@article{chariou_wang_desai_park_robbins_recum_ghiladi_steinmetz_2019, title={Let There Be Light: Targeted Photodynamic Therapy Using High Aspect Ratio Plant Viral Nanoparticles}, volume={19}, ISSN={1616-5187 1616-5195}, url={http://dx.doi.org/10.1002/mabi.201800407}, DOI={10.1002/mabi.201800407}, abstractNote={Abstract}, number={5}, journal={Macromolecular Bioscience}, publisher={Wiley}, author={Chariou, Paul L. and Wang, Lu and Desai, Cian and Park, Jooneon and Robbins, Leanna K. and Recum, Horst A. and Ghiladi, Reza A. and Steinmetz, Nicole F.}, year={2019}, month={Feb}, pages={1800407} }
 @article{robbins_lilly_sommer_ison_2016, title={Effect of the Ancillary Ligand on the Mechanism for CO Migratory Insertion in High-Valent Oxorhenium Complexes}, volume={35}, ISSN={["1520-6041"]}, DOI={10.1021/acs.organomet.6b00570}, abstractNote={Several oxorhenium complexes bearing an SSS pincer ligand were isolated and characterized, and their reactivity with carbon monoxide was explored. The corresponding oxorhenium(V) acyl derivatives were also isolated and characterized. Carbonylation reactions required high pressures (400 psi) and temperatures (50 °C). The mechanism for carbonylation was explored with DFT (M06) calculations and revealed that the most likely mechanism for carbonylation involved stepwise formation of CO adducts followed by migration of the carbonyl ligand to the alkyl/aryl groups.}, number={20}, journal={ORGANOMETALLICS}, publisher={American Chemical Society (ACS)}, author={Robbins, Leanna K. and Lilly, Cassandra P. and Sommer, Roger D. and Ison, Elon A.}, year={2016}, month={Oct}, pages={3530–3537} }
 @article{lambic_lilly_robbins_sommer_ison_2016, title={Reductive Carbonylation of Oxorhenium Hydrides Induced by Lewis Acids}, volume={35}, ISSN={["1520-6041"]}, DOI={10.1021/acs.organomet.6b00393}, abstractNote={Several oxorhenium hydride complexes with chelating diamidopyridine (DAP), diamidoamine (DAAm), and 2-mercaptoethyl sulfide (SSS) groups have been isolated and characterized. Adduct formation is observed when the DAP complex 1a is treated with the Lewis acid B(C6F5)3. However, treatment of 1a,b with B(C6F5)3 or BF3·OEt2 in the presence of CO results in reduction of the metal center by four electrons from Re(V) to Re(I).}, number={17}, journal={ORGANOMETALLICS}, publisher={American Chemical Society (ACS)}, author={Lambic, Nikola S. and Lilly, Cassandra P. and Robbins, Leanna K. and Sommer, Roger D. and Ison, Elon A.}, year={2016}, month={Sep}, pages={2822–2829} }
 @article{robbins_lilly_smeltz_boyle_ison_2015, title={Synthesis and Reactivity of Oxorhenium(V) Methyl, Benzyl, and Phenyl Complexes with CO: Implications for a Unique Mechanism for Migratory Insertion}, volume={34}, ISSN={["1520-6041"]}, DOI={10.1021/acs.organomet.5b00177}, abstractNote={The complexes [(DAAm)Re(O)(R)] [DAAm = N,N-bis(2-arylaminoethyl)methylamine; aryl = C6F5], 1, R = Me; 3a–d (R = benzyl, a; 4-methylbenzyl, b; 4-fluorobenzyl, c; 4-methoxybenzyl, d); and 4, R = Ph, were synthesized. CO insertion into the Re–R bond in 1 and 3a–d resulted in the formation of the acetyl complex, 2, and the (aryl)acetyl complexes, 5a–d respectively. The formation of 5a–d proceeded at a faster rate (7 h) than the formation of 2 (72 h) under the same conditions. No reaction was observed however for the phenyl complex 4 with CO. Kinetics for CO insertion into the various Re–R bonds were examined, and the experimental rate law was determined to be Rate = kobs[Re][CO]. The activation parameters for CO insertion into 1 and 3a were determined to be ΔG⧧(298 K) = 24(1). The enthalpy of activation ΔH⧧ was determined to be 9(1) and 10(3) kcal/mol for 1 and 3a, respectively, and the entropy of activation, ΔS⧧, was −49(2) and −36(4) cal/mol·K. Computational studies (M06) are consistent with the hypothesis ...}, number={13}, journal={ORGANOMETALLICS}, author={Robbins, Leanna K. and Lilly, Cassandra P. and Smeltz, Jessica L. and Boyle, Paul D. and Ison, Elon A.}, year={2015}, month={Jul}, pages={3152–3158} }