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2020 article
Exploiting chemistry and molecular systems for quantum information science
NATURE REVIEWS CHEMISTRY.
2020 article
In Search of Stable, High-Spin Polymers
APPLIED MAGNETIC RESONANCE.
2019 journal article
Long-range spin dependent delocalization promoted by the pseudo Jahn-Teller effect
JOURNAL OF CHEMICAL PHYSICS, 151(20).
2019 journal article
Wave Function Control of Charge-Separated Excited-State Lifetimes
Journal of the American Chemical Society, 141(9), 3986–3992.
2018 journal article
Excited state magnetic exchange interactions enable large spin polarization effects
Journal of the American Chemical Society, 140(6), 2221–2228.
2018 journal article
Ground State Nuclear Magnetic Resonance Chemical Shifts Predict Charge-Separated Excited State Lifetimes
INORGANIC CHEMISTRY, 57(21), 13470–13476.
2017 journal article
Effect of hydrologic alteration on the community succession of macrophytes at xiangyang site, hanjiang river, china
Scientifica.
2017 journal article
Hard X-ray-Induced Valence Tautomeric Interconversion in Cobalt-o-Dioxolene Complexes
The Journal of Physical Chemistry Letters, 8(19), 4774–4778.
2017 journal article
Heterospin biradicals provide insight into molecular conductance and rectification
Chemical Science, 8(8), 5408–5415.
2016 journal article
Influence of Radical Bridges on Electron Spin Coupling
The Journal of Physical Chemistry A, 121(1), 216–225.
2016 journal article
Toward controlling the solid state valence tautomeric interconversion character by solvation
Crystal Growth and Design, 16(4), 2385–2393.
2015 journal article
Determining the conformational landscape of a and pi coupling using para-phenylene and "Aviram-Ratner" bridges
Journal of the American Chemical Society, 137(29), 9222–9225.
2015 journal article
Synthesis, characterization, and photophysical studies of an iron(III) catecholate-nitronylnitroxide spin-crossover complex
Inorganic Chemistry, 54(9), 4466–4474.
2014 journal article
Correction to “Electronic and Exchange Coupling in a Cross-Conjugated D–B–A Biradical: Mechanistic Implications for Quantum Interference Effects”
Correction to “Electronic and Exchange Coupling in a Cross-Conjugated D–B–A Biradical: Mechanistic Implications for Quantum Interference Effects.” Journal of the American Chemical Society, 136(10), 4090–4090.
2014 journal article
Correction to “Superexchange Contributions to Distance Dependence of Electron Transfer/Transport: Exchange and Electronic Coupling in Oligo(para-Phenylene)- and Oligo(2,5-Thiophene)-Bridged Donor–Bridge–Acceptor Biradical Complexes”
Correction to “Superexchange Contributions to Distance Dependence of Electron Transfer/Transport: Exchange and Electronic Coupling in Oligo(para-Phenylene)- and Oligo(2,5-Thiophene)-Bridged Donor–Bridge–Acceptor Biradical Complexes.” Journal of the American Chemical Society, 136(10), 4089–4089.
2014 journal article
Ligand Control of Donor–Acceptor Excited-State Lifetimes
Inorganic Chemistry, 53(10), 4791–4793.
2014 journal article
Molecular spintronics: a web themed issue
Chemical Communications, 50(56), 7401.
2013 journal article
Electronic and Exchange Coupling in a Cross-Conjugated D–B–A Biradical: Mechanistic Implications for Quantum Interference Effects
Journal of the American Chemical Society, 135(39), 14713–14725.
2013 journal article
Iron(ii) spin crossover films on Au(111): scanning probe microscopy and photoelectron spectroscopy
Chemical Communications, 49(89), 10446.
2013 journal article
Modification of Molecular Spin Crossover in Ultrathin Films
Nano Letters, 13(4), 1429–1434.
2013 journal article
Superexchange Contributions to Distance Dependence of Electron Transfer/Transport: Exchange and Electronic Coupling in Oligo(para-Phenylene)- and Oligo(2,5-Thiophene)-Bridged Donor–Bridge–Acceptor Biradical Complexes
Journal of the American Chemical Society, 135(45), 17144–17154.
2013 journal article
Transition metal complexes of donor–acceptor biradicals
Coordination Chemistry Reviews, 257(1), 218–233.
2012 journal article
Complex Materials for Molecular Spintronics Applications: Cobalt Bis(dioxolene) Valence Tautomers, from Molecules to Polymers
The Journal of Physical Chemistry B, 116(43), 13141–13148.
2012 journal article
Spectroscopic Studies of Bridge Contributions to Electronic Coupling in a Donor-Bridge-Acceptor Biradical System
Journal of the American Chemical Society, 134(18), 7812–7819.
2011 journal article
Linear free-energy relationships in semiquinone species and their Mn(II) and Cu(II) complexes
Journal of Physical Organic Chemistry, 25(2), 101–109.
2011 journal article
Nitronyl Nitroxide Radicals as Organic Memory Elements with Both n- and p-Type Properties
Angewandte Chemie International Edition, 50(19), 4414–4418.
2011 journal article
Synthesis of and structure-property relationships in zinc complexes of bis-metaphenylene semiquinone biradical species
Journal of Physical Organic Chemistry, 25(4), 314–321.
2010 journal article
Goldilocks Effect in Magnetic Bistability: Remote Substituent Modulation and Lattice Control of Photoinduced Valence Tautomerism and Light-Induced Thermal Hysteresis
Journal of the American Chemical Society, 132(17), 6261–6273.
2010 journal article
Hyperfine interaction, spin polarization, and spin delocalization as probes of donor-bridge-acceptor interactions in exchange-coupled biradicals
Journal of Physical Chemistry. B, Condensed Matter, Materials, Surfaces, Interfaces & Biophysical, 114(45), 14712–14716.
2010 journal article
Magnetic bistability in a cobalt bis(dioxolene) complex: Long-lived photoinduced valence tautomerism
Inorganic Chemistry, 49(7), 3162–3168.
2009 journal article
Ferromagnetic Nanoscale Electron Correlation Promoted by Organic Spin-Dependent Delocalization
Journal of the American Chemical Society, 131(51), 18304–18313.
2007 journal article
Donor−Acceptor Biradicals as Ground State Analogues of Photoinduced Charge Separated States
Journal of the American Chemical Society, 129(7), 1937–1943.
2007 journal article
Influence of Ligand Geometry in Bimetallic Ytterbocene Complexes of Bridging Bis(bipyridyl) Ligands
Organometallics, 26(17), 4234–4242.
2006 journal article
Design, Synthesis, and Properties of Conformationally Fixed Semiquinone Monoradical Species
The Journal of Organic Chemistry, 71(24), 9104–9113.
2006 journal article
Electron Spin−Spin Exchange Coupling Mediated by the Porphyrin π System
Inorganic Chemistry, 45(15), 5752–5759.
2006 journal article
Ligand design modulates photoinduced properties of cobalt-dioxolene valence tautomers
Chemical Physics Letters, 428(4-6), 400–404.
2006 journal article
Testing Bridge-Mediated Differences in Dinuclear Valence Tautomeric Behavior
Inorganic Chemistry, 45(11), 4461–4467.
2005 journal article
Beyond the active-electron approximation: Origin of ferromagnetic exchange in donor-acceptor heterospin biradicals
Polyhedron, 24(16-17), 2880–2884.
2005 journal article
Supramolecular control of valence-tautomeric equilibrium on nanometer-scale gold clusters
Journal of the American Chemical Society, 127(15), 5328–5329.
2005 journal article
Valence tautomerization and exchange coupling in a cobalt-nitronylnitroxide-semiquinone complex
Polyhedron, 24(16-17), 2876–2879.
2003 journal article
Mechanisms of exchange modulation in trimethylenemethane-type biradicals: The roles of conformation and spin density
Journal of the American Chemical Society, 125(50), 15426–15432.
2003 patent
Nanoparticle composites and nanocapsules for guest encapsulation and methods for synthesizing same
Washington, DC: U.S. Patent and Trademark Office.
2003 journal article
New paradigm for design of high-spin organic molecules: The mechanism of spin-dependent delocalization in exchange-coupled, mixed-valent organic species
Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment & General Theory, 107(21), 4292–4299.
2003 journal article
Polyoxolenes may provide a tool for designing paramagnetic molecules with predetermined spin topologies
Comptes Rendus. Chimie, 6(7), 663–676.
2003 journal article
The donor-acceptor contributions to ferromagnetic exchange coupling in heterospin biradicals
Polyhedron, 22(14-17), 2423–2426.
2003 journal article
Trends in exchange coupling for trimethylenemethane-type bis(semiquinone) biradicals and correlation of magnetic exchange with mixed valency for cross-conjugated systems
Journal of the American Chemical Society, 125(38), 11761–11771.
2003 journal article
Trends in metal-biradical exchange interaction for first-row M- II(nitronyl nitroxide-semiquinone) complexes
Journal of the American Chemical Society, 125(6), 1607–1617.
2002 journal article
High-spin metal complexes containing a ferromagnetically coupled tris(semiquinone) ligand
Inorganic Chemistry, 41(5), 1086–1092.
2002 journal article
Singlet-triplet gap in triplet ground-state biradicals is modulated by substituent effects
Journal of the American Chemical Society, 124(34), 10054–10061.
2002 journal article
Structure-property relationships in new serniquinone-type ligands: Past, present, and future research efforts
Comments on Inorganic Chemistry, 23(1), 1–21.
2001 journal article
A bis-bidentate dioxolene ligand induces thermal hysteresis in valence tautomerism interconversion processes
Chemical Communications (Cambridge, England), (20), 2150–2151.
2001 journal article
Charge distribution in bis-dioxolene radical metal complexes. Synthesis and DFT characterization of dinuclear Co(III) and Cr(III) complexes with a mixed-valent, S=1/2 semiquinone-catecholate ligand
Inorganic Chemistry, 40(7), 1582–1590.
2001 journal article
Ferromagnetically coupled bis(semiquinone) ligand enforces high-spin ground states in bis-metal complexes
Inorganic Chemistry, 40(2), 408.
2001 journal article
Molecular structures of carbonyl-linked bis(dioxolene) complexes: Can a carbonyl group act as an effective ferromagnetic coupler?
Inorganic Chemistry, 40(3), 546–549.
2001 journal article
Observation of a hysteretic phase transition in a crystalline dinitroxide biradical that leads to magnetic bistability
Journal of the American Chemical Society, 123(42), 10403–10404.
2001 journal article
One-electron reduction of an antiferromagnetically coupled triradical yields a mixed-valent biradical with enhanced ferromagnetic coupling
Journal of the American Chemical Society, 123(26), 6431–6432.
2001 journal article
Spin robustness of a new hybrid inorganic-organic high-spin molecule
Journal of the American Chemical Society, 123(13), 3133–3134.
2001 journal article
Structure-property relationships in building blocks for open-shell molecules and materials
Synthetic Metals, 122(3), 495–500.
2001 journal article
Structure-property relationships in cross-conjugated, high-spin, dinuclear ligands: building blocks for open-shell molecules and materials
Polyhedron, 20(11-14), 1627–1631.
2000 journal article
Molecular structure of and exchange coupling in abis(semiquinone) complex
Chemical Communications (Cambridge, England), (01), 93–94.
2000 journal article
Preparation and EPR spectroscopic investigation of conjugated oligomers containing semiquinone repeat units
Chemistry of Materials, 12(2), 580–585.
2000 journal article
Synthesis and structure of a complex having a quartet ground state with three entirely different spin carriers: Nitronyl nitroxide, o-semiquinone, and Cu-II
Inorganic Chemistry, 39(26), 6091–6093.
2000 journal article
Synthesis of nanometer-sized hollow polymer capsules from alkanethiol-coated gold particles
Chemical Communications (Cambridge, England), (9), 775–776.
1999 journal article
Both an oxidation/reduction sequence and deprotonation of a unique paramagnetic ligand lead to a mixed-valent complex
Journal of the American Chemical Society, 121(45), 10664–10665.
1999 chapter
Conformational exchange modulation in trimethylenemethane-type biradicals
In Magnetic properties of organic materials (pp. 103–126). New York: Marcel Dekker.
1999 journal article
Cross-conjugated Bis(Porphryin)S: Synthesis, electrochemical behavior, mixed valency, and biradical dication formation
Journal of Organic Chemistry, 64(25), 9124–9136.
1999 journal article
Electronic properties of bisporphyrin biradical dications
Molecular Crystals and Liquid Crystals Science and Technology. Section A, Molecular Crystals and Liquid Crystals, 334(1999), 459–467.
1999 journal article
Gold nanoparticles as templates for the synthesis of hollow nanometer-sized conductive polymer capsules
Advanced Materials, 11(1), 34–37.
1999 journal article
Paramagnetic zinc(II) complexes of a bis(catechol): Dependence of product spin state on tantomerization of the bis(catechol) ligand
Inorganic Chemistry, 38(3), 591–594.
1999 journal article
Semiempirical computational assessment of porphyrins as building blocks for molecule-based magnets: spin-spin coupling in radical-substituted metalloporphyrins
Journal of Physical Organic Chemistry, 12(1), 10–18.
1999 journal article
Structure-property relationships in Trimethylenemethane-type Biradicals. 2. synthesis and Epr spectral characterization of dinitroxide Biradicals
Journal of Organic Chemistry, 64(12), 4386–4396.
1999 journal article
Synthesis and characterization of a planarized, trimethylenemethane-type bis(semiquinone) biradical
Tetrahedron, 55(41), 12079–12086.
1998 journal article
A modified procedure for sonogashira couplings: Synthesis and characterization of a bisporphyrin, 1,1-bis[zinc(II) 5'-ethynyl-10',15',20'-trimesitylporphyrinyl] methylenecyclohexane
Journal of Organic Chemistry, 63(12), 4034–4038.
1998 journal article
Effect of aliphatic amine bases on the aggregation of alkali metal salts of 3,5-di-tert-butylsemiquinone (3,5-DBSQ)
Inorganic Chemistry, 37(7), 1540–1543.
1998 journal article
Improved method for estimating the ZFS parameter D for delocalized biradicals
Journal of Physical Organic Chemistry, 11(11), 819–824.
1998 personal communication
Oxidation of a bis[Zn(II) porphyrin] yields a nondisjoint, exchange-coupled pi dication-biradical
1998 journal article
PH-gated single-electron tunneling in chemically modified gold nanoclusters
Journal of the American Chemical Society, 120(30), 7645–7646.
1998 journal article
Synthesis and characterization of a nitroxide-semiquinone; biradical
Journal of Organic Chemistry, 63(18), 6254–6257.
1998 journal article
Synthesis and characterization of phenylnitroxide-substituted zinc(II) porphyrins
Journal of Organic Chemistry, 63(3), 769–774.
1998 journal article
Synthesis of bis(semiquinone)s and their electrochemical and electron paramagnetic resonance spectral characterization
Journal of Organic Chemistry, 63(25), 9462–9469.
1997 journal article
Preparation of paramagnetic ligands for coordination complexes and networks with interesting magnetic properties
Molecular Crystals and Liquid Crystals Science and Technology. Section A, Molecular Crystals and Liquid Crystals, 305(1997), 303.
1997 journal article
The biradical, bis(3,5-di-tert-butyl-4-phenoxyl)methyleneadamantane, exhibits matrix-dependent EPR spectra suggesting rotamer bistability with differential exchange coupling
Journal of the American Chemical Society, 119(16), 3846–3847.