@article{zhang_jiang_liu_taniguchi_mandal_evans-storms_pitner_bocian_holten_lindsey_2016, title={Bioconjugatable, PEGylated hydroporphyrins for photochemistry and photomedicine. Narrow-band, near-infrared-emitting bacteriochlorins}, volume={40}, ISSN={["1369-9261"]}, url={http://www.scopus.com/inward/record.url?eid=2-s2.0-84984904482&partnerID=MN8TOARS}, DOI={10.1039/c6nj01155a}, abstractNote={PEGylated bacteriochlorins are soluble in water, can be excited in the ultraviolet, and exhibit a narrow fluorescence band in the NIR spectral region.}, number={9}, journal={NEW JOURNAL OF CHEMISTRY}, author={Zhang, Nuonuo and Jiang, Jianbing and Liu, Mengran and Taniguchi, Masahiko and Mandal, Amit Kumar and Evans-Storms, Rosemary B. and Pitner, J. Bruce and Bocian, David F. and Holten, Dewey and Lindsey, Jonathan S.}, year={2016}, pages={7750–7767} } @article{zhang_reddy_jiang_taniguchi_sommer_lindsey_2015, title={Elaboration of an unexplored substitution site in synthetic bacteriochlorins}, volume={19}, ISSN={["1099-1409"]}, url={http://www.scopus.com/inward/record.url?eid=2-s2.0-84937975805&partnerID=MN8TOARS}, DOI={10.1142/s1088424615500534}, abstractNote={ The ability to introduce substituents at designated sites about the perimeter of synthetic bacteriochlorins – analogs of bacteriochlorophylls of bacterial photosynthesis – remains a subject of ongoing study. Here, the self-condensation of a dihydrodipyrrin-dioxolane affords a 5-[2-(trimethylsiloxy)ethoxy]bacteriochlorin. Like a 5-methoxybacteriochlorin, the latter undergoes regioselective bromination at the 15-position, directed by the distal 5-alkoxy group. On the other hand, attempted bromination of a bacteriochlorin bearing a 5-(2-hydroxyethoxy) group resulted in intramolecular ether formation with the adjacent β-pyrroline position to give an annulated dioxepine ring (confirmed by single-crystal X-ray structural analysis). The hydroxyethoxy group at the 5-position can be derivatized by acylation. In addition, the installation of auxochromes (methoxycarbonyl, phenylethynyl) at the β-pyrrole rings causes a substantial bathochromic shift of the long-wavelength absorption band (812 nm) and companion fluorescence emission band (821 nm). Taken together, the modification of the 5-substituent complements existing methods for installing a single substituent on the bacteriochlorin macrocycle. }, number={7}, journal={JOURNAL OF PORPHYRINS AND PHTHALOCYANINES}, publisher={World Scientific Pub Co Pte Lt}, author={Zhang, Nuonuo and Reddy, Kanumuri Ramesh and Jiang, Jianbing and Taniguchi, Masahiko and Sommer, Roger D. and Lindsey, Jonathan S.}, year={2015}, month={Jul}, pages={887–902} } @article{jiang_chen_zhang_vairaprakash_lindsey_2015, title={Polarity-tunable and wavelength-tunable bacteriochlorins bearing a single carboxylic acid or NHS ester. Use in a protein bioconjugation model system}, volume={39}, ISSN={["1369-9261"]}, DOI={10.1039/c4nj01340a}, abstractNote={10 new near-infrared absorbing bacteriochlorins (soluble in aqueous or membranous media) are equipped for protein bioconjugation.}, number={1}, journal={NEW JOURNAL OF CHEMISTRY}, author={Jiang, Jianbing and Chen, Chih-Yuan and Zhang, Nuonuo and Vairaprakash, Pothiappan and Lindsey, Jonathan S.}, year={2015}, month={Jan}, pages={403–419} }