Thomas Brent Gunnoe

Works (51)

Updated: April 5th, 2024 01:44

2014 journal article

Polymers for the stabilization and delivery of proteins topically and per os to the insect hemocoel through conjugation with aliphatic polyethylene glycol

PESTICIDE BIOCHEMISTRY AND PHYSIOLOGY, 115, 58–66.

author keywords: Insulin; Heliothis virescens; Tobacco budworm; PEGylation; Polyethylene glycol; Protein delivery
MeSH headings : Animals; Cattle; Drug Delivery Systems / methods; Hemolymph / metabolism; Insulin / chemistry; Insulin / metabolism; Larva / growth & development; Larva / metabolism; Moths / growth & development; Moths / metabolism; Polyethylene Glycols / chemistry; Polymers / chemistry; Polymers / metabolism; Protein Stability; Serum Albumin, Bovine / chemistry; Serum Albumin, Bovine / metabolism
TL;DR: Co-feeding of aliphatic polyethylene glycol (PEG), phospholipase A2, anionic and ionic detergents, and amphipathic glycoside with bovine serum albumin as a model protein to fourth stadium tobacco budworms, Heliothis virescens, did not affect the levels of BSA in the hemolymph. (via Semantic Scholar)
UN Sustainable Development Goal Categories
3. Good Health and Well-being (Web of Science; OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2012 journal article

Enhanced activity of an insecticidal protein, trypsin modulating oostatic factor (TMOF), through conjugation with aliphatic polyethylene glycol

PEST MANAGEMENT SCIENCE, 68(1), 49–59.

By: L. Jeffers n, H. Shen n, S. Khalil n, B. Bissinger n, A. Brandt, T. Gunnoe n, R. Roe n

author keywords: trypsin modulating oostatic factor; TMOF; PEGylation; polyethylene glycol; mosquito; tobacco budworm; cotton bollworm; protein delivery
MeSH headings : Aedes / drug effects; Aedes / growth & development; Animals; Insecticides / chemical synthesis; Insecticides / chemistry; Insecticides / pharmacology; Larva / drug effects; Larva / growth & development; Moths / drug effects; Oligopeptides / chemistry; Oligopeptides / pharmacology; Polyethylene Glycols / chemistry
TL;DR: Aliphatic PEG polymers can be used as a new method for increasing the activity of insecticidal proteins, according to research suggests. (via Semantic Scholar)
UN Sustainable Development Goal Categories
2. Zero Hunger (Web of Science)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2011 journal article

Well-Defined Copper(I) Amido Complex and Aryl Iodides Reacting to Form Aryl Amines

ORGANOMETALLICS, 30(1), 55–57.

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2009 journal article

Chlorination of Boron on a Ruthenium-Coordinated Hydridotris(pyrazolyl)borate (Tp) Ligand: A Caveat for the Use of TpRu(PPh3)(2)Cl

ORGANOMETALLICS, 28(1), 374–377.

By: N. Foley n, R. Abernethy n, T. Gunnoe n, A. Hill n, P. Boyle n & M. Sabat n

UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2009 journal article

Novel insecticide polymer chemistry to reduce the enzymatic digestion of a protein pesticide, trypsin modulating oostatic factor (TMOF)

PESTICIDE BIOCHEMISTRY AND PHYSIOLOGY, 93(3), 144–152.

By: H. Shen n, A. Brandt, B. Witting-Bissinger n, T. Gunnoe n & R. Roe n

author keywords: Insecticide; Protein; Polymer chemistry; Trypsin modulating oostatic factor; TMOF; Polyethylene glycol; Digestion; Protease; Leucine aminopeptidase; Protein delivery
TL;DR: Structural activity studies demonstrated a correlation between the molecular weight of the PEG polymer and resistance to digestion and show proof of concept that aliphatic-PEG protein polymerization can be used to prevent protease degradation of a protein insecticide. (via Semantic Scholar)
UN Sustainable Development Goal Categories
2. Zero Hunger (Web of Science)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2008 journal article

Activation of sp(3) carbon-hydrogen bonds complex and subsequent metal-mediated formation

Angewandte Chemie [International Edition in English], 47(4), 726–730.

By: N. Foley, T. Gunnoe, T. Cundari, P. Boyle & J. Petersen

Source: NC State University Libraries
Added: August 6, 2018

2008 journal article

Anti-Markovnikov hydroamination and hydrothiolation of electron-deficient vinylarenes catalyzed by well-defined monomeric copper(I) amido and thiolate complexes

CHEMICAL COMMUNICATIONS, (1), 111–113.

By: C. Munro-Leighton n, S. Delp n, N. Alsop n, E. Blue n & T. Gunnoe n

TL;DR: Monomeric Cu(I) amido and thiolate complexes that are supported by the N-heterocyclic carbene ligand 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene (IPr) catalyze the hydroamination and hydrothiolation of electron-deficient vinylarenes with reactivity patterns that are consistent with an intermolecular nucleophilic addition. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2008 journal article

Aromatic C-H activation and catalytic hydrophenylation of ethylene by TpRu{P(OCH2)(3)CEt}(NCMe)Ph

ORGANOMETALLICS, 27(13), 3007–3017.

Source: Web Of Science
Added: August 6, 2018

2008 review

Chemistry surrounding Group 7 complexes that possess Poly(pyrazolyl)borate ligands

[Review of ]. Organotransition metal chemistry of poly(pyrazolyl)borates, pt 1, 56, 95–153.

By: M. Lail, K. Pittard & T. Gunnoe

Source: NC State University Libraries
Added: August 6, 2018

2008 journal article

Hydroarylation of unactivated olefins catalyzed by platinum(II) complexes

ORGANOMETALLICS, 27(16), 4031–4033.

By: B. McKeown n, N. Foley n, J. Lee n & T. Gunnoe n

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2008 journal article

Preparation and reactivity of a monomeric octahedral platinum(IV) amido complex

Inorganic Chemistry, 47(14), 6124–6126.

By: C. Munro-Leighton, Y. Feng, J. Zhang, N. Alsop, T. Gunnoe, P. Boyle, J. Petersen

Source: NC State University Libraries
Added: August 6, 2018

2008 journal article

Ruthenium(II) complexes possessing the eta(6)-p-cymene ligand

INORGANICA CHIMICA ACTA, 361(11), 3254–3262.

By: T. Sumiyoshi n, T. Gunnoe n, J. Petersen* & P. Boyle n

author keywords: p-cymene; ruthenium; acetylacetonate; half-sandwich complex
UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2007 review

Activation of carbon-hydrogen bonds via 1,2-addition across M-X (X = OH or NH2) bonds of d(6) transition metals as a potential key step in hydrocarbon functionalization: A computational study

[Review of ]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 129(43), 13172–13182.

By: T. Cundari n, T. Grimes n & T. Gunnoe n

TL;DR: Computational examinations of the efficacy of model d6 transition metal complexes of the form [(Tab)M(PH3)2X]q for the activation of benzene C-H bonds and the potential for their incorporation into catalytic functionalization cycles are presented. (via Semantic Scholar)
Source: Web Of Science
Added: August 6, 2018

2007 journal article

Addition of N-H and O-H bonds of amines and alcohols to electron-deficient olefins catalyzed by monomeric copper(I) systems: Reaction scope, mechanistic details, and comparison of catalyst efficiency

ORGANOMETALLICS, 26(6), 1483–1493.

By: C. Munro-Leighton n, S. Delp n, E. Blue n & T. Gunnoe n

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2007 journal article

Addition of s-h bonds across electron-deficient olefins catalyzed by well-defined copper(I) thiolate complexes

INORGANIC CHEMISTRY, 46(7), 2365–2367.

By: S. Delp n, C. Munro-Leighton n, L. Goj n, M. Ramirez n, T. Gunnoe n, J. Petersen n, P. Boyle n

MeSH headings : Alkenes / chemistry; Catalysis; Copper / chemistry; Electrons; Hydrogen / chemistry; Ligands; Models, Molecular; Molecular Conformation; Sulfhydryl Compounds / chemistry; Sulfur / chemistry
TL;DR: A series of monomeric (NHC)Cu(SR) (R = Ph or CH2Ph; NHC = N-heterocyclic carbene) complexes have been synthesized and fully characterized including single-crystal X-ray diffraction studies. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2007 journal article

Combined experimental and computational studies on the nature of aromatic C-H activation by octahedral ruthenium(II) complexes: Evidence for sigma-bond metathesis from Hammett studies

ORGANOMETALLICS, 26(26), 6604–6611.

Source: Web Of Science
Added: August 6, 2018

2007 journal article

Combined experimental and computational study of TpRu{P(pyr)(3)}(NCMe)Me (pyr = N-pyrrolyl): Inter- and intramolecular activation of C-H bonds and the impact of sterics on catalytic hydroarylation of olefins

ORGANOMETALLICS, 26(23), 5507–5516.

Source: Web Of Science
Added: August 6, 2018

2007 journal article

Comparative reactivity of TpRu(L)(NCMe)Ph (L = CO or PMe3): Impact of ancillary ligand L on activation of carbon-hydrogen bonds including catalytic hydroarylation and hydrovinylation/oligomerization of ethylene

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 129(21), 6765–6781.

TL;DR: Kinetic studies, isotopic labeling, and other experimental evidence suggest that the mechanism of benzene C-H activation involves reversible dissociation of acetonitrile, reversible benzene coordination, and rate-determining C-h activation of coordinated benzene. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2007 journal article

Reactivity of TpRu(L)(NCMe)R (L = CO, PMe3; R = Me, Ph) systems with isonitriles: Experimental and computational studies toward the intra- and intermolecular hydroarylation of isonitriles

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 692(11), 2175–2186.

author keywords: ruthenium; hydroarylation; isonitrile; density functional theory studies
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2007 review

Reactivity of ruthenium(II) and copper(I) complexes that possess anionic heteroatomic ligands: Synthetic exploitation of nucleophilicity and basicity of amido, hydroxo, alkoxo, and aryloxo ligands for the activation of substrates that possess polar...

[Review of ]. European Journal of Inorganic Chemistry, (9), 1185–1203.

By: T. Gunnoe

Source: NC State University Libraries
Added: August 6, 2018

2006 journal article

Anti-Markovnikov N-H and O-H additions to electron-deficient olefins catalyzed by well-defined Cu(I) anilido, ethoxide, and phenoxide systems

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 128(5), 1446–1447.

By: C. Munro-Leighton n, E. Blue n & T. Gunnoe n

TL;DR: Catalytic activity has been observed for olefins CH2C(H)(X) with X = CN, C(O)Me, or CO2Me as well as crotononitrile. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2006 journal article

Chemistry surrounding monomeric copper(I) methyl, phenyl, anilido, ethoxide, and phenoxide complexes supported by N-heterocyclic carbene ligands: Reactivity consistent with both early and late transition metal systems

Inorganic Chemistry, 45(22), 9032–9045.

By: L. Goj n, E. Blue n, S. Delp n, T. Gunnoe n, T. Cundari n, A. Pierpont n, J. Petersen n, P. Boyle n

TL;DR: DFT calculations suggest that the HOMO for the series of Cu anilido complexes is localized primarily on the amido nitrogen with some ppi(anilido)-dpi(Cu) pi-character. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: NC State University Libraries
Added: August 6, 2018

2006 journal article

Hydrogen-deuterium exchange between TpRu( PMe3)(L)X (L) = PMe3 and X = OH, OPh, Me, Ph, or NHPh; L = NCMe and X = Ph) and deuterated arene solvents: Evidence for metal-mediated processes

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 128(24), 7982–7994.

MeSH headings : Cadmium Compounds / chemistry; Deuterium / chemistry; Hydrogen / chemistry; Ligands; Mesylates / chemistry; Metals / chemistry; Microscopy, Electron; Organometallic Compounds / chemistry; Ruthenium / chemistry; Selenium Compounds / chemistry; Solvents / chemistry; Spectrum Analysis; Temperature
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2006 journal article

Octahedral [TpRu(PMe3)(2)OR](n+) complexes (Tp = hydridotris(pyrazolyl) borate; R = H or Ph; n=0 or 1): Reactions at Ru(II) and Ru(III) oxidation states with substrates that possess carbon-hydrogen bonds

ORGANOMETALLICS, 25(22), 5456–5465.

By: Y. Feng n, T. Gunnoe n, T. Grimes n & T. Cundari n

Source: Web Of Science
Added: August 6, 2018

2006 journal article

Protonation of N-heterocyclic carbene ligand coordinated to copper(I): Coordination mode of imidazolium cation as a function of counterion as determined by solid-state structures

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 691(26), 5988–5993.

author keywords: copper; N-heterocyclic carbene; imidazolium
UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2006 journal article

Reactions of TpRu(CO)(NCMe)(Ph) with electron-rich olefins: examples of stoichiometric C-S, C-O and C-H bond cleavage

Chemical Communications (Cambridge, England), (9), 982–984.

By: L. Goj, M. Lail, K. Pittard, K. Riley, T. Gunnoe & J. Petersen

Source: NC State University Libraries
Added: August 6, 2018

2006 journal article

Reactions of a Ru(II) phenyl complex with substrates that possess C-N or C-O multiple bonds: C-C bond formation, N-H bond cleavage, and decarbonylation reactions

ORGANOMETALLICS, 25(6), 1500–1510.

Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2006 journal article

Single-electron oxidation of monomeric copper(I) alkyl complexes: Evidence for reductive elimination through bimolecular formation of Alkanes

ORGANOMETALLICS, 25(17), 4097–4104.

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2005 journal article

Cleavage of X-H bonds (X = N, O, or C) by copper(I) alkyl complexes to form monomeric two-coordinate copper(I) systems

INORGANIC CHEMISTRY, 44(24), 8647–8649.

By: L. Goj n, E. Blue n, C. Munro-Leighton n, T. Gunnoe n & J. Petersen n

TL;DR: Solid-state X-ray crystal structures of the anilido, ethoxide, and phenoxide complexes confirm that they are monomeric systems. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2005 journal article

Conversions of ruthenium(III) alkyl complexes to ruthenium(II) through Ru-C-alkyl bond homolysis

ORGANOMETALLICS, 24(6), 1301–1305.

By: M. Lail n, T. Gunnoe n, K. Barakat n & T. Cundari n

Source: Web Of Science
Added: August 6, 2018

2005 journal article

Developments in catalytic aromatic C-H transformations: Promising tools for organic synthesis

CURRENT ORGANIC CHEMISTRY, 9(7), 671–685.

By: L. Goj* & T. Gunnoe*

Source: Web Of Science
Added: August 6, 2018

2005 journal article

Evidence for the net addition of arene C-H bonds across a Ru(II)-hydroxide bond

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 127(41), 14174–14175.

By: Y. Feng n, M. Lail n, K. Barakat n, T. Cundari n, T. Gunnoe n & J. Petersen n

MeSH headings : Crystallography, X-Ray; Hydroxides / chemistry; Models, Molecular; Molecular Conformation; Organometallic Compounds / chemical synthesis; Organometallic Compounds / chemistry; Ruthenium / chemistry
TL;DR: Mechanistic and computational studies suggest that a likely reaction pathway for the H/D exchange involves loss of PMe3 to produce {TpRu(PMe3)(OH2)(OH)}, followed by the net addition of a benzene C-H(D) bond across the Ru-OH bond to form the putative complex. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2005 journal article

Reactions of (PCP)Ru(CO)(NHPh)(PMe3) (PCP=2,6-((CH2PBu2)-Bu-t)(2)C6H3) with substrates that possess polar bonds

INORGANIC CHEMISTRY, 44(8), 2895–2907.

By: J. Zhang n, T. Gunnoe n & J. Peterson

TL;DR: Based on studies of the reaction of complex 1 with acetonitrile, the transformations are suggested to proceed by dissociation of trimethylphosphine, followed by coordination of the organic substrate and then intramolecular N-C bond formation. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2005 journal article

Ruthenium(II)-mediated carbon-carbon bond formation between acetonitrile and pyrrole: Combined experimental and computational study

ORGANOMETALLICS, 24(21), 5015–5024.

By: K. Pittard n, T. Cundari n, T. Gunnoe n, C. Day n & J. Petersen n

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2005 journal article

Synthesis of the five-coordinate ruthenium(II) Complexes [(PCP)Ru(CO)(L)][BAr'(4)] {PCP=2,6-((CH2PBu2)-Bu-t)(2)C6H3, BAr'(4) 3,5-(CF3)(2)C6H3, L = eta(1)-ClCH2Cl, eta-N-2, or mu-Cl-Ru(PCP)(CO)}: Reactions with phenyldiazomethane and phenylacetylene

Inorganic Chemistry, 44(23), 8379–8390.

By: J. Zhang, K. Barakat, T. Cundari, T. Gunnoe, P. Boyle, J. Petersen, C. Day

Source: NC State University Libraries
Added: August 6, 2018

2004 journal article

Experimental and computational studies of ruthenium(II)-catalyzed addition of arene C-H bonds to olefins

ORGANOMETALLICS, 23(21), 5007–5020.

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2004 journal article

Reactions of TpRu(CO)(NCMe)(Me) (Tp = hydridotris(pyrazolyl)borate) with heteroaromatic substrates: Stoichiometric and catalytic C-H activation

ORGANOMETALLICS, 23(23), 5514–5523.

By: K. Pittard n, J. Lee n, T. Cundari n, T. Gunnoe n & J. Petersen n

Source: Web Of Science
Added: August 6, 2018

2004 journal article

Ruthenium(II) anilido complex containing a bisphosphine pincer ligand: Reversible formation of amidinate ligands via intramolecular C-N bond formation

ORGANOMETALLICS, 23(13), 3094–3097.

By: J. Zhang n, T. Gunnoe n & P. Boyle n

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2004 journal article

Synthesis and reactivity of a coordinatively unsaturated ruthenium(II) parent amido complex: Studies of X-H activation (X = H or C)

ORGANOMETALLICS, 23(11), 2724–2733.

By: D. Conner n, K. Jayaprakash n, T. Cundari n & T. Gunnoe n

Source: Web Of Science
Added: August 6, 2018

2003 journal article

Addition of arenes to ethylene and propene catalyzed by ruthenium

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 125(25), 7506–7507.

By: M. Lail n, B. Arrowood n & T. Gunnoe n

TL;DR: TpRuII(CO)(Me)(NCMe) (Tp = hydridotris(pyrazolyl)borate) serves as a catalyst precursor for the conversion of benzene and ethylene or propene to alkylaromatic products. (via Semantic Scholar)
Source: Web Of Science
Added: August 6, 2018

2003 journal article

Computational study of methane activation by TpRe(CO)(2) and CpRe(CO)(2) with a stereoelectronic comparison of cyclopentadienyl and scorpionate ligands

ORGANOMETALLICS, 22(11), 2331–2337.

By: R. Bergman n, T. Cundari n, A. Gillespie n, T. Gunnoe n, W. Harman n, T. Klinckman n, M. Temple n, D. White n

UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2003 journal article

Octahedral Ru(II) amido complexes TpRu(L)(L ')(NHR) (Tp = hydridotris(pyrazolyl)borate; L = L ' = P(OMe)(3) or PMe3 or L = CO and L ' = PPh3; R = H, Ph, or Bu-t): Synthesis, characterization, and reactions with weakly acidic C-H bonds

INORGANIC CHEMISTRY, 42(15), 4759–4772.

By: D. Conner n, K. Jayaprakash n, M. Wells n, S. Manzer n, T. Gunnoe n & P. Boyle n

TL;DR: Kinetic studies indicate that the reaction of TpRu(PMe(3))(2)(NHPh) with phenylacetylene occurs via a pathway that involves Tp Ru(P me(3)(2)Ru[double bond]C[double Bond]C(H)Ph][OTf], and [TpRu (PMe (3)).[OTf] as catalyst. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2003 journal article

Radical polymerization of styrene and methyl methacrylate with Ruthenium(II) complexes

ORGANOMETALLICS, 22(23), 4692–4698.

By: B. Arrowood n, M. Lail n, T. Gunnoe n & P. Boyle n

Source: Web Of Science
Added: August 6, 2018

2003 journal article

Reactions of ruthenium benzylidene complexes with cyclic and acyclic imines: Oligomerization of 1-pyrroline and metathesis via tautomerism

ORGANOMETALLICS, 22(11), 2291–2297.

By: J. Zhang n & T. Gunnoe n

UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2002 journal article

Influence of filled d pi-manifold and L/L ' ligands on the structure, basicity, and bond rotations of the octahedral and d(6) amido complexes TpRu(L)(L ')(NHPh) (Tp = hydridotris(pyrazolyl)borate; L= L ' = PMe3 or P(OMe)(3), or L = CO and L ' = PPh3): Solid-state structures of [TpRu(PMe3)(2)(NH2Ph)][OTf], [TpRu{P(OMe)(3)}(2)(NH2Ph)][OTf], and TpRu{P(OMe)(3)}(2)(NHPh)

INORGANIC CHEMISTRY, 41(11), 3042–3049.

By: D. Conner n, K. Jayaprakash n, T. Gunnoe n & P. Boyle n

UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2002 journal article

Ruthenium(II) anilido complexes TpRuL(2)(NHPh): Oxidative 4,4 '-aryl coupling reactions (Tp = hydridotris(pyrazolylborate); L = PMe3, P(OMe)(3), or CO)

ORGANOMETALLICS, 21(24), 5265–5271.

By: D. Conner n, K. Jayaprakash n, T. Gunnoe n & P. Boyle n

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2002 journal article

Synthesis of the Ru-IV amido complex [TpRu(CO)(PPh3)(NHPh)][OTf](2) (Tp = hydridotris(pyrazolyl)borate; OTf = trifluoromethanesulfonate) and deprotonation to form an octahedral and d(4) imido complex: computational study of Ru-IV-imido bonding

Chemical Communications (Cambridge, England), (4), 372–373.

By: K. Jayaprakash n, A. Gillepsie*, T. Gunnoe n & D. White*

TL;DR: A computational study of the bonding of the imido complex provides a foundation for discussion of its instability in terms of pi-conflict. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Source: NC State University Libraries
Added: August 6, 2018

2002 journal article

Synthesis, spectroscopy, and solid-state structural characterization of the hexanuclear copper macrocycle [Cu6Cl6(mu-PCHP)(6)]

Angewandte Chemie [International Edition in English], 41(14), 2571-.

By: E. Blue, T. Gunnoe & N. Brooks

Source: NC State University Libraries
Added: August 6, 2018

2001 journal article

Preparation of the octahedral d(6) amido complex TpRu(CO)(PPh3)(NHPh) (Tp = hydridotris(pyrazolyl)borate): Solid-state structural characterization and reactivity

INORGANIC CHEMISTRY, 40(25), 6481–6486.

By: K. Jayaprakash n, T. Gunnoe n & P. Boyle n

TL;DR: Variable temperature NMR studies have revealed a rotational barrier around the ruthenium-amido nitrogen bond of 3 of 12 kcal/mol (transformation of the major isomer to the minor isomer). (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2001 journal article

Synthesis and reactivity of the octahedral d(6) parent amido complexes TpRu(L)(L ')(NH2) (Tp = hydridotris(pyrazolyl)borate; L = L ' PMe3, P(OMe)(3); L = CO, L ' PPh3) and [TpRu(PPh3)(NH2)(2)][Li]

ORGANOMETALLICS, 20(25), 5254–5256.

By: K. Jayaprakash n, D. Conner n & T. Gunnoe n

UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2000 personal communication

Comparison of the relative electron-donating abilities of hydridotris(pyrazolyl)borate and cyclopentadienyl ligands: Different interactions with different transition metals

Tellers, D. M., Skoog, S. J., Bergman, R. G., Gunnoe, T. B., & Harman, W. D. (2000, June 26).

By: D. Tellers*, S. Skoog*, R. Bergman*, T. Gunnoe n & W. Harman*

UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

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