Thomas Brent Gunnoe

Polymers for the stabilization and delivery of proteins topically and per os to the insect hemocoel through conjugation with aliphatic polyethylene glycol

PESTICIDE BIOCHEMISTRY AND PHYSIOLOGY, 115, 58–66.

Enhanced activity of an insecticidal protein, trypsin modulating oostatic factor (TMOF), through conjugation with aliphatic polyethylene glycol

PEST MANAGEMENT SCIENCE, 68(1), 49–59.

Well-Defined Copper(I) Amido Complex and Aryl Iodides Reacting to Form Aryl Amines

ORGANOMETALLICS, 30(1), 55–57.

Novel insecticide polymer chemistry to reduce the enzymatic digestion of a protein pesticide, trypsin modulating oostatic factor (TMOF)

PESTICIDE BIOCHEMISTRY AND PHYSIOLOGY, 93(3), 144–152.

Activation of sp(3) carbon-hydrogen bonds complex and subsequent metal-mediated formation

Angewandte Chemie [International Edition in English], 47(4), 726–730.

Aromatic C-H activation and catalytic hydrophenylation of ethylene by TpRu{P(OCH2)(3)CEt}(NCMe)Ph

ORGANOMETALLICS, 27(13), 3007–3017.

Chemistry surrounding Group 7 complexes that possess Poly(pyrazolyl)borate ligands

[Review of ]. Organotransition metal chemistry of poly(pyrazolyl)borates, pt 1, 56, 95–153.

Chlorination of Boron on a Ruthenium-Coordinated Hydridotris(pyrazolyl)borate (Tp) Ligand: A Caveat for the Use of TpRu(PPh3)(2)Cl

ORGANOMETALLICS, 28(1), 374–377.

Hydroarylation of unactivated olefins catalyzed by platinum(II) complexes

ORGANOMETALLICS, 27(16), 4031–4033.

Preparation and reactivity of a monomeric octahedral platinum(IV) amido complex

Inorganic Chemistry, 47(14), 6124–6126.

Activation of carbon-hydrogen bonds via 1,2-addition across M-X (X = OH or NH2) bonds of d(6) transition metals as a potential key step in hydrocarbon functionalization: A computational study

[Review of ]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 129(43), 13172–13182.

Addition of N-H and O-H bonds of amines and alcohols to electron-deficient olefins catalyzed by monomeric copper(I) systems: Reaction scope, mechanistic details, and comparison of catalyst efficiency

ORGANOMETALLICS, 26(6), 1483–1493.

Addition of s-h bonds across electron-deficient olefins catalyzed by well-defined copper(I) thiolate complexes

INORGANIC CHEMISTRY, 46(7), 2365–2367.

Anti-Markovnikov hydroamination and hydrothiolation of electron-deficient vinylarenes catalyzed by well-defined monomeric copper(I) amido and thiolate complexes

CHEMICAL COMMUNICATIONS, (1), 111–113.

Combined experimental and computational studies on the nature of aromatic C-H activation by octahedral ruthenium(II) complexes: Evidence for sigma-bond metathesis from Hammett studies

ORGANOMETALLICS, 26(26), 6604–6611.

Combined experimental and computational study of TpRu{P(pyr)(3)}(NCMe)Me (pyr = N-pyrrolyl): Inter- and intramolecular activation of C-H bonds and the impact of sterics on catalytic hydroarylation of olefins

ORGANOMETALLICS, 26(23), 5507–5516.

Comparative reactivity of TpRu(L)(NCMe)Ph (L = CO or PMe3): Impact of ancillary ligand L on activation of carbon-hydrogen bonds including catalytic hydroarylation and hydrovinylation/oligomerization of ethylene

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 129(21), 6765–6781.

Reactivity of TpRu(L)(NCMe)R (L = CO, PMe3; R = Me, Ph) systems with isonitriles: Experimental and computational studies toward the intra- and intermolecular hydroarylation of isonitriles

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 692(11), 2175–2186.

Reactivity of ruthenium(II) and copper(I) complexes that possess anionic heteroatomic ligands: Synthetic exploitation of nucleophilicity and basicity of amido, hydroxo, alkoxo, and aryloxo ligands for the activation of substrates that possess polar...

[Review of ]. European Journal of Inorganic Chemistry, (9), 1185–1203.

Ruthenium(II) complexes possessing the eta(6)-p-cymene ligand

INORGANICA CHIMICA ACTA, 361(11), 3254–3262.

Anti-Markovnikov N-H and O-H additions to electron-deficient olefins catalyzed by well-defined Cu(I) anilido, ethoxide, and phenoxide systems

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 128(5), 1446–1447.

Chemistry surrounding monomeric copper(I) methyl, phenyl, anilido, ethoxide, and phenoxide complexes supported by N-heterocyclic carbene ligands: Reactivity consistent with both early and late transition metal systems

Inorganic Chemistry, 45(22), 9032–9045.

Hydrogen-deuterium exchange between TpRu( PMe3)(L)X (L) = PMe3 and X = OH, OPh, Me, Ph, or NHPh; L = NCMe and X = Ph) and deuterated arene solvents: Evidence for metal-mediated processes

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 128(24), 7982–7994.

Octahedral [TpRu(PMe3)(2)OR](n+) complexes (Tp = hydridotris(pyrazolyl) borate; R = H or Ph; n=0 or 1): Reactions at Ru(II) and Ru(III) oxidation states with substrates that possess carbon-hydrogen bonds

ORGANOMETALLICS, 25(22), 5456–5465.

Protonation of N-heterocyclic carbene ligand coordinated to copper(I): Coordination mode of imidazolium cation as a function of counterion as determined by solid-state structures

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 691(26), 5988–5993.

Reactions of TpRu(CO)(NCMe)(Ph) with electron-rich olefins: examples of stoichiometric C-S, C-O and C-H bond cleavage

Chemical Communications (Cambridge, England), (9), 982–984.

Reactions of a Ru(II) phenyl complex with substrates that possess C-N or C-O multiple bonds: C-C bond formation, N-H bond cleavage, and decarbonylation reactions

ORGANOMETALLICS, 25(6), 1500–1510.

Single-electron oxidation of monomeric copper(I) alkyl complexes: Evidence for reductive elimination through bimolecular formation of Alkanes

ORGANOMETALLICS, 25(17), 4097–4104.

Cleavage of X-H bonds (X = N, O, or C) by copper(I) alkyl complexes to form monomeric two-coordinate copper(I) systems

INORGANIC CHEMISTRY, 44(24), 8647–8649.

Conversions of ruthenium(III) alkyl complexes to ruthenium(II) through Ru-C-alkyl bond homolysis

ORGANOMETALLICS, 24(6), 1301–1305.

Developments in catalytic aromatic C-H transformations: Promising tools for organic synthesis

CURRENT ORGANIC CHEMISTRY, 9(7), 671–685.

Evidence for the net addition of arene C-H bonds across a Ru(II)-hydroxide bond

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 127(41), 14174–14175.

Reactions of (PCP)Ru(CO)(NHPh)(PMe3) (PCP=2,6-((CH2PBu2)-Bu-t)(2)C6H3) with substrates that possess polar bonds

INORGANIC CHEMISTRY, 44(8), 2895–2907.

Ruthenium(II)-mediated carbon-carbon bond formation between acetonitrile and pyrrole: Combined experimental and computational study

ORGANOMETALLICS, 24(21), 5015–5024.

Synthesis of the five-coordinate ruthenium(II) Complexes [(PCP)Ru(CO)(L)][BAr'(4)] {PCP=2,6-((CH2PBu2)-Bu-t)(2)C6H3, BAr'(4) 3,5-(CF3)(2)C6H3, L = eta(1)-ClCH2Cl, eta-N-2, or mu-Cl-Ru(PCP)(CO)}: Reactions with phenyldiazomethane and phenylacetylene

Inorganic Chemistry, 44(23), 8379–8390.

Experimental and computational studies of ruthenium(II)-catalyzed addition of arene C-H bonds to olefins

ORGANOMETALLICS, 23(21), 5007–5020.

Reactions of TpRu(CO)(NCMe)(Me) (Tp = hydridotris(pyrazolyl)borate) with heteroaromatic substrates: Stoichiometric and catalytic C-H activation

ORGANOMETALLICS, 23(23), 5514–5523.

Ruthenium(II) anilido complex containing a bisphosphine pincer ligand: Reversible formation of amidinate ligands via intramolecular C-N bond formation

ORGANOMETALLICS, 23(13), 3094–3097.

Synthesis and reactivity of a coordinatively unsaturated ruthenium(II) parent amido complex: Studies of X-H activation (X = H or C)

ORGANOMETALLICS, 23(11), 2724–2733.

Addition of arenes to ethylene and propene catalyzed by ruthenium

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 125(25), 7506–7507.

Computational study of methane activation by TpRe(CO)(2) and CpRe(CO)(2) with a stereoelectronic comparison of cyclopentadienyl and scorpionate ligands

ORGANOMETALLICS, 22(11), 2331–2337.

Octahedral Ru(II) amido complexes TpRu(L)(L ')(NHR) (Tp = hydridotris(pyrazolyl)borate; L = L ' = P(OMe)(3) or PMe3 or L = CO and L ' = PPh3; R = H, Ph, or Bu-t): Synthesis, characterization, and reactions with weakly acidic C-H bonds

INORGANIC CHEMISTRY, 42(15), 4759–4772.

Radical polymerization of styrene and methyl methacrylate with Ruthenium(II) complexes

ORGANOMETALLICS, 22(23), 4692–4698.

Reactions of ruthenium benzylidene complexes with cyclic and acyclic imines: Oligomerization of 1-pyrroline and metathesis via tautomerism

ORGANOMETALLICS, 22(11), 2291–2297.

Influence of filled d pi-manifold and L/L ' ligands on the structure, basicity, and bond rotations of the octahedral and d(6) amido complexes TpRu(L)(L ')(NHPh) (Tp = hydridotris(pyrazolyl)borate; L= L ' = PMe3 or P(OMe)(3), or L = CO and L ' = PPh3): Solid-state structures of [TpRu(PMe3)(2)(NH2Ph)][OTf], [TpRu{P(OMe)(3)}(2)(NH2Ph)][OTf], and TpRu{P(OMe)(3)}(2)(NHPh)

INORGANIC CHEMISTRY, 41(11), 3042–3049.

Ruthenium(II) anilido complexes TpRuL(2)(NHPh): Oxidative 4,4 '-aryl coupling reactions (Tp = hydridotris(pyrazolylborate); L = PMe3, P(OMe)(3), or CO)

ORGANOMETALLICS, 21(24), 5265–5271.

Synthesis of the Ru-IV amido complex [TpRu(CO)(PPh3)(NHPh)][OTf](2) (Tp = hydridotris(pyrazolyl)borate; OTf = trifluoromethanesulfonate) and deprotonation to form an octahedral and d(4) imido complex: computational study of Ru-IV-imido bonding

Chemical Communications (Cambridge, England), (4), 372–373.

Synthesis, spectroscopy, and solid-state structural characterization of the hexanuclear copper macrocycle [Cu6Cl6(mu-PCHP)(6)]

Angewandte Chemie [International Edition in English], 41(14), 2571-.

Preparation of the octahedral d(6) amido complex TpRu(CO)(PPh3)(NHPh) (Tp = hydridotris(pyrazolyl)borate): Solid-state structural characterization and reactivity

INORGANIC CHEMISTRY, 40(25), 6481–6486.

Synthesis and reactivity of the octahedral d(6) parent amido complexes TpRu(L)(L ')(NH2) (Tp = hydridotris(pyrazolyl)borate; L = L ' PMe3, P(OMe)(3); L = CO, L ' PPh3) and [TpRu(PPh3)(NH2)(2)][Li]

ORGANOMETALLICS, 20(25), 5254–5256.

Comparison of the relative electron-donating abilities of hydridotris(pyrazolyl)borate and cyclopentadienyl ligands: Different interactions with different transition metals

Tellers, D. M., Skoog, S. J., Bergman, R. G., Gunnoe, T. B., & Harman, W. D. (2000, June 26).