James Martin

Diffuse vs. Bragg Scattering: Understanding Structure Using 3-D Pair Distribution Function Analysis

Martin, J. (2020, July). Presented at the American Crystallographic Association.

K-space algorithmic reconstruction (KAREN): a robust statistical methodology to separate Bragg and diffuse scattering

Journal of Applied Crystallography, 53(1), 159–169.

Nutritional supplements comprising dietary metal complexes in a matrix of cellulosic materials

[Provisional Patent].

Particle Size Is a Primary Determinant for Sigmoidal Kinetics of Nanoparticle Formation: A “Disproof” of the Finke–Watzky (F-W) Nanoparticle Nucleation and Growth Mechanism

Chemistry of Materials, 32(8), 3651–3656.

Transition Zone Theory Compared to Standard Models: Reexamining the Theory of Crystal Growth from Melts

The Journal of Physical Chemistry C, 124(34), 18724–18740.

3-D pair distribution function analysis to resolve real structures

Martin, J. (2019, June). Presented at the Neutron Scattering User Meeting, Oak Ridge Lab, Oak Ridge, TN.

Isotope Effects Reveal the Template Influence on the Crystal Growth of a Metal–Halide Network

The Journal of Physical Chemistry C, 123(12), 7475–7485.

Separating Diffuse from Bragg Scattering: Introducing the K-space Algorithmic REconstructioN (KAREN), First integrated workshop on neutron diffuse scattering from single crystals

Martin, J. (2019, June). Presented at the Oak Ridge National Lab, Oak Ridge, TN.

Understanding Cooperativity in Condensed Phase Reactions: Application of Kauzmann’s configurational entropy and Adam and Gibbs’ cooperativity to crystal growth

Martin, J. (2019, June). Poster presented at the Gordon Conference on Crystal Growth and Assembly, Southern New Hampshire University.

A Nonlinear, “Sticky” Web of Study for Chemistry: A Graphical Curricular Tool for Teaching and Learning Chemistry Built upon the Interconnection of Core Chemical Principles

Journal of Chemical Education, 95(12), 2134–2140.

K-Space Algorithmic Reconstruction (KAREN)

In Mantid [Software]. Retrieved from https://docs.mantidproject.org/nightly/algorithms/DeltaPDF3D.html

Teaching and Learning through Exploration and Discovery

Martin, J., & Nock, K. A. (2018, November). Presented at the National Science Teachers Association, Charlotte, NC.

Transition zone theory of the glass transition

Journal of Non-Crystalline Solids, 491, 24–33.

Aligning Practice to Policies: Changing the Culture to Recognize and Reward Teaching at Research Universities

CBE—Life Sciences Education, 16(4), es5.

Aqueous solutions as ionic liquids that can function as tunable solvents. GRIP-NanoMaterials for Water Treatment

Martin, J. (2017, August). Presented at the NCSU interdisciplinary team meeting, Raleigh, NC.

From rate measurements to mechanistic data for condensed matter reactions: a case study using the crystallization of [Zn(OH2)(6)][ZnCl4]

Crystals, 7(1).

Let science be a springboard for politics

Nature, 546(7660), 577–577.

Nanostructure diffraction analysis of a copper/single walled carbon nanotube nanocomposite synthesized by laser surface implanting

Carbon, 113, 1–9.

Teaching and Learning through Exploration and Discovery

Martin, J., & Nock, K. A. (2017, October). Presented at the North Carolina Science Teachers Association, Greensboro, NC.

The Chemistry of Governing

Martin, J. (2017, August). Presented at the American Chemical Society Fall Meeting, Washington D. C.

Transition Zone Theory of Crystal Growth

Martin, J. (2017, November). Presented at the South East Regional Meeting of the American Chemical Society, Charlotte, NC.

Transition Zone Theory of Crystal Growth for melt crystallization applied to low-dimensional, non-stoichiometric, and glass-to-crystal systems

Poster presented at the Gordon Conference on Crystal Growth and Assembly, University of New England, Portland, ME.

From Rate Measurements to Mechanistic Data for Condensed Matter Reactions: A Case Study Using the Crystallization of [Zn(OH2)6][ZnCl4]

Crystals, 7(1), 11.

Ionic Liquid Character of Zinc Chloride Hydrates Define Solvent Characteristics that Afford the Solubility of Cellulose

The Journal of Physical Chemistry B, 120(6), 1134–1141.

Regulation in free amino acid profile and protein synthesis pathway of growing pig skeletal muscles by low-protein diets for different time periods

Journal of Animal Science, 94(12), 5192–5205.

Synthesis of luminescent nitroxobenzene oligomers by aluminum chloride catalyzed dehydration of nitrobenzene

Polyhedron, 103(Part A), 35–43.

Crystalline and Liquid Structure of Zinc Chloride Trihydrate: A Unique Ionic Liquid

Inorganic Chemistry, 54(3), 1109–1119.

Improve undergraduate science education

Nature, 523(7560), 282–284.

Searching for Better Approaches: Effective Evaluation of Teaching and Learning in STEM

Tuson, AZ: Research Corporation for Science Advancement.

Transition Zone Theory of Crystal Growth and Viscosity

Chemistry of Materials, 27(9), 3526–3532.

Understanding the mechanism of crystallization, viscous relaxation and the glass transition

Poster presented at the Gordon Conference on Crystal Growth and Assembly, University of New England, Portland, ME.

University learning: Improve undergraduate science education

Nature, 523(7560), 282–284.

Crystalsim: Gui For Geometrical Simulations Of Crystal Growth

Dill, E., & Martin, J. D. (2014, October 16). (Vol. 10). Vol. 10.

PlasticSim: Simulator For The Plastic Phase Of Carbon Tetrabromide And Calculator For 2-D Reciprocal Space Slices

[Software].

Ramdog: A Graphical User Interface Program To Interactively Analyze 2D Diffraction Images

[Software].

Crystal Growth Simulations To Establish Physically Relevant Kinetic Parameters from the Empirical Kolmogorov–Johnson–Mehl–Avrami Model

Chemistry of Materials, 25(20), 3941–3951.

Experimental Determination of the Crystallization Phase-Boundary Velocity in the Halozeotype CZX-1

Chemistry of Materials, 25(20), 3932–3940.

Review of Cellulose Non-Derivatizing Solvent Interactions with Emphasis on Activity in Inorganic Molten Salt Hydrates

ACS Sustainable Chemistry & Engineering, 1(8), 858–870.

Effect of axial interactions on the formation of mesophases: Comparison of the phase behavior of dialkyl 2,2′-bipyridyl-4,4′-dicarboxylate complexes of Pt(II), Pt(IV), and Pt(II)/Pt(IV) molecular alloys

Chemistry of Materials, 24(23), 4517–4530.

Hydrated Zinc Chloride, a Potential Solvent for Cellulose

Martin, J. (2012, June). Presented at the IUPAC World Polymer Congress, Virginia Polytechnic Institute and State University, Blacksburg, VA.

Undergraduate Science Education: Sustaining Reform Begins with Faculty

Presented at the Cottrell Scholars, Tucson, AZ.

Reassessing the regioregularity of N -(1-naphthyl)- N ′-(n -octadecyl)polycarbodiimide using solution infrared spectroscopy

Macromolecules, 44(12), 5064–5067.

Goldilocks effect in magnetic bistability: Remote substituent modulation and lattice control of photoinduced valence tautomerism and light-induced thermal hysteresis

Journal of the American Chemical Society, 132(17), 6261–6273.

Magnetic bistability in a cobalt bis(dioxolene) complex: Long-lived photoinduced valence tautomerism

Inorganic Chemistry, 49(7), 3162–3168.

Mixed anion (phosphate/oxalate) bonding to iron(III) materials

Journal of the American Chemical Society, 132(7), 2301–2308.

Coupled orientational and displacive degrees of freedom in the high-temperature plastic phase of the carbon tetrabromide α-C Br4

Physical Review B - Condensed Matter and Materials Physics, 77(14).

Report from the third workshop on future directions of solid-state chemistry: The status of solid-state chemistry and its impact in the physical sciences

Progress in Solid State Chemistry, 36(1-2), 1–133.

Effect of matrix crystal structure on ion abundance of carbohydrates by matrix-assisted laser desorption/ionization Fourier transform ion cyclotron resonance mass spectrometry

Rapid Communications in Mass Spectrometry, 21(5), 807–811.

Phosphate bonding configuration on ferrihydrite based on molecular orbital calculations and XANES fingerprinting

Geochimica Et Cosmochimica Acta, 71(18), 4405–4415.

Stability of organically modified montmorillonites and their polystyrene nanocomposites after prolonged thermal treatment

Chemistry of Materials, 19(11), 2757–2767.

A structure and phase analysis investigation of the "1:1" ordered A2InNbO6 perovskites (A=Ca2+, Sr2+, Ba2+)

Journal of Solid State Chemistry, 179(2), 551–562.

Benzene and ethylene binding to copper(I)-ziconium(IV) chloride materials: The crystal structure and solid-state reactivity of ((bz)2Cu) 2Zr2Cl10 · bz

Polyhedron, 25(2), 349–359.

Hydrogen Bonding in Metal Halides: Lattice Effects and Electronic Distortions

In Inorganic Chemistry in Focus III (pp. 267–277).

Metallotropic liquid crystals formed by surfactant templating of molten metal halides

Nature Materials, 5(4), 271–275.

Sorptive reconstruction of CuMCl4 (M = Al and Ga) upon small-molecule binding and the competitive binding of CO and ethylene

Journal of the American Chemical Society, 128(41), 13463–13473.

Amorphous materials engineering: Designing structure in liquid and glassy metal-halide networks

In Ceramic Transactions (Vol. 170, pp. 57–67).

Property and Morphology Development in Nanocomposite Thermoplastic Elastomer Gels

Langmuir, 21(7), 3106–3115.

Tuning the band gap in hybrid tin iodide perovskite semiconductors using structural templating

Inorganic Chemistry, 44(13), 4699–4705.

XANES investigation of phosphate sorption in single and binary systems of iron and aluminum oxide minerals

Environmental Science and Technology, 39(7), 2152–2160.

Morphological, mechanical and gas-transport characteristics of crosslinked poly(propylene glycol): Homopolymers, nanocomposites and blends

Polymer, 45(17), 5941–5950.

Synthesis of [NH4]MnCl2(OAc) and [NH 4]2MnCl4(H2O)2 by Solvothermal Dehydration and Structure/Property Correlations in a One-Dimensional Antiferromagnet

Inorganic Chemistry, 43(10), 3242–3247.

Templated compositions of inorganic liquids and glasses

Washington, DC: U.S. Patent and Trademark Office.

Transport properties of hectorite based nanocomposite single ion conductors

Journal of Power Sources, 128(2), 247–255.

Chemically tuning between ferromagnetism and antiferromagnetism by combining theory and synthesis in iron/manganese rhodium borides

Chemtracts, 16(8), 496–504.

Dynamic disorder and conformer exchange in the crystalline monomer of polycarbonate

Journal of Physical Chemistry B, 107(48), 13293–13299.

Sorptive reconstruction of the CuAlCl4 framework upon reversible ethylene binding

Journal of the American Chemical Society, 125(36), 11065–11079.

Templated compositions of inorganic liquids and glasses

Washington, DC: U.S. Patent and Trademark Office.

Composition dependence of the nucleation energy of iron antimonides from modulated elemental reactants

Chemtracts, 15(1), 17–25.

Designing intermediate-range order in amorphous materials

Nature, 419(6905), 381–384.

Electronic structure, electrical and magnetic properties of RMo8O14 compounds (R = La, Ce, Pr, Nd, Sm) containing bicapped Mo8 clusters

Inorganic Chemistry, 41(18), 4689–4699.

Structure-Property Relationships in Ionic Liquids

In ACS Symposium Series (Vol. 818, pp. 413–427).

Structure-property relationships in ionic liquids

Ionic Liquids: Industrial Applications for Green Chemistry, 818, 413–427.

Synthesis and characterization of Cu2ZrCl6: A thermochromic, van Vleck paramagnet

Journal of Alloys and Compounds, 338(1-2 SPEC.), 173–184.

Toward separation and purification of olefins using dithiolene complexes: An electrochemical approach

Chemtracts, 15(1), 26–31.

Electronic fine tuning of the structures of reduced rare-earth metal halides

Inorganic Chemistry, 40(2), 389–395.

From the wood-shop to crystal engineering: Teaching three-dimensional chemistry

Journal of Chemical Education, 78(9), 1195–1197.

Kinetics and mechanism of the β- to α-CuAlCl4 phase transition: A time-resolved 63Cu MAS NMR and powder x-ray diffraction study

Journal of the American Chemical Society, 123(31), 7564–7573.

Molecular scale characteristics of Cu(II) bonding in goethite-humate complexes

Geochimica Et Cosmochimica Acta, 65(9), 1355–1366.

Synthesis and structural characterization of tricarbomethoxymethanate complexes of copper(II) and barium(II) and evaluation of their suitability for MOCVD applications

New Journal of Chemistry, 25(3), 400–407.

Templated synthesis of cuprous chloride networks: Synthesis and characterization of [Hpy]Cu3Cl6 and {[H3NMe]6Cl}[H3NMe]2Cu 9Cl16

Chemistry of Materials, 13(2), 392–399.

An illuminating framework: Understanding the photoluminescence of α- CuAlCl4

Journal of the American Chemical Society, 121(43), 10092–10097.

Benzene-copper(I) coordination in a bimetallic chain complex

Inorganic Chemistry, 38(26), 6200–6205.

Halo-zeo-type materials

Washington, DC: U.S. Patent and Trademark Office.

Liquid crystalline zinc chloride

Materials Research Society Symposium - Proceedings, 559, 243–248.

Luminescent copper aluminum halide materials

Washington, DC: U.S. Patent and Trademark Office.

Metal halide framework solids: Analogs of aluminosilicates and aluminophosphates

In ACS Symposium Series (Vol. 727, pp. 28–38).

Understanding the photoluminescence of copper aluminum halide phosphors

Materials Research Society Symposium - Proceedings, 560, 39–44.

[H2NMe2]CuZrCl6: Hydrogen-bond induced distortions in a copper zirconium chloride analogue of a thiophosphate

Inorganic Chemistry, 38(10), 2369–2374.

α-K4R6I14Os (R = La, Pr): A novel iodine-rich structure with a layered network of electron-poor clusters. an incipient delocalized system with metal-like conductivity

Inorganic Chemistry, 38(17), 3825–3830.

Beyond the Textbook: A First-Year Introduction to Research at a Research I University

Journal of Chemical Education, 75(3), 325.

Metal Halide Analogues of Chalcogenides: A Building Block Approach to the Rational Synthesis of Solid-State Materials

Chemistry of Materials, 10(10), 2699–2713.

New Condensed Cluster Structure with Triple Metal Layers: La2INi2 and La2ICu2· Synthesis, Structure, and Bonding

Inorganic Chemistry, 37(13), 3385–3390.

The hydrogen-bonded framework of the first anti-zeotype: [{(H2NEt2)2}2(CuCl4)][AlCl4]

Angewandte Chemie - International Edition, 37(23), 3318–3320.

α- and β-CuAlCl4: Framework Construction Using Corner-Shared Tetrahedral Metal-Halide Building Blocks

Inorganic Chemistry, 37(6), 1341–1346.

Halozeotypes: A new generation of zeolite-type materials

Angewandte Chemie - International Edition in English, 36(19), 2072–2075.

Syntheses, crystal structures, and magnetic properties of Sc19Br28Z4 compounds with Z = Mn, Fe, Ru, or Os. Structural and bonding trends in R16X20Z4-type oligomers

Inorganic Chemistry, 36(27), 6413–6422.

Three Types of Condensed Cluster Phases of Rare-Earth Metal Iodides with Transition Metal Interstitials: Pr4I5Ni, Pr3I3Os, Pr2INi2, and La2IZ2

Journal of Solid State Chemistry, 129(2), 277–286.

Two closely related structure types with unprecedented bioctahedral rare-earth-metal clusters centered by transition metals: A2R10I17Z2 (A = Rb, Cs; R = La, Ce, Pr; Z = Co, Ni, Ru, Os) and La10I15Os2

Journal of the American Chemical Society, 119(3), 513–520.

Two new examples for the unusual R12L17z2-structure type: La12i17fe2 and ce12i17mn2

Journal of Solid State Chemistry, 125(2), 249–254.

β-Mn(O2CMe)2: Solvothermal synthesis and crystal structure of an unprecedented three-dimensional manganese(II) network

Chemical Communications, (21), 2419–2420.

LaI: An unprecedented binary rare earth metal monohalide with a NiAs-type structure

Angewandte Chemie (International Edition in English), 34(2), 233–235.

π-Stabilized, yet reactive, half-sandwich Cp*Ru(PR3)X compounds: Synthesis, structure, and bonding

Inorganic Chemistry, 34(2), 488–499.

Covalent linkage of [Mn4O2(O2CPh) 6(dbm)2] into a dimer and a one-dimensional polymer (dbmH = dibenzoylmethane)

Journal of the Chemical Society, Chemical Communications, (5), 671–673.

Novel chain and oligomeric condensed cluster phases for gadolinium Iodides with manganese interstitials

Inorganic Chemistry, 33(10), 2079–2084.

Preparation, crystal structures, conductivities and electronic structures of [et]3[NiCl4]·H2O and [et]3[AuBr4] [et = bis(ethylenedithio)tetrathiafulvalene]

Journal of the Chemical Society, Dalton Transactions, (13), 1995–2004.

Stepwise activation of σ-thienyl ligands at di-tungsten centres

Journal of the Chemical Society, Chemical Communications, (6), 683–684.

A comparison of heterometallic alkoxide molecules containing copper(I) or copper(II) and zirconium

Journal of Organometallic Chemistry, 449(1-2), 191–201.

A new vanadium(V) persulfide complex: (NEt4)[VO(S2)2(bpy)]

Inorganic Chemistry, 32(13), 2978–2980.

A tetranuclear tungsten carbido alkoxide cluster with a hydride ligand: W4(μ-C)(NMe)(OCH2But)11(H)

Journal of Cluster Science, 4(2), 105–117.

Carbon-carbon coupling of a μ-ethynyl ligand with an isocyanide at a ditungsten center. Preparation and structure of W2(μ-CCCNHXyl)(OSiMe2BUt) 5(CNXyl)4, where Xyl = 2,6-Me2C6H3

Organometallics, 12(6), 2354–2359.

Doubly-hydrated hexafluoroacetylacetone as a tetradentate ligand: Synthesis, magnetochemistry, and thermal transformations of a MnIII 2 complex

Inorganic Chemistry, 32(16), 3463–3470.

Structural and electronic study of donors composed of two TTF moieties linked by tellurium bridges

Chemistry of Materials, 5(9), 1199–1203.

Triple bonds between tungsten atoms with ancillary dimesitylboroalkoxide ligands. Preparations, properties and structures of W2(NMe2)4[OB(Mes)2]2 and W2(OBut)4[OB(Mes)2]2

Inorganica Chimica Acta, 213(1-2), 17–24.

Two new structural types for d3-d3 dimers of molybdenum and tungsten: [K(18-crown-6)]+[Mo2(OCH2But)7]- and [W2{P(c-hexyl)2}3(OCH2But)3{HP(c-hexyl)2}]

Polyhedron, 12(3), 343–345.

[Et3PH][W4O3Cl7(PEt3)3]. A 12-electron tetrahedral tungsten cluster with an interesting arrangement of ligands

Journal of Cluster Science, 4(3), 259–269.

A construction principle of the κ-phase based on the efficient (O-H)donor · · · Oanion structural functionality: The examples of κ-(EDT-TTF(CH2OH))2X (X = ClO4 ⊖ and ReO4 ⊖)

Advanced Materials, 4(9), 579–581.

Molecular interactions, band structure, and BEDT-TTF oxidation states in the molecular conductor (BEDT-TTF)3[V(dmit)3]2

Inorganic Chemistry, 31(14), 3176–3178.

The tungsten-tungsten triple bond. 17.1 mixed amido-phosphido compounds of formula M2(PR2)2(NMe2)4. Comparisons of amido and phosphido ligation and bridged and unbridged isomers

Journal of the American Chemical Society, 114(2), 557–570.

The tungsten-tungsten triple bond. 19. Preparation and characterization of W2 6+-containing compounds supported by amide/alkoxide and trifluoromethanesulfonate ligands

Inorganic Chemistry, 31(22), 4469–4474.

Antiperovskite structure with ternary tetrathiafulvalenium salts: Construction, distortion, and antiferromagnetic ordering

Angewandte Chemie (International Edition in English), 30(11), 1498–1500.

Understanding reactivity trends by structural and theoretical studies of distortions in ground-state reagents

Organometallics, 10(9), 3062–3069.

A visible spectrometer

Journal of Chemical Education, 67(12), 1061–1062.

Twelve-electron tetranuclear tungsten alkoxide clusters are not tetrahedral. Preparation, structure and bonding in W4(O)(OPri)10 and W4(O)(Cl)(OPri)9. Comparisons with the bonding in carbonyl clusters

Polyhedron, 9(15-16), 1829–1841.

Comments on the Molecular Structure and Bonding In [W4Cl(O)(OiPr)9] and [W4(O)(OiPr)10]. Analogies with Tetranuclear Carbonyl Clusters

Angewandte Chemie International Edition in English, 28(10), 1368–1370.

Reactions involving carbon dioxide and mixed amido-phosphido dinuclear compounds: M2(NMe2)4(PR2) 2(M≡M), where M = Mo and W. Comparative study of the insertion of carbon dioxide into metal-nitrogen and metal-phosphorus bonds

Journal of the American Chemical Society, 111(21), 8149–8156.

The tungsten-tungsten triple bondXVI. Bis(cyclopentadienyl)- and bis(indenyl)tetradimethylamidoditungsten (WW)

Polyhedron, 7(19-20), 1991–1999.

Unbridged and bridged isomers of W2(PCy2)2(NMe2)4: preparations, characterizations, and comments on thermodynamic and activation parameters for the closing of phosphido bridges in d3-d3 dinuclear compounds

Journal of the American Chemical Society, 110(19), 6563–6565.