@article{liu_chen_hood_taniguchi_diers_bocian_holten_lindsey_2017, title={Synthesis, photophysics and electronic structure of oxobacteriochlorins}, volume={41}, ISSN={["1369-9261"]}, url={http://www.scopus.com/inward/record.url?eid=2-s2.0-85022033561&partnerID=MN8TOARS}, DOI={10.1039/c6nj04135c}, abstractNote={Synthetic oxobacteriochlorins exhibit strong absorption in the deep-red window flanked by chlorins to the red and bacteriochlorins to the near-infrared.}, number={10}, journal={NEW JOURNAL OF CHEMISTRY}, publisher={Royal Society of Chemistry (RSC)}, author={Liu, Mengran and Chen, Chih-Yuan and Hood, Don and Taniguchi, Masahiko and Diers, James R. and Bocian, David F. and Holten, Dewey and Lindsey, Jonathan S.}, year={2017}, month={May}, pages={3732–3744} } @article{zhang_jiang_liu_taniguchi_mandal_evans-storms_pitner_bocian_holten_lindsey_2016, title={Bioconjugatable, PEGylated hydroporphyrins for photochemistry and photomedicine. Narrow-band, near-infrared-emitting bacteriochlorins}, volume={40}, ISSN={["1369-9261"]}, url={http://www.scopus.com/inward/record.url?eid=2-s2.0-84984904482&partnerID=MN8TOARS}, DOI={10.1039/c6nj01155a}, abstractNote={PEGylated bacteriochlorins are soluble in water, can be excited in the ultraviolet, and exhibit a narrow fluorescence band in the NIR spectral region.}, number={9}, journal={NEW JOURNAL OF CHEMISTRY}, author={Zhang, Nuonuo and Jiang, Jianbing and Liu, Mengran and Taniguchi, Masahiko and Mandal, Amit Kumar and Evans-Storms, Rosemary B. and Pitner, J. Bruce and Bocian, David F. and Holten, Dewey and Lindsey, Jonathan S.}, year={2016}, pages={7750–7767} } @article{liu_chen_mandal_chandrashaker_evans-storms_pitner_bocian_holten_lindsey_2016, title={Bioconjugatable, PEGylated hydroporphyrins for photochemistry and photomedicine. Narrow-band, red-emitting chlorins}, volume={40}, ISSN={["1369-9261"]}, DOI={10.1039/c6nj01154c}, abstractNote={PEGylated chlorins are soluble in water, can be excited in the near-ultraviolet, and exhibit a relatively narrow fluorescence band in the red spectral region.}, number={9}, journal={NEW JOURNAL OF CHEMISTRY}, author={Liu, Mengran and Chen, Chih-Yuan and Mandal, Amit Kumar and Chandrashaker, Vanampally and Evans-Storms, Rosemary B. and Pitner, J. Bruce and Bocian, David F. and Holten, Dewey and Lindsey, Jonathan S.}, year={2016}, pages={7721–7740} } @article{mandal_sahin_liu_lindsey_bocian_holten_2016, title={Photophysical comparisons of PEGylated porphyrins, chlorins and bacteriochlorins in water}, volume={40}, ISSN={["1369-9261"]}, DOI={10.1039/c6nj02091g}, abstractNote={Synthesis of a bioconjugatable water-soluble (PEGylated) trans-AB-porphyrin enables photophysical comparisons (τS, kf, kic, kisc, Φf, Φic, Φisc) with analogous chlorins and bacteriochlorins in DMF and water.}, number={11}, journal={NEW JOURNAL OF CHEMISTRY}, author={Mandal, Amit Kumar and Sahin, Tuba and Liu, Mengran and Lindsey, Jonathan S. and Bocian, David F. and Holten, Dewey}, year={2016}, pages={9648–9656} } @article{yuen_harris_liu_diers_kirmaier_bocian_lindsey_holten_2015, title={Effects of Substituents on Synthetic Analogs of Chlorophylls. Part 4: How Formyl Group Location Dictates the Spectral Properties of Chlorophylls b, d and f}, volume={91}, ISSN={["1751-1097"]}, DOI={10.1111/php.12401}, abstractNote={AbstractPhotosynthetic organisms are adapted to light characteristics in their habitat in part via the spectral characteristics of the associated chlorophyll pigments, which differ in the position of a formyl group around the chlorin macrocycle (chlorophylls b, d, f) or no formyl group (chlorophyll a). To probe the origin of this spectral tuning, the photophysical and electronic structural properties of a new set of synthetic chlorins are reported. The zinc and free base chlorins have a formyl group at either the 2‐ or 3‐position. The four compounds have fluorescence yields in the range 0.19–0.28 and singlet excited‐state lifetimes of ca 4 ns for zinc chelates and ca 8 ns for the free base forms. The photophysical properties of the 2‐ and 3‐formyl zinc chlorins are similar to those observed previously for 13‐formyl or 3,13‐diformyl chlorins, but differ markedly from those for 7‐formyl analogs. Molecular‐orbital characteristics obtained from density functional theory (DFT) calculations were used as input to spectral simulations employing the four‐orbital model. The analysis has uncovered the key changes in electronic structure engendered by the presence/location of a formyl group at various macrocycle positions, which is relevant to understanding the distinct spectral properties of the natural chlorophylls a, b, d and f.}, number={2}, journal={PHOTOCHEMISTRY AND PHOTOBIOLOGY}, author={Yuen, Jonathan M. and Harris, Michelle A. and Liu, Mengran and Diers, James R. and Kirmaier, Christine and Bocian, David F. and Lindsey, Jonathan S. and Holten, Dewey}, year={2015}, pages={331–342} } @article{liu_ptaszek_mass_minkler_sommer_bhaumik_lindsey_2014, title={Regioselective beta-pyrrolic electrophilic substitution of hydrodipyrrin-dialkylboron complexes facilitates access to synthetic models for chlorophyll f}, volume={38}, number={4}, journal={New Journal of Chemistry}, author={Liu, M. R. and Ptaszek, M. and Mass, O. and Minkler, D. F. and Sommer, R. D. and Bhaumik, J. and Lindsey, J. S.}, year={2014}, pages={1717–1730} }