@article{schrickx_kashani_buck_ding_rech_flagg_li_kudenov_you_richter_et al._2024, title={Exceptional Alignment in a Donor-Acceptor Conjugated Polymer via a Previously Unobserved Liquid Crystal Mesophase}, volume={4}, ISSN={["1616-3028"]}, DOI={10.1002/adfm.202315183}, abstractNote={Abstract}, journal={ADVANCED FUNCTIONAL MATERIALS}, author={Schrickx, Harry M. and Kashani, Somayeh and Buck, Lauren and Ding, Kan and Rech, Jeromy J. and Flagg, Lucas Q. and Li, Ruipeng and Kudenov, Michael W. and You, Wei and Richter, Lee J. and et al.}, year={2024}, month={Apr} } @article{kwon_giridharagopal_neu_kashani_chen_quezada_guo_ade_you_ginger_2024, title={Quantifying Doping Efficiency to Probe the Effects of Nanoscale Morphology and Solvent Swelling in Molecular Doping of Conjugated Polymers}, volume={2}, ISSN={["1932-7455"]}, DOI={10.1021/acs.jpcc.4c00153}, abstractNote={We study the doping of conjugated polymers from droplets of molecular dopant solutions, as might be used in additive manufacturing approaches. We compare the doping efficiency of 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F4TCNQ) solutions between two model conjugated polymers, regioregular poly(3-hexylthiophene) (P3HT) and poly(bithiophene-thienothiophene) copolymer with a triethylene glycol side chain (P(g32T-TT)). We find that F4TCNQ dopes P(g32T-TT) more efficiently from solution, producing films with >103 times higher conductivity. Using spectroelectrochemistry to calibrate polaron spectra to known hole injection levels, we quantify the doping efficiency (polarons created/dopant molecule added) to be higher than 170% for P(g32T-TT) but only 47.2% for P3HT. We further explore the differences in molecular doping using a combination of scanning Kelvin probe microscopy (SKPM) and conductive atomic force microscopy (cAFM). We explore doping efficiency and aggregation as a function of the solvent of the dopant solution, side chain, and regioregularity of conjugated polymers; we show that the doping efficiency and dopant aggregation are both correlated with the ability of the dopant/solvent solution to swell the conjugated polymer, with combinations that swell, resulting in more efficient doping and smoother films with less aggregation.}, journal={JOURNAL OF PHYSICAL CHEMISTRY C}, author={Kwon, Sung-Joo and Giridharagopal, Rajiv and Neu, Justin and Kashani, Somayeh and Chen, Shinya E. and Quezada, Ramsess J. and Guo, Jiajie and Ade, Harald and You, Wei and Ginger, David S.}, year={2024}, month={Feb} } @article{ghaffari_kashani_do_weninger_riehn_2023, title={A nanophotonic interferometer}, volume={34}, ISSN={["1361-6528"]}, url={https://doi.org/10.1088/1361-6528/acb443}, DOI={10.1088/1361-6528/acb443}, abstractNote={Abstract}, number={18}, journal={NANOTECHNOLOGY}, author={Ghaffari, Abbas and Kashani, Somayeh and Do, Kevin and Weninger, Keith and Riehn, Robert}, year={2023}, month={Apr} } @article{kashani_rech_liu_baustert_ghaffari_angunawela_xiong_dinku_you_graham_et al._2023, title={Exciton Binding Energy in Organic Polymers: Experimental Considerations and Tuning Prospects}, volume={12}, ISSN={["1614-6840"]}, DOI={10.1002/aenm.202302837}, abstractNote={Abstract}, journal={ADVANCED ENERGY MATERIALS}, author={Kashani, Somayeh and Rech, Jeromy James and Liu, Tuo and Baustert, Kyle and Ghaffari, Abbas and Angunawela, Indunil and Xiong, Yuan and Dinku, Abay and You, Wei and Graham, Kenneth and et al.}, year={2023}, month={Dec} } @article{ghaffari_do_kashani_weninger_riehn_2022, title={A Nanophotonic Interferometer for small particle detection}, volume={12223}, ISBN={["978-1-5106-5430-3"]}, ISSN={["1996-756X"]}, DOI={10.1117/12.2634318}, abstractNote={The transmission of light through sub-wavelength apertures (zero-mode waveguides, ZMW) in metal films is wellexplored. It introduces both an amplitude modulation as well as a phase shift to the transmitted oscillating electromagnetic field. We propose a nanophotonic interferometer by bringing two zero-mode waveguides in proximity and monitoring the distribution of light in the back-focal plane of the collecting microscope objective. We demonstrate that both an asymmetry induced by the binding of a quantum dot in one of the two ZMW, as well as a asymmetry in ZMW diameter yield qualitatively similar deflection patterns. Using ZMW pairs with diameter asymmetries, we find that the complex pattern of the transmitted light can be quantified through a scalar measure of asymmetry along the symmetry axis of the aperture pair. We find that this scalar asymmetry is a monotonous function of the diameter difference of the two apertures.}, journal={INTERFEROMETRY XXI}, author={Ghaffari, A. and Do, K. and Kashani, S. and Weninger, K. and Riehn, Robert}, year={2022} } @article{kashani_wang_risko_ade_2022, title={Relating reorganization energies, exciton diffusion length and non-radiative recombination to the room temperature UV-vis absorption spectra of NF-SMA}, volume={12}, ISSN={["2051-6355"]}, url={https://doi.org/10.1039/D2MH01228F}, DOI={10.1039/d2mh01228f}, abstractNote={Multiparameter Franck–Condon analyses of absorption spectra of Y6 in dilute solutions reveals that Y6 exhibits a high conformation uniformity and the smallest intra-molecular reorganization energy among the materials studied.}, journal={MATERIALS HORIZONS}, author={Kashani, Somayeh and Wang, Zhen and Risko, Chad and Ade, Harald}, year={2022}, month={Dec} } @article{steckmann_angunawela_kashani_zhu_nahid_ade_gadisa_2022, title={Ultrathin P(NDI2OD-T2) Films with High Electron Mobility in Both Bottom-Gate and Top-Gate Transistors}, volume={3}, ISSN={["2199-160X"]}, url={https://doi.org/10.1002/aelm.202101324}, DOI={10.1002/aelm.202101324}, abstractNote={Abstract}, journal={ADVANCED ELECTRONIC MATERIALS}, author={Steckmann, Thomas and Angunawela, Indunil and Kashani, Somayeh and Zhu, Youqin and Nahid, Masrur M. and Ade, Harald and Gadisa, Abay}, year={2022}, month={Mar} } @article{king_melville_rice_kashani_tonnele_raboui_swaraj_grant_mcafee_bender_et al._2021, title={Silicon Phthalocyanines for n-Type Organic Thin-Film Transistors: Development of Structure-Property Relationships}, volume={3}, ISSN={["2637-6113"]}, DOI={10.1021/acsaelm.0c00871}, abstractNote={Silicon phthalocyanines (SiPcs) have shown great potential as n-type or ambipolar organic semiconductors in organic thin-film transistors (OTFTs) and organic photovoltaics. Although properly design...}, number={1}, journal={ACS APPLIED ELECTRONIC MATERIALS}, author={King, Benjamin and Melville, Owen A. and Rice, Nicole A. and Kashani, Somayeh and Tonnele, Claire and Raboui, Hasan and Swaraj, Sufal and Grant, Trevor M. and McAfee, Terry and Bender, Timothy P. and et al.}, year={2021}, month={Jan}, pages={325–336} } @article{balar_siddika_kashani_peng_rech_ye_you_ade_brendan t. o'conner_2020, title={Role of Secondary Thermal Relaxations in Conjugated Polymer Film Toughness}, volume={32}, ISSN={["1520-5002"]}, url={https://publons.com/wos-op/publon/35208553/}, DOI={10.1021/acs.chemmater.0c01910}, abstractNote={Conjugated polymers have proven to be an important class of materials for flexible and stretchable electronics. To ensure long term thermal and mechanical stability of associated devices, there is ...}, number={15}, journal={CHEMISTRY OF MATERIALS}, author={Balar, Nrup and Siddika, Salma and Kashani, Somayeh and Peng, Zhengxing and Rech, Jeromy James and Ye, Long and You, Wei and Ade, Harald and Brendan T. O'Conner}, year={2020}, month={Aug}, pages={6540–6549} }