Thomas Gunnoe

Works (51)

2014 journal article

Polymers for the stabilization and delivery of proteins topically and per os to the insect hemocoel through conjugation with aliphatic polyethylene glycol

Pesticide Biochemistry and Physiology, 115, 58–66.

By: L. Jeffers, H. Shen, B. Bissinger, S. Khalil, T. Gunnoe & R. Roe

Source: NC State University Libraries
Added: August 6, 2018

2012 journal article

Enhanced activity of an insecticidal protein, trypsin modulating oostatic factor (TMOF), through conjugation with aliphatic polyethylene glycol

Pest Management Science, 68(1), 49–59.

By: L. Jeffers, H. Shen, S. Khalil, B. Bissinger, A. Brandt, T. Gunnoe, R. Roe

Source: NC State University Libraries
Added: August 6, 2018

2011 journal article

Well-defined copper(I) amido complex and aryl iodides reacting to form aryl amines

Organometallics, 30(1), 55–57.

By: S. Delp, L. Goj, M. Pouy, C. Munro-Leighton, J. Lee, T. Gunnoe, T. Cundari, J. Petersen

Source: NC State University Libraries
Added: August 6, 2018

2009 journal article

Chlorination of boron on a ruthenium-coordinated hydridotris(pyrazolyl)borate (Tp) ligand: A caveat for the use of TpRu(PPh3)(2)Cl

Organometallics, 28(1), 374–377.

By: N. Foley, R. Abernethy, T. Gunnoe, A. Hill, P. Boyle & M. Sabat

Source: NC State University Libraries
Added: August 6, 2018

2009 journal article

Novel insecticide polymer chemistry to reduce the enzymatic digestion of a protein pesticide, trypsin modulating oostatic factor (TMOF)

Pesticide Biochemistry and Physiology, 93(3), 144–152.

By: H. Shen, A. Brandt, B. Witting-Bissinger, T. Gunnoe & R. Roe

Source: NC State University Libraries
Added: August 6, 2018

2008 journal article

Activation of sp(3) carbon-hydrogen bonds complex and subsequent metal-mediated formation

Angewandte Chemie [International Edition in English], 47(4), 726–730.

By: N. Foley, T. Gunnoe, T. Cundari, P. Boyle & J. Petersen

Source: NC State University Libraries
Added: August 6, 2018

2008 journal article

Anti-Markovnikov hydroamination and hydrothiolation of electron-deficient vinylarenes catalyzed by well-defined monomeric copper(I) amido and thiolate complexes

Chemical Communications (Cambridge, England), (1), 111–113.

By: C. Munro-Leighton, S. Delp, N. Alsop, E. Blue & T. Gunnoe

Source: NC State University Libraries
Added: August 6, 2018

2008 journal article

Aromatic C-H activation and catalytic hydrophenylation of ethylene by TpRu{P(OCH2)(3)CEt}(NCMe)Ph

Organometallics, 27(13), 3007–3017.

By: N. Foley, Z. Ke, T. Gunnoe, T. Cundari & J. Petersen

Source: NC State University Libraries
Added: August 6, 2018

2008 review

Chemistry surrounding Group 7 complexes that possess Poly(pyrazolyl)borate ligands

[Review of ]. Organotransition metal chemistry of poly(pyrazolyl)borates, pt 1, 56, 95–153.

By: M. Lail, K. Pittard & T. Gunnoe

Source: NC State University Libraries
Added: August 6, 2018

2008 journal article

Hydroarylation of unactivated olefins catalyzed by platinum(II) complexes

Organometallics, 27(16), 4031–4033.

By: B. McKeown, N. Foley, J. Lee & T. Gunnoe

Source: NC State University Libraries
Added: August 6, 2018

2008 journal article

Preparation and reactivity of a monomeric octahedral platinum(IV) amido complex

Inorganic Chemistry, 47(14), 6124–6126.

By: C. Munro-Leighton, Y. Feng, J. Zhang, N. Alsop, T. Gunnoe, P. Boyle, J. Petersen

Source: NC State University Libraries
Added: August 6, 2018

2008 journal article

Ruthenium(II) complexes possessing the eta(6)-p-cymene ligand

Inorganica Chimica Acta, 361(11), 3254–3262.

By: T. Sumiyoshi, T. Gunnoe, J. Petersen & P. Boyle

Source: NC State University Libraries
Added: August 6, 2018

2007 review

Activation of carbon-hydrogen bonds via 1,2-addition across M-X (X = OH or NH2) bonds of d(6) transition metals as a potential key step in hydrocarbon functionalization: A computational study

[Review of ]. Journal of the American Chemical Society, 129(43), 13172–13182.

By: T. Cundari, T. Grimes & T. Gunnoe

Source: NC State University Libraries
Added: August 6, 2018

2007 journal article

Addition of N-H and O-H bonds of amines and alcohols to electron-deficient olefins catalyzed by monomeric copper(I) systems: Reaction scope, mechanistic details, and comparison of catalyst efficiency

Organometallics, 26(6), 1483–1493.

By: C. Munro-Leighton, S. Delp, E. Blue & T. Gunnoe

Source: NC State University Libraries
Added: August 6, 2018

2007 journal article

Addition of s-h bonds across electron-deficient olefins catalyzed by well-defined copper(I) thiolate complexes

Inorganic Chemistry, 46(7), 2365–2367.

By: S. Delp, C. Munro-Leighton, L. Goj, M. Ramirez, T. Gunnoe, J. Petersen, P. Boyle

Source: NC State University Libraries
Added: August 6, 2018

2007 journal article

Combined experimental and computational studies on the nature of aromatic C-H activation by octahedral ruthenium(II) complexes: Evidence for sigma-bond metathesis from Hammett studies

Organometallics, 26(26), 6604–6611.

By: N. DeYonker, N. Foley, T. Cundari, T. Gunnoe & J. Petersen

Source: NC State University Libraries
Added: August 6, 2018

2007 journal article

Combined experimental and computational study of TpRu{P(pyr)(3)}(NCMe)Me (pyr = N-pyrrolyl): Inter- and intramolecular activation of C-H bonds and the impact of sterics on catalytic hydroarylation of olefins

Organometallics, 26(23), 5507–5516.

By: N. Foley, M. Lail, T. Gunnoe, T. Cundari, P. Boyle & J. Petersen

Source: NC State University Libraries
Added: August 6, 2018

2007 journal article

Comparative reactivity of TpRu(L)(NCMe)Ph (L = CO or PMe3): Impact of ancillary ligand L on activation of carbon-hydrogen bonds including catalytic hydroarylation and hydrovinylation/oligomerization of ethylene

Journal of the American Chemical Society, 129(21), 6765–6781.

By: N. Foley, M. Lail, J. Lee, T. Gunnoe, T. Cundari & J. Petersen

Source: NC State University Libraries
Added: August 6, 2018

2007 journal article

Reactivity of TpRu(L)(NCMe)R (L = CO, PMe3; R = Me, Ph) systems with isonitriles: Experimental and computational studies toward the intra- and intermolecular hydroarylation of isonitriles

Journal of Organometallic Chemistry, 692(11), 2175–2186.

By: J. Lee, O. Jimenez-Halla, T. Cundari & T. Gunnoe

Source: NC State University Libraries
Added: August 6, 2018

2007 review

Reactivity of ruthenium(II) and copper(I) complexes that possess anionic heteroatomic ligands: Synthetic exploitation of nucleophilicity and basicity of amido, hydroxo, alkoxo, and aryloxo ligands for the activation of substrates that possess polar...

[Review of ]. European Journal of Inorganic Chemistry, (9), 1185–1203.

By: T. Gunnoe

Source: NC State University Libraries
Added: August 6, 2018

2006 journal article

Anti-Markovnikov N-H and O-H additions to electron-deficient olefins catalyzed by well-defined Cu(I) anilido, ethoxide, and phenoxide systems

Journal of the American Chemical Society, 128(5), 1446–1447.

By: C. Munro-Leighton, E. Blue & T. Gunnoe

Source: NC State University Libraries
Added: August 6, 2018

2006 journal article

Chemistry surrounding monomeric copper(I) methyl, phenyl, anilido, ethoxide, and phenoxide complexes supported by N-heterocyclic carbene ligands: Reactivity consistent with both early and late transition metal systems

Inorganic Chemistry, 45(22), 9032–9045.

By: L. Goj, E. Blue, S. Delp, T. Gunnoe, T. Cundari, A. Pierpont, J. Petersen, P. Boyle

Source: NC State University Libraries
Added: August 6, 2018

2006 journal article

Hydrogen-deuterium exchange between TpRu( PMe3)(L)X (L) = PMe3 and X = OH, OPh, Me, Ph, or NHPh; L = NCMe and X = Ph) and deuterated arene solvents: Evidence for metal-mediated processes

Journal of the American Chemical Society, 128(24), 7982–7994.

By: Y. Feng, M. Lail, N. Foley, T. Gunnoe, K. Barakat, T. Cundari, J. Petersen

Source: NC State University Libraries
Added: August 6, 2018

2006 journal article

Octahedral [TpRu(PMe3)(2)OR](n+) complexes (Tp = hydridotris(pyrazolyl) borate; R = H or Ph; n=0 or 1): Reactions at Ru(II) and Ru(III) oxidation states with substrates that possess carbon-hydrogen bonds

Organometallics, 25(22), 5456–5465.

By: Y. Feng, T. Gunnoe, T. Grimes & T. Cundari

Source: NC State University Libraries
Added: August 6, 2018

2006 journal article

Protonation of N-heterocyclic carbene ligand coordinated to copper(I): Coordination mode of imidazolium cation as a function of counterion as determined by solid-state structures

Journal of Organometallic Chemistry, 691(26), 5988–5993.

By: E. Blue, T. Gunnoe, J. Petersen & P. Boyle

Source: NC State University Libraries
Added: August 6, 2018

2006 journal article

Reactions of TpRu(CO)(NCMe)(Ph) with electron-rich olefins: examples of stoichiometric C-S, C-O and C-H bond cleavage

Chemical Communications (Cambridge, England), (9), 982–984.

By: L. Goj, M. Lail, K. Pittard, K. Riley, T. Gunnoe & J. Petersen

Source: NC State University Libraries
Added: August 6, 2018

2006 journal article

Reactions of a Ru(II) phenyl complex with substrates that possess C-N or C-O multiple bonds: C-C bond formation, N-H bond cleavage, and decarbonylation reactions

Organometallics, 25(6), 1500–1510.

By: J. Lee, K. Pittard, N. Deyonker, T. Cundari, T. Gunnoe & J. Petersen

Source: NC State University Libraries
Added: August 6, 2018

2006 journal article

Single-electron oxidation of monomeric copper(I) alkyl complexes: Evidence for reductive elimination through bimolecular formation of Alkanes

Organometallics, 25(17), 4097–4104.

By: L. Goj, E. Blue, S. Delp, T. Gunnoe, T. Cundari & J. Petersen

Source: NC State University Libraries
Added: August 6, 2018

2005 journal article

Cleavage of X-H bonds (X = N, O, or C) by copper(I) alkyl complexes to form monomeric two-coordinate copper(I) systems

Inorganic Chemistry, 44(24), 8647–8649.

By: L. Goj, E. Blue, C. Munro-Leighton, T. Gunnoe & J. Petersen

Source: NC State University Libraries
Added: August 6, 2018

2005 journal article

Conversions of ruthenium(III) alkyl complexes to ruthenium(II) through Ru-C-alkyl bond homolysis

Organometallics, 24(6), 1301–1305.

By: M. Lail, T. Gunnoe, K. Barakat & T. Cundari

Source: NC State University Libraries
Added: August 6, 2018

2005 journal article

Developments in catalytic aromatic C-H transformations: Promising tools for organic synthesis

Current Organic Chemistry, 9(7), 671–685.

By: L. Goj & T. Gunnoe

Source: NC State University Libraries
Added: August 6, 2018

2005 journal article

Evidence for the net addition of arene C-H bonds across a Ru(II)-hydroxide bond

Journal of the American Chemical Society, 127(41), 14174–14175.

By: Y. Feng, M. Lail, K. Barakat, T. Cundari, T. Gunnoe & J. Petersen

Source: NC State University Libraries
Added: August 6, 2018

2005 journal article

Reactions of (PCP)Ru(CO)(NHPh)(PMe3) (PCP=2,6-((CH2PBu2)-Bu-t)(2)C6H3) with substrates that possess polar bonds

Inorganic Chemistry, 44(8), 2895–2907.

By: J. Zhang, T. Gunnoe & J. Peterson

Source: NC State University Libraries
Added: August 6, 2018

2005 journal article

Ruthenium(II)-mediated carbon-carbon bond formation between acetonitrile and pyrrole: Combined experimental and computational study

Organometallics, 24(21), 5015–5024.

By: K. Pittard, T. Cundari, T. Gunnoe, C. Day & J. Petersen

Source: NC State University Libraries
Added: August 6, 2018

2005 journal article

Synthesis of the five-coordinate ruthenium(II) Complexes [(PCP)Ru(CO)(L)][BAr'(4)] {PCP=2,6-((CH2PBu2)-Bu-t)(2)C6H3, BAr'(4) 3,5-(CF3)(2)C6H3, L = eta(1)-ClCH2Cl, eta-N-2, or mu-Cl-Ru(PCP)(CO)}: Reactions with phenyldiazomethane and phenylacetylene

Inorganic Chemistry, 44(23), 8379–8390.

By: J. Zhang, K. Barakat, T. Cundari, T. Gunnoe, P. Boyle, J. Petersen, C. Day

Source: NC State University Libraries
Added: August 6, 2018

2004 journal article

Experimental and computational studies of ruthenium(II)-catalyzed addition of arene C-H bonds to olefins

Organometallics, 23(21), 5007–5020.

By: M. Lail, C. Bell, D. Conner, T. Cundari, T. Gunnoe & J. Petersen

Source: NC State University Libraries
Added: August 6, 2018

2004 journal article

Reactions of TpRu(CO)(NCMe)(Me) (Tp = hydridotris(pyrazolyl)borate) with heteroaromatic substrates: Stoichiometric and catalytic C-H activation

Organometallics, 23(23), 5514–5523.

By: K. Pittard, J. Lee, T. Cundari, T. Gunnoe & J. Petersen

Source: NC State University Libraries
Added: August 6, 2018

2004 journal article

Ruthenium(II) anilido complex containing a bisphosphine pincer ligand: Reversible formation of amidinate ligands via intramolecular C-N bond formation

Organometallics, 23(13), 3094–3097.

By: J. Zhang, T. Gunnoe & P. Boyle

Source: NC State University Libraries
Added: August 6, 2018

2004 journal article

Synthesis and reactivity of a coordinatively unsaturated ruthenium(II) parent amido complex: Studies of X-H activation (X = H or C)

Organometallics, 23(11), 2724–2733.

By: D. Conner, K. Jayaprakash, T. Cundari & T. Gunnoe

Source: NC State University Libraries
Added: August 6, 2018

2003 journal article

Addition of arenes to ethylene and propene catalyzed by ruthenium

Journal of the American Chemical Society, 125(25), 7506–7507.

By: M. Lail, B. Arrowood & T. Gunnoe

Source: NC State University Libraries
Added: August 6, 2018

2003 journal article

Computational study of methane activation by TpRe(CO)(2) and CpRe(CO)(2) with a stereoelectronic comparison of cyclopentadienyl and scorpionate ligands

Organometallics, 22(11), 2331–2337.

By: R. Bergman, T. Cundari, A. Gillespie, T. Gunnoe, W. Harman, T. Klinckman, M. Temple, D. White

Source: NC State University Libraries
Added: August 6, 2018

2003 journal article

Octahedral Ru(II) amido complexes TpRu(L)(L ')(NHR) (Tp = hydridotris(pyrazolyl)borate; L = L ' = P(OMe)(3) or PMe3 or L = CO and L ' = PPh3; R = H, Ph, or Bu-t): Synthesis, characterization, and reactions with weakly acidic C-H bonds

Inorganic Chemistry, 42(15), 4759–4772.

By: D. Conner, K. Jayaprakash, M. Wells, S. Manzer, T. Gunnoe & P. Boyle

Source: NC State University Libraries
Added: August 6, 2018

2003 journal article

Radical polymerization of styrene and methyl methacrylate with Ruthenium(II) complexes

Organometallics, 22(23), 4692–4698.

By: B. Arrowood, M. Lail, T. Gunnoe & P. Boyle

Source: NC State University Libraries
Added: August 6, 2018

2003 journal article

Reactions of ruthenium benzylidene complexes with cyclic and acyclic imines: Oligomerization of 1-pyrroline and metathesis via tautomerism

Organometallics, 22(11), 2291–2297.

By: J. Zhang & T. Gunnoe

Source: NC State University Libraries
Added: August 6, 2018

2002 journal article

Influence of filled d pi-manifold and L/L ' ligands on the structure, basicity, and bond rotations of the octahedral and d(6) amido complexes TpRu(L)(L ')(NHPh) (Tp = hydridotris(pyrazolyl)borate; L= L ' = PMe3 or P(OMe)(3), or L = CO and L ' = PPh3)?

Inorganic Chemistry, 41(11), 3042–3049.

By: D. Conner, K. Jayaprakash, T. Gunnoe & P. Boyle

Source: NC State University Libraries
Added: August 6, 2018

2002 journal article

Ruthenium(II) anilido complexes TpRuL(2)(NHPh): Oxidative 4,4 '-aryl coupling reactions (Tp = hydridotris(pyrazolylborate); L = PMe3, P(OMe)(3), or CO)

Organometallics, 21(24), 5265–5271.

By: D. Conner, K. Jayaprakash, T. Gunnoe & P. Boyle

Source: NC State University Libraries
Added: August 6, 2018

2002 journal article

Synthesis of the Ru-IV amido complex [TpRu(CO)(PPh3)(NHPh)][OTf](2) (Tp = hydridotris(pyrazolyl)borate; OTf = trifluoromethanesulfonate) and deprotonation to form an octahedral and d(4) imido complex: computational study of Ru-IV-imido bonding

Chemical Communications (Cambridge, England), (4), 372–373.

By: K. Jayaprakash, A. Gillepsie, T. Gunnoe & D. White

Source: NC State University Libraries
Added: August 6, 2018

2002 journal article

Synthesis, spectroscopy, and solid-state structural characterization of the hexanuclear copper macrocycle [Cu6Cl6(mu-PCHP)(6)]

Angewandte Chemie [International Edition in English], 41(14), 2571-.

By: E. Blue, T. Gunnoe & N. Brooks

Source: NC State University Libraries
Added: August 6, 2018

2001 journal article

Preparation of the octahedral d(6) amido complex TpRu(CO)(PPh3)(NHPh) (Tp = hydridotris(pyrazolyl)borate): Solid-state structural characterization and reactivity

Inorganic Chemistry, 40(25), 6481–6486.

By: K. Jayaprakash, T. Gunnoe & P. Boyle

Source: NC State University Libraries
Added: August 6, 2018

2001 journal article

Synthesis and reactivity of the octahedral d(6) parent amido complexes TpRu(L)(L ')(NH2) (Tp = hydridotris(pyrazolyl)borate;L = L ' PMe3, P(OMe)(3); L = CO, L ' PPh3) and [TpRu(PPh3)(NH2)(2)][Li]

Organometallics, 20(25), 5254–5256.

By: K. Jayaprakash, D. Conner & T. Gunnoe

Source: NC State University Libraries
Added: August 6, 2018

2000 personal communication

Comparison of the relative electron-donating abilities of hydridotris(pyrazolyl)borate and cyclopentadienyl ligands: Different interactions with different transition metals

By: D. Tellers, S. Skoog, R. Bergman, T. Gunnoe & W. Harman

Source: NC State University Libraries
Added: August 6, 2018