Works (132)

Updated: April 4th, 2024 15:45

2024 article

Rapid screening of dyes for self-aggregation, adsorption and metabolic integrity - Quantitative metrics as a prelude to biological studies

Liu, Q., Taniguchi, M., Goel, S., & Lindsey, J. S. (2024, April). DYES AND PIGMENTS, Vol. 223.

By: Q. Liu n, M. Taniguchi n, S. Goel* & J. Lindsey n

author keywords: Aqueous; Beer's law; Chromophore; Drug development; Hepatic metabolism; logP; Membranes; Non-specific binding; Resins
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: ORCID, Web Of Science, NC State University Libraries
Added: February 1, 2024

2023 journal article

Absorption and fluorescence spectra of open-chain tetrapyrrole pigments-bilirubins, biliverdins, phycobilins, and synthetic analogues

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS, 55.

By: M. Taniguchi n & J. Lindsey n

author keywords: Bile pigment; Bilin; Biliprotein; Luciferin; Phycobilin; Phyllobilin; Phytochrome
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 21, 2023

2023 journal article

Bacteriochlorin syntheses - Status, problems, and exploration

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 8.

By: V. Tran n, P. Wang n, N. Matsumoto n, S. Liu n, H. Jing n, P. Nalaoh n, K. Nguyen n, M. Taniguchi n, J. Lindsey n

author keywords: bacteriochlorophyll; dihydrodipyrrin; dyad; pyrrole; pyrroline; near-infrared
Sources: Web Of Science, NC State University Libraries, ORCID
Added: September 5, 2023

2023 review

Digital Database of Absorption Spectra of Diverse Flavonoids Enables Structural Comparisons and Quantitative Evaluations

[Review of ]. JOURNAL OF NATURAL PRODUCTS, 86(4), 1087–1119.

By: M. Taniguchi n, C. LaRocca n, J. Bernat n & J. Lindsey n

MeSH headings : Humans; Flavonoids / chemistry; Flavones; Plants / chemistry; Genistein
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: ORCID, Web Of Science, NC State University Libraries
Added: February 28, 2023

2023 journal article

Four Routes to 3-(3-Methoxy-1,3-dioxopropyl)pyrrole, a Core Motif of Rings C and E in Photosynthetic Tetrapyrroles

MOLECULES, 28(3).

By: K. Nguyen n, A. Tran n, P. Wang n, S. Zhang n, Z. Wu n, M. Taniguchi n, J. Lindsey n

author keywords: acylation; bacteriochlorophyll; beta-ketoester; Boc-pyrrole; carbonylation; chlorophyll; synthesis; TIPS-pyrrole
MeSH headings : Tetrapyrroles; Pyrroles / chemistry; Chlorophyll / chemistry; Bacteriochlorophylls / chemistry; Photosynthesis
Sources: ORCID, Web Of Science, NC State University Libraries
Added: January 31, 2023

2023 review

Tolyporphins-Exotic Tetrapyrrole Pigments in a Cyanobacterium-A Review

[Review of ]. MOLECULES, 28(16).

By: K. Nguyen n, Y. Zhang n, Q. Liu n, R. Zhang n, X. Jin n, M. Taniguchi n, E. Miller n, J. Lindsey n

author keywords: bacteriochlorin; bioinformatics; biosynthesis; chlorophyll; cyanobacteria; field biology; gene cluster; genomics; natural products; tolyporphins
TL;DR: The identification of putative biosynthetic gene clusters in the HT-58-2 cyanobacterial genome and accompanying studies suggest a new biosynthesis paradigm in the tetrapyrrole arena, which stands alone in the large pigments-of-life family. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: October 2, 2023

2022 article

Balancing Panchromatic Absorption and Multistep Charge Separation in a Compact Molecular Architecture br

Roy, A., Magdaong, N. C. M., Jing, H., Rong, J., Diers, J. R., Kang, H. S., … Holten, D. (2022, December 12). JOURNAL OF PHYSICAL CHEMISTRY A, Vol. 12.

By: A. Roy*, N. Magdaong*, H. Jing n, J. Rong n, J. Diers*, H. Kang*, D. Niedzwiedzki, M. Taniguchi n ...

Contributors: A. Roy*, N. Magdaong*, H. Jing n, J. Rong n, J. Diers*, H. Kang*, D. Niedzwiedzki, M. Taniguchi n ...

MeSH headings : Perylene; Porphyrins; Electron Transport; Imides
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: ORCID, Web Of Science, NC State University Libraries
Added: December 13, 2022

2022 journal article

Beyond green with synthetic chlorophylls - Connecting structural features with spectral properties

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS, 52.

By: M. Taniguchi n, D. Bocian*, D. Holten* & J. Lindsey n

Contributors: M. Taniguchi n, D. Bocian*, D. Holten* & J. Lindsey n

author keywords: Chlorin; Chlorophyll; Four-orbital model; Molar absorption coefficient; Photosynthesis; Quantum yield; Wavelength
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: July 18, 2022

2022 article

Chasing the green echiuran worm Bonellia in tidal pools of Okinawa

FRONTIERS IN BIOLOGICAL DETECTION: FROM NANOSENSORS TO SYSTEMS XIV, Vol. 11979.

By: M. Taniguchi n, M. Taniguchi*, R. Zhang n, R. Goto* & J. Lindsey n

Contributors: M. Taniguchi n, M. Taniguchi*, R. Zhang n, R. Goto* & J. Lindsey n

author keywords: biodiversity; Bonellia viridis; bonellin; chlorophyll; spoon worms; tetrapyrrole; tides
TL;DR: Assessment of information concerning tides at a wide shallow beach in Okinawa is reported, identifying narrowly restricted periods when acquisition of Bonellia specimens could be pursued without diving to expand study of the diversity of these unusual green worms. (via Semantic Scholar)
UN Sustainable Development Goal Categories
14. Life Below Water (Web of Science; OpenAlex)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 15, 2022

2022 journal article

Panchromatic Absorbers Tethered for Bioconjugation or Surface Attachment

MOLECULES, 27(19).

Contributors: R. Liu n, J. Rong n, Z. Wu n, M. Taniguchi n, D. Bocian*, D. Holten*, J. Lindsey n

author keywords: array; artificial photosynthesis; building block; copper-free Sonogashira coupling; ethyne; perylene; porphyrin; solar
MeSH headings : Perylene; Porphyrins
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: October 24, 2022

2022 review

Phenylene-linked tetrapyrrole arrays containing free base and diverse metal chelate forms - Versatile synthetic architectures for catalysis and artificial photosynthesis

[Review of ]. COORDINATION CHEMISTRY REVIEWS, 456.

By: H. Jing n, J. Rong n, M. Taniguchi n & J. Lindsey n

Contributors: H. Jing n, J. Rong n, M. Taniguchi n & J. Lindsey n

author keywords: Bacteriochlorin; Chlorin; Electron; hole transfer; FRET; Light-harvesting; Porphyrin; Rational synthesis; Photophysics
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: May 10, 2022

2022 article

Phyllobilins - Bioactive Natural Products Derived from Chlorophyll - Plant Origins, Structures, Absorption Spectra, and Biomedical Properties

Karg, C. A., Taniguchi, M., Lindsey, J. S., & Moser, S. (2022, December 8). PLANTA MEDICA, Vol. 12.

By: C. Karg*, M. Taniguchi n, J. Lindsey n & S. Moser*

Contributors: C. Karg*, M. Taniguchi n, J. Lindsey n & S. Moser*

author keywords: Bioactivity; chlorophyll catabolites; micronutrients; phyllobilins; phytochemicals; spectral database
MeSH headings : Humans; Chlorophyll / analysis; Chlorophyll / chemistry; Chlorophyll / metabolism; Chlorophyll A / metabolism; Plants / metabolism; Oxidation-Reduction; Plant Extracts / chemistry; Phytochemicals / chemistry
TL;DR: The present review describes the plant origin, molecular structure, and absorption and fluorescence features of the 73 phyllobilins, along with an overview of key medicinal properties, to provide an enabling tool for the community for the straightforward identification of phyll Mobilins in plant extracts. (via Semantic Scholar)
UN Sustainable Development Goal Categories
2. Zero Hunger (OpenAlex)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: January 3, 2023

2022 article

Simple Dipyrrin Analogues of Prodigiosin for Use as Colistin Adjuvants

Siwawannapong, K., Nemeth, A. M., Melander, R. J., Rong, J., Davis, J. R., Taniguchi, M., … Melander, C. (2022, July 8). CHEMMEDCHEM, Vol. 7.

By: K. Siwawannapong n, A. Nemeth*, R. Melander*, J. Rong n, J. Davis n, M. Taniguchi n, M. Carpenter*, J. Lindsey n, C. Melander*

Contributors: K. Siwawannapong n, A. Nemeth*, R. Melander*, J. Rong n, J. Davis n, M. Taniguchi n, M. Carpenter*, J. Lindsey n, C. Melander*

author keywords: dipyrrin; colistin; adjuvant; antibiotic resistance; gram negative
MeSH headings : Acinetobacter baumannii; Adjuvants, Pharmaceutic / pharmacology; Anti-Bacterial Agents / pharmacology; Anti-Bacterial Agents / therapeutic use; Colistin / pharmacology; Drug Resistance, Multiple, Bacterial; Microbial Sensitivity Tests; Prodigiosin / pharmacology; Pseudomonas aeruginosa
TL;DR: A series of dipyrrins and pyrrole derivatives designed as analogues of prodigiosin and obatoclax potentiate the activity of colistin against Klebsiella pneumoniae, with lead compounds also potentiating colist in against Acinetobacter baumannii and Pseudomonas aeruginosa. (via Semantic Scholar)
UN Sustainable Development Goal Categories
3. Good Health and Well-being (Web of Science; OpenAlex)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: July 18, 2022

2021 article

A perspective on the redox properties of tetrapyrrole macrocycles

Diers, J. R., Kirmaier, C., Taniguchi, M., Lindsey, J. S., Bocian, D. F., & Holten, D. (2021, September 7). PHYSICAL CHEMISTRY CHEMICAL PHYSICS, Vol. 9.

Contributors: J. Diers*, C. Kirmaier*, M. Taniguchi n, J. Lindsey n, D. Bocian* & D. Holten*

MeSH headings : Bacteriochlorophylls / chemistry; Chlorophyll / chemistry; Density Functional Theory; Electrons; Oxidation-Reduction; Porphyrins / chemistry; Quantum Theory; Tetrapyrroles / chemistry
TL;DR: From a fundamental framework concerning tetrapyrrole electronic properties, it must be recognized that structural/electronic alterations affect the four frontier molecular orbitals unequally and in many cases the LUMO+1, and not the LumO, may track the HOMO in energy. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: September 20, 2021

2021 journal article

Absorption and Fluorescence Spectral Database of Chlorophylls and Analogues

PHOTOCHEMISTRY AND PHOTOBIOLOGY, 97(1), 136–165.

By: M. Taniguchi n & J. Lindsey n

Contributors: M. Taniguchi n & J. Lindsey n

MeSH headings : Chlorophyll / analogs & derivatives; Chlorophyll / chemistry; Databases, Chemical; Molecular Structure; Spectrum Analysis / methods
TL;DR: The database encompasses photosynthetic tetrapyrroles wherein the chromophore is a porphyrin or chlorin and contains 305 absorption spectra and 72 fluorescence spectra that should facilitate comparisons and quantitative calculations. (via Semantic Scholar)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: November 30, 2020

2021 review

Comprehensive review of photophysical parameters (epsilon, Phi(f), tau(s)) of tetraphenylporphyrin (H2TPP) and zinc tetraphenylporphyrin (ZnTPP) - Critical benchmark molecules in photochemistry and photosynthesis

[Review of ]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS, 46, 100401.

By: M. Taniguchi n, J. Lindsey n, D. Bocian* & D. Holten*

Contributors: M. Taniguchi n, J. Lindsey n, D. Bocian* & D. Holten*

UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: May 17, 2021

2021 journal article

Electronic Structure and Excited-State Dynamics of Rylene-Tetrapyrrole Panchromatic Absorbers

JOURNAL OF PHYSICAL CHEMISTRY A, 125(36), 7900–7919.

Contributors: J. Rong n, N. Magdaong*, M. Taniguchi n, J. Diers*, D. Niedzwiedzki, C. Kirmaier*, J. Lindsey n, D. Bocian*, D. Holten*

TL;DR: Characterization of the spectra, excited-state properties (lifetime, yields, and rate constants of decay pathways, and molecular-orbital characteristics reveals unexpected subtleties), which highlight design constraints for auxiliary pigments with tetrapyrroles to achieve panchromatic absorption with retention of viable excited- state properties. (via Semantic Scholar)
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: September 27, 2021

2021 article

Fluorescence Assay for Tolyporphins Amidst Abundant Chlorophyll in Crude Cyanobacterial Extracts

Nguyen, K.-U., Zhang, R., Taniguchi, M., & Lindsey, J. S. (2021, July 16). PHOTOCHEMISTRY AND PHOTOBIOLOGY, Vol. 7.

By: K. Nguyen n, R. Zhang n, M. Taniguchi n & J. Lindsey n

Contributors: K. Nguyen n, R. Zhang n, M. Taniguchi n & J. Lindsey n

MeSH headings : Chlorophyll / chemistry; Chlorophyll A; Cyanobacteria / chemistry; Fluorescence; Spectrometry, Fluorescence
TL;DR: Tolyporphins were readily detected in cultures of HT‐58‐2 at reasonable growth periods in the absence of environmental stressors, which was not possible previously. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries, ORCID
Added: July 26, 2021

2021 conference paper

PhotochemCAD spectra viewer for web-based visualization of absorption and fluorescence spectra

Progress in Biomedical Optics and Imaging - Proceedings of SPIE, 11660.

By: Z. Wu n, A. Kittinger*, A. Norcross n, M. Taniguchi n & J. Lindsey n

Contributors: Z. Wu n, A. Kittinger*, A. Norcross n, M. Taniguchi n & J. Lindsey n

TL;DR: A web-browser-based PhotochemCAD spectra viewer is described that enables overlay of spectra for comparative evaluation, can be used on any platform (Windows, Mac, Linux), and does not require downloading or installation of the program. (via Semantic Scholar)
Source: ORCID
Added: January 25, 2023

2021 journal article

The fluorescence quantum yield parameter in Förster resonance energy transfer (FRET)—Meaning, misperception, and molecular design

Chemical Physics Reviews, 2(1), 011302.

By: J. Lindsey n, M. Taniguchi n, D. Bocian* & D. Holten*

TL;DR: The equations for FRET are reviewed along with pertinent core concepts in photophysics and an analogy using simple hydraulics provides a pedagogical tool for the non-aficionado to better understand photochemical kinetics. (via Semantic Scholar)
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Source: ORCID
Added: October 17, 2021

2021 article

Tolyporphins A-R, unusual tetrapyrrole macrocycles in a cyanobacterium from Micronesia, assessed quantitatively from the culture HT-58-2

Timothy J. O'Donnell, Gurr, J. R., Dai, J., Taniguchi, M., Williams, P. G., & Lindsey, J. S. (2021, June 8). NEW JOURNAL OF CHEMISTRY, Vol. 6.

By: . Timothy J. O'Donnell*, J. Gurr*, J. Dai*, M. Taniguchi n, P. Williams* & J. Lindsey n

Contributors: . T.J. O'Donnell, J. Gurr*, J. Dai*, M. Taniguchi n, P. Williams* & J. Lindsey n

TL;DR: Tolyporphins A–R are the newest additions to the family of native tetrapyrroles and LC-MS-dMRM and absorption spectroscopy have been employed for analysis of mixtures containing the 18 distinctive natural products. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries, ORCID
Added: June 21, 2021

2020 article

Absorption and fluorescence spectra of organic compounds from 40 sources - archives, repositories, databases, and literature search engines

REPORTERS, MARKERS, DYES, NANOPARTICLES, AND MOLECULAR PROBES FOR BIOMEDICAL APPLICATIONS XII, Vol. 11256.

By: M. Taniguchi n & J. Lindsey n

Contributors: M. Taniguchi n & J. Lindsey n

author keywords: Photophysics; Molar absorption coefficient; Fluorescence quantum yield; Search engine; Database; Fluorophore; Photonics; PhotochemCAD
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries, ORCID
Added: September 28, 2020

2020 article

Analysis of Wikipedia pageviews to identify popular chemicals

REPORTERS, MARKERS, DYES, NANOPARTICLES, AND MOLECULAR PROBES FOR BIOMEDICAL APPLICATIONS XII, Vol. 11256.

By: Y. Cao*, H. Mehta*, A. Norcross n, M. Taniguchi n & J. Lindsey n

Contributors: Y. Cao*, H. Mehta*, A. Norcross n, M. Taniguchi n & J. Lindsey n

author keywords: Wikipedia; Database; Pageview; Search; SMILES; Medicine; Pharmaceutical; World Health Organization
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries, ORCID
Added: September 28, 2020

2020 journal article

Bioconjugatable synthetic chlorins rendered water-soluble with three PEG-12 groups via click chemistry

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 24(1-3), 362–378.

By: N. Matsumoto n, M. Taniguchi n & J. Lindsey n

Contributors: N. Matsumoto n, M. Taniguchi n & J. Lindsey n

author keywords: chlorophyll; fluorescence; fluorophore; bright; diagnostics; aqueous
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: March 16, 2020

2020 journal article

Crystal Structure of 1,9-Dibromo-5-phenyldipyrrin, Tetrapyrrole Synthesis Derivative and Free Base Ligand of BODIPY Building Blocks

X-RAY STRUCTURE ANALYSIS ONLINE, 36, 21–22.

By: . Donal F. O'shea n, R. Sommer n, M. Taniguchi n & J. Lindsey n

Contributors: . D.F. O'Shea, R. Sommer n, M. Taniguchi n & J. Lindsey n

Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 3, 2020

2020 journal article

Photophysical Properties and Electronic Structure of Zinc(II) Porphyrins Bearing 0-4 meso-Phenyl Substituents: Zinc Porphine to Zinc Tetraphenylporphyrin (ZnTPP)

JOURNAL OF PHYSICAL CHEMISTRY A, 124(38), 7776–7794.

TL;DR: Six zinc(II) porphyrins bearing 0-4 meso-phenyl substituents have been examined spectroscopically and theoretically and reveal fundamental insights into the photophysical properties and electronic structure of meso,phenylporphyrins, widely used as benchmarks for tetrapyrrole-based architectures in solar energy and life sciences research. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: October 26, 2020

2019 article

Developing a user community in the photosciences: a website for spectral data and access to PhotochemCAD

(S. Achilefu & R. Raghavachari, Eds.). REPORTERS, MARKERS, DYES, NANOPARTICLES, AND MOLECULAR PROBES FOR BIOMEDICAL APPLICATIONS XI, Vol. 10893.

By: Y. Guo*, Z. Xu*, A. Norcross n, M. Taniguchi n & J. Lindsey n

Contributors: Y. Guo*, Z. Xu*, A. Norcross n, M. Taniguchi n & J. Lindsey n

Ed(s): S. Achilefu & R. Raghavachari

author keywords: Absorption spectra; Fluorescence spectra; Photochemistry; Fluorophores; Software; Website; PhotochemCAD; Web Design; Email Campaign; Search Engine Optimization
TL;DR: A new website, centered on absorption and fluorescence spectra, has been designed for the broad community of members in the photosciences and represents a step toward fulfilling the long-term ambition of assembling all known spectral data worldwide, from print and digital sources, in one carefully curated collection of digital data in a readily accessible site. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries, ORCID
Added: September 9, 2019

2019 journal article

Heuristics from Modeling of Spectral Overlap in Forster Resonance Energy Transfer (FRET)

JOURNAL OF CHEMICAL INFORMATION AND MODELING, 59(2), 652–667.

By: Q. Qi n, M. Taniguchi n & J. Lindsey n

Contributors: Q. Qi n, M. Taniguchi n & J. Lindsey n

MeSH headings : Absorption, Physicochemical; Fluorescence Resonance Energy Transfer; Heuristics; Models, Theoretical; Normal Distribution
TL;DR: Gaussian distributions of absorption and fluorescent spectra have been modeled that encompass varying degrees of overlap, full-width-at-half-maximum (fwhm), and Stokes shift to provide insights into how a variety of factors affect the resulting J values. (via Semantic Scholar)
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: March 18, 2019

2018 journal article

Database of Absorption and Fluorescence Spectra of > 300 Common Compounds for use in PhotochemCAD

Database of Absorption and Fluorescence Spectra of > 300 Common Compounds for use in PhotochemCAD. PHOTOCHEMISTRY AND PHOTOBIOLOGY, 94(2), 290–327.

By: M. Taniguchi n & J. Lindsey n

Contributors: M. Taniguchi n & J. Lindsey n

TL;DR: The previous databases for 150 compounds have been expanded to encompass 339 compounds for which absorption spectra, fluorescence spectra and references to the primary literature have been included where available (552 spectra altogether). (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2018 journal article

PhotochemCAD 3: Diverse Modules for Photophysical Calculations with Multiple Spectral Databases

PHOTOCHEMISTRY AND PHOTOBIOLOGY, 94(2), 277–289.

By: M. Taniguchi n, H. Du n & J. Lindsey n

Contributors: M. Taniguchi n, H. Du n & J. Lindsey n

TL;DR: The PhotochemicalCAD program, developed over 30 years, is described comprehensively with focus on features of the most recent version (PhotochemCAD 3), equipped with a streamlined user interface and provisions for handling multiple spectral databases. (via Semantic Scholar)
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2018 article

Red and near-infrared fluorophores inspired by chlorophylls. Consideration of practical brightness in multicolor flow cytometry and biomedical sciences

(S. Achilefu & R. Raghavachari, Eds.). REPORTERS, MARKERS, DYES, NANOPARTICLES, AND MOLECULAR PROBES FOR BIOMEDICAL APPLICATIONS X, Vol. 10508.

By: M. Taniguchi n, G. Hu n, R. Liu n, H. Du n & J. Lindsey n

Contributors: M. Taniguchi n, G. Hu n, R. Liu n, H. Du n & J. Lindsey n

Ed(s): S. Achilefu & R. Raghavachari

author keywords: Bacteriochlorophyll; Chlorophyll; Flow cytometry; Fluorophores; Multicolor; Near infrared; Stokes shift; Tandem dye
TL;DR: The spectroscopic features of (bacterio)chlorins are evaluated quantitatively to illustrate practical brightness for this novel class of fluorophores in a prospective 8-color panel. (via Semantic Scholar)
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: January 14, 2019

2017 journal article

Hydrogen Evolution Catalysis by a Sparsely Substituted Cobalt Chlorin

ACS CATALYSIS, 7(5), 3597–3606.

By: A. Maher*, G. Passard*, D. Dogutan*, R. Halbach*, B. Anderson*, C. Gagliardi*, M. Taniguchi n, J. Lindsey n, D. Nocera*

Contributors: A. Maher*, G. Passard*, D. Dogutan*, R. Halbach*, B. Anderson*, C. Gagliardi*, M. Taniguchi n, J. Lindsey n, D. Nocera*

author keywords: electrocatalysis; macrocycle; chlorin; cobalt; hydrogen evolution reaction; solar fuels
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2017 journal article

Synthesis and Spectral Properties of meso-Arylbacteriochlorins, Including Insights into Essential Motifs of their Hydrodipyrrin Precursors

Molecules, 22(4), 634.

By: M. Reddy n, S. Zhang n, H. Kim*, O. Mass n, M. Taniguchi n & J. Lindsey n

Contributors: M. Reddy n, S. Zhang n, H. Kim*, O. Mass n, M. Taniguchi n & J. Lindsey n

author keywords: self-condensation; bacteriochlorophyll; near-infrared; tetrahydrodipyrrin; dihydrodipyrrin; absorption; fluorescence; oxocarbenium ion; resonance; oxidation
MeSH headings : Chemistry Techniques, Synthetic; Molecular Structure; Porphyrins / chemical synthesis; Porphyrins / chemistry; Spectrum Analysis
TL;DR: Ten new dihydrodipyrrins and five new bacteriochlorins have been prepared and results revealed the importance of resonance stabilization of the reactive hydrodipirrin intermediate, including a Qy band in the region 726–743 nm. (via Semantic Scholar)
Sources: ORCID, NC State University Libraries, NC State University Libraries
Added: August 6, 2018

2017 journal article

Synthesis, photophysics and electronic structure of oxobacteriochlorins

NEW JOURNAL OF CHEMISTRY, 41(10), 3732–3744.

By: M. Liu n, C. Chen n, D. Hood*, M. Taniguchi n, J. Diers*, D. Bocian*, D. Holten*, J. Lindsey n

Contributors: M. Liu n, C. Chen n, D. Hood*, M. Taniguchi n, J. Diers*, D. Bocian*, D. Holten*, J. Lindsey n

UN Sustainable Development Goal Categories
14. Life Below Water (OpenAlex)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2017 review

Synthetic Chlorins, Possible Surrogates for Chlorophylls, Prepared by Derivatization of Porphyrins

[Review of ]. CHEMICAL REVIEWS, 117(2), 344–535.

By: M. Taniguchi n & J. Lindsey n

Contributors: M. Taniguchi n & J. Lindsey n

MeSH headings : Chlorophyll / chemistry; Porphyrins / chemistry; Stereoisomerism
TL;DR: The synthesis and spectral properties of the vast collection of compounds described herein are expected to illuminate the scope to which synthetic chlorins can serve as surrogates for chlorophylls and be exploited in diverse ways. (via Semantic Scholar)
UN Sustainable Development Goal Categories
15. Life on Land (OpenAlex)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2017 journal article

The Porphobilinogen Conundrum in Prebiotic Routes to Tetrapyrrole Macrocycles

ORIGINS OF LIFE AND EVOLUTION OF BIOSPHERES, 47(1), 93–119.

By: M. Taniguchi n, M. Ptaszek*, V. Chandrashaker n & J. Lindsey n

Contributors: M. Taniguchi n, M. Ptaszek*, V. Chandrashaker n & J. Lindsey n

author keywords: delta-aminolevulinic acid; Porphyrinogen; Porphyrin; DFT; Biosynthesis; Biomimetic
MeSH headings : Aminolevulinic Acid / analogs & derivatives; Aminolevulinic Acid / chemistry; Evolution, Chemical; Kinetics; Origin of Life; Porphobilinogen / chemistry; Tetrapyrroles / chemistry
TL;DR: The results suggest efforts toward a biomimetic, enzyme-free route to tetrapyrroles from ALA should turn away from structure-directed reactions and focus on catalysts that orient the two aminoketones to form PBG in a kinetically controlled process, thereby avoiding formation of pseudo-PBG. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2016 journal article

Bioconjugatable, PEGylated hydroporphyrins for photochemistry and photomedicine. Narrow-band, near-infrared-emitting bacteriochlorins

NEW JOURNAL OF CHEMISTRY, 40(9), 7750–7767.

By: N. Zhang n, J. Jiang n, M. Liu n, M. Taniguchi n, A. Mandal*, R. Evans-Storms*, J. Pitner*, D. Bocian*, D. Holten*, J. Lindsey n

Contributors: N. Zhang n, J. Jiang n, M. Liu n, M. Taniguchi n, A. Mandal*, R. Evans-Storms*, J. Pitner*, D. Bocian*, D. Holten*, J. Lindsey n

TL;DR: The synthesis of five wavelength-tunable, bioconjugatable and water-soluble bacteriochlorins with desirable photophysical properties for use in multiple fields is reported, giving access to a set of water- solubility bacterio chlorin building blocks. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2016 journal article

Complexity in structure-directed prebiotic chemistry. Reaction bifurcation from a beta-diketone in tetrapyrrole formation

NEW JOURNAL OF CHEMISTRY, 40(7), 6434–6440.

By: R. Deans n, M. Taniguchi n, V. Chandrashaker n, M. Ptaszek n & J. Lindsey n

Contributors: R. Deans n, M. Taniguchi n, V. Chandrashaker n, M. Ptaszek n & J. Lindsey n

Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2016 journal article

Complexity in structure-directed prebiotic chemistry. Unexpected compositional richness from competing reactants in tetrapyrrole formation

NEW JOURNAL OF CHEMISTRY, 40(7), 6421–6433.

By: R. Deans n, M. Taniguchi n, V. Chandrashaker n, M. Ptaszek n, D. Chambers n, A. Soares n, J. Lindsey n

Contributors: R. Deans n, M. Taniguchi n, V. Chandrashaker n, M. Ptaszek n, D. Chambers n, A. Soares n, J. Lindsey n

Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2016 journal article

Integration of Cyanine, Merocyanine and Styryl Dye Motifs with Synthetic Bacteriochlorins

Photochemistry and Photobiology, 92(1), 111–125.

TL;DR: The combined photophysical and molecular‐orbital characteristics suggest the altered spectra and enhanced nonradiative S1 decay of B‐1 and B‐2 derive from excited‐state configurations in which electron density is shifted between the macrocycle and the substituents. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Source: ORCID
Added: October 17, 2021

2016 journal article

Photophysical Properties and Electronic Structure of Porphyrins Bearing Zero to Four meso-Phenyl Substituents: New Insights into Seemingly Well Understood Tetrapyrroles

JOURNAL OF PHYSICAL CHEMISTRY A, 120(49), 9719–9731.

MeSH headings : Electrons; Fluorescence; Molecular Structure; Photochemical Processes; Porphyrins / chemistry; Quantum Theory; Tetrapyrroles / chemistry
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2016 journal article

Scope and limitations of two model prebiotic routes to tetrapyrrole macrocycles

NEW JOURNAL OF CHEMISTRY, 40(9), 7445–7455.

By: M. Taniguchi n, R. Deans n, V. Chandrashaker n, M. Ptaszek n & J. Lindsey n

Contributors: M. Taniguchi n, R. Deans n, V. Chandrashaker n, M. Ptaszek n & J. Lindsey n

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2016 journal article

Synthesis of diverse acyclic precursors to pyrroles for studies of prebiotic routes to tetrapyrrole macrocycles

NEW JOURNAL OF CHEMISTRY, 40(10), 8786–8808.

By: V. Chandrashaker n, M. Ptaszek n, M. Taniguchi n & J. Lindsey n

Contributors: V. Chandrashaker n, M. Ptaszek n, M. Taniguchi n & J. Lindsey n

TL;DR: The synthesis of 53 compounds is described, encompassing 28 new compounds as well as 25 known compounds that have been more fully characterized or prepared via alternative routes that may prove useful in mainstream syntheses of diverse tetrapyrroles regardless of possible prebiotic relevance. (via Semantic Scholar)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2015 journal article

Complexity in structure-directed prebiotic chemistry. Effect of a defective competing reactant in tetrapyrrole formation

NEW JOURNAL OF CHEMISTRY, 39(11), 8273–8281.

By: R. Deans n, V. Chandrashaker n, M. Taniguchi n & J. Lindsey n

Contributors: R. Deans n, V. Chandrashaker n, M. Taniguchi n & J. Lindsey n

Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2015 journal article

Elaboration of an unexplored substitution site in synthetic bacteriochlorins

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 19(7), 887–902.

By: N. Zhang n, K. Reddy n, J. Jiang n, M. Taniguchi n, R. Sommer n & J. Lindsey n

Contributors: N. Zhang n, K. Reddy n, J. Jiang n, M. Taniguchi n, R. Sommer n & J. Lindsey n

author keywords: hydroporphyrin; dioxepine; chlorophyllone; bacteriochlorophyllone; auxochrome; artificial photosynthesis
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2015 journal article

Extending the Short and Long Wavelength Limits of Bacteriochlorin Near-Infrared Absorption via Dioxo- and Bisimide-Functionalization

JOURNAL OF PHYSICAL CHEMISTRY B, 119(12), 4382–4395.

By: P. Vairaprakash n, E. Yang*, T. Sahin n, M. Taniguchi n, M. Krayer n, J. Diers*, A. Wang*, D. Niedzwiedzki* ...

Contributors: P. Vairaprakash n, E. Yang*, T. Sahin n, M. Taniguchi n, M. Krayer n, J. Diers*, A. Wang*, D. Niedzwiedzki* ...

MeSH headings : Carbon-13 Magnetic Resonance Spectroscopy; Molecular Structure; Photochemical Processes; Porphyrins / chemical synthesis; Porphyrins / chemistry; Proton Magnetic Resonance Spectroscopy; Spectroscopy, Near-Infrared / methods
TL;DR: Six new bacteriochlorins expanding the range of the strong near-infrared absorption (Qy band) to both shorter and longer wavelengths (∼690 to ∼900 nm) have been synthesized and characterized and have excited-state lifetimes that are sufficiently long for use in molecular-based systems for photochemical applications. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2015 journal article

Near-infrared tunable bacteriochlorins equipped for bioorthogonal labeling

NEW JOURNAL OF CHEMISTRY, 39(6), 4534–4550.

By: J. Jiang n, M. Taniguchi n & J. Lindsey n

Contributors: J. Jiang n, M. Taniguchi n & J. Lindsey n

TL;DR: Nine lipophilic, wavelength-tunable bacteriochlorins (seven free base; two zinc chelates) have been prepared that bear a single bioconjugatable group, fulfilling two key molecular design criteria for use of NIR-active chromophores in a variety of photochemical applications. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2015 journal article

Paley's watchmaker analogy and prebiotic synthetic chemistry in surfactant assemblies. Formaldehyde scavenging by pyrroles leading to porphyrins as a case study

ORGANIC & BIOMOLECULAR CHEMISTRY, 13(39), 10025–10031.

By: E. Alexy n, C. Hintz n, H. Hughes n, M. Taniguchi n & J. Lindsey n

Contributors: E. Alexy n, C. Hintz n, H. Hughes n, M. Taniguchi n & J. Lindsey n

MeSH headings : Formaldehyde / chemistry; Micelles; Origin of Life; Phosphatidylcholines / chemistry; Porphyrins / chemistry; Pyrroles / chemistry; Surface-Active Agents / chemistry; Unilamellar Liposomes / chemistry
TL;DR: The fruitful exchange, accumulation and reaction of minute quantities of reactants in aqueous-surfactant assemblies suggest a general means for formation of prebiotically valuable constituents, even when the statistical odds at the outset are overwhelmingly improbable. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2015 journal article

Photophysical Properties and Electronic Structure of Chlorin-Imides: Bridging the Gap between Chlorins and Bacteriochlorins

JOURNAL OF PHYSICAL CHEMISTRY B, 119(24), 7503–7515.

By: K. Faries*, J. Diers*, J. Springer*, E. Yang*, M. Ptaszek n, D. Lahaye n, M. Krayer n, M. Taniguchi n ...

Contributors: K. Faries*, J. Diers*, J. Springer*, E. Yang*, M. Ptaszek n, D. Lahaye n, M. Krayer n, M. Taniguchi n ...

MeSH headings : Electrons; Fluorescence; Imides / chemistry; Molecular Structure; Photochemical Processes; Porphyrins / chemistry; Quantum Theory
TL;DR: The photophysical properties of a set of six chlorin-imides and nine synthetic chlorin analogues that extend the absorption deeper into these key spectral regions of the solar spectrum and help bridge the gap between typical chlorins and bacteriochlorins are reported. (via Semantic Scholar)
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2015 journal article

Progress towards synthetic chlorins with graded polarity, conjugatable substituents, and wavelength tunability

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 19(4), 547–572.

By: D. Ra n, K. Gauger n, K. Muthukumaran n, T. Balasubramanian n, V. Chandrashaker n, M. Taniguchi n, Z. Yu*, D. Talley* ...

Contributors: D. Ra n, K. Gauger n, K. Muthukumaran n, T. Balasubramanian n, V. Chandrashaker n, M. Taniguchi n, Z. Yu*, D. Talley* ...

author keywords: auxochrome; artificial photosynthesis; chlorophyll; hydroporphyrin; hydrophilic; photomedicine
TL;DR: Twenty new chlorins (17 targets, 6 intermediates) have been prepared and the challenge associated with molecular designs that encompass the combination of "hydrophilic, bioconjugatable and wavelength-tunable" chiefly resides in the nature of the hydrophilic unit. (via Semantic Scholar)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2014 journal article

NMR spectral properties of 16 synthetic bacteriochlorins with site-specific C-13 or N-15 substitution

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 18(6), 433–456.

By: C. Chen n, M. Taniguchi n & J. Lindsey n

Contributors: C. Chen n, M. Taniguchi n & J. Lindsey n

author keywords: bacteriochlorin; chlorin; porphyrin; NMR; coupling constants; macrocycle
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2014 journal article

Photophysical properties and electronic structure of retinylidene–chlorin–chalcones and analogues

Photochemical & Photobiological Sciences, 13(4), 634.

By: J. Springer*, M. Taniguchi n, M. Krayer n, C. Ruzié n, J. Diers*, D. Niedzwiedzki*, D. Bocian*, J. Lindsey n, D. Holten*

Contributors: J. Springer*, M. Taniguchi n, M. Krayer n, C. Ruzié n, J. Diers*, D. Niedzwiedzki*, D. Bocian*, J. Lindsey n, D. Holten*

TL;DR: The spectral and photophysical properties of four chlorin-chalcones reported provide insight into the fundamental properties of chlorins and illustrate the utility of chalcones as a means of both tuning and augmenting the spectral properties of these chromophores. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Crossref, ORCID, NC State University Libraries, NC State University Libraries
Added: August 6, 2018

2014 journal article

Statistical considerations on the formation of circular photosynthetic light-harvesting complexes from Rhodopseudomonas palustris

PHOTOSYNTHESIS RESEARCH, 121(1), 49–60.

By: M. Taniguchi n, S. Henry*, R. Cogdell* & J. Lindsey n

Contributors: M. Taniguchi n, S. Henry*, R. Cogdell* & J. Lindsey n

author keywords: Bacterial photosynthesis; Light-harvesting; Heterogeneous; Oligomer; Diversity; Simulation; Self-assembly
MeSH headings : Bacteriochlorophylls / chemistry; Bacteriochlorophylls / metabolism; Light-Harvesting Protein Complexes / chemistry; Light-Harvesting Protein Complexes / metabolism; Photosynthesis / physiology; Rhodopseudomonas / chemistry; Rhodopseudomonas / metabolism
TL;DR: The software program Cyclaplex, which enables generation and data-mining of virtual libraries of molecular rings formed upon combinatorial reactions, has been used to delineate the possible number and type of distinct nonamers as a function of numbers of distinct protomers. (via Semantic Scholar)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2014 journal article

Versatile design of biohybrid light-harvesting architectures to tune location, density, and spectral coverage of attached synthetic chromophores for enhanced energy capture

PHOTOSYNTHESIS RESEARCH, 121(1), 35–48.

By: M. Harris*, J. Jiang n, D. Niedzwiedzki*, J. Jiao*, M. Taniguchi n, C. Kirmaier*, P. Loach*, D. Bocian* ...

Contributors: M. Harris*, J. Jiang n, D. Niedzwiedzki*, J. Jiao*, M. Taniguchi n, C. Kirmaier*, P. Loach*, D. Bocian* ...

author keywords: Light harvesting; Photosynthetic antenna; Energy transfer; Bacteriochlorin; Bacteriochlorophyll; Bioconjugate; Self-assembly; LH1
MeSH headings : Bacteriochlorophylls / chemistry; Bacteriochlorophylls / genetics; Bacteriochlorophylls / metabolism; Light-Harvesting Protein Complexes / chemistry; Light-Harvesting Protein Complexes / genetics; Light-Harvesting Protein Complexes / metabolism; Protein Structure, Secondary; Rhodobacter sphaeroides / chemistry; Rhodobacter sphaeroides / genetics; Rhodobacter sphaeroides / metabolism
TL;DR: Three new designs, each of which employs analogs of the β-polypeptide from Rhodobacter sphaeroides, have been investigated, and illustrate the great latitude of the biohybrid approach for the design of diverse light-harvesting systems. (via Semantic Scholar)
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2013 journal article

Aqueous–membrane partitioning of β-substituted porphyrins encompassing diverse polarity

New Journal of Chemistry, 37(4), 1087.

By: A. Soares n, Y. Thanaiah n, M. Taniguchi n & J. Lindsey n

Contributors: A. Soares n, Y. Thanaiah n, M. Taniguchi n & J. Lindsey n

UN Sustainable Development Goal Categories
Sources: Crossref, ORCID, NC State University Libraries, NC State University Libraries
Added: August 6, 2018

2013 journal article

ChemInform Abstract: Enumeration of Isomers of Substituted Tetrapyrrole Macrocycles: From Classical Problems in Biology to Modern Combinatorial Libraries

ChemInform, 44(31), no-no.

By: M. Taniguchi* & J. Lindsey*

Source: ORCID
Added: October 17, 2021

2013 journal article

Enumeration of Virtual Libraries of Combinatorial Modular Macrocyclic (Bracelet, Necklace) Architectures and Their Linear Counterparts

JOURNAL OF CHEMICAL INFORMATION AND MODELING, 53(9), 2203–2216.

By: M. Taniguchi n, H. Du n & J. Lindsey n

Contributors: M. Taniguchi n, H. Du n & J. Lindsey n

MeSH headings : Algorithms; Combinatorial Chemistry Techniques; Informatics / methods; Isomerism; Macrocyclic Compounds / chemistry; Software; User-Computer Interface
TL;DR: A software program has been developed to determine the number, identity, and relative amounts of linear and cyclic architectures from a given number and ratio of reacting monomers. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2013 journal article

Expanded combinatorial formation of porphyrin macrocycles in aqueous solution containing vesicles. A prebiotic model

New Journal of Chemistry, 37(4), 1073.

By: A. Soares n, M. Taniguchi n, V. Chandrashaker n & J. Lindsey n

Contributors: A. Soares n, M. Taniguchi n, V. Chandrashaker n & J. Lindsey n

TL;DR: The relative insensitivity of physicochemical properties (partitioning, photoactivity) toward combinatorial expansion may be a valuable yet unappreciated attribute for prebiotic functionality. (via Semantic Scholar)
Sources: Crossref, ORCID, NC State University Libraries, NC State University Libraries
Added: August 6, 2018

2013 journal article

Synthesis and photophysical properties of chlorins bearing 0–4 distinct meso-substituents

Photochemical & Photobiological Sciences, 12(12), 2089.

By: K. Aravindu n, H. Kim*, M. Taniguchi n, P. Dilbeck*, J. Diers*, D. Bocian*, D. Holten*, J. Lindsey n

Contributors: K. Aravindu n, H. Kim*, M. Taniguchi n, P. Dilbeck*, J. Diers*, D. Bocian*, D. Holten*, J. Lindsey n

MeSH headings : Cyclization; Magnetic Resonance Spectroscopy; Metalloporphyrins / chemical synthesis; Metalloporphyrins / chemistry; Models, Molecular; Oxidation-Reduction; Pheophytins / chemistry; Quantum Theory; Spectrometry, Fluorescence; Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization
TL;DR: Density functional theory calculations show that of the frontier molecular orbitals of the chlorin, the energy of the HOMO-1 is the most affected by meso-aryl substituents, undergoing progressive destabilization as the number of meso -aryl groups is increased. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Crossref, ORCID, NC State University Libraries, NC State University Libraries
Added: August 6, 2018

2012 journal article

A tandem combinatorial model for the prebiogenesis of diverse tetrapyrrole macrocycles

New Journal of Chemistry, 36(4), 1057.

By: M. Taniguchi n, A. Soares n, V. Chandrashaker n & J. Lindsey n

Contributors: M. Taniguchi n, A. Soares n, V. Chandrashaker n & J. Lindsey n

TL;DR: In terms of the polarity of the tetrapyrrole macrocycles formed, an all-at-once non-enzymic combinatorial process recapitulates features of the stepwise biosynthetic pathway. (via Semantic Scholar)
Sources: Crossref, ORCID, NC State University Libraries, NC State University Libraries
Added: August 6, 2018

2012 journal article

Competing Knorr and Fischer-Fink pathways to pyrroles in neutral aqueous solution

TETRAHEDRON, 68(34), 6957–6967.

By: V. Chandrashaker, M. Taniguchi*, M. Ptaszek* & J. Lindsey*

Contributors: V. Chandrashaker, M. Taniguchi*, M. Ptaszek* & J. Lindsey*

author keywords: Prebiotic; Mass balance; Tetrapyrrole; Aminolevulinic acid; Biomimetic; Pyrrole
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2012 journal article

Diversity, isomer composition, and design of combinatorial libraries of tetrapyrrole macrocycles

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 16(1), 1–13.

By: M. Taniguchi n & J. Lindsey n

Contributors: M. Taniguchi n & J. Lindsey n

author keywords: combinatorial chemistry; library; chemset; pyrrole; porphyrin; phthalocyanine; porphyrazine; mass degeneracy; prebiotic
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2012 article

Enumeration of Isomers of Substituted Tetrapyrrole Macrocycles: From Classical Problems in Biology to Modern Combinatorial Libraries

Taniguchi, M., & Lindsey, J. S. (2012, July). Handbook of Porphyrin Science (Volume 23), pp. 1–80.

By: M. Taniguchi* & J. Lindsey

Source: ORCID
Added: October 17, 2021

2012 journal article

Primordial Oil Slick and the Formation of Hydrophobic Tetrapyrrole Macrocycles

Astrobiology, 12(11), 1055–1068.

By: A. Soares n, M. Taniguchi n, V. Chandrashaker n & J. Lindsey n

Contributors: A. Soares n, M. Taniguchi n, V. Chandrashaker n & J. Lindsey n

MeSH headings : Hydrogen-Ion Concentration; Hydrophobic and Hydrophilic Interactions; Kinetics; Oils / chemistry; Photosynthesis; Porphyrins / chemical synthesis; Solutions; Tetrapyrroles / chemical synthesis; Water / chemistry
TL;DR: The results indicate a facile means for the formation of highly hydrophobic constituents of potential value for prebiotic photosynthesis. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: NC State University Libraries, ORCID, NC State University Libraries
Added: August 6, 2018

2012 journal article

Self-organization of tetrapyrrole constituents to give a photoactive protocell

Chemical Science, 3(6), 1963.

By: A. Soares n, M. Taniguchi n, V. Chandrashaker n & J. Lindsey n

Contributors: A. Soares n, M. Taniguchi n, V. Chandrashaker n & J. Lindsey n

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Crossref, ORCID, NC State University Libraries, NC State University Libraries
Added: August 6, 2018

2012 journal article

Synthesis and Physicochemical Properties of Metallobacteriochlorins

INORGANIC CHEMISTRY, 51(17), 9443–9464.

By: C. Chen n, E. Sun n, D. Fan n, M. Taniguchi n, B. McDowell n, E. Yang*, J. Diers*, D. Bocian*, D. Holten*, J. Lindsey n

Contributors: C. Chen n, E. Sun n, D. Fan n, M. Taniguchi n, B. McDowell n, E. Yang*, J. Diers*, D. Bocian*, D. Holten*, J. Lindsey n

MeSH headings : Absorption; Chemical Phenomena; Chemistry Techniques, Synthetic; Electrochemistry; Electrons; Metalloporphyrins / chemical synthesis; Metalloporphyrins / chemistry; Porphyrins / chemistry
TL;DR: Electrochemical characteristics of (metal-free) bacteriochlorins were probed through electrochemical measurements along with density functional theory calculation of the energies of the frontier molecular orbitals and photophysical properties are generally similar to those of the metal-free analogues. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2011 journal article

Abiotic formation of uroporphyrinogen and coproporphyrinogen from acyclic reactants

NEW JOURNAL OF CHEMISTRY, 35(1), 65–75.

By: J. Lindsey n, V. Chandrashaker n, M. Taniguchi n & M. Ptaszek n

Contributors: J. Lindsey n, V. Chandrashaker n, M. Taniguchi n & M. Ptaszek n

Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2011 journal article

Encoding isotopic watermarks in molecular electronic materials as an anti-counterfeiting strategy. Application to porphyrins for information storage

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 15(7-8), 505–516.

By: J. Lindsey n, P. Thamyongkit n, M. Taniguchi n & D. Bocian*

Contributors: J. Lindsey n, P. Thamyongkit n, M. Taniguchi n & D. Bocian*

author keywords: watermark; mass encoding; isotope; porphyrin; capacitor; chip; resonance Raman; mass spectrometry
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2011 journal article

Photophysical Properties and Electronic Structure of Stable, Tunable Synthetic Bacteriochlorins: Extending the Features of Native Photosynthetic Pigments

JOURNAL OF PHYSICAL CHEMISTRY B, 115(37), 10801–10816.

By: E. Yang*, C. Kirmaier*, M. Krayer n, M. Taniguchi n, H. Kim n, J. Diers*, D. Bocian*, J. Lindsey n, D. Holten*

Contributors: E. Yang*, C. Kirmaier*, M. Krayer n, M. Taniguchi n, H. Kim n, J. Diers*, D. Bocian*, J. Lindsey n, D. Holten*

MeSH headings : Bacteriochlorophylls / chemistry; Electrons; Pheophytins / chemistry; Photosynthesis; Porphyrins / chemical synthesis; Porphyrins / chemistry; Quantum Theory; Spectroscopy, Near-Infrared
TL;DR: The studies show how the palette of synthetic bacteriochlorins extends the properties of the native photosynthetic pigments (bacteriochlorophylls) and elucidated design principles for tuning the spectral and photophysical characteristics as required for a wide variety of photochemical applications. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2011 journal article

Structural characteristics that make chlorophylls green: interplay of hydrocarbon skeleton and substituents

NEW JOURNAL OF CHEMISTRY, 35(1), 76–88.

By: O. Mass n, M. Taniguchi n, M. Ptaszek n, J. Springer*, K. Faries*, J. Diers*, D. Bocian*, D. Holten*, J. Lindsey n

Contributors: O. Mass n, M. Taniguchi n, M. Ptaszek n, J. Springer*, K. Faries*, J. Diers*, D. Bocian*, D. Holten*, J. Lindsey n

UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2011 journal article

Virtual Libraries of Tetrapyrrole Macrocycles. Combinatorics, Isomers, Product Distributions, and Data Mining

JOURNAL OF CHEMICAL INFORMATION AND MODELING, 51(9), 2233–2247.

By: M. Taniguchi n, H. Du n & J. Lindsey n

Contributors: M. Taniguchi n, H. Du n & J. Lindsey n

TL;DR: A software program has been developed to enumerate the type and relative amounts of substituted tetrapyrrole macrocycles in a virtual library formed by one of four different classes of reactions, and Pólya's theorem (for enumeration of cyclic entities) has been implemented and provides validation for reaction classes 3 and 4. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2010 journal article

Activation Energies for Oxidation of Porphyrin Monolayers Anchored to Au(111)

LANGMUIR, 26(20), 15718–15721.

By: J. Jiao*, M. Taniguchi n, J. Lindsey n & D. Bocian*

Contributors: J. Jiao*, M. Taniguchi n, J. Lindsey n & D. Bocian*

TL;DR: The activation energy for the oxidation of porphyrin monolayers anchored to gold surfaces is determined via measurement of the temperature dependence of the electron-transfer rates. (via Semantic Scholar)
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2010 journal article

Probing the Rate of Hole Transfer in Oxidized Porphyrin Dyads Using Thallium Hyperfine Clocks

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 132(34), 12121–12132.

By: J. Diers n, M. Taniguchi n, D. Holten n, J. Lindsey n & D. Bocian n

Contributors: J. Diers n, M. Taniguchi n, D. Holten n, J. Lindsey n & D. Bocian n

MeSH headings : Molecular Conformation; Organometallic Compounds / chemical synthesis; Organometallic Compounds / chemistry; Oxidation-Reduction; Photochemistry; Porphyrins / chemistry; Stereoisomerism; Thallium / chemistry
TL;DR: Variable-temperature EPR studies further demonstrate that the hole/electron-transfer process is at best weakly activated at room temperature and somewhat below, and provide the physical basis for the rational design of multicomponent architectures for efficient hole/Electron transfer. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2010 journal article

Probing the Rate of Hole Transfer in Oxidized Synthetic Chlorin Dyads via Site-Specific C-13-Labeling

JOURNAL OF ORGANIC CHEMISTRY, 75(10), 3193–3202.

Contributors: E. Nieves-Bernier n, J. Diers*, M. Taniguchi n, D. Holten*, D. Bocian* & J. Lindsey n

MeSH headings : Carbon Isotopes; Electrons; Magnetic Resonance Spectroscopy; Metalloporphyrins / chemical synthesis; Metalloporphyrins / chemistry; Molecular Structure; Oxidation-Reduction; Porphyrins / chemistry; Stereoisomerism; Zinc / chemistry
TL;DR: The studies of the chlorin and porphyrin dyads provide insights into the structural features that influence the hole/electron-transfer process. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2010 patent

Refined routes to chlorin building blocks

By: J. Lindsey, M. Taniguchi, D. Ra, G. Mo & T. Balasubramanian

Source: NC State University Libraries
Added: August 6, 2018

2010 journal article

Structural studies of sparsely substituted synthetic chlorins and phorbines establish benchmarks for changes in the ligand core and framework of chlorophyll macrocycles

JOURNAL OF MOLECULAR STRUCTURE, 979(1-3), 27–45.

Contributors: M. Taniguchi n, O. Mass n, P. Boyle n, Q. Tang*, J. Diers*, D. Bocian*, D. Holten*, J. Lindsey n

author keywords: Chlorophyll; Chlorin; Phorbine; Isocyclic ring; Chiral volume; Aromaticity
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2010 journal article

Synthesis of oligo(p-phenylene)-linked dyads containing free base, zinc(II) or thallium(III) porphyrins for studies in artificial photosynthesis

TETRAHEDRON, 66(30), 5549–5565.

By: M. Taniguchi n & J. Lindsey n

Contributors: M. Taniguchi n & J. Lindsey n

author keywords: Artificial photosynthesis; Porphyrin; Building block; Array; Electron transfer; Energy transfer; Hole transfer; Thallium; Zinc; Free base; Suzuki; Sonogashira
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2009 journal article

Excited-State Energy Flow in Phenylene-Linked Multiporphyrin Arrays

JOURNAL OF PHYSICAL CHEMISTRY B, 113(23), 8011–8019.

Contributors: H. Song n, M. Taniguchi n, M. Speckbacher n, L. Yu n, D. Bocian n, J. Lindsey n, D. Holten n

TL;DR: Simulations of the energy-transfer properties of fictive dodecameric arrays based on the data reported herein show that nonadjacent transfer steps make a significant contribution to the observed performance of such larger molecular architectures and indicate that energy transfer betweenNonadjacent sites has important implications for the design of multichromophore arrays for molecular-photonic and solar-energy applications. (via Semantic Scholar)
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2009 journal article

Linker Dependence of Energy and Hole Transfer in Neutral and Oxidized Multiporphyrin Arrays

JOURNAL OF PHYSICAL CHEMISTRY B, 113(52), 16483–16493.

TL;DR: Insight is given into the effects of linker characteristics (length, orbital energies, orbital overlap with the porphyrin orbital characteristics, and linker attachment site) on the rate constants for excited-state energy transfer, excited- state hole transfer, and ground-state hole transfer. (via Semantic Scholar)
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2009 patent

Methods and intermediates for the synthesis of porphyrins

By: J. Lindsey, M. Taniguchi, A. Balakumar & D. Fan

Source: NC State University Libraries
Added: August 6, 2018

2009 journal article

Probing Ground-state Hole Transfer Between Equivalent, Electrochemically Inaccessible States in Multiporphyrin Arrays Using Time-resolved Optical Spectroscopy

PHOTOCHEMISTRY AND PHOTOBIOLOGY, 85(3), 693–704.

Contributors: H. Song*, M. Taniguchi n, C. Kirmaier*, D. Bocian*, J. Lindsey n & D. Holten*

TL;DR: Two complementary strategies provide unique approaches for probing hole transfer between equivalent sites in multiporphyrin arrays, with the choice of method being guided by the particular target process and the ease of synthesis of the necessary architectures. (via Semantic Scholar)
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2009 journal article

Refined syntheses of hydrodipyrrin precursors to chlorin and bacteriochlorin building blocks

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 13(10), 1098–1110.

By: M. Krayer n, T. Balasubramanian n, C. Ruzie n, M. Ptaszek n, D. Cramer n, M. Taniguchi n, J. Lindsey n

Contributors: M. Krayer n, T. Balasubramanian n, C. Ruzié n, M. Ptaszek n, D. Cramer n, M. Taniguchi n, J. Lindsey n

author keywords: chlorin; bacteriochlorin; bromination; dihydrodipyrrin; tetrahydrodipyrrin; McMurry cyclization; Michael addition
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2009 journal article

Regioselective Bromination Tactics in the de Novo Synthesis of Chlorophyll b Analogues

JOURNAL OF ORGANIC CHEMISTRY, 74(9), 3237–3247.

By: C. Muthiah n, D. Lahaye n, M. Taniguchi n, M. Ptaszek n & J. Lindsey n

Contributors: C. Muthiah n, D. Lahaye n, M. Taniguchi n, M. Ptaszek n & J. Lindsey n

MeSH headings : Chlorophyll / chemical synthesis; Chlorophyll / chemistry; Halogenation; Porphyrins / chemistry; Spectrum Analysis; Stereoisomerism; Substrate Specificity
TL;DR: Taken together, the facile access to chlorins and 13(1)-oxophorbines bearing substituents at distinct sites should enable fundamental spectroscopic studies and diverse applications. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2009 journal article

Simple Formation of an Abiotic Porphyrinogen in Aqueous Solution

ORIGINS OF LIFE AND EVOLUTION OF BIOSPHERES, 39(6), 495–515.

By: J. Lindsey n, M. Ptaszek n & M. Taniguchi n

Contributors: J. Lindsey n, M. Ptaszek n & M. Taniguchi n

author keywords: Prebiotic; Pyrrole; Porphyrinogen; Porphyrin; Self-assembly; Micelle; Photosynthesis
MeSH headings : Acetoacetates / chemistry; Aminolevulinic Acid / chemistry; Anaerobiosis; Cetrimonium; Cetrimonium Compounds / chemistry; Cetrimonium Compounds / metabolism; Esters / chemistry; Hot Temperature; Micelles; Oxidation-Reduction; Oxygen / metabolism; Photochemical Processes; Porphyrinogens / chemical synthesis; Porphyrinogens / metabolism; Solutions; Tetrapyrroles / chemistry; Water
TL;DR: The simple self-organization of eight acyclic molecules into a tetrapyrrole macrocycle, from which a porphyrin is derived that is photoactive in lipid assemblies, augurs well for the spontaneous origin of catalysts and pigments essential for prebiotic metabolism and proto-photosynthesis. (via Semantic Scholar)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2009 journal article

Synthesis and Photochemical Properties of 12-Substituted versus 13-Substituted Chlorins

JOURNAL OF ORGANIC CHEMISTRY, 74(15), 5276–5289.

By: O. Mass n, M. Ptaszek n, M. Taniguchi n, J. Diers*, H. Kee*, D. Bocian*, D. Holten*, J. Lindsey n

Contributors: O. Mass n, M. Ptaszek n, M. Taniguchi n, J. Diers*, L. Hooi*, D. Bocian*, D. Holten*, J. Lindsey n

MeSH headings : Computer Simulation; Electrochemistry; Organometallic Compounds / chemical synthesis; Organometallic Compounds / chemistry; Oxidation-Reduction; Photochemistry; Porphyrins / chemical synthesis; Porphyrins / chemistry; Quantum Theory
TL;DR: A new rational route was developed for the synthesis of 8,9-dibromo-1-formyldipyrromethane that entailed InCl(3)-catalyzed condensation of 4-bromo -2-(hydroxymethyl)pyrrole and pyrrole to give the 8- bromodipyromethane, (ii) 1-formylation, and (iii) 9-Bromination. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2009 journal article

Synthetic Chlorins Bearing Auxochromes at the 3- and 13-Positions

The Journal of Organic Chemistry, 74(14), 5122–5122.

By: J. Laha, C. Muthiah, M. Taniguchi*, B. McDowell, M. Ptaszek & J. Lindsey*

Contributors: J. Laha, C. Muthiah, M. Taniguchi*, B. McDowell, M. Ptaszek & J. Lindsey*

Sources: Crossref, ORCID, NC State University Libraries
Added: August 28, 2020

2008 journal article

Accessing the near-infrared spectral region with stable, synthetic, wavelength-tunable bacteriochlorins

NEW JOURNAL OF CHEMISTRY, 32(6), 947–958.

By: M. Taniguchi n, D. Cramer n, A. Bhise n, H. Kee*, D. Bocian*, D. Holten*, J. Lindsey n

Contributors: M. Taniguchi n, D. Cramer n, A. Bhise n, H. Kee*, D. Bocian*, D. Holten*, J. Lindsey n

UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2008 journal article

Comparison of Electron-Transfer Rates for Metal- versus Ring-Centered Redox Processes of Porphyrins in Monolayers on Au(111)

LANGMUIR, 24(20), 12047–12053.

By: J. Jiao n, I. Schmidt n, M. Taniguchi n, J. Lindsey n & D. Bocian n

Contributors: J. Jiao n, I. Schmidt n, M. Taniguchi n, J. Lindsey n & D. Bocian n

TL;DR: The faster rates for the ring- versus metal-centered redox process are attributed to the participating molecular orbitals and their proximity to the surface (given that the porphyrins are relatively upright on the surface): a pi molecular orbital that has significant electron density at the meso-carbon atoms. (via Semantic Scholar)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2008 journal article

Determination of Ground-State Hole-Transfer Rates Between Equivalent Sites in Oxidized Multiporphyrin Arrays Using Time-Resolved Optical Spectroscopy

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 130(46), 15636–15648.

TL;DR: The ground-state hole-transfer processes are probed in a series of oxidized porphyrin triads with the focus being on determination of the rates between the nominally equivalent sites (Zn/Zn), which should aid the design of next-generation molecular architectures for applications in solar-energy conversion. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2008 patent

Refined routes to chlorin building blocks

By: J. Lindsey, M. Taniguchi, D. Ra, G. Mo & T. Balasubramanian

Source: NC State University Libraries
Added: August 6, 2018

2007 journal article

Effects of substituents on synthetic analogs of chlorophylls. Part 1: Synthesis, vibrational properties and excited-state decay characteristics

PHOTOCHEMISTRY AND PHOTOBIOLOGY, 83(5), 1110–1124.

By: H. Kee*, C. Kirmaier*, Q. Tang*, J. Diers*, C. Muthiah n, M. Taniguchi n, J. Laha n, M. Ptaszek n ...

Contributors: H. Kee*, C. Kirmaier*, Q. Tang*, J. Diers*, C. Muthiah n, M. Taniguchi n, J. Laha n, M. Ptaszek n ...

TL;DR: The spectral, vibrational and excited‐state decay characteristics are examined for a set of synthetic chlorins and the zinc chlorins with the red‐most fluorescence also have the greatest radiative decay rate constant and are expected to have the fastest nonradiative internal conversion to the ground state. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2007 journal article

Effects of substituents on synthetic analogs of chlorophylls. Part 2: Redox properties, optical spectra and electronic structure

PHOTOCHEMISTRY AND PHOTOBIOLOGY, 83(5), 1125–1143.

By: H. Kee*, C. Kirmaier*, G. Tang*, J. Diers*, C. Muthiah n, M. Taniguchi n, J. Laha n, M. Ptaszek n ...

Contributors: H. Kee*, C. Kirmaier*, Q. Tang*, J. Diers*, C. Muthiah n, M. Taniguchi n, J. Laha n, M. Ptaszek n ...

MeSH headings : Chlorophyll / chemistry; Mass Spectrometry / methods; Molecular Structure; Nuclear Magnetic Resonance, Biomolecular; Oxidation-Reduction; Porphyrins / chemistry; Spectrometry, Fluorescence; Spectrum Analysis / methods
TL;DR: Insight is provided into the effects of substituents on the optical absorption, redox and other photophysical properties of the chlorins that form a framework that underpins the rational design of chlorins for applications encompassing photomedicine and solar‐energy conversion. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2007 journal article

Examination of tethered porphyrin, chlorin, and bacteriochlorin molecules in mesoporous metal-oxide solar cells

JOURNAL OF PHYSICAL CHEMISTRY C, 111(42), 15464–15478.

By: J. Stromberg n, A. Marton n, H. Kee n, C. Kirmaier n, J. Diers n, C. Muthiah n, M. Taniguchi n, J. Lindsey n ...

Contributors: J. Stromberg n, A. Marton n, H. Kee n, C. Kirmaier n, J. Diers n, C. Muthiah n, M. Taniguchi n, J. Lindsey n ...

UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (Web of Science; OpenAlex)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2007 journal article

PhotochemCAD 2: A Refined Program with Accompanying Spectral Databases for Photochemical Calculations¶

Photochemistry and Photobiology, 81(1), 212–213.

By: J. Dixon n, M. Taniguchi n & J. Lindsey n

UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Source: ORCID
Added: October 17, 2021

2007 journal article

Regioselective 15-bromination and functionalization of a stable synthetic bacteriochlorin

JOURNAL OF ORGANIC CHEMISTRY, 72(14), 5350–5357.

By: D. Fan n, M. Taniguchi n & J. Lindsey n

Contributors: D. Fan n, M. Taniguchi n & J. Lindsey n

MeSH headings : Bromine / chemistry; Deuterium Exchange Measurement; Magnetic Resonance Spectroscopy; Molecular Structure; Palladium / chemistry; Porphyrins / chemical synthesis; Porphyrins / chemistry; Spectrophotometry; Stereoisomerism
TL;DR: The 15-bromo-5-methoxybacteriochlorin MeO-BC-Br15 was subjected to three types of Pd-mediated coupling reactions to give six bacteriochlorins bearing functional groups at the 15-position, which enables synthetic bacterio chlorins to be tailored for a variety of applications. (via Semantic Scholar)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2007 review

Sparsely substituted chlorins as core constructs in chlorophyll analogue chemistry. Part 1: Synthesis

[Review of ]. TETRAHEDRON, 63(18), 3826–3839.

By: M. Ptaszek n, B. McDowell n, M. Taniguchi n, H. Kim n & J. Lindsey n

Contributors: M. Ptaszek n, B. McDowell n, M. Taniguchi n, H. Kim n & J. Lindsey n

author keywords: chlorin; hydroporphyrin; hydrodipyrrin; dipyrromethane
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2007 journal article

Sparsely substituted chlorins as core constructs in chlorophyll analogue chemistry. Part 2: Derivatization

TETRAHEDRON, 63(18), 3840–3849.

By: M. Taniguchi n, M. Ptaszek n, B. McDowell n & J. Lindsey n

Contributors: M. Taniguchi n, M. Ptaszek n, B. McDowell n & J. Lindsey n

author keywords: chlorin; deuteration; bromination; metalation
TL;DR: The kinetics of deuteration also have been determined for two oxochlorins and a series of chlorins bearing 0, 1, 2, or 3 meso-aryl substituents. (via Semantic Scholar)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2007 journal article

Sparsely substituted chlorins as core constructs in chlorophyll analogue chemistry. Part 3: Spectral and structural properties

TETRAHEDRON, 63(18), 3850–3863.

By: M. Taniguchi n, M. Ptaszek n, B. McDowell n, P. Boyle n & J. Lindsey n

Contributors: M. Taniguchi n, M. Ptaszek n, B. McDowell n, P. Boyle n & J. Lindsey n

author keywords: chlorin; NMR; absorption spectra; X-ray
TL;DR: The studies described herein report absorption spectra of diverse chlorins, comparative NMR features of chlorins bearing 0-3 meso-aryl substituents, and X-ray structures of the fully unsubstituted chlorin and the oxochlorin. (via Semantic Scholar)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2007 journal article

Synthesis and photophysical characterization of porphyrin, chlorin and bacteriochlorin molecules bearing tethers for surface attachment

PHOTOCHEMISTRY AND PHOTOBIOLOGY, 83(6), 1513–1528.

By: C. Muthiah n, M. Taniguchi n, H. Kim n, I. Schmidt n, H. Kee*, D. Holten*, D. Bocian*, J. Lindsey n

Contributors: C. Muthiah n, M. Taniguchi n, H. Kim n, I. Schmidt n, H. Kee*, D. Holten*, D. Bocian*, J. Lindsey n

MeSH headings : Molecular Structure; Photochemistry; Porphyrins / chemical synthesis; Porphyrins / chemistry; Spectrophotometry; Surface Properties
TL;DR: The synthesis and characterization of the tetrapyrrole compounds underpin their use as sensitizers in molecular‐based solar cells and hold promise for diverse studies in artificial photosynthesis. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2006 journal article

A new route for installing the isocyclic ring on chlorins yielding 13(1)-oxophorbines

JOURNAL OF ORGANIC CHEMISTRY, 71(18), 7049–7052.

By: J. Laha n, C. Muthiah n, M. Taniguchi n & J. Lindsey n

Contributors: J. Laha n, C. Muthiah n, M. Taniguchi n & J. Lindsey n

MeSH headings : Chemistry, Organic / methods; Heterocyclic Compounds / chemical synthesis; Heterocyclic Compounds / chemistry; Porphyrins / chemistry; Spectrometry, Fluorescence; Spectrum Analysis / methods
TL;DR: A new route to 13(1)-oxophorbines, the parent macrocycle of chlorophylls, begins with the synthesis of a 13-bromochlorin through pd-mediated coupling of the latter with tributyl(1-ethoxyvinyl)tin and subsequent acidic hydrolysis. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2006 journal article

Alkylthio unit as an alpha-pyrrole protecting group for use in dipyrromethane synthesis

JOURNAL OF ORGANIC CHEMISTRY, 71(3), 903–910.

By: P. Thamyongkit n, A. Bhise n, M. Taniguchi n & J. Lindsey n

Contributors: P. Thamyongkit n, A. Bhise n, M. Taniguchi n & J. Lindsey n

MeSH headings : Alkylation; Benzaldehydes / chemistry; Kinetics; Methylation; Molecular Structure; Oxidation-Reduction; Pyrroles / chemical synthesis; Pyrroles / chemistry; Sulfhydryl Compounds / chemistry
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2006 journal article

Masked imidazolyl-dipyrromethanes in the synthesis of imidazole-substituted porphyrins

JOURNAL OF ORGANIC CHEMISTRY, 71(23), 8807–8817.

By: J. Bhaumik n, Z. Yao n, K. Borbas n, M. Taniguchi n & J. Lindsey n

Contributors: J. Bhaumik n, Z. Yao n, K. Borbas n, M. Taniguchi n & J. Lindsey n

MeSH headings : Imidazoles / chemistry; Molecular Conformation; Porphyrins / chemical synthesis; Porphyrins / chemistry; Pyrroles / chemistry; Stereoisomerism
TL;DR: This work establishes the foundation for the rational synthesis of a variety of porphyrins containing imidazole units by using the 2-(trimethylsilyl)ethoxymethyl (SEM) group at the imdazole pyrrolic nitrogen and a dialkylboron motif. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2006 patent

Scalable synthesis of dipyrromethanes

Washington, DC: U.S. Patent and Trademark Office.

By: J. Lindsey, S. Dhanalekshmi, J. Laha & M. Taniguchi

Source: NC State University Libraries
Added: August 6, 2018

2006 journal article

Synthetic chlorins bearing auxochromes at the 3- and 13-positions

JOURNAL OF ORGANIC CHEMISTRY, 71(11), 4092–4102.

By: J. Laha n, C. Muthiah n, M. Taniguchi n, B. McDowell n, M. Ptaszek n & J. Lindsey n

Contributors: J. Laha n, C. Muthiah n, M. Taniguchi n, B. McDowell n, M. Ptaszek n & J. Lindsey n

MeSH headings : Chlorophyll / chemistry; Molecular Structure; Porphyrins / chemical synthesis
TL;DR: This study provides access to finely tuned chlorins for spectroscopic studies and diverse applications using zinc chlorins bearing a 3-TIPS-ethynyl-13-acetyl or a 3,13-diacetyl group exhibit a number of spectral properties resembling those of chlorophyll a or its zinc analogue. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2005 journal article

1,9-bis(N,N-dimethylaminomethyl)dipyrromethanes in the synthesis of porphyrins bearing one or two meso substituents

TETRAHEDRON, 61(43), 10291–10302.

By: D. Fan n, M. Taniguchi n, Z. Yao n, S. Dhanalekshmi n & J. Lindsey n

Contributors: D. Fan n, M. Taniguchi n, Z. Yao n, S. Dhanalekshmi n & J. Lindsey n

author keywords: dipyrromethane; aminomethylation; porphyrin; zinc
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2005 journal article

Imine-substituted dipyrromethanes in the synthesis of porphyrins bearing one or two meso substituents

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 9(8), 554–574.

By: M. Taniguchi n, A. Balakumar n, D. Fan n, B. McDowell n & J. Lindsey n

Contributors: M. Taniguchi n, A. Balakumar n, D. Fan n, B. McDowell n & J. Lindsey n

author keywords: dipyrromethane; pyrrole; imine; Schiff's base; porphyrin; aerobic oxidation; dipyrrin; self-assembly; zinc
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2005 journal article

Introduction of a third meso substituent into 5,10-diaryl chlorins and oxochlorins

JOURNAL OF ORGANIC CHEMISTRY, 70(1), 275–285.

By: M. Taniguchi n, M. Kim n, D. Ra n & J. Lindsey n

Contributors: M. Taniguchi n, N. Man n, D. Ra n & J. Lindsey n

MeSH headings : Catalysis; Hydrocarbons, Halogenated / chemistry; Magnetic Resonance Spectroscopy; Metalloporphyrins / chemical synthesis; Metalloporphyrins / chemistry; Molecular Structure; Palladium / chemistry; Porphyrins / chemical synthesis; Porphyrins / chemistry; Zinc / chemistry
TL;DR: Access is provided to new chlorins/oxochlorins that can be utilized in diverse applications and causes an approximately 5-nm red shift of the long wavelength Q(y) absorption band. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2005 journal article

PhotochemCAD 2: A Refined Program with Accompanying Spectral Databases for Photochemical Calculations

PHOTOCHEMISTRY AND PHOTOBIOLOGY, 81(1), 212–213.

By: J. Dixon*, M. Taniguchi* & J. Lindsey*

Contributors: J. Dixon*, M. Taniguchi* & J. Lindsey*

TL;DR: The PhotochemCAD program has been revised extensively and the user interface has been streamlined to facilitate visual display, operation of the various modules, input of user data via a wizard and output of spectra and calculations. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2005 patent

Refined routes to chlorin building blocks

Washington, DC: U.S. Patent and Trademark Office.

By: J. Lindsey, M. Taniguchi, D. Ra, G. M & T. Balasubramanian

Source: NC State University Libraries
Added: August 6, 2018

2005 journal article

Refined synthesis of 2,3,4,5-tetrahydro-1,3,3-trimethyidipyrrin, a deceptively simple precursor to hydroporphyrins

ORGANIC PROCESS RESEARCH & DEVELOPMENT, 9(5), 651–659.

By: M. Ptaszek n, J. Bhaumik n, H. Kim n, M. Taniguchi n & J. Lindsey n

Contributors: M. Ptaszek n, J. Bhaumik n, H. Kim n, M. Taniguchi n & J. Lindsey n

TL;DR: The prior 5-step synthesis of 1 from pyrrole-2-carboxaldehyde employed relatively simple and well-known reactions yet suffered from several drawbacks, including limited scale and lessened reliance on chromatography. (via Semantic Scholar)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2004 journal article

A tin-complexation strategy for use with diverse acylation methods in the preparation of 1,9-diacyldipyrromethanes

JOURNAL OF ORGANIC CHEMISTRY, 69(3), 765–777.

By: S. Tamaru n, L. Yu n, W. Youngblood n, K. Muthukumaran n, M. Taniguchi n & J. Lindsey n

Contributors: S. Tamaru n, L. Yu n, W. Youngblood n, K. Muthukumaran n, M. Taniguchi n & J. Lindsey n

MeSH headings : Acylation; Crystallography, X-Ray; Indicators and Reagents / chemistry; Methane / analogs & derivatives; Methane / chemical synthesis; Methanol / analogs & derivatives; Molecular Structure; Organotin Compounds / chemistry; Porphyrins / chemical synthesis; Pyrroles / chemical synthesis; Pyrroles / chemistry
TL;DR: The tin-complexation strategy has broad scope, is compatible with diverse acylation methods, and greatly facilitates access to 1,9-diacyldipyrromethane-tin complexes. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2004 journal article

PhotochemCAD 2. A Refined Program with Accompanying Spectral Database for Photochemical Calculations

Photochemistry and Photobiology.

By: J. Dixon n, M. Taniguchi n & J. Lindsey n

TL;DR: The PhotochemCAD program has been revised extensively and the user interface has been streamlined to facilitate visual display, operation of the various modules, input of user data via a wizard and output of spectra and calculations. (via Semantic Scholar)
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Source: ORCID
Added: October 17, 2021

2004 journal article

Photophysical properties of phenylethyne-linked porphyrin and oxochlorin dyads

JOURNAL OF PHYSICAL CHEMISTRY B, 108(24), 8190–8200.

By: E. Hindin n, C. Kirmaier n, . Diers n, K. Tomizaki n, M. Taniguchi n, J. Lindsey n, D. Bocian n, D. Holten n

Contributors: E. Hindin n, C. Kirmaier n, J. Diers n, K. Tomizaki n, M. Taniguchi n, J. Lindsey n, D. Bocian n, D. Holten n

UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2004 patent

Regioisomerically pure oxochlorins and methods of synthesis

Washington, DC: U.S. Patent and Trademark Office.

By: J. Lindsey, M. Taniguchi, S. Prathapan, M. Kim & H. Kim

Source: NC State University Libraries
Added: August 6, 2018

2004 journal article

Synthesis of phenylethyne-linked porphyrin dyads

TETRAHEDRON, 60(9), 2011–2023.

By: K. Tomizaki n, A. Lysenko n, M. Taniguchi n & J. Lindsey n

Contributors: K. Tomizaki n, A. Lysenko n, M. Taniguchi n & J. Lindsey n

author keywords: porphyrin; dipyrromethane; ethyne; phenylethyne; energy transfer
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2003 journal article

A scalable synthesis of meso-substituted dipyrromethanes

ORGANIC PROCESS RESEARCH & DEVELOPMENT, 7(6), 799–812.

By: J. Laha n, S. Dhanalekshmi n, M. Taniguchi n, A. Ambroise n & J. Lindsey n

Contributors: J. Laha n, S. Dhanalekshmi n, M. Taniguchi n, A. Ambroise n & J. Lindsey n

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2003 journal article

Comparison of excited-state energy transfer in arrays of hydroporphyrins (chlorins, oxochlorins) versus porphyrins: Rates, mechanisms, and design criteria

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 125(44), 13461–13470.

By: M. Taniguchi n, D. Ra n, C. Kirmaier n, E. Hindin n, J. Schwartz n, . Diers n, R. Knox n, D. Bocian n, J. Lindsey n, D. Holten n

Contributors: M. Taniguchi n, D. Ra n, C. Kirmaier n, E. Hindin n, J. Schwartz n, J. Diers n, R. Knox n, D. Bocian n, J. Lindsey n, D. Holten n

TL;DR: Taken together, the chlorin and oxochlorin dyads examined herein serve as benchmarks for elucidating the energy-transfer, electrochemical, and other properties of light-harvesting arrays containing multiple chlorins or Oxochlorins. (via Semantic Scholar)
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2003 journal article

Synthesis and excited-state photodynamics of perylene-bis(imide)-oxochlorin dyads. A charge-separation motif

JOURNAL OF PHYSICAL CHEMISTRY B, 107(15), 3443–3454.

By: C. Kirmaier n, E. Hindin n, J. Schwartz n, . Sazanovich n, . Diers n, K. Muthukumaran n, M. Taniguchi n, D. Bocian n, J. Lindsey n, D. Holten n

Contributors: C. Kirmaier n, E. Hindin n, J. Schwartz n, I. Sazanovich n, J. Diers n, K. Muthukumaran n, M. Taniguchi n, D. Bocian n, J. Lindsey n, D. Holten n

UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: ORCID, Web Of Science, NC State University Libraries
Added: August 6, 2018

2002 journal article

Synthesis and electronic properties of regioisomerically pure oxochlorins

JOURNAL OF ORGANIC CHEMISTRY, 67(21), 7329–7342.

By: M. Taniguchi n, H. Kim n, D. Ra n, J. Schwartz n, C. Kirmaier n, E. Hindin n, . Diers n, S. Prathapan n ...

Contributors: M. Taniguchi n, D. Holten n, J. Lindsey n, H. Kim n, D. Ra n, J. Schwartz n, C. Kirmaier n, E. Hindin n ...

MeSH headings : Indicators and Reagents; Models, Molecular; Molecular Conformation; Molecular Structure; Oxidation-Reduction; Porphyrins / chemical synthesis; Porphyrins / chemistry; Spectrophotometry; Stereoisomerism
TL;DR: Collectively, the fluorescence yields, excited-state lifetimes, oxidation potentials, and various spectral characteristics of the chlorin and oxochlorin building blocks provide the foundation for studies of photochemical processes in larger architectures based on these chromophores. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2001 journal article

Synthesis of meso-substituted chlorins via tetrahydrobilene-a intermediates

JOURNAL OF ORGANIC CHEMISTRY, 66(22), 7342–7354.

By: M. Taniguchi n, D. Ra n, G. Mo n, T. Balasubramanian n & J. Lindsey n

Contributors: M. Taniguchi n, D. Ra n, G. Mo n, T. Balasubramanian n & J. Lindsey n

MeSH headings : Photochemistry; Pigments, Biological / chemical synthesis; Pigments, Biological / chemistry; Porphyrins / chemical synthesis; Porphyrins / chemistry; Spectrum Analysis; Zinc
UN Sustainable Development Goal Categories
Sources: ORCID, Web Of Science, NC State University Libraries
Added: August 6, 2018

1999 journal article

Layered [3.3]Orthocyclophane Tricarbonylchromium Complexes

Zeitschrift Für Anorganische Und Allgemeine Chemie, 625(8), 1249–1251.

By: M. Taniguchi*, T. Thiemann*, T. Sawada* & S. Mataka*

author keywords: cyclophanes; chromium; pi-interaction
Source: ORCID
Added: October 17, 2021

1999 journal article

Novel rearrangement of conformationally restrained [3.3]orthocyclophanes

Journal of the Chemical Society, Perkin Transactions 1, (15), 2101–2108.

By: S. Isobe, M. Taniguchi*, T. Sawada*, T. Thiemann, T. Yonemitsu & S. Mataka*

Source: ORCID
Added: October 17, 2021

1999 journal article

Synthesis of 8,16-dimethyl- and 8,16-dimethoxy-5,13-di-t-butyl[2.2]metacyclophane-1,2,9,10-tetraone

Tetrahedron Letters, 40(25), 4691–4692.

By: K. Tsukamoto*, D. Sahade*, M. Taniguchi*, T. Sawada*, T. Thiemann* & S. Mataka*

Source: ORCID
Added: October 17, 2021

1999 journal article

Thieno[3.3]orthocyclophanes: preparations and structures

New Journal of Chemistry, 23(7), 675–678.

By: T. Thiemann*, D. Ohira*, Y. Li*, T. Sawada*, M. Taniguchi*, M. Tashiro*, S. Mataka*

Source: ORCID
Added: October 17, 2021

1998 journal article

Benzo[3.3]benzo[3.3]benzo- and naphtho[3.3]benzo[3.3]naphtho-orthocyclophane bis(alcohol)s. Preparations and structures

Tetrahedron, 54(20), 5171–5186.

By: S. Mataka*, Y. Mitoma*, T. Sawada*, T. Thiemann*, M. Taniguchi* & M. Tashiro*

Source: ORCID
Added: October 17, 2021

1998 journal article

Quadrupeldecker-[3.3][3.3][3.3]Orthocyclophanacetal: eine Orthocyclophan-Leiter

Angewandte Chemie, 110(18), 2626–2628.

By: S. Mataka*, K. Shigaki*, T. Sawada*, Y. Mitoma*, M. Taniguchi*, T. Thiemann*, K. Ohga*, N. Egashira*

Source: ORCID
Added: October 17, 2021

1998 journal article

Quadruple Decker [3.3][3.3][3.3]Orthocyclophane Acetal—An Orthocyclophane Ladder

Angewandte Chemie International Edition, 37(18), 2532–2534.

By: S. Mataka*, K. Shigaki*, T. Sawada*, Y. Mitoma*, M. Taniguchi*, T. Thiemann*, K. Ohga*, N. Egashira*

author keywords: cations; cyclic voltammetry; cyclophanes; stacking interactions
TL;DR: Through clever bridging of orthocyclophanes (in this case by acetalization), molecules such as 1 can be formed with four benzene rings in a stacked face-to-face arrangement that governs UV/Vis spectroscopic and electrochemical properties. (via Semantic Scholar)
Source: ORCID
Added: October 17, 2021

1998 journal article

Radiosynthesis of [18F]N-(4-phenylbutyl)-4-(4-fluorobenzoyl)piperidine for studying serotonin 5-HT2a receptors

Journal of Labelled Compounds and Radiopharmaceuticals, 41(10), 941–949.

By: K. Hashimoto*, K. Hatano, Y. Minabe*, M. Iyo*, M. Taniguchi*, O. Hoshino*, Y. Sakiyama, Y. Kawasumi

author keywords: serotonin 5-HT2A receptor; fluorine-18; radiolabeling; positron emission tomography (PET)
TL;DR: N-( 4-Phenylbutyl)-4-(4-fluorobenzoyl)piperidine [4-PBFBP] shows highly selective binding to serotonin 5-HT 2A receptors with high affinity and is prepared for in vivo study of 5- HT2A receptors in the brain using positron emission tomography (PET). (via Semantic Scholar)
Source: ORCID
Added: October 17, 2021

1998 journal article

The Study of π–π Interaction in Layered [3.3]Orthocyclophanes. Charge-Transfer Complexes of [3.3]Orthocyclophanes with Tetracyanoethylene

Bulletin of the Chemical Society of Japan, 71(11), 2661–2668.

By: M. Taniguchi*, S. Mataka*, T. Thiemann*, T. Sawada*, K. Mimura & Y. Mitoma

Source: ORCID
Added: October 17, 2021

1997 journal article

Bisacetals of aromatic ring-annelated . [3.3][3.3]Orthocyclophanes with triple-layered benzo/benzo/benzo- and naphtho/benzo/naphtho-system

Tetrahedron, 53(9), 3015–3026.

By: S. Mataka, Y. Mitoma, T. Thiemann, T. Sawada, M. Taniguchi*, M. Kobuchi, M. Tashiro

Source: ORCID
Added: October 17, 2021

1997 journal article

Conformational Analysis of Spirocyclopropane- and Spirooxirane-annelated Dibenzobicyclo[4.4.1]undecanes by 1H NMR Spectroscopy and X-Ray Crystallography

Journal of Chemical Research, (2), 48–49.

By: S. Mataka*, T. Sawada*, M. Tashiro*, M. Taniguchi* & Y. Mitroma*

Source: ORCID
Added: October 17, 2021

1996 journal article

Triple-layered orthonaphtho[3.3]orthobenzeno[3.3]orthonaphthophane

Tetrahedron Letters, 37(1), 65–68.

By: S. Mataka*, Y. Mitoma*, T. Sawada* & M. Tashiro*

Source: ORCID
Added: October 17, 2021

Employment

Updated: June 29th, 2016 18:36

NCSU Raleigh, NC, US
Chemsitry

Education

Updated: August 1st, 2018 09:15

1995 - 2000

Kyushu University, Graduate School of Engineering and Sciences Kasuga, Fukuoka, JP
PhD in Engineering Graduate School of Engineering and Sciences

1991 - 1995

Science University of Tokyo Tokyo, Tokyo, JP
Bs in Pharmacy Faculty of Pharmaceutical Sciences

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