@article{orenstein_li_dirican_cheng_chang_yanilmaz_yan_zhang_2024, title={A Comparatively Low Cost, Easy-To-Fabricate, and Environmentally Friendly PVDF/Garnet Composite Solid Electrolyte for Use in Lithium Metal Cells Paired with Lithium Iron Phosphate and Silicon}, volume={6}, ISSN={["1944-8252"]}, url={https://doi.org/10.1021/acsami.4c04145}, DOI={10.1021/acsami.4c04145}, abstractNote={Solid electrolytes may be the answer to overcome many obstacles in developing the next generation of renewable batteries. A novel composite solid electrolyte (CSE) composed of a poly(vinylidene fluoride) (PVDF) base with an active nanofiber filler of aluminum-doped garnet Li ceramic, Li salt lithium bis-(trifluoromethanesulfonyl)imide (LiTFSI), Li fluoride (LiF) stabilizing additive, and plasticizer sulfolane was fabricated. In a Li|CSE|LFP cell with this CSE, a high capacity of 168 mAh g–1 with a retention of 98% after 200 cycles was obtained, representing the best performance to date of a solid electrolyte with a PVDF base and a garnet inorganic filler. In a Li metal cell with Si and Li, it yielded a discharge capacity of 2867 mAh g–1 and was cycled 60 times at a current density of 100 mAh g–1, a significant step forward in utilizing a solid electrolyte of any kind with the desirable Si anode. In producing this CSE, the components and fabrication process were chosen to have a lower cost and improved safety and environmental impact compared with the current state-of-the-art Li-ion battery.}, journal={ACS APPLIED MATERIALS & INTERFACES}, author={Orenstein, Raphael and Li, Zezhao and Dirican, Mahmut and Cheng, Hui and Chang, Liang and Yanilmaz, Meltem and Yan, Chaoyi and Zhang, Xiangwu}, year={2024}, month={Jun} } @article{liu_yuan_chen_yuan_yanilmaz_he_liu_zhang_2024, title={Advancements in flame-retardant strategies for lithium-sulfur batteries: from mechanisms to materials}, volume={6}, ISSN={["2050-7496"]}, DOI={10.1039/d4ta01780c}, abstractNote={Due to the extraordinary theoretical energy density, high specific capacity, and environment friendly, lithium-sulfur batteries (LSBs) have been considered as the most promising candidates for energy storage systems. In recent...}, journal={JOURNAL OF MATERIALS CHEMISTRY A}, author={Liu, Jian and Yuan, Hairui and Chen, Lei and Yuan, Yehui and Yanilmaz, Meltem and He, Jin and Liu, Yong and Zhang, Xiangwu}, year={2024}, month={Jun} } @article{yanilmaz_chen_cheng_lee_kim_2024, title={Flexible Centrifugally Spun N, S-Doped SnS2-Including Porous Carbon Nanofiber Electrodes for Na-Ion Batteries}, ISSN={["2470-1343"]}, DOI={10.1021/acsomega.4c01138}, abstractNote={Carbon nanofibers are promising for various applications such as energy storage, sensors, and biomedical applications; however, the brittle structure of nanofibers limits the usage of carbon nanofibers. For the first time, a facile and effective strategy is reported to fabricate flexible carbon nanofibers via a fast and safe nanofiber fabrication technique, centrifugal spinning, followed by heat treatment. Moreover, sulfidization was employed to fabricate high-performance flexible N, S-doped SnS}, journal={ACS OMEGA}, author={Yanilmaz, Meltem and Chen, Lei and Cheng, Hui and Lee, Kyung Eun and Kim, Juran}, year={2024}, month={May} } @article{zhang_chen_orenstein_lu_wang_yanilmaz_peng_dong_liu_zhang_2024, title={Zincophilic and hydrophobic groups of surfactant-type electrolyte additive enabled stable anode/electrolyte interface toward long-lifespan aqueous zinc ion batteries}, volume={70}, ISSN={["2405-8289"]}, DOI={10.1016/j.ensm.2024.103500}, journal={ENERGY STORAGE MATERIALS}, author={Zhang, Xiaoliang and Chen, Lei and Orenstein, Raphael and Lu, Xiaojie and Wang, Chunxia and Yanilmaz, Meltem and Peng, Mao and Dong, Yongchun and Liu, Yong and Zhang, Xiangwu}, year={2024}, month={Jun} } @article{chen_hu_yang_yanilmaz_han_liu_zhang_2023, title={A braided flexible Zn-MnO2 yarn battery based on cobweb-like carbonized polypyrrole modified carbon fiber electrodes}, volume={215}, ISSN={["1873-3891"]}, url={https://doi.org/10.1016/j.carbon.2023.118461}, DOI={10.1016/j.carbon.2023.118461}, abstractNote={Flexible zinc ion batteries (ZIBs) are promising candidates for energy storage devices because of high safety and low cost. Carbon fibers (CFs) are ideal current collectors for ZIBs due to their good flexibility, electrical conductivity and corrosion resistance. Herein, a novel CFs-based current collector is proposed. At first, the inertness and non-polarity of CFs were significantly modified by activating and etching to obtain a multi-layered porous structure. Thereafter, carbonized polypyrrole (CPPy) nanowire conductive networks were built up on etched carbon fibers (ECFs) by electrochemical in situ growth and carbonization. Based on the CPPy network, MnO2 nanoflowers were grown firmly by the hydrothermal method to construct multi-layer MnO2@CPPy@ECFs composite electrode. The multi-layered 3D CPPy conductive network is rooted in MnO2, providing a dedicated transmission path for both electrons and ions during electrochemical redox reactions. The MnO2@CPPy@ECFs electrode had an initial capacity of 346.1 mA h·g−1 at 0.1 A g−1 and 252.8 mA h·g−1 after 800 cycles. In addition, the integrated flexible Zn–MnO2 2D fabric battery with MnO2@CPPy@ECFs fabric cathode shows a specific capacity of 254.7 mA h·g−1 at 0.1 A g−1. Finally, a flexible Zn–MnO2 yarn battery with high flexibility, shape adaptability, structural integrity and good mechanical stability was fabricated by the 2D braid method. The initial specific capacity of the flexible Zn–MnO2 yarn battery is 111.7 mA h·g−1 at 0.1C, which also presents a remarkable volumetric energy density of 30.5 mW h cm−3. This work opens up a new pathway for the rational design of flexible electrodes for wearable ZIBs.}, journal={CARBON}, author={Chen, Lei and Hu, Kairui and Yang, Ke and Yanilmaz, Meltem and Han, Xu and Liu, Yong and Zhang, Xiangwu}, year={2023}, month={Nov} } @article{chen_yuan_orenstein_yanilmaz_he_liu_liu_zhang_2023, title={Carbon materials dedicate to bendable supports for flexible lithium-sulfur batteries}, volume={60}, ISSN={["2405-8289"]}, url={https://doi.org/10.1016/j.ensm.2023.102817}, DOI={10.1016/j.ensm.2023.102817}, abstractNote={As a new energy storage device, lithium-sulfur battery (LSB) has a sulfur cathode with a much higher theoretical specific capacity (1675 mAh g−1) and energy density (2600 Wh kg−1) compared with current lithium-ion batteries, making it a promising candidate for the next generation of energy storage devices. In recent years, the emergence of wearable electronic devices and smart textiles has placed a new demand on energy storage batteries - flexibility. Carbon materials, namely carbon fibers and several carbon nanomaterials (such as carbon nanotubes, graphene, carbon nanofibers, porous carbon skeletons, and their derivatives) possess remarkable structural and functional adjustability, and are thus well suited for building components of flexible LSBs. These components include current collectors, interlayers, solid electrolytes and anodes. This paper systematically reviews research progress in carbon materials used in different components of flexible LSBs, including the sulfur cathode, interlayer, lithium anode, and dual-functional host carbon materials that can be used as both cathode and anode. Additionally, the relationship between the processing and modification methods and the carbon materials’ structure, flexibility, and electrochemical properties is described. Finally, the problems of flexible LSBs based on carbon materials are analyzed, and the future development trend is delineated, in a part, respectively.}, journal={ENERGY STORAGE MATERIALS}, author={Chen, Lei and Yuan, Yehui and Orenstein, Raphael and Yanilmaz, Meltem and He, Jin and Liu, Jian and Liu, Yong and Zhang, Xiangwu}, year={2023}, month={Jun} } @article{yanilmaz_asiri_zhang_2020, title={Centrifugally spun porous carbon microfibers as interlayer for Li-S batteries}, volume={55}, ISSN={["1573-4803"]}, DOI={10.1007/s10853-019-04215-y}, number={8}, journal={JOURNAL OF MATERIALS SCIENCE}, author={Yanilmaz, Meltem and Asiri, Abdullah M. and Zhang, Xiangwu}, year={2020}, month={Mar}, pages={3538–3548} } @article{yanilmaz_dirican_asiri_zhang_2019, title={Flexible polyaniline-carbon nanofiber supercapacitor electrodes}, volume={24}, ISSN={["2352-152X"]}, url={https://publons.com/publon/22573151/}, DOI={10.1016/j.est.2019.100766}, abstractNote={Flexible polyaniline-carbon nanofiber (PANI-CNF) composites were fabricated and evaluated for use as supercapacitor electrodes. Sol-gel and electrospinning techniques were employed to produce flexible carbon nanofibers and polyaniline coating was applied via in-situ chemical polymerization to further improve the electrochemical properties of the electrodes. The performance of flexible PANI-CNF electrodes was investigated in symmetric supercapacitor cells. Results showed that binder-free flexible PANI-CNF electrodes had high capacitance of 234 F/g and excellent cycling stability with capacitance retention of about 90% after 1000 cycles. Ragone plots were also presented and a high energy density of 32 Wh/kg at the power density of 500 W/kg was achieved for the flexible PANI-CNF electrode prepared with 12 h polymerization. In addition, mechanical tests demonstrated that free-standing PANI-CNF electrodes were durable and highly flexible. Therefore, combining sol-gel and electrospinning techniques is a facile and effective way to achieve flexible carbon nanofiber electrodes and this work provides a new approach for designing flexible electrodes with exceptional electrochemical performance, which is very promising for practical application in the energy storage field.}, journal={JOURNAL OF ENERGY STORAGE}, author={Yanilmaz, Meltem and Dirican, Mahmut and Asiri, Abdullah M. and Zhang, Xiangwu}, year={2019}, month={Aug} } @article{ge_zhu_dirican_jia_yanilmaz_lu_chen_qiu_zhang_2017, title={Fabrication and electrochemical behavior study of nano-fibrous sodium titanate composite}, volume={188}, ISSN={["1873-4979"]}, url={https://publons.com/publon/26924645/}, DOI={10.1016/j.matlet.2016.11.025}, abstractNote={Nanofiber structured Na2Ti3O7 was synthesized via electrospinning process which was further used as an anode material for sodium-ion batteries for the first time. One-dimensional construction of Na2Ti3O7 composite could contribute to better electrochemical activity. It was demonstrated that the capacity of Na2Ti3O7 nanofibers was significantly improved to 257.8 mAh g−1 at 30 mA g−1. Furthermore, the rate capability of Na2Ti3O7 nanofibers was significantly enhanced, showing charge capacities were 161.8, 116.5, and 72.4 mAh g−1 at 100, 200, and 400 mA g−1, respectively. Therefore, improved specific capacity and rate capability made Na2Ti3O7 nanofibers composite as a promising anode material for sodium-ion batteries.}, journal={MATERIALS LETTERS}, publisher={Elsevier BV}, author={Ge, Yeqian and Zhu, Jiadeng and Dirican, Mahmut and Jia, Hao and Yanilmaz, Meltem and Lu, Yao and Chen, Chen and Qiu, Yiping and Zhang, Xiangwu}, year={2017}, month={Feb}, pages={176–179} } @article{yanilmaz_zhu_lu_ge_zhang_2017, title={High-strength, thermally stable nylon 6,6 composite nanofiber separators for lithium-ion batteries}, volume={52}, ISSN={["1573-4803"]}, url={https://publons.com/publon/26924646/}, DOI={10.1007/s10853-017-0764-8}, number={9}, journal={JOURNAL OF MATERIALS SCIENCE}, publisher={Springer Nature}, author={Yanilmaz, Meltem and Zhu, Jiadeng and Lu, Yao and Ge, Yeqian and Zhang, Xiangwu}, year={2017}, month={May}, pages={5232–5241} } @article{lu_fu_zhu_chen_yanilmaz_dirican_ge_jiang_zhang_2016, title={Comparing the structures and sodium storage properties of centrifugally spun SnO2 microfiber anodes with/without chemical vapor deposition}, volume={51}, ISSN={["1573-4803"]}, url={https://publons.com/publon/26924656/}, DOI={10.1007/s10853-016-9768-z}, number={9}, journal={JOURNAL OF MATERIALS SCIENCE}, publisher={Springer Nature}, author={Lu, Yao and Fu, Kun and Zhu, Jiadeng and Chen, Chen and Yanilmaz, Meltem and Dirican, Mahmut and Ge, Yeqian and Jiang, Han and Zhang, Xiangwu}, year={2016}, month={May}, pages={4549–4558} } @article{yanilmaz_lu_zhu_zhang_2016, title={Silica/polyacrylonitrile hybrid nanofiber membrane separators via sol-gel and electrospinning techniques for lithium-ion batteries}, volume={313}, ISSN={["1873-2755"]}, url={https://publons.com/publon/26924661/}, DOI={10.1016/j.jpowsour.2016.02.089}, abstractNote={Silica/polyacrylonitrile (SiO2/PAN) hybrid nanofiber membranes were fabricated by using sol-gel and electrospinning techniques and their electrochemical performance was evaluated for use as separators in lithium-ion batteries. The aim of this study was to design high-performance separator membranes with enhanced electrochemical performance and good thermal stability compared to microporous polyolefin membranes. In this study, SiO2 nanoparticle content up to 27 wt% was achieved in the membranes by using sol-gel technique. It was found that SiO2/PAN hybrid nanofiber membranes had superior electrochemical performance with good thermal stability due to their high SiO2 content and large porosity. Compared with commercial microporous polyolefin membranes, SiO2/PAN hybrid nanofiber membranes had larger liquid electrolyte uptake, higher electrochemical oxidation limit, and lower interfacial resistance with lithium. SiO2/PAN hybrid nanofiber membranes with different SiO2 contents (0, 16, 19 and 27 wt%) were also assembled into lithium/lithium iron phosphate cells, and high cell capacities and good cycling performance were demonstrated at room temperature. In addition, cells using SiO2/PAN hybrid nanofiber membranes with high SiO2 contents showed superior C-rate performance compared to those with low SiO2 contents and commercial microporous polyolefin membrane.}, journal={JOURNAL OF POWER SOURCES}, publisher={Elsevier BV}, author={Yanilmaz, Meltem and Lu, Yao and Zhu, Jiadeng and Zhang, Xiangwu}, year={2016}, month={May}, pages={205–212} } @article{zhu_yanilmaz_fu_chen_lu_ge_kim_zhang_2016, title={Understanding glass fiber membrane used as a novel separator for lithium-sulfur batteries}, volume={504}, ISSN={["1873-3123"]}, url={https://publons.com/publon/26924654/}, DOI={10.1016/j.memsci.2016.01.020}, abstractNote={Glass fiber (GF) membrane is evaluated as a potential separator for lithium–sulfur batteries. It is found that GF membrane has a highly porous structure with superior thermal stability, resulting in high liquid electrolyte uptake and enhanced electrochemical performance. Li–S cells using GF membrane as the separator can retain a capacity of 617 mA h g−1 after 100 cycles at a current density of 0.2 C, which is 42% higher than that of cells using commercial microporous polypropylene separator. During rate capability tests, the capacity of Li–S cells using GF membrane decreases slowly from the reversible capacity of 616 mA h g−1 at 0.2 C to 505, 394 and 262 mA h g−1 at 0.5 C, 1 C, and 2 C, respectively. It should be noted that these cells can still deliver a high capacity of 587 mA h g−1 with a high retention of 95% when the current density is lowered back to 0.2 C. The improved cycling and rate performance are ascribed to the fact that the highly porous GF membrane can increase the intake of soluble polysulfide intermediates and slow down their rapid diffusion to the Li anode side, which can not only improve the utilization of active material, but help protect the Li anode surface as well.}, journal={JOURNAL OF MEMBRANE SCIENCE}, publisher={Elsevier BV}, author={Zhu, Jiadeng and Yanilmaz, Meltem and Fu, Kun and Chen, Chen and Lu, Yao and Ge, Yeqian and Kim, David and Zhang, Xiangwu}, year={2016}, month={Apr}, pages={89–96} } @article{lu_fu_zhang_li_chen_zhu_yanilmaz_dirican_zhang_2015, title={Centrifugal spinning: A novel approach to fabricate porous carbon fibers as binder-free electrodes for electric double-layer capacitors}, volume={273}, ISSN={["1873-2755"]}, url={https://doi.org/10.1016/j.jpowsour.2014.09.130}, DOI={10.1016/j.jpowsour.2014.09.130}, abstractNote={Carbon nanofibers (CNFs), among various carbonaceous candidates for electric double-layer capacitor (EDLC) electrodes, draw extensive attention because their one-dimensional architecture offers both shortened electron pathways and high ion-accessible sites. Creating porous structures on CNFs yields larger surface area and enhanced capacitive performance. Herein, porous carbon nanofibers (PCNFs) were synthesized via centrifugal spinning of polyacrylonitrile (PAN)/poly(methyl methacrylate) (PMMA) solutions combined with thermal treatment and were used as binder-free EDLC electrodes. Three precursor fibers with PAN/PMMA weight ratios of 9/1, 7/3 and 5/5 were prepared and carbonized at 700, 800, and 900 °C, respectively. The highest specific capacitance obtained was 144 F g−1 at 0.1 A g−1 with a rate capability of 74% from 0.1 to 2 A g−1 by PCNFs prepared with PAN/PMMA weight ratio of 7/3 at 900 °C. These PCNFs also showed stable cycling performance. The present work demonstrates that PCNFs are promising EDLC electrode candidate and centrifugal spinning offers a simple, cost-effective strategy to produce PCNFs.}, journal={JOURNAL OF POWER SOURCES}, publisher={Elsevier BV}, author={Lu, Yao and Fu, Kun and Zhang, Shu and Li, Ying and Chen, Chen and Zhu, Jiadeng and Yanilmaz, Meltem and Dirican, Mahmut and Zhang, Xiangwu}, year={2015}, month={Jan}, pages={502–510} } @article{yanilmaz_zhang_2015, title={Polymethylmethacrylate/Polyacrylonitrile Membranes via Centrifugal Spinning as Separator in Li-Ion Batteries}, volume={7}, ISSN={["2073-4360"]}, url={https://publons.com/publon/26924671/}, DOI={10.3390/polym7040629}, abstractNote={Electrospun nanofiber membranes have been extensively studied as separators in Li-ion batteries due to their large porosity, unique pore structure, and high electrolyte uptake. However, the electrospinning process has some serious drawbacks, such as low spinning rate and high production cost. The centrifugal spinning technique can be used as a fast, cost-effective and safe technique to fabricate high-performance fiber-based separators. In this work, polymethylmethacrylate (PMMA)/polyacrylonitrile (PAN) membranes with different blend ratios were produced via centrifugal spinning and characterized by using different electrochemical techniques for use as separators in Li-ion batteries. Compared with commercial microporous polyolefin membrane, centrifugally-spun PMMA/PAN membranes had larger ionic conductivity, higher electrochemical oxidation limit, and lower interfacial resistance with lithium. Centrifugally-spun PMMA/PAN membrane separators were assembled into Li/LiFePO4 cells and these cells delivered high capacities and exhibited good cycling performance at room temperature. In addition, cells using centrifugally-spun PMMA/PAN membrane separators showed superior C-rate performance compared to those using microporous polypropylene (PP) membranes. It is, therefore, demonstrated that centrifugally-spun PMMA/PAN membranes are promising separator candidate for high-performance Li-ion batteries.}, number={4}, journal={POLYMERS}, publisher={MDPI AG}, author={Yanilmaz, Meltem and Zhang, Xiangwu}, year={2015}, month={Apr}, pages={629–643} } @article{yanilmaz_lu_li_zhang_2015, title={SiO2/polyacrylonitrile membranes via centrifugal spinning as a separator for Li-ion batteries}, volume={273}, ISSN={["1873-2755"]}, url={https://doi.org/10.1016/j.jpowsour.2014.10.015}, DOI={10.1016/j.jpowsour.2014.10.015}, abstractNote={Centrifugal spinning is a fast, cost-effective and safe alternative to the electrospinning technique, which is commonly used for making fiber-based separator membranes. In this work, SiO2/polyacrylonitrile (PAN) membranes were produced by using centrifugal spinning and they were characterized by using different electrochemical techniques for use as separators in Li-ion batteries. SiO2/PAN membranes exhibited good wettability and high ionic conductivity due to their highly porous fibrous structure. Compared with commercial microporous polyolefin membranes, SiO2/PAN membranes had larger liquid electrolyte uptake, higher electrochemical oxidation limit, and lower interfacial resistance with lithium. SiO2/PAN membrane separators were assembled into lithium/lithium iron phosphate cells and these cells delivered high capacities and exhibited good cycling performance at room temperature. In addition, cells using SiO2/PAN membranes showed superior C-rate performance compared to those using microporous PP membrane.}, journal={JOURNAL OF POWER SOURCES}, publisher={Elsevier BV}, author={Yanilmaz, Meltem and Lu, Yao and Li, Ying and Zhang, Xiangwu}, year={2015}, month={Jan}, pages={1114–1119} } @misc{lee_yanilmaz_toprakci_fu_zhang_2014, title={A review of recent developments in membrane separators for rechargeable lithium-ion batteries}, volume={7}, ISSN={["1754-5706"]}, url={https://publons.com/publon/674379/}, DOI={10.1039/c4ee01432d}, abstractNote={The separator of a lithium-ion battery prevents the direct contact between the positive and negative electrodes while serving as the electrolyte reservoir to enable the transportation of lithium ions between the two electrodes.}, number={12}, journal={ENERGY & ENVIRONMENTAL SCIENCE}, publisher={Royal Society of Chemistry (RSC)}, author={Lee, Hun and Yanilmaz, Meltem and Toprakci, Ozan and Fu, Kun and Zhang, Xiangwu}, year={2014}, pages={3857–3886} } @article{dirican_yanilmaz_fu_yildiz_kizil_hu_zhang_2014, title={Carbon-Confined PVA-Derived Silicon/Silica/Carbon Nanofiber Composites as Anode for Lithium-Ion Batteries}, volume={161}, ISSN={["1945-7111"]}, url={https://publons.com/publon/20548471/}, DOI={10.1149/2.0811414jes}, abstractNote={component of the composite anodes provided sufficient buffer function toaccommodate the volume expansion of the Si nanoparticles and the CVD amorphous carbon coating helped maintain the Sinanoparticleswithinthecarbonnanofibermatrixduringrepetitivecharginganddischargingprocesses.Electrochemicalperformancetests showed that the capacity retention of CVD carbon-coated Si/SiO}, number={14}, journal={JOURNAL OF THE ELECTROCHEMICAL SOCIETY}, publisher={The Electrochemical Society}, author={Dirican, Mahmut and Yanilmaz, Meltem and Fu, Kun and Yildiz, Ozkan and Kizil, Huseyin and Hu, Yi and Zhang, Xiangwu}, year={2014}, pages={A2197–A2203} } @article{dirican_yanilmaz_fu_lu_kizil_zhang_2014, title={Carbon-enhanced electrodeposited SnO2/carbon nanofiber composites as anode for lithium-ion batteries}, volume={264}, ISSN={["1873-2755"]}, url={https://publons.com/publon/20548470/}, DOI={10.1016/j.jpowsour.2014.04.102}, abstractNote={Tin oxides (SnO2) are promising anode material candidate for next-generation lithium-ion batteries due to their high capacity, low cost, high abundance, and low toxicity. However, the practical use of SnO2 anodes is currently limited by their large volume changes during cycling. Severe volume changes of SnO2 anodes lead to intense pulverization and loss of electrical contact between the active material and carbon conductor. Herein, we introduce binder-free SnO2-electrodeposited carbon nanofibers (CNF@SnO2) and SnO2-electrodeposited porous carbon nanofibers (PCNF@SnO2) composites that can maintain their structural stability during repeated charge–discharge cycling. Results indicated that the amount of the electrodeposited SnO2 nanoparticles and the capacity of the resultant composites were successfully enhanced by using a porous nanofiber structure. Both CNF@SnO2 and PCNF@SnO2 composites were also coated with amorphous carbon layers by chemical vapor deposition to further improve the structural stability. Electrochemical performance results demonstrated that the combination of porous nanofiber structure and CVD amorphous coating led to a novel carbon-coated PCNF@SnO2 composite anode with high capacity retention of 78% and large coulombic efficiency of 99.8% at the 100th cycle.}, journal={JOURNAL OF POWER SOURCES}, author={Dirican, Mahmut and Yanilmaz, Meltem and Fu, Kun and Lu, Yao and Kizil, Huseyin and Zhang, Xiangwu}, year={2014}, month={Oct}, pages={240–247} } @article{fu_lu_dirican_chen_yanilmaz_shi_bradford_zhang_2014, title={Chamber-confined silicon-carbon nanofiber composites for prolonged cycling life of Li-ion batteries}, volume={6}, ISSN={["2040-3372"]}, url={https://publons.com/publon/26924684/}, DOI={10.1039/c4nr00518j}, abstractNote={Silicon is confined within the empty chambers of carbon nanofibers, in which the volume expansion of Si can be buffered and SEI formation is controlled. This self-supported composite is a promising electrode candidate for use in flexible batteries.}, number={13}, journal={NANOSCALE}, publisher={Royal Society of Chemistry (RSC)}, author={Fu, Kun and Lu, Yao and Dirican, Mahmut and Chen, Chen and Yanilmaz, Meltem and Shi, Quan and Bradford, Philip D. and Zhang, Xiangwu}, year={2014}, pages={7489–7495} } @article{li_xu_yao_xue_yanilmaz_lee_zhang_2014, title={Coaxial electrospun Si/C-C core-shell composite nanofibers as binder-free anodes for lithium-ion batteries}, volume={258}, ISSN={["1872-7689"]}, url={https://publons.com/publon/11754002/}, DOI={10.1016/j.ssi.2014.02.003}, abstractNote={Si/C–C core–shell nanofiber structure was designed by dual nozzle coaxial electrospinning and subsequent carbonization. This core–shell nanofiber structure has Si/C composite as the core and carbon as the shell. Used as an anode in lithium-ion batteries, the carbon shell can help buffer the large volume expansion/contraction of the Si/C core during charge/discharge and restrain the capacity fading caused by the mechanical failure of the active material. Results showed that after 50 cycles, the discharge capacity of Si/C–C core–shell composite nanofibers was 63% higher than that of Si/C composite nanofibers and the capacity retention increased from 48.6 to 72.4%. It is, therefore, demonstrated that Si/C–C core–shell composite nanofibers are promising anode material with large reversible capacity and good cycling stability.}, journal={SOLID STATE IONICS}, author={Li, Ying and Xu, Guanjie and Yao, Yingfang and Xue, Leigang and Yanilmaz, Meltem and Lee, Hun and Zhang, Xiangwu}, year={2014}, month={May}, pages={67–73} } @article{yanilmaz_dirican_zhang_2014, title={Evaluation of electrospun SiO2/nylon 6,6 nanofiber membranes as a thermally-stable separator for lithium-ion batteries}, volume={133}, ISSN={["1873-3859"]}, url={https://publons.com/publon/26924686/}, DOI={10.1016/j.electacta.2014.04.109}, abstractNote={Electrospun SiO2/nylon 6,6 nanofiber membranes were fabricated and their electrochemical performance was evaluated for use as separators in Li-ion batteries. The aim of this study was to design new high-performance separator membranes with enhanced mechanical properties and good thermal stability, as well as superior electrochemical performance compared to microporous polyolefin membranes. It was found that SiO2/nylon 6,6 nanofiber membranes had superior thermal stability and mechanical strength with highly porous structure. Enhanced electrochemical properties were also obtained for these nanofiber membranes due to their high porosity values. Compared with commercial microporous polyolefin membranes, SiO2/nylon 6,6 nanofiber membranes had larger liquid electrolyte uptake, higher electrochemical oxidation limit, and lower interfacial resistance with lithium. SiO2/nylon 6,6 nanofiber membranes with different SiO2 contents (0, 3, 6, 9 and 12%) were assembled into lithium/lithium cobalt oxide and lithium/lithium iron phosphate cells. High cell capacities and good cycling performance were demonstrated at room temperature. In addition, cells using SiO2/nylon 6,6 nanofiber membrane separators showed superior C-rate performance compared to those using commercial microporous polyolefin membrane.}, journal={ELECTROCHIMICA ACTA}, publisher={Elsevier BV}, author={Yanilmaz, Meltem and Dirican, Mahmut and Zhang, Xiangwu}, year={2014}, month={Jul}, pages={501–508} } @article{dirican_yanilmaz_zhang_2014, title={Free-standing polyaniline-porous carbon nanofiber electrodes for symmetric and asymmetric supercapacitors}, volume={4}, ISSN={["2046-2069"]}, url={https://publons.com/publon/26924689/}, DOI={10.1039/c4ra09103e}, abstractNote={Polyaniline–porous carbon nanofiber composites were introduced for use as flexible, binder-less electrodes for high-performance supercapacitors.}, number={103}, journal={RSC ADVANCES}, publisher={Royal Society of Chemistry (RSC)}, author={Dirican, Mahmut and Yanilmaz, Meltem and Zhang, Xiangwu}, year={2014}, pages={59427–59435} } @article{yanilmaz_lu_dirican_fu_zhang_2014, title={Nanoparticle-on-nanofiber hybrid membrane separators for lithium-ion batteries via combining electrospraying and electrospinning techniques}, volume={456}, ISSN={["1873-3123"]}, url={https://publons.com/publon/26924682/}, DOI={10.1016/j.memsci.2014.01.022}, abstractNote={Nanoparticle-on-nanofiber hybrid membranes were prepared by electrospraying of SiO2 dispersions and electrospinning of polyvinylidene fluoride (PVDF) solution simultaneously. The aim of this study was to design new high-performance separator membranes with superior electrochemical properties such as high C-rate performance and good thermal stability compared to polyolefin based membranes. Uniform, bead-free fibrous structure with high amount of SiO2 nanoparticles exposed on PVDF nanofiber surfaces was observed. It was found that wettability and ionic conductivity were improved by dispersing SiO2 nanoparticles onto PVDF nanofiber surfaces. Electrochemical properties were enhanced due to the increased surface area caused by the unique hybrid structure of SiO2 nanoparticles and PVDF nanofibers. Compared with commercial microporous polyolefin membranes, SiO2/PVDF hybrid membranes had larger liquid electrolyte uptake, higher electrochemical oxidation limit, and lower interfacial resistance with lithium. SiO2/PVDF hybrid membrane separators were assembled into lithium/lithium iron phosphate cells and demonstrated high cell capacities and good cycling performance at room temperature. In addition, cells using SiO2/PVDF hybrid membrane separators showed superior C-rate performance compared to those using commercial microporous PP membrane.}, journal={JOURNAL OF MEMBRANE SCIENCE}, author={Yanilmaz, Meltem and Lu, Yao and Dirican, Mahmut and Fu, Kun and Zhang, Xiangwu}, year={2014}, month={Apr}, pages={57–65} } @article{yanilmaz_chen_zhang_2013, title={Fabrication and Characterization of SiO2/PVDF Composite Nanofiber-Coated PP Nonwoven Separators for Lithium-Ion Batteries}, volume={51}, ISSN={["1099-0488"]}, url={https://publons.com/publon/7178359/}, DOI={10.1002/polb.23387}, abstractNote={ABSTRACT}, number={23}, journal={JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS}, author={Yanilmaz, Meltem and Chen, Chen and Zhang, Xiangwu}, year={2013}, month={Dec}, pages={1719–1726} }