2021 journal article

DFT Analysis of Organotin Catalytic Mechanisms in Dehydration Esterification Reactions for Terephthalic Acid and 2,2,4,4-Tetramethyl-1,3-cyclobutanediol


By: J. Clark n, P. Thacker n, C. McGill n, J. Miles n, P. Westmoreland n, K. Efimenko n, J. Genzer n, E. Santiso n

TL;DR: Calculations are used to show that esterification of TMCD and TPA will reduce and subsequently dehydrate a dimethyl tin oxide catalyst, becoming ligands on the now four-coordinate complex, a key first step in understanding polyester synthesis and avoiding undesirable side reactions during production. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID
Added: June 9, 2021

2020 journal article

Dependence of deposition method on the molecular structure and stability of organosilanes revealed from degrafting by tetrabutylammonium fluoride


By: J. Miles n, Y. Ko n & J. Genzer n

TL;DR: Fast degrafting for organosilane SAMs deposited from the vapor phase is observed, indicating that SAMs prepared in this manner form more loosely packed arrays, with less in-plane connectivity, compared to their solution-deposited counterparts. (via Semantic Scholar)
Sources: Web Of Science, ORCID
Added: February 3, 2020

2019 journal article

Determining Water Sorption and Desorption in Thin Hydrophilic Polymer Films by Thermal Treatment


By: Y. Ko n, J. Miles n & J. Genzer n

author keywords: polymer film; ellipsometry; dry thickness; moisture; charge density; CTE; TOC
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID
Added: October 7, 2019

2018 journal article

Kinetic Study of Degrafting Poly(methyl methacrylate) Brushes from Flat Substrates by Tetrabutylammonium Fluoride

MACROMOLECULES, 51(24), 10237–10245.

By: R. Patil n, J. Miles n, Y. Ko n, P. Datta n, B. Rao n, D. Kiserow*, J. Genzer n

Sources: Web Of Science, ORCID
Added: January 14, 2019

2017 journal article

Design and Fabrication of Wettability Gradients with Tunable Profiles through Degrafting Organosilane Layers from Silica Surfaces by Tetrabutylammonium Fluoride

LANGMUIR, 33(51), 14556–14564.

By: J. Miles n, S. Schlenker n, Y. Ko n, R. Patil n, B. Rao n & J. Genzer n

TL;DR: The fabrication of surface wettability gradients on flat surfaces is described by a simple, two-step procedure that permits precise tuning of the gradient profile and observes a relatively homogeneous coverage of silane throughout the degrafting process, providing a much more uniform surface when compared to additive approaches of gradient formation. (via Semantic Scholar)
UN Sustainable Development Goal Categories
14. Life Below Water (OpenAlex)
Sources: Web Of Science, ORCID
Added: August 6, 2018

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