Works (7)
Updated: July 5th, 2023 15:43
2016 journal article
Ionic Liquid Character of Zinc Chloride Hydrates Define Solvent Characteristics that Afford the Solubility of Cellulose
The Journal of Physical Chemistry B, 120(6), 1134–1141.
Contributors: n, B. Losey n, E. Gordon n, D. Argyropoulos n & J. Martin n
MeSH headings : Cellulose / chemistry; Chlorides / chemistry; Ionic Liquids / chemistry; Molecular Conformation; Solubility; Solvents / chemistry; Water / chemistry; Zinc Compounds / chemistry
TL;DR:
Neutron diffraction and differential pair distribution function analysis of cellulose and model compound solutions suggest that cellulose solubility occurs via coordination of the primary OH to the hydrated zinc cation with ring hydroxyls forming part of a second coordination shell around the cation of the ionic liquid.
(via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation
(OpenAlex)
Sources: Web Of Science, ORCID, Crossref
Added: August 6, 2018
2016 journal article
Toward Carbon Fibers from Single Component Kraft Lignin Systems: Optimization of Chain Extension Chemistry
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 4(10), 5230–5237.
author keywords: Softwood kraft lignin; Claisen rearrangement; Thermal polymerization; Methylation; Propargylation; P-31 NMR; DSC; Phenolic-OH
Sources: Web Of Science, ORCID
Added: August 6, 2018
2015 journal article
Methylation of softwood kraft lignin with dimethyl carbonate
GREEN CHEMISTRY, 17(2), 1077–1087.
Sources: Web Of Science, ORCID
Added: August 6, 2018
2015 review
Thermal properties of lignin in copolymers, blends, and composites: a review
[Review of ]. GREEN CHEMISTRY, 17(11), 4862–4887.
Sources: Web Of Science, ORCID
Added: August 6, 2018
2014 journal article
Synthesis and Characterization of Poly(arylene ether sulfone) Kraft Lignin Heat Stable Copolymers
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2(2), 264–271.
author keywords: Polyarylene ether sulfone; Softwood kraft lignin; Glass transition temperature; Thermogravimetry analysis; Characterization; Difluorodiphenyl sulphone
Sources: Web Of Science, ORCID
Added: August 6, 2018
2013 journal article
Kraft Lignin Chain Extension Chemistry via Propargylation, Oxidative Coupling, and Claisen Rearrangement
BIOMACROMOLECULES, 14(10), 3399–3408.
MeSH headings : Lignin / chemical synthesis; Lignin / chemistry; Methylation; Molecular Structure; Molecular Weight; Oxidation-Reduction; Pargyline / analogs & derivatives; Pargyline / chemistry; Polymerization; Polymers / chemical synthesis; Polymers / chemistry; Temperature
TL;DR:
It is shown that it is possible to modulate the reactivity of softwood kraft lignin via a combination of methylation and chain extension providing a rational means for the creation of higher molecular weight polymers with the potential for thermoplastic materials and carbon fibers with the desired control of structure-property relations.
(via Semantic Scholar)
Sources: Web Of Science, ORCID
Added: August 6, 2018
2013 journal article
Review of Cellulose Non-Derivatizing Solvent Interactions with Emphasis on Activity in Inorganic Molten Salt Hydrates
ACS Sustainable Chemistry & Engineering, 1(8), 858–870.
Contributors: *, J. Martin* & D. Argyropoulos*
author keywords: Cellulose; Non-derivatizing solvents of cellulose; Inorganic molten salt hydrates; Crystallinity; Cellulose hydrolysis; Degradation of cellulose
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation
(OpenAlex)
Sources: Web Of Science, Crossref, ORCID
Added: August 6, 2018
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