@article{gupta_echekki_2011, title={One-dimensional turbulence model simulations of autoignition of hydrogen/carbon monoxide fuel mixtures in a turbulent jet}, volume={158}, ISSN={["1556-2921"]}, url={http://www.scopus.com/inward/record.url?eid=2-s2.0-78650171975&partnerID=MN8TOARS}, DOI={10.1016/j.combustflame.2010.09.003}, abstractNote={The autoignition of hydrogen/carbon monoxide in a turbulent jet with preheated co-flow air is studied using the one-dimensional turbulence (ODT) model. The simulations are performed at atmospheric pressure based on varying the jet Reynolds number and the oxidizer preheat temperature for two compositions corresponding to varying the ratios of H2 and CO in the fuel stream. Moreover, simulations for homogeneous autoignition are implemented for similar mixture conditions for comparison with the turbulent jet results. The results identify the key effects of differential diffusion and turbulence on the onset and eventual progress of autoignition in the turbulent jets. The differential diffusion of hydrogen fuels results in a reduction of the ignition delay relative to similar conditions of homogeneous autoignition. Turbulence may play an important role in delaying ignition at high-turbulence conditions, a process countered by the differential diffusion of hydrogen relative to carbon monoxide; however, when ignition is established, turbulence enhances the overall rates of combustion of the non-premixed flame downstream of the ignition point.}, number={2}, journal={COMBUSTION AND FLAME}, author={Gupta, Kamlesh G. and Echekki, Tarek}, year={2011}, month={Feb}, pages={327–344} } @article{echekki_gupta_2009, title={Hydrogen autoignition in a turbulent jet with preheated co-flow air}, volume={34}, ISSN={["1879-3487"]}, url={http://www.scopus.com/inward/record.url?eid=2-s2.0-70349194387&partnerID=MN8TOARS}, DOI={10.1016/j.ijhydene.2009.06.085}, abstractNote={The autoignition of hydrogen in a turbulent jet with preheated air is studied computationally using the stand-alone one-dimensional turbulence (ODT) model. The simulations are based on varying the jet Reynolds number and the mixture pressure. Also, computations are carried out for homogeneous autoignition at different mixture fractions and the same two pressure conditions considered for the jet simulations. The simulations show that autoignition is delayed in the jet configuration relative to the earliest autoignition events in homogeneous mixtures. This delay is primarily due to the presence of scalar dissipation associated with the scalar mixing layer in the jet configuration as well as with the presence of turbulent stirring. Turbulence plays additional roles in the subsequent stages of the autoignition process. Pressure effects also are present during the autoignition process and the subsequent high-temperature combustion stages. These effects may be attributed primarily to the sensitivity of the autoignition delay time to the mixture conditions and the role of pressure and air preheating on molecular transport properties. The overall trends are such that turbulence increases autoignition delay times and accordingly the ignition length and pressure further contribute to this delay.}, number={19}, journal={INTERNATIONAL JOURNAL OF HYDROGEN ENERGY}, author={Echekki, Tarek and Gupta, Kamlesh G.}, year={2009}, month={Oct}, pages={8352–8377} }