Robert David Schmidt

Works (7)

Updated: July 17th, 2023 21:15

2012 journal article

Spectroscopic Studies of Bridge Contributions to Electronic Coupling in a Donor-Bridge-Acceptor Biradical System

Journal of the American Chemical Society, 134(18), 7812–7819.

By: M. Kirk *, D. Shultz n , E. Depperman*, D. Habel-Rodriguez* & R. Schmidt n

MeSH headings : Benzene / chemistry; Benzoquinones / chemistry; Electron Transport; Electrons; Models, Molecular; Nitrogen Oxides / chemistry; Spectrum Analysis, Raman; Zinc / chemistry
TL;DR: The results show the importance of the phenylene bridge in promoting (1) electron transfer in D-Ph-A systems and (2) electron transport in biased electrode devices that employ a 1,4-phenylene linkage. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, Crossref, NC State University Libraries
Added: August 6, 2018

2011 journal article

Nitronyl Nitroxide Radicals as Organic Memory Elements with Both n- and p-Type Properties

Angewandte Chemie International Edition, 50(19), 4414–4418.

By: J. Lee *, E. Lee *, S. Kim*, G. Bang*, D. Shultz n , R. Schmidt n, M. Forbes *, H. Lee  n

author keywords: electron paramagnetic resonance; memory devices; molecular electronics; nitrogen radicals; organic radicals
TL;DR: Novel molecular radical memory behavior using a stable organic radical molecule that contains an unpaired electron that is capable of undergoing oxidation or reduction by applied bias voltages is reported. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, Crossref, NC State University Libraries
Added: August 6, 2018

2010 journal article

Goldilocks Effect in Magnetic Bistability: Remote Substituent Modulation and Lattice Control of Photoinduced Valence Tautomerism and Light-Induced Thermal Hysteresis

Journal of the American Chemical Society, 132(17), 6261–6273.

By: R. Schmidt n, D. Shultz n , J. Martin n  & P. Boyle n

Contributors: R. Schmidt n, D. Shultz n , J. Martin n  & P. Boyle n

TL;DR: The coordination geometry (trans-pyridines), pyridine substitution, and crystal packing forces conspire to create the comparatively thermally stable photogenerated hs-Co(II) tautomer, thus providing an excellent handle for molecular and crystal engineering studies. (via Semantic Scholar)
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (Web of Science; OpenAlex)
Sources: Web Of Science, Crossref, ORCID, NC State University Libraries
Added: August 6, 2018

2010 journal article

Hyperfine Interaction, Spin Polarization, and Spin Delocalization as Probes of Donor-Bridge-Acceptor Interactions in Exchange-Coupled Biradicals

JOURNAL OF PHYSICAL CHEMISTRY B, 114(45), 14712–14716.

By: M. Kirk  n, D. Shultz n , D. Habel-Rodriguez n, R. Schmidt n & U. Sullivan n

TL;DR: Detailed spectroscopic and bonding calculations have been used to elucidate the role of the bridge fragment and its conformation relative to donor (SQ) and acceptor (NN) on spin density distributions and correlate well with experimental nitrogen hyperfine coupling constants. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2010 journal article

Magnetic Bistability in a Cobalt Bis(dioxolene) Complex: Long-Lived Photoinduced Valence Tautomerism

INORGANIC CHEMISTRY, 49(7), 3162–3168.

By: R. Schmidt n, D. Shultz*  & J. Martin* 

Contributors: R. Schmidt n, D. Shultz*  & J. Martin* 

TL;DR: This lattice stabilization results in unmatched kinetic and thermal stability for a valence tautomer from 10-50 K, with residual hs-Co(II) persisting until about 90 K. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2009 journal article

Ferromagnetic Nanoscale Electron Correlation Promoted by Organic Spin-Dependent Delocalization

Journal of the American Chemical Society, 131(51), 18304–18313.

By: M. Kirk  n, D. Shultz n , R. Schmidt n, D. Habel-Rodriguez n, H. Lee  n & J. Lee  n

MeSH headings : Electrons; Ferric Compounds / chemistry; Free Radicals / chemistry; Magnetics; Organometallic Compounds / chemistry; Temperature
TL;DR: It is shown that ferromagnetic coupling promoted by organic mixed-valency provides keen insight into the ability of single molecules to communicate spin information over nanoscale distances. (via Semantic Scholar)
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (Web of Science; OpenAlex)
Sources: NC State University Libraries, Crossref, NC State University Libraries
Added: August 6, 2018

2009 journal article

Microwave-Mediated Pyrazole Fluorinations Using Selectfluor (R)

HETEROATOM CHEMISTRY, 20(6), 341–345.

By: J. Sloop *, J. Jackson* & R. Schmidt n

UN Sustainable Development Goal Categories
13. Climate Action (Web of Science)
Source: Web Of Science
Added: August 6, 2018

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