2021 journal article

DFT Analysis of Organotin Catalytic Mechanisms in Dehydration Esterification Reactions for Terephthalic Acid and 2,2,4,4-Tetramethyl-1,3-cyclobutanediol

JOURNAL OF PHYSICAL CHEMISTRY A, 125(23), 4943–4956.

By: J. Clark n, P. Thacker n, C. McGill n, J. Miles n, P. Westmoreland n, K. Efimenko n, J. Genzer n, E. Santiso n

TL;DR: Calculations are used to show that esterification of TMCD and TPA will reduce and subsequently dehydrate a dimethyl tin oxide catalyst, becoming ligands on the now four-coordinate complex, a key first step in understanding polyester synthesis and avoiding undesirable side reactions during production. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID
Added: June 9, 2021

2020 journal article

Dependence of deposition method on the molecular structure and stability of organosilanes revealed from degrafting by tetrabutylammonium fluoride

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 22(2), 658–666.

By: J. Miles n, Y. Ko n & J. Genzer n

TL;DR: Fast degrafting for organosilane SAMs deposited from the vapor phase is observed, indicating that SAMs prepared in this manner form more loosely packed arrays, with less in-plane connectivity, compared to their solution-deposited counterparts. (via Semantic Scholar)
Sources: Web Of Science, ORCID
Added: February 3, 2020

2019 journal article

Determining Water Sorption and Desorption in Thin Hydrophilic Polymer Films by Thermal Treatment

ACS APPLIED POLYMER MATERIALS, 1(9), 2495–2502.

By: Y. Ko n, J. Miles n & J. Genzer n

author keywords: polymer film; ellipsometry; dry thickness; moisture; charge density; CTE; TOC
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID
Added: October 7, 2019

2018 journal article

Kinetic Study of Degrafting Poly(methyl methacrylate) Brushes from Flat Substrates by Tetrabutylammonium Fluoride

MACROMOLECULES, 51(24), 10237–10245.

By: R. Patil n, J. Miles n, Y. Ko n, P. Datta n, B. Rao n, D. Kiserow*, J. Genzer n

Sources: Web Of Science, ORCID
Added: January 14, 2019

2017 journal article

Design and Fabrication of Wettability Gradients with Tunable Profiles through Degrafting Organosilane Layers from Silica Surfaces by Tetrabutylammonium Fluoride

LANGMUIR, 33(51), 14556–14564.

By: J. Miles n, S. Schlenker n, Y. Ko n, R. Patil n, B. Rao n & J. Genzer n

TL;DR: The fabrication of surface wettability gradients on flat surfaces is described by a simple, two-step procedure that permits precise tuning of the gradient profile and observes a relatively homogeneous coverage of silane throughout the degrafting process, providing a much more uniform surface when compared to additive approaches of gradient formation. (via Semantic Scholar)
UN Sustainable Development Goal Categories
14. Life Below Water (OpenAlex)
Sources: Web Of Science, ORCID
Added: August 6, 2018

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