Works (6)
Updated: July 5th, 2023 14:22
2021 journal article
A biohybrid strategy for enabling photoredox catalysis with low-energy light
CHEM, 8(1), 174–185.
open access via www.cell.com (publisher PDF)
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy
(Web of Science; OpenAlex)
13. Climate Action
(Web of Science)
Sources: Web Of Science, NC State University Libraries
Added: February 7, 2022
2020 journal article
Long-Lived Mixed 2MLCT/MC States in Antiferromagnetically Coupled d3 Vanadium(II) Bipyridine and Phenanthroline Complexes
Inorganic Chemistry, 59(20), 14706–14715.
TL;DR:
Transient absorption studies of the vanadium(II) species probing in the visible and near-IR, in combination with spectroelectrochemical techniques and computational chemistry, lead to the conclusion that long-lived states with MLCT character are rare in first-row transition-metal complexes.
(via Semantic Scholar)
Source: ORCID
Added: February 12, 2022
2020 journal article
Photochemical Upconversion in Water Using Cu(I) MLCT Excited States: Role of Energy Shuttling at the Micellar/Water Interface
ACS Applied Energy Materials, 3(12), 12557–12564.
author keywords: photochemical upconversion; triplet-triplet annihilation; copper(I) MLCT excited states; earth-abundant photosensitizer; energy transfer
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy
(OpenAlex)
Sources: Web Of Science, NC State University Libraries, ORCID, Crossref
Added: December 15, 2020
2017 journal article
A Synthetically-Tunable System to Control MLCT Excited-State Lifetimes and Spin States in Iron(II) Polypyridines
Journal of the American Chemical Society, 3(12), 4493–4505.
TL;DR:
It is found that increasing the amount of steric strain serves to extend the lifetime of the 5,7MLCT from 14.0 ps for [Fe(dftpy)2]2+ to the largest known value at 17.4 ps for[Fe(dbtpy]2+.
(via Semantic Scholar)
Source: ORCID
Added: January 6, 2022
2016 journal article
Highly Strained Iron(II) Polypyridines: Exploiting the Quintet Manifold To Extend the Lifetime of MLCT Excited States
J. Am. Chem. Soc., 138(9), 2949–2952.
TL;DR:
Evidence is presented that the quintet metal-to-ligand charge-transfer excited state ((5) MLCT) can be accessed via visible light absorption and that the thermalized (5,7)MLCT is long-lived at 16 ps, representing a > 100 fold increase compared to the (1,3)ML CT within species such as [Fe(bpy)3](2+).
(via Semantic Scholar)
Source: ORCID
Added: January 6, 2022
2016 journal article
Uncovering the Roles of Oxygen in Cr(III) Photoredox Catalysis
J. Am. Chem. Soc., 138(16), 5451–5464.
TL;DR:
The key finding is that oxygen acts as a renewable energy and electron shuttle following photoexcitation of the Cr(III) catalyst, providing insight into how oxygen can participate as a sustainable reagent in photocatalysis.
(via Semantic Scholar)
Source: ORCID
Added: January 6, 2022
Employment
Updated: November 13th, 2022 22:55
2022 - present
Haverford College Philadelphia, Pennsylvania, US
Visiting Assistant Professor
Chemistry
2019 - 2022
NC State University Raleigh, NC, US
Postdoc
Chemistry
Education
Updated: October 24th, 2019 11:18
2012 - 2019
University of Colorado Boulder Boulder, CO, US
PhD
Chemistry
2007 - 2011
Amherst College Amherst, MA, US
BA
Chemistry
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