@article{zhu_yan_li_cheng_li_liu_mao_cho_gao_gao_et al._2024, title={Recent developments of electrospun nanofibers for electrochemical energy storage and conversion}, volume={65}, ISSN={["2405-8289"]}, DOI={10.1016/j.ensm.2023.103111}, abstractNote={Electrochemical energy storage and conversion systems have received remarkable attention during the past decades because of the high demand of the world energy consumption. Various materials along with the structure designs have been utilized to enhance the overall performance. Among them, nanofibers have been widely explored due to their unique properties (i.e., high surface area, multi-functionality, high porosity, outstanding flexibility, etc.) during the past few decades. Meanwhile, electrospinning, considered a simple and low-cost approach, has attracted tremendous attention because those nanofibrous materials with functional properties prepared by this unique technique can address numerous issues, especially in energy fields. This paper aims to comprehensively review the latest advances in developing advanced electrospun nanofibers for electrochemical devices. It starts with a brief introduction to the advantages of the electrospinning technique. It highlights ongoing research activities, followed by the history of electrospinning, the principle of electrospinning, and the uniqueness of electrospun nanofibers. Afterward, state-of-the-art developments for their applications in electrochemical devices, including but not limited to rechargeable batteries, supercapacitors, fuel cells, solar cells, hydrogen storage, etc., are discussed in detail. A future vision regarding challenges and solutions is proposed at the end. This review aims to provide an extensive and comprehensive reference to apply functional electrospun nanofibers in energy areas.}, journal={ENERGY STORAGE MATERIALS}, author={Zhu, Jiadeng and Yan, Chaoyi and Li, Guoqing and Cheng, Hui and Li, Ya and Liu, Tianyi and Mao, Qian and Cho, Hyunjin and Gao, Qiang and Gao, Chunxia and et al.}, year={2024}, month={Feb} } @misc{zhu_yan_zhang_yang_jiang_zhang_2020, title={A sustainable platform of lignin: From bioresources to materials and their applications in rechargeable batteries and supercapacitors}, volume={76}, ISSN={["1873-216X"]}, DOI={10.1016/j.pecs.2019.100788}, abstractNote={Lignin, as a renewable bioresource, has been widely explored in cellulosic biofuel and several other industries. There are limited applications of lignin in the energy industry, especially in rechargeable batteries and supercapacitors, even though tremendous research work has been done regarding the use of lignin in these fields. It is vital to take lignin into consideration because its usage not only improves the performance of these devices but also reduces the cost, contributing to obtaining more sustainable and greener energy devices. This paper reviews recent developments of lignin-derived materials in rechargeable batteries and supercapacitors. It starts with a brief introduction of the benefits of lignin, followed by the fundamental nature and preparation of lignin-derived materials. Significant attention is paid to applications of lignin-derived materials in rechargeable batteries and supercapacitors including their use as binders and electrodes for rechargeable batteries, and electrodes and electrolytes for supercapacitors with a focus on the mechanisms behind their operation. The goal is to provide a detailed review of the critical aspects related to lignin utilized as an important resource for researchers working in a diverse range of fields dealing with energy storage and conversion. Lastly, a future vision on challenges and their possible solutions are presented.}, journal={PROGRESS IN ENERGY AND COMBUSTION SCIENCE}, author={Zhu, Jiadeng and Yan, Chaoyi and Zhang, Xin and Yang, Chen and Jiang, Mengjin and Zhang, Xiangwu}, year={2020}, month={Jan} } @article{zhu_zang_zhu_lu_chen_jiang_yan_dirican_selvan_kim_et al._2018, title={Effect of reduced graphene oxide reduction degree on the performance of polysulfide rejection in lithium-sulfur batteries}, volume={126}, ISSN={["1873-3891"]}, url={https://publons.com/publon/1678921/}, DOI={10.1016/j.carbon.2017.10.063}, abstractNote={Lithium-sulfur (Li-S) batteries are considered as a promising candidate for large-scale applications such as electrical vehicles (EVs) because of their high theoretical capacity, large energy density and low cost. However, due to the shuttling effect of polysulfides, the continuous capacity fading during cycling remains a substantial bumper for the practical use of Li-S batteries. Here, reduced graphene oxide (rGO) materials with different reduction degrees were used as the polysulfide inhibitor and were coated onto glass fiber separators to minimize the shutting of polysulfides. The influence of reduction degree on the effort of polysulfide rejection was investigated. The incorporation of rGO coating with higher reduction degree largely minimized the polysulfide shuttling, thus the Li-S cells with separators modified with high-reduction degree rGO was able to maintain a capacity of 733 mAh g−1 after 100 cycles and delivered a high capacity of 519 mAh g−1 at 2C, which were 42% and 90% higher than those of cells with separators coated with low-reduction degree rGO. Therefore, it was found that rGO with higher reduction degree demonstrated better polysulfide rejection performance than rGO with lower reduction degree. This study provides a promising strategy in the rGO selection for high-performance Li-S batteries.}, journal={CARBON}, publisher={Elsevier BV}, author={Zhu, Pei and Zang, Jun and Zhu, Jiadeng and Lu, Yao and Chen, Chen and Jiang, Mengjin and Yan, Chaoyi and Dirican, Mahmut and Selvan, R. Kalai and Kim, David and et al.}, year={2018}, month={Jan}, pages={594–600} } @article{chen_li_zhu_lu_jiang_hu_shen_zhang_2017, title={In-situ formation of tin-antimony sulfide in nitrogen-sulfur Co-doped carbon nanofibers as high performance anode materials for sodium-ion batteries}, volume={120}, ISSN={["1873-3891"]}, url={https://doi.org/10.1016/j.carbon.2017.05.072}, DOI={10.1016/j.carbon.2017.05.072}, abstractNote={As potential alternatives to lithium-ion batteries in grid energy storage application, sodium-ion batteries (SIBs) have attracted tremendous attention. Absence of high-performance anode material remains a challenge to commercialize SIBs. Herein, a SnSbSx/porous carbon nanofiber (SnSbSx/PCNF) composite with superior performance is successfully prepared via electrospinning, followed by a sulfuration treatment. The as-prepared SnSbSx/PCNF composite exhibits a unique two-dimensional nano-sheet morphology. As a result, the SnSbSx/PCNFs can deliver a high reversible capacity of 566.7 mAh g−1 after 80 cycles and achieve good cycling stability and rate capability when used as anode materials for SIBs. The improved electrochemical performance of SnSbSx/PCNFs can be ascribed to the synergistic effects of SnSbSx nano-sheets and enhanced diffusion coefficient of Na+ in sulfurated PCNFs (SPCNFs), which can not only provide good electronic conductivity but also buffer the volume change of the SnSbSx nano-sheets during sodiation/desodiation process. Additionally, the sulfuration process generates a sulfur doping effect on the PCNFs, further enhancing their sodium storage ability. Therefore, the excellent Na-storage ability demonstrates SnSbSx/PCNFs a great potential as anode material for high-performance SIBs.}, journal={CARBON}, publisher={Elsevier BV}, author={Chen, Chen and Li, Guoqing and Zhu, Jiadeng and Lu, Yao and Jiang, Mengjin and Hu, Yi and Shen, Zhen and Zhang, Xiangwu}, year={2017}, month={Aug}, pages={380–391} } @article{zhu_ge_kim_lu_chen_jiang_zhang_2016, title={A novel separator coated by carbon for achieving exceptional high performance lithium-sulfur batteries}, volume={20}, ISSN={["2211-3282"]}, url={https://doi.org/10.1016/j.nanoen.2015.12.022}, DOI={10.1016/j.nanoen.2015.12.022}, abstractNote={Lithium-sulfur batteries have received intense attention because of their high theoretical capacity, low cost and environmental friendliness. However, low active material utilization and poor cycle life limit their practical applications. Here, we report a strategy to obtain high capacity with long cycle life and rapid charge rate by introducing a carbon coating on the separator. Excellent cycling performance with a high capacity 956 mAh g−1 after 200 cycles and outstanding high-rate response up to 4 C are achieved, which are among the best reports so far. High electrochemical performance can be obtained even at a high sulfur loading of 3.37 mg cm−2. Such improved results could be ascribed to the conductive carbon coating, which not only reduces the cell resistance but blocks the diffusion of soluble polysulfides avoiding shuttle effect during cycling. This study demonstrates a feasible, low cost and scalable approach to address the long-term cycling challenge for lithium-sulfur batteries.}, journal={NANO ENERGY}, publisher={Elsevier BV}, author={Zhu, Jiadeng and Ge, Yeqian and Kim, David and Lu, Yao and Chen, Chen and Jiang, Mengjin and Zhang, Xiangwu}, year={2016}, month={Feb}, pages={176–184} } @article{chen_li_lu_zhu_jiang_hu_cao_zhang_2016, title={Chemical vapor deposited MoS2/electrospun carbon nanofiber composite as anode material for high-performance sodium-ion batteries}, volume={222}, ISSN={["1873-3859"]}, url={https://publons.com/publon/26924666/}, DOI={10.1016/j.electacta.2016.11.170}, abstractNote={Due to its high theoretical capacity and unique layered structure, MoS2 has attracted attention as a sodium-ion battery anode material. However, the electrochemical performance of MoS2 based anodes is hindered by their low intrinsic conductivity and large volume change during cycling. In this report, nano-sized MoS2 sheets are synthesized using a scalable chemical vapor deposition method on the surface of electrospun carbon nanofibers (CNFs). The morphology of the resultant MoS2@CNFs is investigated by scanning electron microscopy, transmission electron microscopy and X-ray diffraction, while their electrochemical performance is studied using cyclic voltammetry and galvanostatic charge-discharge. The results demonstrate that a strong interconnection between MoS2 nanosheets and CNFs is formed and the conductive network of CNFs is beneficial for the sodium ion kinetics. When investigated as an anode for sodium-ion batteries, a high reversible capacity of 380 mA h g−1 is obtained after 50 cycles with good cycling stability. In particular, MoS2@CNFs can deliver a capacity of 198 mA h g−1 under a high current density of 1 A g−1 after 500 cycles, indicating their great potential as anode material for long-life sodium-ion batteries.}, journal={ELECTROCHIMICA ACTA}, publisher={Elsevier BV}, author={Chen, Chen and Li, Guoqing and Lu, Yao and Zhu, Jiadeng and Jiang, Mengjin and Hu, Yi and Cao, Linyou and Zhang, Xiangwu}, year={2016}, month={Dec}, pages={1751–1760} } @article{zhu_yildirim_aly_shen_chen_lu_jiang_kim_tonelli_pasquinelli_et al._2016, title={Hierarchical multi-component nanofiber separators for lithium polysulfide capture in lithium-sulfur batteries: an experimental and molecular modeling study}, volume={4}, ISSN={["2050-7496"]}, url={http://www.scopus.com/inward/record.url?eid=2-s2.0-84984804707&partnerID=MN8TOARS}, DOI={10.1039/c6ta04577d}, abstractNote={A multi-functional nanofiber membrane significantly improves the overall performance of Li–S batteries.}, number={35}, journal={JOURNAL OF MATERIALS CHEMISTRY A}, publisher={Royal Society of Chemistry (RSC)}, author={Zhu, Jiadeng and Yildirim, Erol and Aly, Karim and Shen, Jialong and Chen, Chen and Lu, Yao and Jiang, Mengjin and Kim, David and Tonelli, Alan E. and Pasquinelli, Melissa A. and et al.}, year={2016}, pages={13572–13581} } @article{zhu_chen_lu_zang_jiang_kim_zhang_2016, title={Highly porous polyacrylonitrile/graphene oxide membrane separator exhibiting excellent anti-self-discharge feature for high-performance lithium-sulfur batteries}, volume={101}, ISSN={["1873-3891"]}, url={https://doi.org/10.1016/j.carbon.2016.02.007}, DOI={10.1016/j.carbon.2016.02.007}, abstractNote={Lithium–sulfur (Li–S) batteries have been considered as a promising candidate for next-generation energy-storage devices due to their high theoretical capacity and energy density. However, the severe self-discharge behavior of Li–S batteries strongly limits their use in practical applications. Here, we report a sustainable and highly porous polyacrylonitrile/graphene oxide (PAN/GO) nanofiber membrane separator that simultaneously enables large capacity and excellent anti-self-discharge capability for lithium–sulfur batteries. A low retention loss (5%) can be achieved even after a resting time of 24 h. Besides benefitting from the highly porous structure and excellent electrolyte wettability of the nanofiber separator, the improved performance can also be ascribed to the excellent barrier effects caused by the relatively high energy binding between –C≡N and Li2S/polysulfides and the electrostatic interactions between GO and negatively charged species (Sn2−). It is, therefore, demonstrated that this GO incorporated PAN nanofiber separator with highly porous structure and excellent electrolyte wettability is a promising separator candidate for high-performance Li–S batteries.}, journal={CARBON}, publisher={Elsevier BV}, author={Zhu, Jiadeng and Chen, Chen and Lu, Yao and Zang, Jun and Jiang, Mengjin and Kim, David and Zhang, Xiangwu}, year={2016}, month={May}, pages={272–280} } @article{jiang_zhu_chen_lu_ge_zhang_2016, title={Poly(vinyl Alcohol) Borate Gel Polymer Electrolytes Prepared by Electrodeposition and Their Application in Electrochemical Supercapacitors}, volume={8}, ISSN={["1944-8244"]}, url={https://publons.com/publon/26924655/}, DOI={10.1021/acsami.5b11984}, abstractNote={Gel polymer electrolytes (GPEs) have been studied for preparing flexible and compact electrochemical energy storage devices. However, the preparation and use of GPEs are complex, and most GPEs prepared through traditional methods do not have good wettability with the electrodes, which retard them from achieving their performance potential. In this study, these problems are addressed by conceiving and implementing a simple, but effective, method of electrodepositing poly(vinyl alcohol) potassium borate (PVAPB) GPEs directly onto the surfaces of active carbon electrodes for electrochemical supercapacitors. PVAPB GPEs serve as both the electrolyte and the separator in the assembled supercapacitors, and their scale and shape are determined solely by the geometry of the electrodes. PVAPB GPEs have good bonding to the active electrode materials, leading to excellent and stable electrochemical performance of the supercapacitors. The electrochemical performance of PVAPB GPEs and supercapacitors can be manipulated simply by adjusting the concentration of KCl salt used during the electrodeposition process. With a 0.9 M KCl concentration, the as-prepared supercapacitors deliver a specific capacitance of 65.9 F g(-1) at a current density of 0.1 A g(-1) and retain more than 95% capacitance after 2000 charge/discharge cycles at a current density of 1 A g(-1). These supercapacitors also exhibit intelligent high voltage self-protection function due to the electrolysis-induced cross-linking effect of PVAPB GPEs.}, number={5}, journal={ACS APPLIED MATERIALS & INTERFACES}, publisher={American Chemical Society (ACS)}, author={Jiang, Mengjin and Zhu, Jiadeng and Chen, Chen and Lu, Yao and Ge, Yeqian and Zhang, Xiangwu}, year={2016}, month={Feb}, pages={3473–3481} } @article{zhu_lu_chen_ge_jasper_leary_li_jiang_zhang_2016, title={Porous one-dimensional carbon/iron oxide composite for rechargeable lithium-ion batteries with high and stable capacity}, volume={672}, ISSN={["1873-4669"]}, url={https://doi.org/10.1016/j.jallcom.2016.02.160}, DOI={10.1016/j.jallcom.2016.02.160}, abstractNote={Hematite iron oxide (α-Fe2O3) is considered to be a prospective anode material for lithium-ion batteries (LIBs) because of its high theoretical capacity (1007 mAh g−1), nontoxicity, and low cost. However, the low electrical conductivity and large volume change during Li insertion/extraction of α-Fe2O3 hinder its use in practical batteries. In this study, carbon-coated α-Fe2O3 nanofibers, prepared via an electrospinning method followed by a thermal treatment process, are employed as the anode material for LIBs. The as-prepared porous nanofibers with a carbon content of 12.5 wt% show improved cycling performance and rate capability. They can still deliver a high and stable capacity of 715 mAh g−1 even at superior high current density of 1000 mA g−1 after 200 cycles with a large Coulombic efficiency of 99.2%. Such improved electrochemical performance can be assigned to their unique porous fabric structure as well as the conductive carbon coating which shorten the distance for Li ion transport, enhancing Li ion reversibility and kinetic properties. It is, therefore, demonstrated that carbon-coated α-Fe2O3 nanofiber prepared under optimized conditions is a promising anode material candidate for LIBs.}, journal={JOURNAL OF ALLOYS AND COMPOUNDS}, publisher={Elsevier BV}, author={Zhu, Jiadeng and Lu, Yao and Chen, Chen and Ge, Yeqian and Jasper, Samuel and Leary, Jennifer D. and Li, Dawei and Jiang, Mengjin and Zhang, Xiangwu}, year={2016}, month={Jul}, pages={79–85} } @article{jiang_zhu_chen_lu_pampal_luo_zhu_zhang_2016, title={Superior high-voltage aqueous carbon/ carbon supercapacitors operating with in situ electrodeposited polyvinyl alcohol borate gel polymer electrolytes}, volume={4}, ISSN={["2050-7496"]}, url={https://publons.com/publon/26924664/}, DOI={10.1039/c6ta07063a}, abstractNote={The special ionic conductive mechanism of aqueous polyvinyl alcohol borate gel polymer electrolytes leads to their high operating voltages.}, number={42}, journal={JOURNAL OF MATERIALS CHEMISTRY A}, publisher={Royal Society of Chemistry (RSC)}, author={Jiang, Mengjin and Zhu, Jiadeng and Chen, Chen and Lu, Yao and Pampal, Esra Serife and Luo, Lei and Zhu, Pei and Zhang, Xiangwu}, year={2016}, pages={16588–16596} }