@article{brenner_lu_christopher j. o'brien_bucholz_rak_2015, title={A particle assembly/constrained expansion (PACE) model for the formation and structure of porous metal oxide deposits on nuclear fuel rods in pressurized light water reactors}, volume={457}, ISSN={["1873-4820"]}, url={http://www.scopus.com/inward/record.url?eid=2-s2.0-84915820676&partnerID=MN8TOARS}, DOI={10.1016/j.jnucmat.2014.11.061}, abstractNote={A new model is proposed for the structure and properties of porous metal oxide scales (aka Chalk River Unidentified Deposits (CRUD)) observed on the nuclear fuel rod cladding in Pressurized Water Reactors (PWR). The model is based on the thermodynamically-driven expansion of agglomerated octahedral nickel ferrite particles in response to pH and temperature changes in the CRUD. The model predicts that porous nickel ferrite with internal {1 1 1} surfaces is a thermodynamically stable structure under PWR conditions even when the free energy of formation of bulk nickel ferrite is positive. This explains the pervasive presence of nickel ferrite in CRUD, observed CRUD microstructures, why CRUD maintains its porosity, and variations in porosity within the CRUD observed experimentally. This model is a stark departure from decades of conventional wisdom and detailed theoretical analysis of CRUD chemistry, and defines new research directions for model validation, and for understanding and ultimately controlling CRUD formation.}, journal={JOURNAL OF NUCLEAR MATERIALS}, author={Brenner, Donald W. and Lu, Shijing and Christopher J. O'Brien and Bucholz, Eric W. and Rak, Zsolt}, year={2015}, month={Feb}, pages={209–212} }
 @article{lu_mily_irving_maria_brenner_2015, title={New method for extracting diffusion-controlled kinetics from differential scanning calorimetry: Application to energetic nanostructures}, volume={119}, number={25}, journal={Journal of Physical Chemistry. C}, author={Lu, S. J. and Mily, E. J. and Irving, D. L. and Maria, J. P. and Brenner, D. W.}, year={2015}, pages={14411–14418} }