@article{hubbe_wu_rojas_park_2011, title={Permeation of a cationic polyelectrolyte into mesoporous silica Part 3. Using adsorption isotherms to elucidate streaming potential results}, volume={381}, number={1-3}, journal={Colloids and Surfaces. A, Physicochemical and Engineering Aspects}, author={Hubbe, M. A. and Wu, N. and Rojas, O. J. and Park, S.}, year={2011}, pages={1–6} } @article{wu_hubbe_rojas_park_2010, title={Permeation of a cationic polyelectrolyte into meso-porous silica Part 1. Factors affecting changes in streaming potential}, volume={364}, number={1-3}, journal={Colloids and Surfaces. A, Physicochemical and Engineering Aspects}, author={Wu, N. and Hubbe, M. A. and Rojas, O. J. and Park, S.}, year={2010}, pages={1–6} } @article{hubbe_wu_rojas_park_2010, title={Permeation of a cationic polyelectrolyte into mesoporous silica. Part 2. Effects of time and pore size on streaming potential}, volume={364}, ISSN={0927-7757}, url={http://dx.doi.org/10.1016/j.colsurfa.2010.05.005}, DOI={10.1016/j.colsurfa.2010.05.005}, abstractNote={Streaming potential tests were carried out to determine effects of time and pore size in the adsorption and desorption from aqueous suspensions of cationic polyelectrolytes on silica gel particles. Results in Part 1 of this series showed that the adsorption of cationic polyelectrolytes exposed to mesoporous silica gels can be highly dependent on pH, the polyelectrolyte's molecular mass, and the solution's electrical conductivity. Also, the observed changes in streaming potential indicated that the adsorption tended to be relatively slow and incomplete under the conditions of analysis. The present results indicate that the rate of change of streaming potential is proportional to the logarithm of exposure time. The related changes in adsorbed amounts of polyelectrolyte were below the detection limits of typical polyelectrolyte titration procedures. Contrasting charge behaviors were observed on the exterior vs. interior surfaces of silica gel particles as a function of pore size, electrical conductivity, and polyelectrolyte molecular mass. Increasing ionic strength tended to enhance the effect of adsorption of high-mass cationic polymers on the outer surfaces, but produced only a relatively small effect on streaming potential related to their permeation into silica gel (nominal pore sizes of 6 nm or 30 nm). Adsorption of very-low-mass cationic polymer onto the outer surfaces and inside the 6 nm pore size silica gel appeared to be maximized at an intermediate salt level. Finally, electrokinetic tests were used for the first time in a protocol designed to provide evidence of polyelectrolyte desorption from the interiors of mesoporous materials.}, number={1-3}, journal={Colloids and Surfaces A: Physicochemical and Engineering Aspects}, publisher={Elsevier BV}, author={Hubbe, Martin A. and Wu, Ning and Rojas, Orlando J. and Park, Sunkyu}, year={2010}, month={Jul}, pages={7–15} } @inproceedings{wu_hubbe_rojas_yamaguchi_2008, title={Penetration of high-charge cationic polymers into silica gel particles and cellulosic fibers}, volume={Book B}, booktitle={Proceedings of the 2nd IPEC Conference}, publisher={Tianjin, China: Tianjin University of Science & Technology}, author={Wu, N. and Hubbe, M. A. and Rojas, O. J. and Yamaguchi, T.}, year={2008}, pages={626–649} }