@article{gyenes_purrington_liu_1999, title={Friedel-Crafts reactions of fluorinated allylic compounds}, volume={64}, ISSN={["0022-3263"]}, DOI={10.1021/jo981670e}, abstractNote={ADVERTISEMENT RETURN TO ISSUEPREVNoteNEXTFriedel−Crafts Reactions of Fluorinated Allylic CompoundsFerenc Gyenes, Suzanne T. Purrington, and Yan-Song LiuView Author Information Department of Chemistry, North Carolina State University Raleigh, North Carolina 27695-8204 Cite this: J. Org. Chem. 1999, 64, 4, 1366–1368Publication Date (Web):January 16, 1999Publication History Received17 August 1998Published online16 January 1999Published inissue 1 February 1999https://pubs.acs.org/doi/10.1021/jo981670ehttps://doi.org/10.1021/jo981670ebrief-reportACS PublicationsCopyright © 1999 American Chemical SocietyRequest reuse permissionsArticle Views526Altmetric-Citations8LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-AlertscloseSupporting Info (1)»Supporting Information Supporting Information SUBJECTS:Anions,Aromatic compounds,Distillation,Fluorine,Substitution reactions Get e-Alerts}, number={4}, journal={JOURNAL OF ORGANIC CHEMISTRY}, author={Gyenes, F and Purrington, ST and Liu, YS}, year={1999}, month={Feb}, pages={1366–1368} } @article{mcelroy_purrington_bumgardner_burgess_1999, title={Lack of polymerization of fluorinated acrylates}, volume={95}, DOI={10.1016/S0022-1139(99)00019-6}, abstractNote={trans-Ethyl 3-fluoroacrylate and ethyl 2-methyl-3,3-difluoroacrylate do not undergo radical initiated polymerization. They form 1:1 adducts with α-alkoxy radicals in high yield.}, number={1-2}, journal={Journal of Fluorine Chemistry}, author={McElroy, K. T. and Purrington, S. T. and Bumgardner, C. L. and Burgess, J. P.}, year={1999}, pages={117–120} } @article{keefer_bereman_purrington_knight_boyle_1999, title={The Pt-195 NMR of L2Pt(1,2-dithiolene) complexes}, volume={38}, ISSN={["0020-1669"]}, DOI={10.1021/ic980369d}, abstractNote={The syntheses and characterizations of the novel platinum(II) mono-1,2-dithiolenes (COD)Pt(dddt) (1), (Ph3P)2Pt(dddt) (2), (COD)Pt(edt) (3), (Ph3P)2Pt(edt) (4), (bipy)Pt(edt) (5), and (Ph3P)(CO)Pt(dddt) (6) (COD = 1,5-cyclooctadiene; dddt = 5,6-dihydro-1,4-dithiin-2,3-dithiolate; edt = ethylene-1,2-dithiolate, bipy = 2,2‘-bipyridyl) are reported. 195Pt NMR spectral analysis was performed on the above-mentioned compounds along with the previously reported compounds (COD)Pt(dmid) (7), (Ph3P)2Pt(dmid) (8), (Ph3P)2Pt(dmit) (9), (COD)Pt(mnt) (10), (Ph3P)2Pt(mnt) (11), (COD)Pt(dt) (12), and (Ph3P)2Pt(dt) (13) (dmid = 1,3-dithiole-2-oxo-4,5-dithiolate; dmit = 1,3-dithiole-2-thione-4,5-dithiolate; mnt = maleonitrile-1,2-dithiolate; dt = ethane-1,2-dithiolate). 195Pt NMR results show that, depending on the nature of L2 in L2Pt(1,2-dithiolene) complexes, the 1,2-dithiolene ligands behave as either π donors or acceptors toward the Pt metal center. 195Pt NMR is also sensitive to the relative electron-withdrawing abil...}, number={10}, journal={INORGANIC CHEMISTRY}, author={Keefer, CE and Bereman, RD and Purrington, ST and Knight, BW and Boyle, PD}, year={1999}, month={May}, pages={2294–2302} } @article{keefer_purrington_bereman_boyle_1999, title={The first systematic synthesis of heterobimetallic dithiolene-bridged complexes. Synthesis and characterization of metal complexes of 4-(1 ',2 '-ethylenedithiolate)-1,3-dithiole-2-one and dimeric metal complexes of 1,2,3,4-butadienetetrathiolate}, volume={38}, ISSN={["0020-1669"]}, DOI={10.1021/ic990841a}, abstractNote={The 1,2-dithiolene ligands 4-(1‘,2‘-ethylenedithiolate)-1,3-dithiole-2-one (eddo2-) and 1,2,3,4-butadienetetrathiolate (bdt4-) are synthesized by the controlled single or double 1,3-dithiole-2-one ring opening of 4,4‘-bis(1,3-dithiole-2-one) (bdo) (1). The synthesis and characterization of the novel transition metal complexes (COD)Pt(eddo) (2), (diphos)Ni(eddo) (3), [Bu4N][Ni(eddo)2] (4), (COD)Pt(bdt)Pt(COD) (5), and (diphos)Ni(bdt)Pt(COD) (6) (where COD = 1,5-cyclooctadiene, diphos = 1,2-bis(diphenylphosphino)ethane) are reported. Use of eddo2- and bdt4- results in the selective systematic synthesis of transition metal monomers and dimers. In addition, the synthesis of mixed metal dimeric complexes utilizing a “transition metal 1,2-dithiolene” ligand is demonstrated. The single-crystal X-ray structural analyses of the cocrystallized (COD)Pt(eddo)·1/2bdo, monoclinic, P21/n, a = 13.0388(4) A, b = 9.2048(3) A, c = 16.2384(5) A, β = 97.289(5)°, Z = 4, and [Bu4N][Ni(eddo)2], monoclinic, P21/n, a = 8.3508(2) A...}, number={23}, journal={INORGANIC CHEMISTRY}, author={Keefer, CE and Purrington, ST and Bereman, RD and Boyle, PD}, year={1999}, month={Nov}, pages={5437–5442} } @article{shofran_purrington_breidt_fleming_1998, title={Antimicrobial properties of sinigrin and its hydrolysis products}, volume={63}, DOI={10.1111/j.1365-2621.1998.tb15798.x}, abstractNote={ABSTRACT}, number={4}, journal={Journal of Food Science}, author={Shofran, B. G. and Purrington, S. T. and Breidt, F. and Fleming, H. P.}, year={1998}, pages={621–624} } @article{liu_purrington_huang_1998, title={Formation of fluorinated heterocycles from aromatic silyl enol ethers}, volume={63}, ISSN={["0022-3263"]}, DOI={10.1021/jo971989j}, abstractNote={ADVERTISEMENT RETURN TO ISSUEPREVNoteNEXTFormation of Fluorinated Heterocycles from Aromatic Silyl Enol EthersYan-Song Liu, Suzanne T. Purrington, and Wei-Yuan HuangView Author Information Department of Chemistry, Box 8204, North Carolina State University, Raleigh North Carolina 27695-8204, and Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Rd., Shanghai 200032, China Cite this: J. Org. Chem. 1998, 63, 16, 5623–5626Publication Date (Web):July 18, 1998Publication History Received29 October 1997Published online18 July 1998Published inissue 1 August 1998https://pubs.acs.org/doi/10.1021/jo971989jhttps://doi.org/10.1021/jo971989jbrief-reportACS PublicationsCopyright © 1998 American Chemical SocietyRequest reuse permissionsArticle Views190Altmetric-Citations7LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-AlertscloseSupporting Info (1)»Supporting Information Supporting Information SUBJECTS:Alkyls,Anions,Chemical reactions,Enolates,Organic compounds Get e-Alerts}, number={16}, journal={JOURNAL OF ORGANIC CHEMISTRY}, author={Liu, YS and Purrington, ST and Huang, WY}, year={1998}, month={Aug}, pages={5623–5626} } @article{keefer_purrington_bereman_1998, title={On the reported existence of ethylenetetrathiolate (C2S44-):The synthesis and characterization of 4,5-bis(acetylthio)-1,3-dithiol-2-one}, number={12}, journal={Synthesis (Stuttgart)}, author={Keefer, C. E. and Purrington, S. T. and Bereman, R. D.}, year={1998}, pages={1710–1712} } @article{purrington_thomas_1998, title={Rapid lithiation of 1,1-difluoroalkenes}, volume={90}, ISSN={["0022-1139"]}, DOI={10.1016/S0022-1139(98)00150-X}, abstractNote={The dehydrofluorination reaction of trifluoroethoxy compounds to form 1,1-difluoroalkenes requires a two-fold excess of n-butyllithium. The initially formed alkene is rapidly lithiated by the reagent. Thus, when only one equivalent of base is used 50% of the difluoroalkene results along with 50% of starting material after quenching.}, number={1}, journal={JOURNAL OF FLUORINE CHEMISTRY}, author={Purrington, ST and Thomas, HN}, year={1998}, month={Jun}, pages={47–48} } @article{liebman_purrington_1998, title={Some thoughts on hydrogen fluoride traps in fluorine bomb calorimetry}, volume={9}, ISSN={["1040-0400"]}, DOI={10.1023/A:1022479216205}, number={3}, journal={STRUCTURAL CHEMISTRY}, author={Liebman, JF and Purrington, ST}, year={1998}, month={Jun}, pages={237–238} } @article{keefer_purrington_bereman_knight_bedgood_boyle_1998, title={The synthesis and characterization of platinum monodithiolene complexes containing 1,3-dithiole-2-oxo-4,5-dithiolate (dmid(2-)) and 1,3-dithiole-2-thione-4,5-dithiolate (dmit(2-))}, volume={282}, ISSN={["0020-1693"]}, DOI={10.1016/S0020-1693(98)00244-8}, abstractNote={The platinum monodithiolene complexes (COD)Pt(dmid) (1), (COD)Pt(dmit) (2), (Ph3P)2Pt(dmid) (3) and (Ph3P)2Pt(dmit) (4) (where COD = 1.5-cyclooctadiene, dmid = 1,3-dithiole-2-oxo-4,5-dithiolate, dmit = 1,3-dithiole-2-thione-4,5-dithiolate) have been synthesized and characterized. We report here their 1H NMR, 195Pt NMR, UV-Vis spectra and electrochemistry. The X-ray crystal structures are also reported. 2: orthorhombic, Cmcm, a = 10.8535(6), b = 16.8503(7), c = 7.3622(3)Å, Z = 4, 3: triclinic, P1¯, a = 11.2051(4), b = 11.4409(5), c = 15.2212(9)Å, α = 71.882(4), β = 73.125(4), γ = 84.589(6)°, Z = 2. 4·CHCl3: triclinic, P1¯, a = 10.2521(5), b = 13.9387(14), c = 15.6884(18)Å, α = 67.154(9), β = 89.380(15), γ = 83.570(13)°, Z = 2. The crystal structure of 2 exhibits a molecular stacking pattern which has alternating Pt and S(thione) atoms forming a one-dimensional chain which suggests the presence of a weak axial interaction between the Pt and S(thione). A correlation exists between the 195Pt NMR chemical shifts and the one-electron oxidation potentials of these complexes. In addition, it is shown that the carbonyl of the dmid2− ligand is not susceptible to alkoxide attack when coordinated to platinum.}, number={2}, journal={INORGANICA CHIMICA ACTA}, author={Keefer, CE and Purrington, ST and Bereman, RD and Knight, BW and Bedgood, DR and Boyle, PD}, year={1998}, month={Nov}, pages={200–208} }