@article{faraji_yildiz_rost_stano_farahbakhsh_zhu_bradford_2017, title={Radial growth of multi-walled carbon nanotubes in aligned sheets through cyclic carbon deposition and graphitization}, volume={111}, ISSN={["1873-3891"]}, DOI={10.1016/j.carbon.2016.10.012}, abstractNote={Carbon coated aligned multi-walled carbon nanotube (AMWCNT/C) sheets were used for studying the controlled radial growth of MWCNTs. Pyrolytic carbon (PyC) was deposited on the surface of nanotubes using multiple cycles of chemical vapor infiltration. Morphological and structural characterization showed that when graphitization was done in one step, after the deposition of multiple cycles of PyC, the presence of a large amount of disordered carbon on the surface of nanotubes led to a poorly graphitized coating structure that did not resembled nanotube walls anymore. Graphitization of the AMWCNT/C sheets after each deposition cycle prevented the development of disordered carbon during the subsequent PyC deposition cycles. Using the cyclic-graphitization method, thick PyC coating layers were successfully graphitized into a crystalline structure that could not be differentiated from the original nanotube walls. TEM observation and X-ray data confirmed radial growth of nanotubes, while spectra collected from Raman spectroscopy revealed that radially grown CNTs had the same quality as graphitized pristine nanotubes. The focus of this study was to compare the effect of cyclic graphitization with a one-step graphitization method to gain insight on the necessary parameters needed to radially grow high quality CNTs.}, journal={CARBON}, author={Faraji, Shaghayegh and Yildiz, Ozkan and Rost, Christina and Stano, Kelly and Farahbakhsh, Nasim and Zhu, Yuntian and Bradford, Philip D.}, year={2017}, month={Jan}, pages={411–418} } @article{stano_faraji_yildiz_akyildiz_bradford_jur_2017, title={Strong and resilient alumina nanotube and CNT/alumina hybrid foams with tuneable elastic properties}, volume={7}, ISSN={["2046-2069"]}, DOI={10.1039/c7ra02452e}, abstractNote={Alumina foams from anisotropic structured carbon nanotube structures are studied for their unique mechanical and thermal performance characteristics.}, number={45}, journal={RSC ADVANCES}, author={Stano, Kelly L. and Faraji, Shaghayegh and Yildiz, Ozkan and Akyildiz, Halil and Bradford, Philip D. and Jur, Jesse S.}, year={2017}, pages={27923–27931} } @article{stano_faraji_hodges_yildiz_wells_akyildiz_zhao_jur_bradford_2016, title={Ultralight Interconnected Metal Oxide Nanotube Networks}, volume={12}, ISSN={["1613-6829"]}, DOI={10.1002/smll.201503267}, abstractNote={Record-breaking ultralow density aluminum oxide structures are prepared using a novel templating technique. The alumina structures are unique in that they are comprised by highly aligned and interconnected nanotubes yielding anisotropic behavior. Large-scale network structures with complex form-factors can easily be made using this technique. The application of the low density networks as humidity sensing materials as well as thermal insulation is demonstrated.}, number={18}, journal={SMALL}, author={Stano, Kelly L. and Faraji, Shaghayegh and Hodges, Ryan and Yildiz, Ozkan and Wells, Brian and Akyildiz, Halil I. and Zhao, Junjie and Jur, Jesse and Bradford, Philip D.}, year={2016}, month={May}, pages={2432–2438} } @article{yildiz_stano_faraji_stone_willis_zhang_jur_bradford_2015, title={High performance carbon nanotube - polymer nanofiber hybrid fabrics}, volume={7}, ISSN={["2040-3372"]}, url={https://publons.com/publon/26924675/}, DOI={10.1039/c5nr02732b}, abstractNote={A novel hybridization process combining carbon nanotube sheet drawing and electrospinning is a versatile way to produce multifunctional, binder free fabrics which contain ultra high aspect ratio carbon nanotubes intermingled with polymer nanofibers.}, number={40}, journal={NANOSCALE}, publisher={Royal Society of Chemistry (RSC)}, author={Yildiz, Ozkan and Stano, Kelly and Faraji, Shaghayegh and Stone, Corinne and Willis, Colin and Zhang, Xiangwu and Jur, Jesse S. and Bradford, Philip D.}, year={2015}, pages={16744–16754} } @article{faraji_stano_yildiz_li_zhu_bradford_2015, title={Ultralight anisotropic foams from layered aligned carbon nanotube sheets}, volume={7}, ISSN={["2040-3372"]}, DOI={10.1039/c5nr03899e}, abstractNote={A novel nanofabrication method is demonstrated to produce large size, elastically resilient, ultra-low density carbon nanotube foams (3.8 mg cm−3) with anisotropic and tunable properties. Potential applications of this unique material are explored.}, number={40}, journal={NANOSCALE}, author={Faraji, Shaghayegh and Stano, Kelly L. and Yildiz, Ozkan and Li, Ang and Zhu, Yuntian and Bradford, Philip D.}, year={2015}, pages={17038–17047} } @article{zhou_wang_faraji_bradford_li_zhu_2014, title={Mechanical and electrical properties of aligned carbon nanotube/carbon matrix composites}, volume={75}, ISSN={["1873-3891"]}, DOI={10.1016/j.carbon.2014.04.008}, abstractNote={To synthesize carbon nanotube/carbon matrix (CNT/C) composites rivaling or exceeding the mechanical and electrical properties of current carbon fiber/carbon matrix composites, it is essential to align carbon nanotubes in the composite. In this work, we fabricated CNT/polyacrylonitrile (PAN) precursor composites with high degree of CNT alignment, and carbonized and graphitized them at high temperatures. Carbonizing the precursor composites significantly improved their elastic modulus, strength, and electrical conductivity. The matrix was uniformly carbonized and highly graphitized. The excellent mechanical and electrical properties make the CNT/C composites promising for many high temperature aerospace applications.}, journal={CARBON}, author={Zhou, Zhou and Wang, Xin and Faraji, Shaghayegh and Bradford, Philip D. and Li, Qingwen and Zhu, Yuntian}, year={2014}, month={Aug}, pages={307–313} } @article{faraji_stano_rost_maria_zhu_bradford_2014, title={Structural annealing of carbon coated aligned multi-walled carbon nanotube sheets}, volume={79}, ISSN={0008-6223}, url={http://dx.doi.org/10.1016/J.CARBON.2014.07.049}, DOI={10.1016/j.carbon.2014.07.049}, abstractNote={Sheets of aligned multi-walled carbon nanotubes (AMWCNTs) were used to study the structural annealing of pyrolytic carbon (PyC) coatings with various thicknesses on MWCNTs. PyC was deposited using chemical vapor infiltration and the thickness was controlled via the infiltration time. Structural annealing of the PyC coated AMWCNT (AMWCNT/C) sheets at 2150 °C provided different results for different thickness coatings. Transmission electron microscopy images showed that the carbon deposited from acetylene formed laminar PyC coatings, resembling rough tube walls, on the CNT surfaces. Following the high temperature heat treatment, coatings from short PyC deposition times changed their structure, resulting in radial growth of the MWCNTs. Raman and X-ray diffraction measurements also revealed that the radially grown MWCNTs had graphitic quality very close to pristine nanotubes after annealing. Electrical conductivity of AMWCNT/C sheets after high temperature heat treatment was twice that of pristine AMWCNT sheets. The focus of this study was to determine the PyC coating thickness at which a rough PyC coating would no longer change its structure into new CNT walls. The samples treated longer than 30 min had much more disordered PyC deposited on the surface and the additional material did not form additional tube walls after thermal annealing.}, journal={Carbon}, publisher={Elsevier BV}, author={Faraji, Shaghayegh and Stano, Kelly and Rost, Christina and Maria, Jon-Paul and Zhu, Yuntian and Bradford, Philip D.}, year={2014}, month={Nov}, pages={113–122} }