David Shultz

Works (76)

2020 article

Exploiting chemistry and molecular systems for quantum information science

NATURE REVIEWS CHEMISTRY.

By: M. Wasielewski, M. Forbes, N. Frank, K. Kowalski, G. Scholes, J. Yuen-Zhou, M. Baldo, D. Freedman ...

Source: Web Of Science
Added: July 27, 2020

2019 journal article

Long-range spin dependent delocalization promoted by the pseudo Jahn-Teller effect

JOURNAL OF CHEMICAL PHYSICS, 151(20).

By: B. Stein, D. Dickie, S. Nedungadi, D. Brook, D. Shultz & M. Kirk

Source: Web Of Science
Added: January 13, 2020

2019 journal article

Wave Function Control of Charge-Separated Excited-State Lifetimes

Journal of the American Chemical Society, 141(9), 3986–3992.

By: C. Tichnell, D. Daley, B. Stein, D. Shultz, M. Kirk & E. Danilov

Source: Crossref
Added: February 24, 2020

2018 journal article

Excited state magnetic exchange interactions enable large spin polarization effects

Journal of the American Chemical Society, 140(6), 2221–2228.

By: B. Stein, C. Tichnell, J. Chen, D. Shultz & M. Kirk

Source: NC State University Libraries
Added: August 6, 2018

2018 journal article

Ground State Nuclear Magnetic Resonance Chemical Shifts Predict Charge-Separated Excited State Lifetimes

INORGANIC CHEMISTRY, 57(21), 13470–13476.

By: J. Yang, D. Kersi, C. Richers, L. Giles, R. Dangi, B. Stein, C. Feng, C. Tichnell, D. Shultz, M. Kirk

Source: NC State University Libraries
Added: November 26, 2018

2017 journal article

Effect of hydrologic alteration on the community succession of macrophytes at xiangyang site, hanjiang river, china

Scientifica.

By: N. Yang, Y. Zhang & K. Duan

Source: NC State University Libraries
Added: August 6, 2018

2017 journal article

Hard X-ray-Induced Valence Tautomeric Interconversion in Cobalt-o-Dioxolene Complexes

The Journal of Physical Chemistry Letters, 8(19), 4774–4778.

By: T. Francisco, W. Gee, H. Shepherd, M. Warren, D. Shultz, P. Raithby, C. Pinheiro

Source: Crossref
Added: June 6, 2020

2017 journal article

Heterospin biradicals provide insight into molecular conductance and rectification

Chemical Science, 8(8), 5408–5415.

By: M. Kirk, D. Shultz, J. Zhang, R. Dangi, L. Ingersol, J. Yang, N. Finney, R. Sommer, L. Wojtas

Source: Crossref
Added: February 24, 2020

2016 journal article

Toward controlling the solid state valence tautomeric interconversion character by solvation

Crystal Growth and Design, 16(4), 2385–2393.

By: M. Ribeiro, D. Stasiw, P. Pattison, P. Raithby, D. Shultz & C. Pinheiro

Source: NC State University Libraries
Added: August 6, 2018

2015 journal article

Determining the conformational landscape of a and pi coupling using para-phenylene and "Aviram-Ratner" bridges

Journal of the American Chemical Society, 137(29), 9222–9225.

By: D. Stasiw, J. Zhang, G. Wang, R. Dangi, B. Stein, D. Shultz, M. Kirk, L. Wojtas, R. Sommer

Source: NC State University Libraries
Added: August 6, 2018

2015 journal article

Synthesis, characterization, and photophysical studies of an iron(III) catecholate-nitronylnitroxide spin-crossover complex

Inorganic Chemistry, 54(9), 4466–4474.

By: C. Tichnell, D. Shultz, C. Popescu, I. Sokirniy & P. Boyle

Source: NC State University Libraries
Added: August 6, 2018

2014 journal article

Correction to “Electronic and Exchange Coupling in a Cross-Conjugated D–B–A Biradical: Mechanistic Implications for Quantum Interference Effects”

Correction to “Electronic and Exchange Coupling in a Cross-Conjugated D–B–A Biradical: Mechanistic Implications for Quantum Interference Effects.” Journal of the American Chemical Society, 136(10), 4090–4090.

By: M. Kirk, D. Shultz, D. Stasiw, D. Habel-Rodriguez, B. Stein & P. Boyle

Source: Crossref
Added: August 28, 2020

2014 journal article

Ligand Control of Donor–Acceptor Excited-State Lifetimes

Inorganic Chemistry, 53(10), 4791–4793.

By: J. Yang, D. Kersi, L. Giles, B. Stein, C. Feng, C. Tichnell, D. Shultz, M. Kirk

Source: Crossref
Added: August 28, 2020

2014 journal article

Molecular spintronics: a web themed issue

Chemical Communications, 50(56), 7401.

By: D. Shultz & M. Kirk

Source: Crossref
Added: February 24, 2020

2013 journal article

Electronic and Exchange Coupling in a Cross-Conjugated D–B–A Biradical: Mechanistic Implications for Quantum Interference Effects

Journal of the American Chemical Society, 135(39), 14713–14725.

By: M. Kirk, D. Shultz, D. Stasiw, D. Habel-Rodriguez, B. Stein & P. Boyle

Source: Crossref
Added: August 28, 2020

2013 journal article

Iron(ii) spin crossover films on Au(111): scanning probe microscopy and photoelectron spectroscopy

Chemical Communications, 49(89), 10446.

By: A. Pronschinske, R. Bruce, G. Lewis, Y. Chen, A. Calzolari, M. Buongiorno-Nardelli, D. Shultz, W. You, D. Dougherty

Source: Crossref
Added: August 28, 2020

2013 journal article

Modification of Molecular Spin Crossover in Ultrathin Films

Nano Letters, 13(4), 1429–1434.

By: A. Pronschinske, Y. Chen, G. Lewis, D. Shultz, A. Calzolari, M. Buongiorno Nardelli, D. Dougherty

Source: Crossref
Added: August 28, 2020

2013 journal article

Transition metal complexes of donor–acceptor biradicals

Coordination Chemistry Reviews, 257(1), 218–233.

By: M. Kirk & D. Shultz

Source: Crossref
Added: August 28, 2020

2012 journal article

Complex Materials for Molecular Spintronics Applications: Cobalt Bis(dioxolene) Valence Tautomers, from Molecules to Polymers

The Journal of Physical Chemistry B, 116(43), 13141–13148.

By: A. Calzolari, Y. Chen, G. Lewis, D. Dougherty, D. Shultz & M. Buongiorno Nardelli

Source: Crossref
Added: August 28, 2020

2012 journal article

Spectroscopic Studies of Bridge Contributions to Electronic Coupling in a Donor-Bridge-Acceptor Biradical System

Journal of the American Chemical Society, 134(18), 7812–7819.

By: M. Kirk, D. Shultz, E. Depperman, D. Habel-Rodriguez & R. Schmidt

Source: Crossref
Added: August 28, 2020

2011 journal article

Nitronyl Nitroxide Radicals as Organic Memory Elements with Both n- and p-Type Properties

Angewandte Chemie International Edition, 50(19), 4414–4418.

By: J. Lee, E. Lee, S. Kim, G. Bang, D. Shultz, R. Schmidt, M. Forbes, H. Lee

Source: Crossref
Added: August 28, 2020

2010 journal article

Goldilocks Effect in Magnetic Bistability: Remote Substituent Modulation and Lattice Control of Photoinduced Valence Tautomerism and Light-Induced Thermal Hysteresis

Journal of the American Chemical Society, 132(17), 6261–6273.

By: R. Schmidt, D. Shultz, J. Martin & P. Boyle

Source: Crossref
Added: August 28, 2020

2010 journal article

Hyperfine interaction, spin polarization, and spin delocalization as probes of donor-bridge-acceptor interactions in exchange-coupled biradicals

Journal of Physical Chemistry. B, Condensed Matter, Materials, Surfaces, Interfaces & Biophysical, 114(45), 14712–14716.

By: M. Kirk, D. Shultz, D. Habel-Rodriguez, R. Schmidt & U. Sullivan

Source: NC State University Libraries
Added: August 6, 2018

2010 journal article

Magnetic bistability in a cobalt bis(dioxolene) complex: Long-lived photoinduced valence tautomerism

Inorganic Chemistry, 49(7), 3162–3168.

By: R. Schmidt, D. Shultz & J. Martin

Source: NC State University Libraries
Added: August 6, 2018

2009 journal article

Ferromagnetic Nanoscale Electron Correlation Promoted by Organic Spin-Dependent Delocalization

Journal of the American Chemical Society, 131(51), 18304–18313.

By: M. Kirk, D. Shultz, R. Schmidt, D. Habel-Rodriguez, H. Lee & J. Lee

Source: Crossref
Added: August 28, 2020

2007 journal article

Donor−Acceptor Biradicals as Ground State Analogues of Photoinduced Charge Separated States

Journal of the American Chemical Society, 129(7), 1937–1943.

By: M. Kirk, D. Shultz, E. Depperman & C. Brannen

Source: Crossref
Added: August 28, 2020

2007 journal article

Influence of Ligand Geometry in Bimetallic Ytterbocene Complexes of Bridging Bis(bipyridyl) Ligands

Organometallics, 26(17), 4234–4242.

By: C. Carlson, C. Kuehl, L. Ogallo, D. Shultz, J. Thompson, M. Kirk, R. Martin, K. John, D. Morris

Source: Crossref
Added: August 28, 2020

2006 journal article

Design, Synthesis, and Properties of Conformationally Fixed Semiquinone Monoradical Species

The Journal of Organic Chemistry, 71(24), 9104–9113.

By: D. Shultz, J. Sloop & G. Washington

Source: Crossref
Added: August 28, 2020

2006 journal article

Electron Spin−Spin Exchange Coupling Mediated by the Porphyrin π System

Inorganic Chemistry, 45(15), 5752–5759.

By: D. Shultz, C. Mussari, K. Ramanathan & J. Kampf

Source: Crossref
Added: August 28, 2020

2006 journal article

Ligand design modulates photoinduced properties of cobalt-dioxolene valence tautomers

Chemical Physics Letters, 428(4-6), 400–404.

By: A. Beni, A. Dei, D. Shultz & L. Sorace

Source: NC State University Libraries
Added: August 6, 2018

2006 journal article

Testing Bridge-Mediated Differences in Dinuclear Valence Tautomeric Behavior

Inorganic Chemistry, 45(11), 4461–4467.

By: S. Bin-Salamon, S. Brewer, E. Depperman, S. Franzen, J. Kampf, M. Kirk, R. Kumar, S. Lappi ...

Source: Crossref
Added: August 28, 2020

2005 journal article

Beyond the active-electron approximation: Origin of ferromagnetic exchange in donor-acceptor heterospin biradicals

Polyhedron, 24(16-17), 2880–2884.

By: M. Kirk, D. Shultz & E. Depperman

Source: NC State University Libraries
Added: August 6, 2018

2005 journal article

Supramolecular control of valence-tautomeric equilibrium on nanometer-scale gold clusters

Journal of the American Chemical Society, 127(15), 5328–5329.

Source: NC State University Libraries
Added: August 6, 2018

2005 journal article

Valence tautomerization and exchange coupling in a cobalt-nitronylnitroxide-semiquinone complex

Polyhedron, 24(16-17), 2876–2879.

By: D. Shultz, R. Kumar, S. Bin-Salamon & M. Kirk

Source: NC State University Libraries
Added: August 6, 2018

2003 journal article

Mechanisms of exchange modulation in trimethylenemethane-type biradicals: The roles of conformation and spin density

Journal of the American Chemical Society, 125(50), 15426–15432.

By: D. Shultz, R. Fico, H. Lee, J. Kampf, K. Kirschbaum, A. Pinkerton, P. Boyle

Source: NC State University Libraries
Added: August 6, 2018

2003 patent

Nanoparticle composites and nanocapsules for guest encapsulation and methods for synthesizing same

Washington, DC: U.S. Patent and Trademark Office.

By: D. Feldheim, S. Marinakos & D. Shultz

Source: NC State University Libraries
Added: August 6, 2018

2003 journal article

New paradigm for design of high-spin organic molecules: The mechanism of spin-dependent delocalization in exchange-coupled, mixed-valent organic species

Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment & General Theory, 107(21), 4292–4299.

By: S. Franzen & D. Shultz

Source: NC State University Libraries
Added: August 6, 2018

2003 journal article

Polyoxolenes may provide a tool for designing paramagnetic molecules with predetermined spin topologies

Comptes Rendus. Chimie, 6(7), 663–676.

By: A. Bencini, A. Caneschi, A. Dei, D. Gatteschi, C. Sangregorio, D. Shultz, L. Sorace, M. Vaz

Source: NC State University Libraries
Added: August 6, 2018

2003 journal article

The donor-acceptor contributions to ferromagnetic exchange coupling in heterospin biradicals

Polyhedron, 22(14-17), 2423–2426.

By: D. Shultz

Source: NC State University Libraries
Added: August 6, 2018

2003 journal article

Trends in exchange coupling for trimethylenemethane-type bis(semiquinone) biradicals and correlation of magnetic exchange with mixed valency for cross-conjugated systems

Journal of the American Chemical Society, 125(38), 11761–11771.

By: D. Shultz, R. Fico, S. Bodnar, R. Kumar, K. Vostrikova, J. Kampf, P. Boyle

Source: NC State University Libraries
Added: August 6, 2018

2003 journal article

Trends in metal-biradical exchange interaction for first-row M- II(nitronyl nitroxide-semiquinone) complexes

Journal of the American Chemical Society, 125(6), 1607–1617.

By: D. Shultz, K. Vostrikova, S. Bodnar, H. Koo, M. Whangbo, M. Kirk, E. Depperman, J. Kampf

Source: NC State University Libraries
Added: August 6, 2018

2002 journal article

High-spin metal complexes containing a ferromagnetically coupled tris(semiquinone) ligand

Inorganic Chemistry, 41(5), 1086–1092.

By: A. Caneschi, A. Dei, C. Mussari, D. Shultz, L. Sorace & K. Vostrikova

Source: NC State University Libraries
Added: August 6, 2018

2002 journal article

Singlet-triplet gap in triplet ground-state biradicals is modulated by substituent effects

Journal of the American Chemical Society, 124(34), 10054–10061.

By: D. Shultz, S. Bodnar, H. Lee, J. Kampf, C. Incarvito & A. Rheingold

Source: NC State University Libraries
Added: August 6, 2018

2002 journal article

Structure-property relationships in new serniquinone-type ligands: Past, present, and future research efforts

Comments on Inorganic Chemistry, 23(1), 1–21.

By: D. Shultz

Source: NC State University Libraries
Added: August 6, 2018

2001 journal article

A bis-bidentate dioxolene ligand induces thermal hysteresis in valence tautomerism interconversion processes

Chemical Communications (Cambridge, England), (20), 2150–2151.

By: S. Bodnar, A. Caneschi, A. Dei, D. Shultz & L. Sorace

Source: NC State University Libraries
Added: August 6, 2018

2001 journal article

Charge distribution in bis-dioxolene radical metal complexes. Synthesis and DFT characterization of dinuclear Co(III) and Cr(III) complexes with a mixed-valent, S=1/2 semiquinone-catecholate ligand

Inorganic Chemistry, 40(7), 1582–1590.

By: A. Bencini, C. Daul, A. Dei, F. Mariotti, H. Lee, D. Shultz, L. Sorace

Source: NC State University Libraries
Added: August 6, 2018

2001 journal article

Ferromagnetically coupled bis(semiquinone) ligand enforces high-spin ground states in bis-metal complexes

Inorganic Chemistry, 40(2), 408.

By: A. Caneschi, A. Dei, H. Lee, D. Shultz & L. Sorace

Source: NC State University Libraries
Added: August 6, 2018

2001 journal article

Molecular structures of carbonyl-linked bis(dioxolene) complexes: Can a carbonyl group act as an effective ferromagnetic coupler?

Inorganic Chemistry, 40(3), 546–549.

By: D. Shultz, S. Bodnar, R. Kumar, H. Lee & J. Kampf

Source: NC State University Libraries
Added: August 6, 2018

2001 journal article

Observation of a hysteretic phase transition in a crystalline dinitroxide biradical that leads to magnetic bistability

Journal of the American Chemical Society, 123(42), 10403–10404.

By: D. Shultz, R. Fico, P. Boyle & J. Kampf

Source: NC State University Libraries
Added: August 6, 2018

2001 journal article

One-electron reduction of an antiferromagnetically coupled triradical yields a mixed-valent biradical with enhanced ferromagnetic coupling

Journal of the American Chemical Society, 123(26), 6431–6432.

By: D. Shultz & R. Kumar

Source: NC State University Libraries
Added: August 6, 2018

2001 journal article

Spin robustness of a new hybrid inorganic-organic high-spin molecule

Journal of the American Chemical Society, 123(13), 3133–3134.

By: E. Depperman, S. Bodnar, K. Vostrikova, D. Shultz & M. Kirk

Source: NC State University Libraries
Added: August 6, 2018

2001 journal article

Structure-property relationships in building blocks for open-shell molecules and materials

Synthetic Metals, 122(3), 495–500.

By: D. Shultz

Source: NC State University Libraries
Added: August 6, 2018

2001 journal article

Structure-property relationships in cross-conjugated, high-spin, dinuclear ligands: building blocks for open-shell molecules and materials

Polyhedron, 20(11-14), 1627–1631.

By: D. Shultz

Source: NC State University Libraries
Added: August 6, 2018

2000 journal article

Molecular structure of and exchange coupling in abis(semiquinone) complex

Chemical Communications (Cambridge, England), (01), 93–94.

By: D. Shultz, S. Bodnar & J. Kampf

Source: NC State University Libraries
Added: August 6, 2018

2000 journal article

Preparation and EPR spectroscopic investigation of conjugated oligomers containing semiquinone repeat units

Chemistry of Materials, 12(2), 580–585.

By: D. Shultz & M. Hollomon

Source: NC State University Libraries
Added: August 6, 2018

2000 journal article

Synthesis and structure of a complex having a quartet ground state with three entirely different spin carriers: Nitronyl nitroxide, o-semiquinone, and Cu-II

Inorganic Chemistry, 39(26), 6091–6093.

By: D. Shultz, S. Bodnar, K. Vostrikova & J. Kampf

Source: NC State University Libraries
Added: August 6, 2018

2000 journal article

Synthesis of nanometer-sized hollow polymer capsules from alkanethiol-coated gold particles

Chemical Communications (Cambridge, England), (9), 775–776.

Source: NC State University Libraries
Added: August 6, 2018

1999 journal article

Both an oxidation/reduction sequence and deprotonation of a unique paramagnetic ligand lead to a mixed-valent complex

Journal of the American Chemical Society, 121(45), 10664–10665.

By: D. Shultz, S. Bodnar, R. Kumar & J. Kampf

Source: NC State University Libraries
Added: August 6, 2018

1999 chapter

Conformational exchange modulation in trimethylenemethane-type biradicals

In Magnetic properties of organic materials (pp. 103–126). New York: Marcel Dekker.

By: D. Shultz

Source: NC State University Libraries
Added: August 6, 2018

1999 journal article

Cross-conjugated Bis(Porphryin)S: Synthesis, electrochemical behavior, mixed valency, and biradical dication formation

Journal of Organic Chemistry, 64(25), 9124–9136.

By: D. Shultz, H. Lee, R. Kumar & K. Gwaltney

Source: NC State University Libraries
Added: August 6, 2018

1999 journal article

Electronic properties of bisporphyrin biradical dications

Molecular Crystals and Liquid Crystals Science and Technology. Section A, Molecular Crystals and Liquid Crystals, 334(1999), 459–467.

By: D. Shultz, H. Lee, K. Gwaltney & K. Sandberg

Source: NC State University Libraries
Added: August 6, 2018

1999 journal article

Gold nanoparticles as templates for the synthesis of hollow nanometer-sized conductive polymer capsules

Advanced Materials, 11(1), 34–37.

By: S. Marinakos, D. Shultz & D. Feldheim

Source: NC State University Libraries
Added: August 6, 2018

1999 journal article

Paramagnetic zinc(II) complexes of a bis(catechol): Dependence of product spin state on tantomerization of the bis(catechol) ligand

Inorganic Chemistry, 38(3), 591–594.

By: D. Shultz & S. Bodnar

Source: NC State University Libraries
Added: August 6, 2018

1999 journal article

Semiempirical computational assessment of porphyrins as building blocks for molecule-based magnets: spin-spin coupling in radical-substituted metalloporphyrins

Journal of Physical Organic Chemistry, 12(1), 10–18.

By: D. Shultz & K. Sandberg

Source: NC State University Libraries
Added: August 6, 2018

1999 journal article

Structure-property relationships in Trimethylenemethane-type Biradicals. 2. synthesis and Epr spectral characterization of dinitroxide Biradicals

Journal of Organic Chemistry, 64(12), 4386–4396.

By: D. Shultz, A. Boal, H. Lee & G. Farmer

Source: NC State University Libraries
Added: August 6, 2018

1999 journal article

Synthesis and characterization of a planarized, trimethylenemethane-type bis(semiquinone) biradical

Tetrahedron, 55(41), 12079–12086.

By: D. Shultz, H. Lee & R. Fico

Source: NC State University Libraries
Added: August 6, 2018

1998 journal article

A modified procedure for sonogashira couplings: Synthesis and characterization of a bisporphyrin, 1,1-bis[zinc(II) 5'-ethynyl-10',15',20'-trimesitylporphyrinyl] methylenecyclohexane

Journal of Organic Chemistry, 63(12), 4034–4038.

By: D. Shultz, K. Gwaltney & H. Lee

Source: NC State University Libraries
Added: August 6, 2018

1998 journal article

Effect of aliphatic amine bases on the aggregation of alkali metal salts of 3,5-di-tert-butylsemiquinone (3,5-DBSQ)

Inorganic Chemistry, 37(7), 1540–1543.

By: D. Shultz, A. Boal & N. Campbell

Source: NC State University Libraries
Added: August 6, 2018

1998 journal article

Improved method for estimating the ZFS parameter D for delocalized biradicals

Journal of Physical Organic Chemistry, 11(11), 819–824.

By: K. Sandberg & D. Shultz

Source: NC State University Libraries
Added: August 6, 2018

1998 personal communication

Oxidation of a bis[Zn(II) porphyrin] yields a nondisjoint, exchange-coupled pi dication-biradical

By: D. Shultz, H. Lee & K. Gwaltney

Source: NC State University Libraries
Added: August 6, 2018

1998 journal article

PH-gated single-electron tunneling in chemically modified gold nanoclusters

Journal of the American Chemical Society, 120(30), 7645–7646.

By: L. Brousseau, Q. Zhao, D. Shultz & D. Feldheim

Source: NC State University Libraries
Added: August 6, 2018

1998 journal article

Synthesis and characterization of a nitroxide-semiquinone; biradical

Journal of Organic Chemistry, 63(18), 6254–6257.

By: D. Shultz & G. Farmer

Source: NC State University Libraries
Added: August 6, 2018

1998 journal article

Synthesis and characterization of phenylnitroxide-substituted zinc(II) porphyrins

Journal of Organic Chemistry, 63(3), 769–774.

By: D. Shultz, K. Gwaltney & H. Lee

Source: NC State University Libraries
Added: August 6, 2018

1998 journal article

Synthesis of bis(semiquinone)s and their electrochemical and electron paramagnetic resonance spectral characterization

Journal of Organic Chemistry, 63(25), 9462–9469.

By: D. Shultz, A. Boal & G. Farmer

Source: NC State University Libraries
Added: August 6, 2018

1997 journal article

Preparation of paramagnetic ligands for coordination complexes and networks with interesting magnetic properties

Molecular Crystals and Liquid Crystals Science and Technology. Section A, Molecular Crystals and Liquid Crystals, 305(1997), 303.

By: D. Shultz, A. Boal, D. Driscoll, G. Farmer, J. Kitchin, D. Miller, G. Tew

Source: NC State University Libraries
Added: August 6, 2018

1997 journal article

The biradical, bis(3,5-di-tert-butyl-4-phenoxyl)methyleneadamantane, exhibits matrix-dependent EPR spectra suggesting rotamer bistability with differential exchange coupling

Journal of the American Chemical Society, 119(16), 3846–3847.

By: D. Shultz, A. Boal & G. Farmer

Source: NC State University Libraries
Added: August 6, 2018