(3). https://doi.org/10.1103/physreve.84.031408

Wang, J.-Y., Wang, Y., Sheiko, S. S., Betts, D. E., & DeSimone, J. M. (2012). Tuning Multiphase Amphiphilic Rods to Direct Self-Assembly. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 134(13), 5801–5806. https://doi.org/10.1021/ja2066187

Merkel, T. J., Jones, S. W., Herlihy, K. P., Kersey, F. R., Shields, A. R., Napier, M., … DeSimone, J. M. (2011). Using mechanobiological mimicry of red blood cells to extend circulation times of hydrogel microparticles. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 108(2), 586–591. https://doi.org/10.1073/pnas.1010013108

Jeong, W., Napier, M. E., & DeSimone, J. M. (2010). [Review of Challenging nature's monopoly on the creation of well-defined nanoparticles]. NANOMEDICINE, 5(4), 633–639. https://doi.org/10.2217/nnm.10.34

Ahmed, T. S., DeSimone, J. M., & Roberts, G. W. (2010). Continuous precipitation polymerization of vinylidene fluoride in supercritical carbon dioxide: A model for understanding the molecular-weight distribution. CHEMICAL ENGINEERING SCIENCE, 65(2), 651–659. https://doi.org/10.1016/j.ces.2009.08.039

Hampton, M. J., Templeton, J. L., & DeSimone, J. M. (2010). Direct Patterning of CdSe Quantum Dots into Sub-100 nm Structures. LANGMUIR, 26(5), 3012–3015. https://doi.org/10.1021/la904787k

Brown, E., Forman, N. A., Orellana, C. S., Zhang, H., Maynor, B. W., Betts, D. E., … Jaeger, H. M. (2010). Generality of shear thickening in dense suspensions. Nature Materials, 9(3), 220–224. https://doi.org/10.1038/nmat2627

Wang, Y., Merkel, T. J., Chen, K., Fromen, C. A., Betts, D. E., & DeSimone, J. M. (2011). Generation of a Library of Particles Having Controlled Sizes and Shapes via the Mechanical Elongation of Master Templates. LANGMUIR, 27(2), 524–528. https://doi.org/10.1021/la1045095

Nunes, J. K., Ertas, M., Du, L., & DeSimone, J. M. (2010). Hierarchical Control of Polymer Composite Nano- and Micro-Structure with Lithography. CHEMISTRY OF MATERIALS, 22(13), 4069–4075. https://doi.org/10.1021/cm100931r

Hu, Z., Pitet, L. M., Hillmyer, M. A., & DeSimone, J. M. (2010). High Modulus, Low Surface Energy, Photochemically Cured Materials from Liquid Precursors. MACROMOLECULES, 43(24), 10397–10405. https://doi.org/10.1021/ma101180k

Williams, S. S., Retterer, S., Lopez, R., Ruiz, R., Samulski, E. T., & DeSimone, J. M. (2010). High-Resolution PFPE-based Molding Techniques for Nanofabrication of High-Pattern Density, Sub-20 nm Features: A Fundamental Materials Approach. NANO LETTERS, 10(4), 1421–1428. https://doi.org/10.1021/nl100326q

Knight, T. E., Goldstein, A. P., Brennaman, M. K., Cardolaccia, T., Pandya, A., DeSimone, J. M., & Meyer, T. J. (2011). Influence of the Fluid-to-Film Transition on Photophysical Properties of MLCT Excited States in a Polymerizable Dimethacrylate Fluid. The Journal of Physical Chemistry B, 115(1), 64–70. https://doi.org/10.1021/jp107077t

Juliano, R. L., Sunnarborg, S., DeSimone, J., & Haroon, Z. (2011). Institutional Profile: The Carolina Center of Cancer Nanotechnology Excellence: past accomplishments and future perspectives. Nanomedicine, 6(1), 19–24. https://doi.org/10.2217/nnm.10.142

Galloway, A. L., Murphy, A., Rolland, J. P., Herlihy, K. P., Petros, R. A., Napier, M. E., & DeSimone, J. M. (2010). Micromolding for the Fabrication of Biological Microarrays. In Methods in Molecular Biology (pp. 249–260). https://doi.org/10.1007/978-1-59745-551-0_15

Nunes, J., Herlihy, K. P., Mair, L., Superfine, R., & DeSimone, J. M. (2010). Multifunctional Shape and Size Specific Magneto-Polymer Composite Particles. NANO LETTERS, 10(4), 1113–1119. https://doi.org/10.1021/nl904152e

DeSimone, J. M., Siripurapu, S., Khan, S. A., Spontak, R. J., & Royer, J. (2010). Nano-and micro-cellular foamed thin-walled material, and processes and apparatuses for making the same.

Merkel, T. J., Herlihy, K. P., Nunes, J., Orgel, R. M., Rolland, J. P., & DeSimone, J. M. (2010). Scalable, Shape-Specific, Top-Down Fabrication Methods for the Synthesis of Engineered Colloidal Particles. LANGMUIR, 26(16), 13086–13096. https://doi.org/10.1021/la903890h

Brown, E., Zhang, H., Forman, N. A., Maynor, B. W., Betts, D. E., DeSimone, J. M., & Jaeger, H. M. (2010). Shear thickening in densely packed suspensions of spheres and rods confined to few layers. Journal of Rheology, 54(5), 1023–1046. https://doi.org/10.1122/1.3474580

Petros, R. A., & DeSimone, J. M. (2010). [Review of Strategies in the design of nanoparticles for therapeutic applications]. NATURE REVIEWS DRUG DISCOVERY, 9(8), 615–627. https://doi.org/10.1038/nrd2591

Wang, J., Tian, S., Petros, R. A., Napier, M. E., & DeSimone, J. M. (2010). The Complex Role of Multivalency in Nanoparticles Targeting the Transferrin Receptor for Cancer Therapies. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 132(32), 11306–11313. https://doi.org/10.1021/ja1043177

Parrott, M. C., Luft, J. C., Byrne, J. D., Fain, J. H., Napier, M. E., & DeSimone, J. (2010). Tunable Bifunctional Silyl Ether Cross-Linkers for the Design of Acid-Sensitive Biomaterials. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 132(50), 17928–17932. https://doi.org/10.1021/ja108568g

Kim, J., Rolland, J. P., Carbonell, R. G., & DeSimone, J. M. (2010). Ultrathin Cross-Linked Perfluoropolyether Film Coatings from Liquid CO2 and Subsequent UV Curing. CHEMISTRY OF MATERIALS, 22(8), 2411–2413. https://doi.org/10.1021/cm903598v

Kim, J., Taylor, D., DeYoung, J., McClain, J. B., DeSimone, J. M., & Carbonell, R. G. (2009). Deposition of Copper Particles and Films by the Displacement of Two Immiscible Supercritical Phases and Subsequent Reaction. Chemistry of Materials, 21(5), 913–924. https://doi.org/10.1021/cm802659j

Zhang, H., Nunes, J. K., Gratton, S. E. A., Herlihy, K. P., Pohlhaus, P. D., & DeSimone, J. M. (2009). Fabrication of multiphasic and regio-specifically functionalized PRINT (R) particles of controlled size and shape. NEW JOURNAL OF PHYSICS, 11. https://doi.org/10.1088/1367-2630/11/7/075018

Du, L., Kelly, J. Y., Roberts, G. W., & DeSimone, J. M. (2009). [Review of Fluoropolymer synthesis in supercritical carbon dioxide]. JOURNAL OF SUPERCRITICAL FLUIDS, 47(3), 447–457. https://doi.org/10.1016/j.supflu.2008.11.011

Du, L., DeSimone, J. M., & Roberts, G. W. (2009). Green Chemistry and Engineering with Gas Expanded Liquids and Near-Critical Media. In K. W. Hutchenson, A. M. Scurto, & B. Subramaniam (Eds.), ACS Symposium Series (Vol. 90, pp. 259–273).

Hu, Z., Finlay, J. A., Chen, L., Betts, D. E., Hillmyer, M. A., Callow, M. E., … DeSimone, J. M. (2009). Photochemically Cross-Linked Perfluoropolyether-Based Elastomers: Synthesis, Physical Characterization, and Biofouling Evaluation. MACROMOLECULES, 42(18), 6999–7007. https://doi.org/10.1021/ma901227k

Ko, D.-H., Tumbleston, J. R., Zhang, L., Williams, S., DeSimone, J. M., Lopez, R., & Samulski, E. T. (2009). Photonic Crystal Geometry for Organic Solar Cells. Nano Letters, 9(7), 2742–2746. https://doi.org/10.1021/nl901232p

Canelas, D. A., Herlihy, K. P., & DeSimone, J. M. (2009). [Review of Top-down particle fabrication: control of size and shape for diagnostic imaging and drug delivery]. WILEY INTERDISCIPLINARY REVIEWS-NANOMEDICINE AND NANOBIOTECHNOLOGY, 1(4), 391–404. https://doi.org/10.1002/wnan.40

Ahmed, T. S., DeSimone, J. M., & Roberts, G. W. (2008). Continuous copolymerization of vinylidene fluoride with hexafluoropropylene in Supercritical carbon dioxide: High-hexafluoropropylene-content amorphous copolymers. MACROMOLECULES, 41(9), 3086–3097. https://doi.org/10.1021/ma702526u

Herlihy, K. P., Nunes, J., & DeSimone, J. M. (2008). Electrically driven alignment and crystallization of unique anisotropic polymer particles. LANGMUIR, 24(16), 8421–8426. https://doi.org/10.1021/la801250g

Ahmed, T. S., DeSimone, J. M., & Roberts, G. W. (2009). Kinetics of the Homopolymerization of Vinylidene Fluoride and Its Copolymerization with Hexafluoropropylene in Supercritical Carbon Dioxide: The Locus of Polymerization. Macromolecules, 42(1), 148–155. https://doi.org/10.1021/ma801911j

Gratton, S. E. A., Napier, M. E., Ropp, P. A., Tian, S., & DeSimone, J. M. (2008). Microfabricated Particles for Engineered Drug Therapies: Elucidation into the Mechanisms of Cellular Internalization of PRINT Particles. PHARMACEUTICAL RESEARCH, 25(12), 2845–2852. https://doi.org/10.1007/s11095-008-9654-8

Yu-Su, S. Y., Thomas, D. R., Alford, J. E., LaRue, I., Pitsikalis, M., Hadjichristidis, N., … Sheiko, S. S. (2008). Molding Block Copolymer Micelles: A Framework for Molding of Discrete Objects on Surfaces. Langmuir, 24(21), 12671–12679. https://doi.org/10.1021/la802549s

Williams, S. S., Hampton, M. J., Gowrishankar, V., Ding, I.-K., Templeton, J. L., Samulski, E. T., … McGehee, M. D. (2008). Nanostructured Titania−Polymer Photovoltaic Devices Made Using PFPE-Based Nanomolding Techniques. Chemistry of Materials, 20(16), 5229–5234. https://doi.org/10.1021/cm800729q

Hu, Z., Chen, L., Betts, D. E., Pandya, A., Hillmyer, M. A., & DeSimone, J. M. (2008). Optically Transparent, Amphiphilic Networks Based on Blends of Perfluoropolyethers and Poly(ethylene glycol). JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 130(43), 14244–14252. https://doi.org/10.1021/ja803991n

Petros, R. A., Ropp, P. A., & DeSimone, J. M. (2008). Reductively Labile PRINT Particles for the Delivery of Doxorubicin to HeLa Cells. Journal of the American Chemical Society, 130(15), 5008–5009. https://doi.org/10.1021/ja801436j

Kelly, J. Y., & DeSimone, J. M. (2008). Shape-specific, monodisperse nano-molding of protein particles. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 130(16), 5438-+. https://doi.org/10.1021/ja8014428

Gratton, S. E. A., Williams, S. S., Napier, M. E., Pohlhaus, P. D., Zhou, Z., Wiles, K. B., … Desimone, J. M. (2008). [Review of The Pursuit of a Scalable Nanofabrication Platform for Use in Material and Life Science Applications]. ACCOUNTS OF CHEMICAL RESEARCH, 41(12), 1685–1695. https://doi.org/10.1021/ar8000348

Gratton, S. E. A., Ropp, P. A., Pohlhaus, P. D., Luft, J. C., Madden, V. J., Napier, M. E., & DeSimone, J. M. (2008). The effect of particle design on cellular internalization pathways. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 105(33), 11613–11618. https://doi.org/10.1073/pnas.0801763105

Hampton, M. J., Williams, S. S., Zhou, Z., Nunes, J., Ko, D. H., Templeton, J. L., … DeSimone, J. M. (2008). The patterning of sub-500 nm inorganic oxide structures. Advanced Materials, 20(14), 2667-. https://doi.org/10.1002/adma.200702495

Guo, J., Resnick, P., Efimenko, K., Genzer, J., & DeSimone, J. M. (2008). Alternative fluoropolymers to avoid the challenges associated with perfluorooctanoic acid. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 47(3), 502–508. https://doi.org/10.1021/ie0703179

Ahmed, T. S., DeSimone, J. M., & Roberts, G. W. (2007). Continuous copolymerization of vinylidene fluoride with hexafluoropropylene in Supercritical carbon dioxide: Low hexafluoropropylene content semicrystalline copolymers. MACROMOLECULES, 40(26), 9322–9331. https://doi.org/10.1021/ma0713613

Choi, J.-P., Coble, M. M., Branham, M. R., DeSimone, J. M., & Murray, R. W. (2007). Dynamics of CO2-Plasticized Electron Transport in Au Nanoparticle Films:  Opposing Effects of Tunneling Distance and Local Site Mobility. The Journal of Physical Chemistry C, 111(9), 3778–3785. https://doi.org/10.1021/jp068349h

Li, Y. X., Yang, D., Jones, C. A., DeSimone, J. M., & Irene, E. A. (2007). Etching SiO[sub 2] with HF/pyridine-supercritical carbon dioxide solutions and resultant interfacial electronic properties. Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, 25(4), 1139. https://doi.org/10.1116/1.2743651

Gratton, S. E. A., PohhauS, P. D., Lee, J., Guo, Ii, Cho, M. J., & DeSimone, J. M. (2007, August 16). Nanofabricated particles for engineered drug therapies: A preliminary Biodistribution study of PRINT (TM) nanoparticles. JOURNAL OF CONTROLLED RELEASE, Vol. 121, pp. 10–18. https://doi.org/10.1016/j.jconrel.2007.05.027

Napier, M. E., & DeSimone, J. M. (2007). Nanoparticle Drug Delivery Platform. Polymer Reviews, 47(3), 321–327. https://doi.org/10.1080/15583720701454999

Canelas, D. A., & DeSimone, J. M. (1997). Polymerizations in Liquid and Supercritical Carbon Dioxide. In D. A. Canelas, J. M. DeSimone, A. Harada, E. Ihara, K. Mashima, A. Nakamura, … H. Yasuda (Eds.), Metal Complex Catalysts Supercritical Fluid Polymerization Supramolecular Architecture (pp. 103–140). https://doi.org/10.1007/3-540-68442-5_3

Maynor, B. W., LaRue, I., Hu, Z., Rolland, J. P., Pandya, A., Fu, Q., … DeSimone, J. M. (2007). Supramolecular nanomimetics: Replication of micelles, viruses, and other naturally occurring nanoscale objects. SMALL, 3(5), 845–849. https://doi.org/10.1002/smll.200600507

Russell-Tanner, J. M., Takayama, S., Sugimura, A., DeSimone, J. M., & Samulski, E. T. (2007). Weak surface anchoring energy of 4-cyano-4′-pentyl-1,1′-biphenyl on perfluoropolyether Langmuir-Blodgett films. The Journal of Chemical Physics, 126(24), 244706. https://doi.org/10.1063/1.2743404

Boggiano, M. K., Vellenga, D., Carbonell, R., Ashby, V. S., & DeSimone, J. M. (2006). Alicyclic photoresists for CO2-based next-generation microlithography: A tribute to James E. McGrath. POLYMER, 47(11), 4012–4017. https://doi.org/10.1016/j.polymer.2006.03.001

Olson, D. A., Gratton, S. E. A., DeSimone, J. M., & Sheares, V. V. (2006). Amorphous Linear Aliphatic Polyesters for the Facile Preparation of Tunable Rapidly Degrading Elastomeric Devices and Delivery Vectors. Journal of the American Chemical Society, 128(41), 13625–13633. https://doi.org/10.1021/ja063092m

Yarbrough, J. C., Rolland, J. P., DeSimone, J. M., Callow, M. E., Finlay, J. A., & Callow, J. A. (2006). Contact angle analysis, surface dynamics, and biofouling characteristics of cross-linkable, random perfluoropolyether-based graft terpolymers. MACROMOLECULES, 39(7), 2521–2528. https://doi.org/10.1021/ma0524777

Liu, T., DeSimone, J. M., & Roberts, G. W. (2006). Cross-linking polymerization of acrylic acid in supercritical carbon dioxide. POLYMER, 47(12), 4276–4281. https://doi.org/10.1016/j.polymer.2006.03.103

Forbes, M. D. E., Dukes, K. E., Avdievich, N. I., Harbron, E. J., & DeSimone, J. M. (2006). Flexible Biradicals in Liquid and Supercritical Carbon Dioxide:  The Exchange Interaction, the Chain Dynamics, and a Comparison with Conventional Solvents. The Journal of Physical Chemistry A, 110(5), 1767–1774. https://doi.org/10.1021/jp053183q

Euliss, L. E., DuPont, J. A., Gratton, S., & DeSimone, J. (2006). Imparting size, shape, and composition control of materials for nanomedicine. Chemical Society Reviews, 35(11), 1095. https://doi.org/10.1039/b600913c

Liu, T., DeSimone, J. M., & Roberts, G. W. (2006). Kinetics of the precipitation polymerization of acrylic acid in supercritical carbon dioxide: The locus of polymerization. CHEMICAL ENGINEERING SCIENCE, 61(10), 3129–3139. https://doi.org/10.1016/j.ces.2005.11.052

Zhou, Z., Dominey, R. N., Rolland, J. P., Maynor, B. W., Pandya, A. A., & DeSimone, J. M. (2006). Molded, high surface area polymer electrolyte membranes from cured liquid precursors. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 128(39), 12963–12972. https://doi.org/10.1021/ja064391e

Liu, T., Garner, P., DeSimone, J. M., Roberts, G. W., & Bothun, G. D. (2006). Particle formation in precipitation polymerization: Continuous precipitation polymerization of acrylic acid in supercritical carbon dioxide. MACROMOLECULES, 39(19), 6489–6494. https://doi.org/10.1021/ma061260p

Ye, W. J., Keiper, J. S., & DeSimone, J. M. (2006). Polymeric nanoparticles from supercritical CO2 microemulsion polymerization. CHINESE JOURNAL OF POLYMER SCIENCE, 24(1), 95–101. https://doi.org/10.1142/S0256767906001084

Guo, J., Andre, P., Adam, M., Panyukov, S., Rubinstein, M., & DeSimone, J. M. (2006). Solution properties of a fluorinated alkyl methacrylate polymer in carbon dioxide. MACROMOLECULES, 39(9), 3427–3434. https://doi.org/10.1021/ma052409k

Visintin, P. M., Eichenlaub, S. K., Portnow, L. E., Carbonell, R. G., Beaudoin, S. P., Schauer, C. K., & DeSimone, J. M. (2006). Studies on CO2-based slurries and fluorinated silica and alumina particles for chemical mechanical polishing of copper films. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 153(12), G1064–G1071. https://doi.org/10.1149/1.2358085

Zhang, L., Zhou, Z., Cheng, B., DeSimone, J. M., & Samulski, E. T. (2006). Superhydrophobic Behavior of a Perfluoropolyether Lotus-Leaf-like Topography. Langmuir, 22(20), 8576–8580. https://doi.org/10.1021/la061400o

DeYoung, J. P., Romack, T. J., & DeSimone, J. M. (2002). Synthesis of Fluoropolymers in Liquid and Supercritical Carbon Dioxide Solvent Systems. In G. Hougham, P. E. Cassidy, K. Johns, & T. Davidson (Eds.), Fluoropolymers 1: Synthesis (pp. 191–205). https://doi.org/10.1007/0-306-46918-9_13

Dunbar, A., Omiatek, D. M., Thai, S. D., Kendrex, C. E., Grotzinger, L. L., Boyko, W. J., … DeSimone, J. M. (2006). Use of substituted bis(acetylacetone) ethylenediimine and dialkyldithiocarbamate ligands for copper chelation in supercritical carbon dioxide. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 45(26), 8779–8787. https://doi.org/10.1021/ie060947v

Young, J. L., & DeSimone, J. M. (2005). Advantages of supercritical carbon dioxide for composite particle synthesis using water-soluble or water-reactive monomers. MACROMOLECULES, 38(10), 4542–4544. https://doi.org/10.1021/ma0478310

Visintin, P. M., Carbonell, R. G., Schauer, C. K., & DeSimone, J. M. (2005). Chemical functionalization of silica and alumina particles for dispersion in carbon dioxide. LANGMUIR, 21(11), 4816–4823. https://doi.org/10.1021/la047823c

Liu, T., Desimone, J. M., & Roberts, G. W. (2005). Continuous precipitation polymerization of acrylic acid in swercritical carbon dioxide: The polymerization rate and the polymer molecular weight. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 43(12), 2546–2555. https://doi.org/10.1002/pola.20728

Siripurapu, S., DeSimone, J. M., Khan, S. A., & Spontak, R. J. (2005). Controlled foaming of polymer films through restricted surface diffusion and the addition of nanosilica particles or CO2-philic surfactants. MACROMOLECULES, 38(6), 2271–2280. https://doi.org/10.1021/ma047991b

Ahmed, T. S., DeSimone, J. M., & Roberts, G. W. (2006). Copolymerization of vinylidene fluoride with hexafluoropropylene in supercritical carbon dioxide. MACROMOLECULES, 39(1), 15–18. https://doi.org/10.1021/ma051268j

Rolland, J. P., Maynor, B. W., Euliss, L. E., Exner, A. E., Denison, G. M., & DeSimone, J. M. (2005). Direct fabrication and harvesting of monodisperse, shape-specific nanobiomaterials. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 127(28), 10096–10100. https://doi.org/10.1021/ja051977c

Denison, G. M., Evans, A. O., Bessel, C. A., Skaf, D. W., Murray, R. W., & DeSimone, J. M. (2005). Electrochemical behavior of bis(beta-diketonate)copper complexes. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 152(11), B435–B440. https://doi.org/10.1149/1.2047387

Ye, W. J., & DeSimone, J. M. (2005). Emulsion polymerization of N-ethylacrylamide in supercritical carbon dioxide. MACROMOLECULES, 38(6), 2180–2190. https://doi.org/10.1021/ma048863q

Liu, B., Rolland, J. P., DeSimone, J. M., & Bard, A. J. (2005). Fabrication of Ultramicroelectrodes Using A “Teflon-like” Coating Material. Analytical Chemistry, 77(9), 3013–3017. https://doi.org/10.1021/ac0482918

Kennedy, K. A., Roberts, G. W., & DeSimone, J. M. (2005). Heterogeneous polymerization of fluoroolefins in supercritical carbon dioxide. POLYMER PARTICLES, Vol. 175, pp. 329–346. https://doi.org/10.1007/b100114

Dickson, J. L., Smith, P. G., Dhanuka, V. V., Srinivasan, V., Stone, M. T., Rossky, P. J., … Johnston, K. P. (2005). Interfacial Properties of Fluorocarbon and Hydrocarbon Phosphate Surfactants at the Water−CO2Interface. Industrial & Engineering Chemistry Research, 44(5), 1370–1380. https://doi.org/10.1021/ie048999c

Xu, B., Lynn, G. W., Guo, J., Melnichenko, Y. B., Wignall, G. D., McClain, J. B., … Johnson, C. S. (2005). NMR and SANS studies of aggregation and microemulsion formation by phosphorus fluorosurfactants in liquid and supercritical carbon dioxide. JOURNAL OF PHYSICAL CHEMISTRY B, 109(20), 10261–10269. https://doi.org/10.1021/jp0580322

Wood, C. D., Yarbrough, J. C., Roberts, G., & DeSimone, J. (2006). Production of Fluoropolymers in Supercritical Carbon Dioxide. In Supercritical Carbon Dioxide (pp. 189–204). https://doi.org/10.1002/3527606726.ch9

Kiserow, D. J., Shi, C. M., Roberts, G. W., Gross, S. M., & DeSimone, J. M. (2005). Solid-state polymerization of poly(bisphenol A carbonate) facilitated by supercritical carbon dioxide. ADVANCES IN POLYCARBONATES, Vol. 898, pp. 86–94. https://doi.org/10.1021/bk-2005-0898.ch007

Kim, J., Novick, B. J., DeSimone, J. M., & Carbonell, R. G. (2006). Ultrathin film deposition by liquid CO2 free meniscus coating-uniformity and morphology. LANGMUIR, 22(2), 642–657. https://doi.org/10.1021/la0521600

Hoggan, E. N., Wang, K., Flowers, D., DeSimone, J. M., & Carbonell, R. G. (2004). "dry" lithography using liquid and supercritical carbon dioxide based chemistries and processes. IEEE TRANSACTIONS ON SEMICONDUCTOR MANUFACTURING, 17(4), 510–516. https://doi.org/10.1109/tsm.2004.837002

Jones, C. A., Zweber, A., DeYoung, J. P., McClain, J. B., Carbonell, R., & DeSimone, J. M. (2004). [Review of Applications of "dry" processing in the microelectronics industry using carbon dioxide]. CRITICAL REVIEWS IN SOLID STATE AND MATERIALS SCIENCES, 29(3-4), 97–109. https://doi.org/10.1080/10408430490888968

DeSimone, J. M., Carbonell, R. G., Kendall, J., & McAdams, C. L. (2004). CO2-processes photoresists, polymers, and photoactive compounds for microlithography. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., Birnbaum, E., Carbonell, R. G., Crette, S., McClain, J. B., McCleskey, T. M., … Tumas, W. (2004). Carbon dioxide-soluble polymers and swellable polymers for carbon dioxide applications. Washington, DC: U.S. Patent and Trademark Office.

Ahmed, T. S., DeSimone, J. M., & Roberts, G. W. (2004). Continuous precipitation polymerization of vinylidene fluoride in supercritical carbon dioxide: modeling the molecular weight distribution. Chemical Engineering Science, 59(22-23), 5139–5144. https://doi.org/10.1016/j.ces.2004.07.078

Wood, C. D., Cooper, A. I., & DeSimone, J. M. (2004). [Review of Green synthesis of polymers using supercritical carbon dioxide]. CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 8(5), 325–331. https://doi.org/10.1016/j.cossms.2005.02.001

Rolland, J. P., Hagberg, E. C., Denison, G. M., Carter, K. R., & DeSimone, J. M. (2004). High-resolution soft lithography: Enabling materials for nanotechnologies. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 43(43), 5796–5799. https://doi.org/10.1002/anie.200461122

Andre, P., Folk, S. L., Adam, M., Rubinstein, M., & DeSimone, J. M. (2004). Light scattering study of polydimethyl siloxane in liquid and supercritical carbon dioxide. JOURNAL OF PHYSICAL CHEMISTRY A, 108(45), 9901–9907. https://doi.org/10.1021/jp0481308

Siripurapu, S., DeSimone, J. M., Khan, S. A., & Spontak, R. J. (2004). Low-temperature, surface-mediated foaming of polymer films. ADVANCED MATERIALS, 16(12), 989-+. https://doi.org/10.1002/adma.200306068

Lacroix-Desmazes, P., Andre, P., Desimone, J. M., Ruzette, A.-V., & Boutevin, B. (2004). Macromolecular surfactants for supercritical carbon dioxide applications: Synthesis and characterization of fluorinated block copolymers prepared by nitroxide-mediated radical polymerization. Journal of Polymer Science Part A: Polymer Chemistry, 42(14), 3537–3552. https://doi.org/10.1002/pola.20193

DeSimone, J. M., Khan, S. A., Royer, J. R., Spontak, R. J., Walker, T. A., Gay, Y. J., & Siripurapu, S. (2004). Methods of making foamed materials of blended thermoplastic polymers using carbon dioxide. Washington, DC: U.S. Patent and Trademark Office.

Paisner, S. N., & Desimone, J. M. (2004). Micro- and nanoporous materials developed using Supercritical CO2 - Novel synthetic methods for the development of micro- and nanoporous materials toward microelectronic applications. ACS Symposium Series, 874(2004), 223–235. https://doi.org/10.1021/bk-2004-0874.ch017

DeSimone, J. M., Roberts, G. W., & Charpentier, P. A. (2004). Multimodal fluoropolymers and methods of making the same. Washington, DC: U.S. Patent and Trademark Office.

Wood, C. D., Michel, U., Rolland, J. P., & DeSimone, J. A. (2004, November). New fluoropolymer materials. JOURNAL OF FLUORINE CHEMISTRY, Vol. 125, pp. 1671–1676. https://doi.org/10.1016/j.jfluchem.2004.09.029

Visintin, P. M., Bessel, C. A., White, P. S., Schauer, C. K., & DeSimone, J. M. (2005). Oxidative dissolution of copper and zinc metal in carbon dioxide with tert-butyl peracetate and a beta-diketone chelating agent. INORGANIC CHEMISTRY, 44(2), 316–324. https://doi.org/10.1021/ic049765o

DeSimone, J. M., & Keiper, J. S. (2004). Phosphate fluorosurfactants for use in carbon dioxide. Washington, DC: U.S. Patent and Trademark Office.

Keiper, J. S., Behles, J. A., Bucholz, T. L., Simhan, R., DeSimone, J. M., Lynn, G. W., … Frielinghaus, H. (2004). Self-assembly of phosphate fluorosurfactants in carbon dioxide. LANGMUIR, 20(4), 1065–1072. https://doi.org/10.1021/la034742s

Rolland, J. P., Van Dam, R. M., Schorzman, D. A., Quake, SR, & DeSimone, J. M. (2004). Solvent-resistant photocurable "liquid teflon" for microfluidic device fabrication. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 126(8), 2322–2323. https://doi.org/10.1021/ja031657y

Hoggan, E. N., Flowers, D., Wang, K., DeSimone, J. M., & Carbonell, R. G. (2004). Spin coating of photoresists using liquid carbon dioxide. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 43(9), 2113–2122. https://doi.org/10.1021/ie0308543

Lo Celso, F., Triolo, A., Triolo, F., Thiyagarajan, P., Amenitsch, H., Steinhart, M., … Triolo, R. (2003). A combined small-angle neutron and X-ray scattering study of block copolymers micellisation in supercritical carbon dioxide. Journal of Applied Crystallography, 36(3), 660–663. https://doi.org/10.1107/s0021889803003959

Carbonell, R. G., DeSimone, J. M., & Novick, B. J. (2003). Apparatus for meniscus coating with liquid carbon dioxide. Washington, DC: U.S. Patent and Trademark Office.

Michel, U., Resnick, P., Kipp, B., & DeSimone, J. M. (2003). Copolymerization of tetrafluoroethylene and 2,2-bis(trifluoromethyl)-4,5-difluoro-1,3-dioxole in Supercritical carbon dioxide. MACROMOLECULES, 36(19), 7107–7113. https://doi.org/10.1021/ma0344240

Novick, B. J., DeSimone, J. M., & Carbonell, R. G. (2004). Deposition of Thin Polymeric Films from Liquid Carbon Dioxide Using a High-Pressure Free-Meniscus Coating Process. Industrial & Engineering Chemistry Research, 43(2), 515–524. https://doi.org/10.1021/ie030688z

Bessel, C. A., Denison, G. M., DeSimone, J. M., DeYoung, J., Gross, S., Schauer, C. K., & Visintin, P. M. (2003). Etchant solutions for the removal of Cu(0) in a supercritical CO2-based "dry" chemical mechanical planarization process for device fabrication. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 125(17), 4980–4981. https://doi.org/10.1021/ja034091m

DeSimone, J. M., & Tumas, W. (Eds.). (2003). Green Chemistry Using Liquid and Supercritical Carbon Dioxide. New York: Oxford University Press.

Jones, C. A., Yang, D. X., Irene, E. A., Gross, S. M., Wagner, M., DeYoung, J., & DeSimone, J. M. (2003). HF etchant solutions in supercritical carbon dioxide for "Dry" etch processing of microelectronic devices. CHEMISTRY OF MATERIALS, 15(15), 2867–2869. https://doi.org/10.1021/cm034235w

Monge, S., Mas, A., Hamzaoui, A., Kassis, C. M., Desimone, J. M., & Schué, F. (2003). Improvement of silicone endothelialization by treatment with allylamine and/or acrylic acid low-pressure plasma. Journal of Applied Polymer Science, 87(11), 1794–1802. https://doi.org/10.1002/app.11608

Lee, D., Harper, A. S., DeSimone, J. M., & Murray, R. W. (2003). Ion Atmosphere Relaxation Control of Electron Transfer Dynamics in a Plasticized Carbon Dioxide Redox Polyether Melt. Journal of the American Chemical Society, 125(4), 1096–1103. https://doi.org/10.1021/ja0287128

Carbonell, R. G., DeSimone, J. M., & Novick, B. J. (2003). Method for meniscuscoating a substrate with a polymeric precurso. Washington, DC: U.S. Patent and Trademark Office.

Nagashima, K., Lee, C. T., Xu, B., Johnston, K. P., DeSimone, J. M., & Johnson, C. S. (2003). NMR studies of water transport and proton exchange in water-in-carbon dioxide microemulsions. JOURNAL OF PHYSICAL CHEMISTRY B, 107(9), 1962–1968. https://doi.org/10.1021/jp0222705

DeSimone, J. M., Carson, T. J., Shiho, H., & Lizotte, J. (2003). Polymerization of non-fluorinated monomers in carbon dioxide. Washington, DC: U.S. Patent and Trademark Office.

Folk, S. L., & Desimone, J. A. (2003). Polysiloxanes in compressed carbon dioxide. In Synthesis and properties of silicones and silicone-modified materials (Vol. 838, pp. 79–93). https://doi.org/10.1021/bk-2003-0838.ch008

Lee, D., Donkers, R. L., DeSimone, J. M., & Murray, R. W. (2003). Voltammetry and Electron-Transfer Dynamics in a Molecular Melt of a 1.2 nm Metal Quantum Dot. Journal of the American Chemical Society, 125(5), 1182–1183. https://doi.org/10.1021/ja029030n

Kennedy, K. A., Desimone, J. M., & Roberts, G. W. (2002). A commentary on "Carbon dioxide-poly(vinylidene fluoride) interactions at high pressure". JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 40(6), 602–604. https://doi.org/10.1002/polb.10103

Saraf, M. K., Gerard, S., Wojcinski, L. M., Charpentier, P. A., DeSimone, J. M., & Roberts, G. W. (2002). Continuous precipitation polymerization of vinylidene fluoride in supercritical carbon dioxide: Formation of polymers with bimodal molecular weight distributions. MACROMOLECULES, 35(21), 7976–7985. https://doi.org/10.1021/ma0203602

Saraf, M. K., Wojcinski, L. M., Kennedy, K. A., Gerard, S., Charpentier, P. A., DeSimone, J., & Roberts, G. W. (2002, June). Continuous precipitation polymerization of vinylidene fluoride in supercritical carbon dioxide: Molecular weight distribution. MACROMOLECULAR SYMPOSIA, Vol. 182, pp. 119–129. https://doi.org/10.1002/1521-3900(200206)182:1<119::AID-MASY119>3.0.CO;2-P

Flowers, D., Hoggan, E., DeSimone, J. M., & Carbonell, R. (2002). Designing Photoresist Systems for Microlithography in Carbon Dioxide. Materials Research Society Symposium Proceedings, 705, 81–87.

Xu, B., Nagashima, K., DeSimone, J. M., & Johnson, C. S. (2003). Diffusion of water in liquid and supercritical carbon dioxide: An NMR study. JOURNAL OF PHYSICAL CHEMISTRY A, 107(1), 1–3. https://doi.org/10.1021/jp021943g

Henon, F. E., Carbonell, R. G., & DeSimone, J. M. (2002). Effect of polymer coatings from CO2 on water-vapor transport in porous media. AICHE JOURNAL, 48(5), 941–952. https://doi.org/10.1002/aic.690480504

Lee, D., Hutchison, J. C., Leone, A. M., DeSimone, J. M., & Murray, R. W. (2002). Electron and Mass Transport in Hybrid Redox Polyether Melts Contacted with Carbon Dioxide. Journal of the American Chemical Society, 124(31), 9310–9317. https://doi.org/10.1021/ja026209p

Deitzel, J. M., Kosik, W., McKnight, S. H., Beck Tan, N. C., DeSimone, J. M., & Crette, S. (2002). Electrospinning of polymer nanofibers with specific surface chemistry. Polymer, 43(3), 1025–1029. https://doi.org/10.1016/s0032-3861(01)00594-8

Efimenko, K., Novick, B., Carbonell, R. G., DeSimone, J. M., & Genzer, J. (2002). Formation of self-assembled monolayers of semifluorinated and hydrocarbon chlorosilane precursors on silica surfaces from liquid carbon dioxide. LANGMUIR, 18(16), 6170–6179. https://doi.org/10.1021/la011813j

Siripurapu, S., Gay, Y. J., Royer, JR, DeSimone, J. M., Spontak, R. J., & Khan, S. A. (2002). Generation of microcellular foams of PVDF and its blends using supercritical carbon dioxide in a continuous process. POLYMER, 43(20), 5511–5520. https://doi.org/10.1016/S0032-3861(02)00407-X

Lo Celso, F., Triolo, A., Triolo, F., McClain, J., Desimone, J. M., Heenan, R. K., … Triolo, R. (2002). Industrial applications of the aggregation of block copolymers in supercritical CO 2 : a SANS study. Applied Physics A: Materials Science & Processing, 74(0), s1427–s1429. https://doi.org/10.1007/s003390101240

Triolo, A., Lo Celso, F., Triolo, F., Amenitsch, H., Steinhart, M., Thiyagarajan, P., … Triolo, R. (2002). Kinetics of block-copolymer aggregation in super critical CO2. Journal of Non-Crystalline Solids, 307-310, 725–730. https://doi.org/10.1016/s0022-3093(02)01553-3

DeSimone, J. M., Khan, S. A., Royer, J. R., Spontak, R. J., & Walker, T. A. (2002). Method of making foamed materialsUSing surfactants and carbon dioxide. Washington, DC: U.S. Patent and Trademark Office.

Arnold, M. E., Nagai, K., Spontak, R., Freeman, B. D., Leroux, D., Betts, D. E., … al. (2002). Microphase-Separated Block Copolymers Comprising Low Surface Energy Fluorinated Blocks and Hydrophilic Blocks:  Synthesis and Characterization. Macromolecules, 35(9), 3697–3707. https://doi.org/10.1021/ma0119631

Keiper, J. S., Simhan, R., DeSimone, J. M., Wignall, G. D., Melnichenko, Y. B., & Frielinghaus, H. (2002). New phosphate fluorosurfactants for carbon dioxide. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 124(9), 1834–1835. https://doi.org/10.1021/ja0122142

Hoggan, E. N., Novick, B. J., DeSimone, J. M., & Carbonell, R. G. (2002). Novel Electronic Coatings Using Liquid CO2. Semiconductor Fabtech, 16, 169–173.

Royer, JR, Gay, Y. J., Adam, M., DeSimone, J. M., & Khan, S. A. (2002). Polymer melt rheology with high-pressure CO2 using a novel magnetically levitated sphere rheometer. POLYMER, 43(8), 2375–2383. https://doi.org/10.1016/S0032-3861(01)00804-7

Taylor, D. K., Keiper, J. S., & DeSimone, J. M. (2002). Polymer self-assembly in carbon dioxide. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 41(18), 4451–4459. https://doi.org/10.1021/ie010715q

McAllister, K., Sazani, P., Adam, M., Cho, M. J., Rubinstein, M., Samulski, R. J., & DeSimone, J. M. (2002). Polymeric nanogels produced via inverse microemulsion polymerization as potential gene and antisense delivery agents. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 124(51), 15198–15207. https://doi.org/10.1021/ja027759q

DeSimone, J. M. (2002). Practical approaches to green solvents. SCIENCE, 297(5582), 799–803. https://doi.org/10.1126/science.1069622

Carbonell, R. G., & DeSimone, J. M. (2002). Spin cleaning methods. Washington, DC: U.S. Patent and Trademark Office.

Senapati, S., Keiper, J. S., DeSimone, J. M., Wignall, G. D., Melnichenko, Y. B., Frielinghaus, H., & Berkowitz, M. L. (2002). Structure of Phosphate Fluorosurfactant Based Reverse Micelles in Supercritical Carbon Dioxide. Langmuir, 18(20), 7371–7376. https://doi.org/10.1021/la025952s

DeSimone, J. M., & Carbonell, R. G. (2001). Apparatus for liquid carbon dioxide systems. Washington, DC: U.S. Patent and Trademark Office.

Ledford, J., Shultz, C. S., Gates, D. P., White, P. S., DeSimone, J. M., & Brookhart, M. (2001). Bond Angle Effects on the Migratory Insertion of Ethylene and Carbon Monoxide into Palladium(II)−Methyl Bonds in Complexes Bearing Bidentate Phosphine Ligands. Organometallics, 20(25), 5266–5276. https://doi.org/10.1021/om010489k

Wells, S. L., & DeSimone, J. (2001). CO2 Technology Platform: An Important Tool for Environmental Problem Solving. Angewandte Chemie International Edition, 40(3), 518–527. https://doi.org/10.1002/1521-3773(20010202)40:3<518::aid-anie518>3.0.co;2-4

Jones, III, C. A., & DeSimone, J. M. (2001). Critical Phase Polymerizations. In H. Mark (Ed.), Encyclopedia of Polymer Science and Engineering (3rd ed., pp. 111–127). Hoboken: Wiley-Interscience.

Gross, S. M., Bunyard, W. C., Erford, K., Roberts, G. W., Kiserow, D. J., & DeSimone, J. M. (2002). Determination of the equilibrium constant for the reaction between bisphenol A and diphenyl carbonate. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 40(1), 171–178. https://doi.org/10.1002/pola.10098

Behles, J. A., & DeSimone, J. M. (2001). Developments in CO2 research. Pure and Applied Chemistry, 73(8), 1281–1285. https://doi.org/10.1351/pac200173081281

Lee, D., Hutchison, J. C., DeSimone, J. M., & Murray, R. W. (2001). Diffusive Transport of Micelles and Monomeric Solutes in Supercritical CO2. Journal of the American Chemical Society, 123(34), 8406–8407. https://doi.org/10.1021/ja0162818

Shiho, H., & DeSimone, J. M. (2001). Dispersion polymerization of glycidyl methacrylate in supercritical carbon dioxide. MACROMOLECULES, 34(5), 1198–1203. https://doi.org/10.1021/ma0010074

DeSimone, J. M., Carbonell, R. G., Crette, S. A., & Kendall, J. L. (2001). Enzyme catalysis in carbon dioxide fluids. Washington, DC: U.S. Patent and Trademark Office.

Chernyak, Y., Henon, F., Harris, R. B., Gould, R. D., Franklin, R. K., Edwards, JR, … Carbonell, R. G. (2001). Formation of perfluoropolyether coatings by the rapid expansion of supercritical solutions (RESS) process. Part 1: Experimental results. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 40(26), 6118–6126. https://doi.org/10.1021/ie010267m

Shultz, C. S., DeSimone, J. M., & Brookhart, M. (2001). Four- and Five-Coordinate CO Insertion Mechanisms in d8-Nickel(II) Complexes. Journal of the American Chemical Society, 123(37), 9172–9173. https://doi.org/10.1021/ja0160896

Arnold, M. E., Nagai, K., Freeman, B. D., Spontak, R. J., Betts, D. E., DeSimone, J. M., & Pinnau, I. (2001). Gas permeation properties of poly(1,1 '-dihydroperfluorooctyl acrylate), poly(1,1 '-dihydroperfluorooetyl methacrylate), and poly(styrene)-b-poly(1,1 '-dihydroperfluorooctyl acrylate) block copolymers. MACROMOLECULES, 34(16), 5611–5619. https://doi.org/10.1021/ma010355i

Royer, J. R., DeSimone, J. M., & Khan, S. A. (2001). High-pressure rheology and viscoelastic scaling predictions of polymer melts containing liquid and supercritical carbon dioxide. Journal of Polymer Science Part B: Polymer Physics, 39(23), 3055–3066. https://doi.org/10.1002/polb.10057

Crette, S. A., & DeSimone, J. M. (2001). Latest Applications of Compressed Carbon Dioxide. Nachrichten Aus Der Chemie, 49(4), 462–466. https://doi.org/10.1002/nadc.20010490407

Yoshida, E., Wells, S. L., & DeSimone, J. M. (2001). Light scattering study of poly(tert-butyl methacrylate) -block-poly(1,1-dihydroperfluorooctyl methacrylate) in liquid and supercritical carbon dioxide - Towards the reversible control of self-assembly. KOBUNSHI RONBUNSHU, 58(10), 507–513. https://doi.org/10.1295/koron.58.507

DeSimone, J. M., & Carbonell, R. G. (2001). Methods of spin cleaning substrates using carbon dioxide liquid. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J., Selva, M., & Tundo, P. (2001). Nucleophilic Displacements in Supercritical Carbon Dioxide Using Silica-Supported Phase-Transfer Agents. The Journal of Organic Chemistry, 66(11), 4047–4049. https://doi.org/10.1021/jo001337m

Powell, K. R., McCleskey, T. M., Tumas, W., & DeSimone, J. M. (2001). Polymers with Multiple Ligand Sites for Metal Extractions in Dense-Phase Carbon Dioxide†. Industrial & Engineering Chemistry Research, 40(5), 1301–1305. https://doi.org/10.1021/ie000811b

Shi, C., DeSimone, J. M., Kiserow, D. J., & Roberts, G. W. (2001). Reaction Kinetics of the Solid-State Polymerization of Poly(bisphenol A carbonate) Facilitated by Supercritical Carbon Dioxide. Macromolecules, 34(22), 7744–7750. https://doi.org/10.1021/ma011068h

Shi, C. M., Gross, S. M., DeSimone, J. M., Kiserow, D. J., & Roberts, G. W. (2001). Reaction kinetics of the solid state polymerization of poly(bisphenol A carbonate). MACROMOLECULES, 34(7), 2060–2064. https://doi.org/10.1021/ma001942r

Hartshorn, C. M., Maxwell, K. A., White, P. S., DeSimone, J. M., & Meyer, T. J. (2001). Separation of Positional Isomers of Oxidation Catalyst Precursors. Inorganic Chemistry, 40(4), 601–606. https://doi.org/10.1021/ic9911724

Nagai, K., Tanaka, S., Hirata, Y., Nakagawa, T., Arnold, M. E., Freeman, B. D., … DiGiano, F. A. (2001). Solubility and diffusivity of sodium chloride in phase-separated block copolymers of poly(2-dimethylaminoethyl methacrylate), poly (1,1'-dihydroperfluorooctyl methacrylate) and poly(1,1,2,2-tetrahydroperfluorooctyl acrylate). POLYMER, 42(25), 9941–9948. https://doi.org/10.1016/S0032-3861(01)00549-3

Wells, S. L., Taylor, D., Adam, M., DeSimone, J. M., & Farago, B. (2001). Study of the Association of a Diblock Copolymer and Absorption of an Insoluble Homopolymer in CO2. Macromolecules, 34(18), 6161–6163. https://doi.org/10.1021/ma002187k

DeSimone, J. M., & Keiper, J. S. (2001). [Review of Surfactants and self-assembly in carbon dioxide]. CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 5(4), 333–341. https://doi.org/10.1016/s1359-0286(00)00041-3

Carson, T., Wells, S. L., & DeSimone, J. M. (2001). Surfactants for Supercritical and Near-Critical Fluids. In J. Texter (Ed.), Reactions and Synthesis in Surfactant Systems (pp. 129–143). New York: Marcel Dekker, Inc.

Gross, S. M., Roberts, G. W., Kiserov, D. J., & DeSimone, J. M. (2001). Synthesis of high molecular weight polycarbonate by solid-state polymerization. MACROMOLECULES, 34(12), 3916–3920. https://doi.org/10.1021/ma001958h

Fleming, C. N., Maxwell, K. A., DeSimone, J. M., Meyer, T. J., & Papanikolas, J. M. (2001). Ultrafast Excited-State Energy Migration Dynamics in an Efficient Light-Harvesting Antenna Polymer Based on Ru(II) and Os(II) Polypyridyl Complexes. Journal of the American Chemical Society, 123(42), 10336–10347. https://doi.org/10.1021/ja016304i

Bunyard, W. C., Kadla, J. F., & DeSimone, J. M. (2001). Viscosity effects on the thermal decomposition of bis(perfluoro-2-N-propoxypropionyl) peroxide in dense carbon dioxide and fluorinated solvents. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 123(30), 7199–7206. https://doi.org/10.1021/ja0103344

Ye, W. J., Wells, S., & DeSimone, J. M. (2001). Well-defined glycopolyrner amphiphiles for liquid and supercritical carbon dioxide applications. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 39(21), 3841–3849. https://doi.org/10.1002/pola.10018

Goodner, M. D., DeSimone, J. M., Kiserow, D. J., & Roberts, G. W. (2000). An equilibrium model for diffusion-limited solid-state polycondensation. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 39(8), 2797–2806. https://doi.org/10.1021/ie990648o

Goodner, M. D., Gross, S. M., Desimone, J. M., Roberts, G. W., & Kiserow, D. J. (2001). Broadening of molecular-weight distribution in solid-state polymerization resulting from condensate diffusion. JOURNAL OF APPLIED POLYMER SCIENCE, 79(5), 928–943. https://doi.org/10.1002/1097-4628(20010131)79:5<928::AID-APP170>3.0.CO;2-X

Shultz, C. S., DeSimone, J. M., & Brookhart, M. (2001). Cationic Four- and Five-Coordinate Nickel(II) Complexes:  Insights into the Nickel(II)-Catalyzed Copolymerization of Ethylene and Carbon Monoxide. Organometallics, 20(1), 16–18. https://doi.org/10.1021/om0008023

Charpentier, P. A., DeSimone, J. M., & Roberts, G. W. (2000, December). Continuous precipitation polymerization of vinylidene fluoride in supercritical carbon dioxide: Modeling the rate of polymerization. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, Vol. 39, pp. 4588–4596. https://doi.org/10.1021/ie000354z

Triolo, F., Triolo, A., Triolo, R., Betts, D. E., McClain, J. B., De Simone, J. M., … Heenan, R. K. (2000). Critical micellisation density: a SAS structural study of the unimer–aggregate transition of block-copolymers in supercritical CO2. Journal of Applied Crystallography, 33(3), 641–644. https://doi.org/10.1107/s0021889899013539

Triolo, A., Triolo, F., Lo Celso, F., Betts, D. E., McClain, J. B., DeSimone, J. M., … Triolo, R. (2000). Critical micellization density: A small-angle-scattering structural study of the monomer-aggregate transition of block copolymers in supercritical CO2. Physical Review E, 62(4), 5839–5842. https://doi.org/10.1103/physreve.62.5839

Charpentier, P. A., DeSimone, J. M., & Roberts, G. W. (2000). Decomposition of polymerisation initiators in supercritical CO2: a novel approach to reaction kinetics using a CSTR. CHEMICAL ENGINEERING SCIENCE, 55(22), 5341–5349. https://doi.org/10.1016/s0009-2509(00)00148-2

Carson, T., Lizotte, J., & Desimone, J. M. (2000). Dispersion Polymerization of 1-Vinyl-2-pyrrolidone in Supercritical Carbon Dioxide. Macromolecules, 33(6), 1917–1920. https://doi.org/10.1021/ma991222o

Shiho, H., & Desimone, J. M. (2000). Dispersion polymerization of 2-hydroxyethyl methacrylate in supercritical carbon dioxide. Journal of Polymer Science. Part A, Polymer Chemistry, 38(20), 3783–3790. https://doi.org/10.1002/1099-0518(20001015)38:20<3783::AID-POLA90>3.0.CO;2-X

Shiho, H., & DeSimone, J. M. (2000). Dispersion polymerization of acrylonitrile in supercritical carbon dioxide. MACROMOLECULES, 33(5), 1565–1569. https://doi.org/10.1021/ma990737c

Shiho, H., & Desimone, J. M. (2000). Dispersion polymerization of styrene in supercritical carbon dioxide utilizing random copolymers containing a fluorinated acrylate for preparing micron-size polystyrene particles. Journal of Polymer Science. Part A, Polymer Chemistry, 38(7), 1146–1153.

Young, J. L., & DeSimone, J. M. (2000). Frontiers in green chemistry utilizing carbon dioxide for polymer synthesis and applications. Pure and Applied Chemistry, 72(7), 1357–1363. https://doi.org/10.1351/pac200072071357

Royer, J. R., Gay, Y. J., Desimone, J. M., & Khan, S. A. (2000). High-pressure rheology of polystyrene melts plasticized with CO2: Experimental measurement and predictive scaling relationships. Journal of Polymer Science. Part B, Polymer Physics, 38(23), 3168–3180.

Shultz, C. S., Ledford, J., DeSimone, J. M., & Brookhart, M. (2000). Kinetic Studies of Migratory Insertion Reactions at the (1,3-Bis(diphenylphosphino)propane)Pd(II) Center and Their Relationship to the Alternating Copolymerization of Ethylene and Carbon Monoxide. Journal of the American Chemical Society, 122(27), 6351–6356. https://doi.org/10.1021/ja994251n

Carbonel, R. G., DeSimone, J. M., & Henon, F. E. (2000). Method and compositions for protecting civil infrastructure. Washington, DC: U.S. Patent and Trademark Office.

Carbonell, R. G., DeSimone, J. M., & Novick, B. J. (2000). Method for meniscus coating with liquid carbon. Washington, DC: U.S. Patent and Trademark Office.

Carbonell, R. G., DeSimone, J. M., & Novick, B. J. (2000). Method for meniscus coating with liquid carbon dioxide. Washington, DC: U.S. Patent and Trademark Office.

Sykora, M., Maxwell, K. A., DeSimone, J. M., & Meyer, T. J. (2000). Mimicking the antenna-electron transfer properties of photosynthesis. Proceedings of the National Academy of Sciences, 97(14), 7687–7691. https://doi.org/10.1073/pnas.97.14.7687

Taylor, D. K., Carbonell, R., & DeSimone, J. M. (2000). [Review of Opportunities for pollution prevention and energy efficiency enabled by the carbon dioxide technology platform]. ANNUAL REVIEW OF ENERGY AND THE ENVIRONMENT, 25, 115–146. https://doi.org/10.1146/annurev.energy.25.1.115

Shiho, H., & DeSimone, J. M. (2000). Preparation of silicone-graft copolymers by homogeneous radical copolymerization in supercritical carbon dioxide. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 38(7), 1139–1145. https://doi.org/10.1002/(sici)1099-0518(20000401)38:7<1139::aid-pola12>3.0.co;2-3

Triolo, R., Arrighi, V., Triolo, A., Migliardo, P., Magazù, S., McClain, J. B., … Middendorf, H. D. (2000). QENS from polymer aggregates in supercritical CO2. Physica B: Condensed Matter, 276-278, 386–387. https://doi.org/10.1016/s0921-4526(99)01500-8

Shiho, H., & DeSimone, J. M. (2000). Radical polymerizations of a silicone-containing acrylic monomer in supercritical carbon dioxide. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 38(17), 3100–3105. https://doi.org/10.1002/1099-0518(20000901)38:17<3100::AID-POLA110>3.0.CO;2-#

Smith, G. D., Maxwell, K. A., DeSimone, J. M., Meyer, T. J., & Palmer, R. A. (2000). Step-Scan FTIR Time-Resolved Spectroscopy Study of Excited-State Dipole Orientation in Soluble Metallopolymers. Inorganic Chemistry, 39(5), 893–898. https://doi.org/10.1021/ic990819h

Triolo, R., Triolo, A., Triolo, F., Steytler, D. C., Lewis, C. A., Heenan, R. K., … DeSimone, J. M. (2000). Structure of diblock copolymers in supercritical carbon dioxide and critical micellization pressure. Physical Review E, 61(4), 4640–4643. https://doi.org/10.1103/physreve.61.4640

Ye, W., & DeSimone, J. M. (2000). Synthesis of Sugar-Containing Amphiphiles for Liquid and Supercritical Carbon Dioxide. Industrial & Engineering Chemistry Research, 39(12), 4564–4566. https://doi.org/10.1021/ie000184q

Xia, J., Johnson, T., Gaynor, S. G., Matyjaszewski, K., & DeSimone, J. (1999). Atom Transfer Radical Polymerization in Supercritical Carbon Dioxide. Macromolecules, 32(15), 4802–4805. https://doi.org/10.1021/ma9900380

Royer, JR, DeSimone, J. M., & Khan, S. A. (1999). Carbon dioxide-induced swelling of poly( dimethylsiloxane). MACROMOLECULES, 32(26), 8965–8973. https://doi.org/10.1021/ma9904518

Charpentier, P. A., Kennedy, K. A., DeSimone, J. M., & Roberts, G. W. (1999). Continuous Polymerizations in Supercritical Carbon Dioxide:  Chain-Growth Precipitation Polymerizations. Macromolecules, 32(18), 5973–5975. https://doi.org/10.1021/ma990377t

Triolo, F., Triolo, A., Triolo, R., Londono, J. D., Wignall, G. D., McClain, J. B., … DeSimone, J. M. (2000). Critical Micelle Density for the Self-Assembly of Block Copolymer Surfactants in Supercritical Carbon Dioxide. Langmuir, 16(2), 416–421. https://doi.org/10.1021/la990140q

Gross, S. M., Roberts, G. W., Kiserow, D. J., & DeSimone, J. M. (2000). Crystallization and solid-state polymerization of poly(bisphenol A carbonate) facilitated by supercritical CO2. MACROMOLECULES, 33(1), 40–45. https://doi.org/10.1021/ma990901w

DeSimone, J. M., Wei, H.-C., & Romack, T. J. (1999). Fluorination in liquid or supercritical carbon dioxide. Washington, DC: U.S. Patent and Trademark Office.

Maxwell, K. A., Sykora, M., DeSimone, J. M., & Meyer, T. J. (2000). One-Pot Synthesis and Characterization of a Chromophore−Donor−Acceptor Assembly. Inorganic Chemistry, 39(1), 71–75. https://doi.org/10.1021/ic990512i

Bunyard, W. C., Romack, T. J., & DeSimone, J. M. (1999). Perfluoropolyether Synthesis in Liquid Carbon Dioxide by Hexafluoropropylene Photooxidation. Macromolecules, 32(24), 8224–8226. https://doi.org/10.1021/ma981588l

Davidson, T., & DeSimone, J. M. (1999). Polymerizations in Dense Carbon Dioxide. In P. G. Jessop & W. Leitner (Eds.), Chemical Synthesis Using Supercritical Fluids (pp. 297–325). https://doi.org/10.1002/9783527613687.ch15

Kendall, J. L., Canelas, D. A., Young, J. L., & DeSimone, J. M. (1999). Polymerizations in Supercritical Carbon Dioxide. Chemical Reviews, 99(2), 543–564. https://doi.org/10.1021/cr9700336

Shiho, H., & Desimone, J. M. (1999). Preparation of micron-size polystyrene particles in supercritical carbon dioxide. Journal of Polymer Science Part A: Polymer Chemistry, 37(14), 2429–2437. https://doi.org/10.1002/(sici)1099-0518(19990715)37:14<2429::aid-pola17>3.0.co;2-b

Betts, D. E., Canelas, D. A., Cochran, H. D., DeSimone, J. M., Londono, J. D., McClain, J. B., … Wignall, G. D. (1999). Small Angle Neutron Scattering from Polymers in Supercritical Carbon Dioxide. Neutron News, 10(2), 10–15. https://doi.org/10.1080/10448639908233669

Gross, S. M., Flowers, D., Roberts, G., Kiserow, D. J., & DeSimone, J. M. (1999). Solid-State Polymerization of Polycarbonates Using Supercritical CO2. Macromolecules, 32(9), 3167–3169. https://doi.org/10.1021/ma981395y

DeSimone, J. M., & Carbonell, R. G. (1999). Spin coating method and apparatus for liquid carbon dioxide systems. Washington, DC: U.S. Patent and Trademark Office.

Henon, F. E., Camaiti, M., Burke, A. L. C., Carbonell, R. G., DeSimone, J. M., & Piacenti, F. (1999). Supercritical CO2 as a solvent for polymeric stone protective materials. JOURNAL OF SUPERCRITICAL FLUIDS, 15(2), 173–179. https://doi.org/10.1016/S0896-8446(99)00005-4

Betts, D. E., Johnson, T., LeRoux, D., & DeSimone, J. M. (1998). In K. Matyjaszewski (Ed.), Controlled Radical Polymerization (pp. 418–432). Washington, DC: American Chemical Society.

Hoggan, E. N., Carbonell, R. G., DeSimone, J. M., Cramer, G. L., & Stewart, G. M. (1998). Detergent-Aided Cleaning of Metal Surfaces in Liquid Carbon Dioxide. CleanTech98 Proceedings, 137–146. Flemington, NJ: Witter Publishing.

Cain, J. B., Zhang, K., Betts, D. E., DeSimone, J. M., & Johnson, C. S. (1998). Diffusion of Block Copolymers in Liquid CO2:  Evidence of Self-Assembly from Pulsed Field Gradient NMR. Journal of the American Chemical Society, 120(36), 9390–9391. https://doi.org/10.1021/ja981328j

Dardin, A., DeSimone, J. M., & Samulski, E. T. (1998). Fluorocarbons Dissolved in Supercritical Carbon Dioxide. NMR Evidence for Specific Solute−Solvent Interactions. The Journal of Physical Chemistry B, 102(10), 1775–1780. https://doi.org/10.1021/jp972127p

Harrison, K. L., da Rocha, S. R. P., Yates, M. Z., Johnston, K. P., Canelas, D., & DeSimone, J. M. (1998). Interfacial Activity of Polymeric Surfactants at the Polystyrene−Carbon Dioxide Interface. Langmuir, 14(24), 6855–6863. https://doi.org/10.1021/la980323x

Buhler, E., Dobrynin, A. V., DeSimone, J. M., & Rubinstein, M. (1998). Light-Scattering Study of Diblock Copolymers in Supercritical Carbon Dioxide:  CO2Density-Induced Micellization Transition. Macromolecules, 31(21), 7347–7355. https://doi.org/10.1021/ma980442j

Mistele, C., & DeSimone, J. M. (1998). Metal catalysis and processing utilizing carbon dioxide. In P. T. Anastas & T. C. Williamson (Eds.), Green Chemistry: Frontiers in Benign Chemical Synthesis and Processing (pp. 286–312). Oxford, England: Oxford University Press.

Luna-Bárcenas, G., Mawson, S., Takishima, S., DeSimone, J. M., Sanchez, I. C., & Johnston, K. P. (1998). Phase behavior of poly(1,1-dihydroperfluorooctylacrylate) in supercritical carbon dioxide. Fluid Phase Equilibria, 146(1-2), 325–337. https://doi.org/10.1016/s0378-3812(98)00215-5

Canelas, D. A., Betts, D. E., DeSimone, J. M., Yates, M. Z., & Johnston, K. P. (1998). Poly(vinyl acetate) and poly(vinyl acetate-co-ethylene) latexes via dispersion polymerizations in carbon dioxide. MACROMOLECULES, 31(20), 6794–6805. https://doi.org/10.1021/ma980596z

Canelas, D., & De Simone, J. (1998). Polymer shake up. Chemistry in Britain, 34(8), 38–40.

Quadir, M. A., DeSimone, J. M., van Herk, A. M., & German, A. L. (1998). Pulsed-Laser Polymerization of Methyl Methacrylate in Liquid and Supercritical Carbon Dioxide. Macromolecules, 31(19), 6481–6485. https://doi.org/10.1021/ma980658l

Hamilton, J. G., Rooney, J. J., DeSimone, J. M., & Mistele, C. (1998). Stereochemistry of Ring-Opened Metathesis Polymers Prepared in Liquid CO2at High Pressure Using Ru(H2O)6(Tos)2as Catalyst. Macromolecules, 31(13), 4387–4389. https://doi.org/10.1021/ma9715536

Jaimes, C., Arcana, M., Brethon, A., Mathieu, A., Schue, F., & DeSimone, J. M. (1998). Structure and Morphology of Poly([R,S]-beta-butyrolactone) Synthesized from Aluminoxane Catalysts. European Polymer Journal, 34(2), 175–185. https://doi.org/10.1016/S0014-3057(97)00106-7

Gross, S. M., Givens, R. D., Jikei, M., Royer, J. R., Khan, S., DeSimone, J. M., … Hamer, G. K. (1998). Synthesis and Swelling of Poly(bisphenol A carbonate) Using Supercritical CO2. Macromolecules, 31(25), 9090–9092. https://doi.org/10.1021/ma980234r

Gross, S. M., Givens, R. D., Jikei, M., Royer, J. R., Khan, S., Desimone, J. M., … Hamer, G. R. (1998, December 15). Synthesis and swelling of poly(bisphenol A carbonate) using supercritical CO2.

Kassis, C. E., DeSimone, J. M., Linton, R. W., Remsen, E. E., Lange, G. W., & Friedman, R. M. (1997). A Direct Deposition Method for Coupling Matrix-assisted Laser Desorption/Ionization Mass Spectrometry with Gel Permeation Chromatography for Polymer Characterization. Rapid Communications in Mass Spectrometry, 11(10), 1134–1138. https://doi.org/10.1002/(sici)1097-0231(19970630)11:10<1134::aid-rcm910>3.0.co;2-0

Kassis, C. M., DeSimone, J. M., Linton, R. W., Lange, G. W., & Friedman, R. M. (1997). An Investigation into the Importance of Polymer-Matrix Miscibility Using Surfactant Modified Matrix-assisted Laser Desorption/Ionization Mass Spectrometry. Rapid Communications in Mass Spectrometry, 11(13), 1462–1466. https://doi.org/10.1002/(sici)1097-0231(19970830)11:13<1462::aid-rcm44>3.0.co;2-2

Canelas, D. A., Burke, A., & DeSimone, J. M. (1997). Carbon Dioxide as a Continuous Phase for Polymer Synthesis. Plastics Engineering, 53(12), 37–40.

Clark, M. R., Kendall, J. L., & DeSimone, J. M. (1997). Cationic Dispersion Polymerizations in Liquid Carbon Dioxide. Macromolecules, 30(20), 6011–6014. https://doi.org/10.1021/ma9619344

Canelas, D. A., & DeSimone, J. M. (1997). Dispersion Polymerizations of Styrene in Carbon Dioxide Stabilized with Poly(styrene-b-dimethylsiloxane). Macromolecules, 30(19), 5673–5682. https://doi.org/10.1021/ma970579u

Hsiao, Y.-L., & Desimone, J. M. (1997). Dispersion polymerization of methyl methacrylate in supercritical carbon dioxide: Influence of helium concentration on particle size and particle size distribution. Journal of Polymer Science Part A: Polymer Chemistry, 35(10), 2009–2013. https://doi.org/10.1002/(sici)1099-0518(19970730)35:10<2009::aid-pola16>3.0.co;2-k

Quadir, M. A., Snook, R., Gilbert, R. G., & DeSimone, J. M. (1997). Emulsion Polymerization in a Hybrid Carbon Dioxide/Aqueous Medium. Macromolecules, 30(20), 6015–6023. https://doi.org/10.1021/ma970259a

O'Neill, M. L., Yates, M. Z., Harrison, K. L., Johnston, K. P., Canelas, D. A., Betts, D. E., … Wilkinson, S. P. (1997). Emulsion Stabilization and Flocculation in CO2. 1. Turbidimetry and Tensiometry. Macromolecules, 30(17), 5050–5059. https://doi.org/10.1021/ma9616930

Yates, M. Z., O'Neil, M. L., Johnston, K. P., Webber, S., Canelas, D. A., Betts, D. E., & DeSimone, J. M. (1997). Emulsion Stabilization and Flocculation in CO2. 2. Dynamic Light Scattering. Macromolecules, 30(17), 5060–5067. https://doi.org/10.1021/ma961694s

Cooper, A. I., Londono, J. D., Wignall, G., McClain, J. B., Samulski, E. T., Lin, J. S., … DeSimone, J. M. (1997). Extraction of a hydrophilic compound from water into liquid CO2 using dendritic surfactants. Nature, 389(6649), 368–371. https://doi.org/10.1038/38706

Dukes, K. E., Harbron, E. J., Forbes, M. D. E., & DeSimone, J. M. (1997). Flow system and 9.5 GHz microwave resonators for time-resolved and steady-state electron paramagnetic resonance spectroscopy in compressed and supercritical fluids. Review of Scientific Instruments, 68(6), 2505–2510. https://doi.org/10.1063/1.1148149

Dardin, A., Cain, J. B., DeSimone, J. M., Johnson, C. S., & Samulski, E. T. (1997). High-Pressure NMR of Polymers Dissolved in Supercritical Carbon Dioxide. Macromolecules, 30(12), 3593–3599. https://doi.org/10.1021/ma961917e

Mas, A., Jaaba, H., Schue, F., Belu, A. M., Kassis, C. M., Linton, R. W., & Desimone, J. M. (1997). Modification de Surface de Poly  (Hydroxybutyrate-co-9% Hydroxyvalerate) Par Polymerisation Par Plasma d'Alcool Allylique. European Polymer Journal, 33(3), 331–337. https://doi.org/10.1016/s0014-3057(96)00154-1

Tanner, M. J., Brookhart, M., & DeSimone, J. M. (1997). Observation of an Inverse Kinetic Isotope Effect in a Co(III)-Catalyzed Polymerization of Ethylene. Journal of the American Chemical Society, 119(32), 7617–7618. https://doi.org/10.1021/ja971300s

Li, Y., Desimone, J. M., Poon, C.-D., & Samulski, E. T. (1997). Photoinduced graft polymerization of styrene onto polypropylene substrates. Journal of Applied Polymer Science, 64(5), 883–889. https://doi.org/10.1002/(sici)1097-4628(19970502)64:5<883::aid-app8>3.0.co;2-l

Mas, A., Jaaba, H., Schue, F., Belu, A. M., Kassis, C., Linton, R. W., & Desimone, J. M. (1997). Poly(Hydroxybutyrate-co-9% Hydroxyvalerate) Film Surface Modification by Ar, O2, H2,O/O2, H2O, and H2O2 Plasma Treatment. Journal of Macromolecular Science, Part A, 34(1), 67–79. https://doi.org/10.1080/10601329708014935

van Herk, A. M., Manders, B. G., Canelas, D. A., Quadir, M. A., & DeSimone, J. M. (1997). Propagation Rate Coefficients of Styrene and Methyl Methacrylate in Supercritical CO2. Macromolecules, 30(16), 4780–4782. https://doi.org/10.1021/ma9703416

Mawson, S., Johnston, K. P., Betts, D. E., McClain, J. B., & DeSimone, J. M. (1997). Stabilized Polymer Microparticles by Precipitation with a Compressed Fluid Antisolvent. 1. Poly(fluoro acrylates). Macromolecules, 30(1), 71–77. https://doi.org/10.1021/ma961048t

Londono, J. D., Dharmapurikar, R., Cochran, H. D., Wignall, G. D., McClain, J. B., Betts, D. E., … Triolo, R. (1997). The Morphology of Block Copolymer Micelles in Supercritical Carbon Dioxide by Small-Angle Neutron and X-ray Scattering. Journal of Applied Crystallography, 30(5), 690–695. https://doi.org/10.1107/s0021889897002446

Avdievich, N. I., Dukes, K. E., Forbes, M. D. E., & DeSimone, J. M. (1997). Time-Resolved EPR Study of a 1,9-Flexible Biradical Dissolved in Liquid Carbon Dioxide. Observation of a New Spin-Relaxation Phenomenon:  Alternating Intensities in Spin-Correlated Radical Pair Spectra. The Journal of Physical Chemistry A, 101(4), 617–621. https://doi.org/10.1021/jp961947j

Mas, A., Jaaba, H., Schué, F., Belu, A. M., Kassis, C. M., Linton, R. W., & Desimone, J. M. (1997). XPS analysis of poly[(3-hydroxybutyric acid)-co-(3-hydroxyvaleric acid)] film surfaces exposed to an allylamine low-pressure plasma. Macromolecular Chemistry and Physics, 198(11), 3737–3752. https://doi.org/10.1002/macp.1997.021981133

McClain, J. B., Betts, D. E., Canelas, D. A., Samulski, E. T., DeSimone, J. M., Londono, J. D., … Triolo, R. (1996). Design of Nonionic Surfactants for Supercritical Carbon Dioxide. Science, 274(5295), 2049–2052. https://doi.org/10.1126/science.274.5295.2049

Canelas, D. A., Betts, D. E., & DeSimone, J. M. (1996). Dispersion Polymerization of Styrene in Supercritical Carbon Dioxide:  Importance of Effective Surfactants. Macromolecules, 29(8), 2818–2821. https://doi.org/10.1021/ma951642n

Shaffer, K. A., Jones, T. A., Canelas, D. A., DeSimone, J. M., & Wilkinson, S. P. (1996). Dispersion Polymerizations in Carbon Dioxide Using Siloxane-Based Stabilizers. Macromolecules, 29(7), 2704–2706. https://doi.org/10.1021/ma9516798

Belu, A. M., DeSimone, J. M., Linton, R. W., Lange, G. W., & Friedman, R. M. (1996). Evaluation of matrix-assisted laser desorption ionization mass spectrometry for polymer characterization. Journal of the American Society for Mass Spectrometry, 7(1), 11–24. https://doi.org/10.1016/1044-0305(95)00589-7

Mas, A., Jaaba, H., Schué, F., Bellu, A. M., Kassis, C., Linton, R., & Desimone, J. M. (1996). Modification of poly[(3-hydroxybutyric acid)-co-(3-hydroxyvaleric acid)] film surfaces in an oxygen low pressure plasma. Macromolecular Chemistry and Physics, 197(7), 2331–2341. https://doi.org/10.1002/macp.1996.021970723

Chillura-Martino, D., Triolo, R., McClain, J. B., Combes, J. R., Betts, D. E., Canelas, D. A., … Wignall, G. D. (1996). Neutron scattering characterization of homopolymers and graft-copolymer micelles in supercritical carbon dioxide. Journal of Molecular Structure, 383(1-3), 3–10. https://doi.org/10.1016/s0022-2860(96)09260-5

Cooper, A. I., & DeSimone, J. M. (1996). Polymer synthesis and characterization in liquid / supercritical carbon dioxide. Current Opinion in Solid State and Materials Science, 1(6), 761–768. https://doi.org/10.1016/s1359-0286(96)80100-8

Mistele, C. D., Thorp, H. H., & Desimone, J. M. (1996). Ring-Opening Metathesis Polymerizations in Carbon Dioxide. Journal of Macromolecular Science, Part A, 33(7), 953–960. https://doi.org/10.1080/10601329608014644

McClain, J. B., Londono, D., Combes, J. R., Romack, T. J., Canelas, D. A., Betts, D. E., … DeSimone, J. M. (1996). Solution Properties of a CO2-Soluble Fluoropolymer via Small Angle Neutron Scattering. Journal of the American Chemical Society, 118(4), 917–918. https://doi.org/10.1021/ja952750s

Kapellen, K. K., Mistele, C. D., & DeSimone, J. M. (1996). Synthesis of Poly(2,6-dimethylphenylene oxide) in Carbon Dioxide. Macromolecules, 29(1), 495–496. https://doi.org/10.1021/ma951299m

Betts, D. E., McClain, J. B., & DeSimone, J. M. (1996). The importance of surfactants for polymerizations in carbon dioxide. In High Pressure Chemical Engineering, Proceedings of the 3rd International Symposium on High Pressure Chemical Engineering (pp. 23–30). https://doi.org/10.1016/s0921-8610(96)80006-9

Dukes, K. E., Forbes, M. D. E., Jeevarajan, A. S., Belu, A. M., DeSimone, J. M., Linton, R. W., & Sheares, V. V. (1996). Useful Model Systems for the Study of SRN1 Chemistry in the Synthesis of Poly(arylene ether ketone)s. Macromolecules, 29(9), 3081–3089. https://doi.org/10.1021/ma951381h

Kassis, C. M., Steehler, J. K., Betts, D. E., Guan, Z., Romack, T. J., DeSimone, J. M., & Linton, R. W. (1996). XPS Studies of Fluorinated Acrylate Polymers and Block Copolymers with Polystyrene. Macromolecules, 29(9), 3247–3254. https://doi.org/10.1021/ma951782x

Fulton, J. L., Pfund, D. M., McClain, J. B., Romack, T. J., Maury, E. E., Combes, J. R., … Capel, M. (1995). Aggregation of Amphiphilic Molecules in Supercritical Carbon Dioxide: A Small Angle X-ray Scattering Study. Langmuir, 11(11), 4241–4249. https://doi.org/10.1021/la00011a014

DeSimone, J. M. (1995). Branching Out into New Polymer Markets. Science, 269(5227), 1060–1061. https://doi.org/10.1126/science.269.5227.1060

Clark, M. R., & DeSimone, J. M. (1995). Cationic Polymerization of Vinyl and Cyclic Ethers in Supercritical and Liquid Carbon Dioxide. Macromolecules, 28(8), 3002–3004. https://doi.org/10.1021/ma00112a059

Shaffer, K. A., & DeSimone, J. M. (1995). Chain Polymerizations in Inert Near- and Supercritical Fluids. Trends in Polymer Science, 3, 146–153.

Brookhart, M., DeSimone, J. M., Grant, B. E., & Tanner, M. J. (1995). Cobalt(III)-Catalyzed Living Polymerization of Ethylene: Routes to End-Capped Polyethylene with a Narrow Molar Mass Distribution. Macromolecules, 28(15), 5378–5380. https://doi.org/10.1021/ma00119a033

Hsiao, Y.-L., Maury, E. E., DeSimone, J. M., Mawson, S., & Johnston, K. P. (1995). Dispersion Polymerization of Methyl Methacrylate Stabilized with Poly(1,1-dihydroperfluorooctyl acrylate) in Supercritical Carbon Dioxide. Macromolecules, 28(24), 8159–8166. https://doi.org/10.1021/ma00128a028

Mawson, S., Johnston, K. P., Combes, J. R., & DeSimone, J. M. (1995). Formation of Poly(1,1,2,2-tetrahydroperfluorodecyl acrylate) Submicron Fibers and Particles from Supercritical Carbon Dioxide Solutions. Macromolecules, 28(9), 3182–3191. https://doi.org/10.1021/ma00113a021

Romack, T. J., Combes, J. R., & DeSimone, J. M. (1995). Free-Radical Telomerization of Tetrafluoroethylene in Supercritical Carbon Dioxide. Macromolecules, 28(5), 1724–1726. https://doi.org/10.1021/ma00109a057

Romack, T. J., Kipp, B. E., & DeSimone, J. M. (1995). Polymerization of Tetrafluoroethylene in a Hybrid Carbon Dioxide/Aqueous Medium. Macromolecules, 28(24), 8432–8434. https://doi.org/10.1021/ma00128a066

Romack, T. J., Maury, E. E., & DeSimone, J. M. (1995). Precipitation Polymerization of Acrylic Acid in Supercritical Carbon Dioxide. Macromolecules, 28(4), 912–915. https://doi.org/10.1021/ma00108a017

Wignall, G. D., Affholter, K. A., Bunick, G. J., DeSimone, J. M., Hunt, M. O., Menceloglu, Y. Z., & Samulski, E. T. (1995). Synthesis and SANS Structural Characterization of Polymer-Substituted Fullerenes (Flagellenes). Macromolecules, 28(18), 6000–6006. https://doi.org/10.1021/ma00122a003

Romack, T. J., DeSimone, J. M., & Treat, T. A. (1995). Synthesis of Tetrafluoroethylene-Based, Nonaqueous Fluoropolymers in Supercritical Carbon Dioxide. Macromolecules, 28(24), 8429–8431. https://doi.org/10.1021/ma00128a065

Peters, M. A., Belu, A. M., Linton, R. W., Dupray, L., Meyer, T. J., & DeSimone, J. M. (1995). Termination of Living Anionic Polymerizations Using Chlorosilane Derivatives: A General Synthetic Methodology for the Synthesis of End-Functionalized Polymers. Journal of the American Chemical Society, 117(12), 3380–3388. https://doi.org/10.1021/ja00117a008

Rix, F., Barborak, J., Wagner, M., Tahliani, S., Desimone, J., Brookhart, M., & Elder, D. (1995). Transition metal catalyzed alternating copolymerizations of olefins and co. Macromolecular Symposia, 98(1), 219–219. https://doi.org/10.1002/masy.19950980118

DeSimone, J. M., Maury, E. E., Menceloglu, Y. Z., McClain, J. B., Romack, T. J., & Combes, J. R. (1994). Dispersion Polymerizations in Supercritical Carbon Dioxide. Science, 265(5170), 356–359. https://doi.org/10.1126/science.265.5170.356

Belu, A. M., Hunt, M. O., DeSimone, J. M., & Linton, R. W. (1994). End-Functionalized Polymers. 2. Quantification of Functionalization by Time-of-Flight Secondary Ion Mass Spectrometry. Macromolecules, 27(7), 1905–1910. https://doi.org/10.1021/ma00085a037

Guan, Z., & DeSimone, J. M. (1994). Fluorocarbon-Based Heterophase Polymeric Materials. 1. Block Copolymer Surfactants for Carbon Dioxide Applications. Macromolecules, 27(20), 5527–5532. https://doi.org/10.1021/ma00098a002

Combes, J. R., Guan, Z., & DeSimone, J. M. (1994). Homogeneous free-radical polymerizations in carbon dioxide. 3. Telomerization of 1,1-difluoroethylene in supercritical carbon dioxide. Macromolecules, 27(3), 865–867. https://doi.org/10.1021/ma00081a036

Phillips, R. W., Sheares, V. V., Samulski, E. T., & DeSimone, J. M. (1994). Isomeric Poly(benzophenone)s: synthesis of Highly Crystalline Poly(4,4'-benzophenone) and Amorphous Poly(2,5-benzophenone), a Soluble Poly(p-phenylene) Derivative. Macromolecules, 27(8), 2354–2356. https://doi.org/10.1021/ma00086a064

Affholter, K. A., Bunick, G. J., Desimone, J. M., Hunt, M. O., JR., Menceloglu, Y. Z., Samulski, E. T., & Wignall, G. D. (1994). Structural Characterization of a Polymer Substituted Fullerene (Flagellene) by Small Angle Neutron Scattering. MRS Proceedings, 359, 335–340. https://doi.org/10.1557/proc-359-335

Sheares, V. V., DeSimone, J. M., Hedrick, J. L., Carter, K. R., & Labadie, J. W. (1994). Thiophene-based poly(arylene ether)s: 5. Imide-arylene ether statistical copolymers. Polymer, 35(17), 3782–3785. https://doi.org/10.1016/0032-3861(94)90562-2

DeSimone, J. M., & Sheares, V. V. (1993). Clarification of the introduction to the communication "New polymerization methodology: synthesis of thiophene-based poly(arylene ether ketones)". Macromolecules, 26(10), 2642–2642. https://doi.org/10.1021/ma00062a042

Hunt, M. O., Belu, A. M., Linton, R. W., & DeSimone, J. M. (1993). End-functionalized polymers. 1. Synthesis and characterization of perfluoroalkyl-terminated polymers via chlorosilane derivatives. Macromolecules, 26(18), 4854–4859. https://doi.org/10.1021/ma00070a020

Guan, Z., Combes, J. R., Menceloglu, Y. Z., & DeSimone, J. M. (1993). Homogeneous free radical polymerizations in supercritical carbon dioxide: 2. Thermal decomposition of 2,2'-azobis(isobutyronitrile). Macromolecules, 26(11), 2663–2669. https://doi.org/10.1021/ma00063a003

Desimone, J. M., Maury, E. E., Lemert, R. M., & Combes, J. R. (1993). Near- and supercritical fluid solvents for living anionic polymerizations. Makromolekulare Chemie. Macromolecular Symposia, 67(1), 251–260. https://doi.org/10.1002/masy.19930670120

Brennan, A. B., Wang, Y. Q., DeSimone, J. M., Stompel, S., & Samulski, E. T. (1993). Thiophene-based poly(arylene ether ketone)s: 2. Thermal and mechanical properties of amorphous systems using bis(p-fluorobenzoyl)aryl monomers. Polymer, 34(4), 807–812. https://doi.org/10.1016/0032-3861(93)90366-i

Archibald, R. S., Sheares, V. V., Samulski, E. T., & DeSimone, J. M. (1993). Thiophene-based poly(arylene ethers). 4. Synthesis of poly(arylene ether sulfones). Macromolecules, 26(25), 7083–7085. https://doi.org/10.1021/ma00077a057

Linton, R. W., Mawn, M. P., Belu, A. M., DeSimone, J. M., Hunt, M. O., Menceloglu, Y. Z., … Benninghoven, A. (1993). Time-of-flight secondary ion mass spectrometric analysis of polymer surfaces and additives. Surface and Interface Analysis, 20(12), 991–999. https://doi.org/10.1002/sia.740201210

Samulski, E. T., DeSimone, J. M., Hunt, M. O., Menceloglu, Y. Z., Jarnagin, R. C., York, G. A., … Wang, H. (1992). Flagellenes: nanophase-separated, polymer-substituted fullerenes. Chemistry of Materials, 4(6), 1153–1157. https://doi.org/10.1021/cm00024a011

DeSimone, J. M., & Sheares, V. V. (1992). New polymerization methodology: synthesis of thiophene-based heterocyclic polyethers. Macromolecules, 25(16), 4235–4236. https://doi.org/10.1021/ma00042a033

Brookhart, M., Rix, F. C., DeSimone, J. M., & Barborak, J. C. (1992). Palladium(II) catalysts for living alternating copolymerization of olefins and carbon monoxide. Journal of the American Chemical Society, 114(14), 5894–5895. https://doi.org/10.1021/ja00040a082

Bowden, M. J., Gozdz, A. S., DeSimone, J. M., McGrath, J. E., Ito, S., & Matsuda, M. (1992). Reactive-ion etch resistant polysulfones for microlithography. Makromolekulare Chemie. Macromolecular Symposia, 53(1), 125–137. https://doi.org/10.1002/masy.19920530113

Smith, S. D., DeSimone, J. M., Huang, H., York, G., Dwight, D. W., Wilkes, G. L., & McGrath, J. E. (1992). Synthesis and characterization of poly(methyl methacrylate)-g-poly(dimethylsiloxane)copolymers. I. Bulk and surface characterization. Macromolecules, 25(10), 2575–2581. https://doi.org/10.1021/ma00036a002

DeSimone, J. M., Guan, Z., & Elsbernd, C. S. (1992). Synthesis of Fluoropolymers in Supercritical Carbon Dioxide. Science, 257(5072), 945–947. https://doi.org/10.1126/science.257.5072.945

DeSimone, J. M., Stompel, S., Samulski, E. T., Wang, Y. Q., & Brennan, A. B. (1992). Thiophene-containing poly(arylene ether ketones). 1. Polymerization of bis(p-fluorobenzoyl)aryl systems with 4,4'-isopropylidenediphenol. Macromolecules, 25(9), 2546–2550. https://doi.org/10.1021/ma00035a038

Desimone, J. M., Stangle, M., Riffle, J. S., & McGrath, J. E. (1991). Aluminium-27 NMR studies of aluminiumporphyrins. Makromolekulare Chemie. Macromolecular Symposia, 42-43(1), 373–385. https://doi.org/10.1002/masy.19910420131

Lemert, R. M., & Desimone, J. M. (1991). Solvatochromic characterization of near- and supercritical ethane, propane, and dimethyl ether using 9-(α-perfluoroheptyl-β,β-dicyano-vinyl)julolidine. The Journal of Supercritical Fluids, 4(3), 186–193. https://doi.org/10.1016/0896-8446(91)90007-s

DeSimone, J. M., York, G. A., McGrath, J. E., Gozdz, A. S., & Bowden, M. J. (1991). Synthesis, bulk, surface and microlithographic characterization of poly(1-butene sulfone)-g-poly(dimethylsiloxane). Macromolecules, 24(19), 5330–5339. https://doi.org/10.1021/ma00019a019

Siochi, E. J., DeSimone, J. M., Hellstern, A. M., McGrath, J. E., & Ward, T. C. (1990). Dilute solution properties of model PMMA-g-PMMA's. Macromolecules, 23(21), 4696–4706. https://doi.org/10.1021/ma00223a030

Desimone, J. M., Hellstern, A. M., Siochi, E. J., Smith, S. D., Ward, T. C., McGrath, J. E., … Krukonis, V. J. (1990). Homogeneous and multiphase poly(methyl methacrylate) graft polymers via the macromonomer method. Makromolekulare Chemie. Macromolecular Symposia, 32(1), 21–45. https://doi.org/10.1002/masy.19900320105

McGrath, J. E., DeSimone, J. M., Hellstern, A. M., Long, T. E., Hoover, J. M., Smith, S. D., … Riffle, J. (1989). Advances in Heterophase Copolymer Synthesis. In W. Culbertson (Ed.), Multiphase Macromolecular Systems (pp. 213–226). Washington, D. C: American Chemical Society.

DeSimone, J. M., York, G. A., Smith, S. D., Gozdz, A. S., Bowden, M. J., & McGrath, J. E. (1989). Synthesis and Characterization of Poly(1-butene sulfone)-g-Polydimethylsiloxane): A New Electron-Beam Resist for Two-Layer Lithography. Proceedings of the 3rd International SAMPE Electronics Conference, 3, 872–881.

DeSimone, J. M., Hellstern, A. M., Ward, T. C., McGrath, J. E., Smith, S. D., Gallagher, P. M., … Kratochvil, P. (1989). Synthesis, Characterization, and Chemical Composition Distribution Investigations of Graft Copolymers Prepared by the Macromonomer Technique. In W. Culbertson (Ed.), Multiphase Macromolecular Systems (pp. 227–241). Washington, D. C: American Chemical Society.

Tunnicliffe, H., & DeSimone, J. A passion for innovation Joseph DeSimone. Chemical Engineer (London, England), pp. 56–57.

Charpentier, P. A., DeSimone, J. M., & Roberts, G. W. Apparatus for continuous production of polymers in carbon dioxide.

Williams, M. S., & DeSimone, J. M. Carbon dioxide-assisted methods of providing biocompatible intraluminal prostheses. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., Romack, T., Betts, D. E., & McClain, J. B. Cleaning process using carbon dioxide as a solvent and employing molecularly engineered surfactants. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., Romack, T., Betts, D. E., & McClain, J. B. Cleaning process using carbon dioxide as a solvent and employing molecularly engineered surfactants. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., Romack, T. J., Betts, D. E., & McClain, J. B. Cleaning process using carbon dioxide as a solvent and employing molecularly engineered surfactants. Washington, DC: U.S. Patent and Trademark Office.

Carbonell, R. G., DeSimone, J. M., & Henon, F. E. Compositions for protecting civil infrastructure. Washington, DC: U.S. Patent and Trademark Office.

Charpentier, P. A., Desimone, J. M., & Roberts, G. W. Continuous polymerizations in supercritical carbon dioxide. Clean Solvents: Alternative Media for Chemical Reactions and Processing, 819, 113–135.

Charpentier, P. A., DeSimone, J. M., & Roberts, G. W. Continuous process for making polymers in carbon dioxide. Washington, DC: U.S. Patent and Trademark Office.

Williams, M. S., Glenn, R. A., Smith, J. A., Holbrook, K. D., & DeSimone, J. M. Endoprostheses and methods of manufacture. Washington, DC: U.S. Patent and Trademark Office.

Williams, M. S., Glenn, R. A., Smith, J. A., Holbrook, K. D., & DeSimone, J. M. Endoprostheses and methods of manufacture. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., Carson, T. J., Miller, J. F., & Wells, S. Fluorinated copolymer surfactants and use thereof in aerosol compositions. Washington, DC: U.S. Patent and Trademark Office.

Joseph M. DeSimone, W. T. Green chemistry using liquid and supercritical carbon dioxide. New York: Oxford University Press.

DeSimone, J. M., Maury, E. E., Combes, J. R., & Menceloglu, Y. Z. Heterogeneous polymerization in carbon dioxide. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., Maury, E. E., Combes, J. R., & Menceloglu, Y. Z. Heterogeneous polymerization in carbon dioxide. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., Maury, E. E., Combes, J. R., & Menceloglu, Y. Z. Heterogeneous polymerization in carbon dioxide. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., Maury, E. E., Combes, J. R., & Menceloglu, Y. Z. Heterogeneous polymerization in carbon dioxide. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., Maury, E. E. C., J. R., & Menceloglu, Y. A. Heterogeneous polymerization in carbon dioxide. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., Maury, E. E., Combes, J. R., & Menceloglu, Y. Z. Heterogeneous polymerization in carbon dioxide. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., Romack, T. J., Canelas, D. A., & Shaffer, K. A. Heterogeneous polymerizations in carbon dioxide. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., Maury, E. E., Combes, J. R., & Menceloglu, Y. Z. Heterogenous polymerization in carbon dioxide. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., & Williams, M. S. Intraluminal prostheses having polymeric material with selectively modified crystallinity and methods of making same. Washington, DC: U.S. Patent and Trademark Office.

Barborak, J. C., Brookhart, M. S., & DeSimone, J. M. Late transition metal catalysts for the CO- and terpolymerization of olefin and alkyne monomers with carbon monoxide. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., DeYoung, J. P., & McClain, J. B. Method and apparatus for cleaning substrates using liquid carbon dioxide. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., & Romack, T. J. Method for olefin oxidation. Washington, DC: U.S. Patent and Trademark Office.

DeYoung, J. P., McClain, J. B., DeSimone, J. M., & Romack, T. J. Method of dyeing substrates in carbon dioxide. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., Romack, T., Betts, D. E., & McClain, J. B. Method of entraining solid particulates in carbon dioxide fluids. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., & Hunt, M. O. Method of making fluorinated copolymers. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M. Method of making fluoropolymers. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M. Method of making fluoropolymers. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M. Method of making fluoropolymers. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M. Method of making fluoropolymers. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M. Method of making fluoropolymers. Washington, DC: U.S. Patent and Trademark Office.

McClain, J. B., Romack, T. J., DeYoung, J. P., Lienhart, R. B., DeSimone, J. M., & Huggins, K. L. Methods for carbon dioxide dry cleaning with integrated distribution. Washington, DC: U.S. Patent and Trademark Office.

McClain, J. B., Romack, T. J., DeYoung, J. P., Lienhart, R. B., DeSimone, J. M., & Huggins, K. L. Methods for carbon dioxide dry cleaning with integrated distribution. Washington, DC: U.S. Patent and Trademark Office.

DeYoung, J. P., McClain, J. B., Gross, S. M., & Simone, J. M. Methods for cleaning microelectronic structures with aqueous carbon dioxide systems. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., & Maier, G. Methods for solid state polymerizing polyesters utilizing carbon dioxide. Washington, DC: U.S. Patent and Trademark Office.

Royer, J., DeSimone, J. M., Roberts, G. W., & Khan, S. A. Methods of CO2-assisted reactive extrusion. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., & Paisner, S. N. Methods of forming polymeric structures using carbon dioxide and polymeric structures formed therapy. Washington, DC: U.S. Patent and Trademark Office.

McClain, J. B., & DeSimone, J. M. Methods, apparatus and slurries for chemical mechanical planarization. Washington, DC: U.S. Patent and Trademark Office.

McClain, J. B., & DeSimone, J. M. Methods, apparatus and slurries for chemical mechanical planarization. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., & Romack, T. Multi-phase polymerization process. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., & Romack, T. Multi-phase polymerization process. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., & Romack, T. Multi-phase polymerization process. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., & Romack, T. Multi-phase polymerization process. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., & Romack, T. Multi-phase polymerization process. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., & Romack, T. Nonaqueous polymerization of fluoromonomers. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., & Romack, T. Nonaqueous polymerization of fluoromonomers. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., & Romack, T. Nonaqueous polymerization of fluoromonomers. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., & Romack, T. Nonaqueous polymerization of fluoromonomers. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., & Romack, T. Nonaqueous polymerization of fluoromonomers. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., & Mistele, C. D. Olefin metathesis reactions in carbon dioxide medium. Washington, DC: U.S. Patent and Trademark Office.

Khodabandehlou, K., Tian, S. M., Luft, J. C., Khan, S. A., & DeSimone, J. M. Particles for local delivery of proteins using intra-articular route. Advanced Healthcare Materials, 5(6), 653–658.

DeSimone, J. M., & Keiper, J. S. Phosphate fluorosurfactants for use in carbon dioxide. Washington, DC: U.S. Patent and Trademark Office.

Williams, M. S., Holbrook, K. D., Glenn, R. A., Smith, J. A., & DeSimone, J. M. Photocurable endoprosthesis system. Washington, DC: U.S. Patent and Trademark Office.

Royer, J. R., Gay, Y. J., Adam, M., DeSimone, J. M., & Khan, S. A. Polymer melt rheology with high-pressure co<inf>2</inf> using a novel magnetically levitated sphere rheometer. Polymer, 43(8), 2375–2383.

DeSimone, J. M., Tumas, W., Powell, K. R., McCleskey, T. M., Romack, T. J., McClain, J. B., & Birnbaum, E. R. Polymers for metal extractions in carbon dioxide. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M. Positive tone lithography with carbon dioxide development systems. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., & Maier, G. Process for the preparation of polyester in carbon dioxide. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., & Maier, G. Process for the preparation of polyesters in carbon dioxide. Washington, DC: U.S. Patent and Trademark Office.

Khodabandehlou, K., Kumbhar, A. S., Habibi, S., Pandya, A. A., Luft, J. C., Khan, S. A., & DeSimone, J. M. Silylated precision particles for controlled release of proteins. ACS Applied Materials & Interfaces, 7(10), 5756–5767.

DeSimone, J. M., & Y., N. Synthesis of conductive polymers in liquid and supercritical CO.sub.2. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., Givens, R., Jikei, M., & Cohen, J. D. Synthesis of polycarbonates using Co2. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M. The role of diversity in commercializing basic science. Research Technology Management, 57(6), 16–20.

Samulski, E. T., & DeSimone, J. M. Thiophene-based polymers. Washington, DC: U.S. Patent and Trademark Office.

Samulski, E. T., & DeSimone, J. M. Thiophene-based polymers. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., Samulski, E. T., Archibald, R. S., & Sheares, V. V. Thiophene-containing poly(arylene ether) sulfones. Washington, DC: U.S. Patent and Trademark Office.

DeSimone, J. M., Gulari, E., & Manke, C. Use of CO.sub.2 -soluble materials in making molds. Washington, DC: U.S. Patent and Trademark Office.

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