Thomas Gunnoe

Jeffers, L. A., Shen, H., Bissinger, B. W., Khalil, S., Gunnoe, T. B., & Roe, R. M. (2014). Polymers for the stabilization and delivery of proteins topically and per os to the insect hemocoel through conjugation with aliphatic polyethylene glycol. PESTICIDE BIOCHEMISTRY AND PHYSIOLOGY, 115, 58–66. https://doi.org/10.1016/j.pestbp.2014.08.006

Jeffers, L. A., Shen, H., Khalil, S., Bissinger, B. W., Brandt, A., Gunnoe, T. B., & Roe, R. M. (2012). Enhanced activity of an insecticidal protein, trypsin modulating oostatic factor (TMOF), through conjugation with aliphatic polyethylene glycol. PEST MANAGEMENT SCIENCE, 68(1), 49–59. https://doi.org/10.1002/ps.2219

Delp, S. A., Goj, L. A., Pouy, M. J., Munro-Leighton, C., Lee, J. P., Gunnoe, T. B., … Petersen, J. L. (2011). Well-Defined Copper(I) Amido Complex and Aryl Iodides Reacting to Form Aryl Amines. ORGANOMETALLICS, 30(1), 55–57. https://doi.org/10.1021/om101084e

Foley, N. A., Abernethy, R. J., Gunnoe, T. B., Hill, A. F., Boyle, P. D., & Sabat, M. (2009). Chlorination of Boron on a Ruthenium-Coordinated Hydridotris(pyrazolyl)borate (Tp) Ligand: A Caveat for the Use of TpRu(PPh3)(2)Cl. ORGANOMETALLICS, 28(1), 374–377. https://doi.org/10.1021/om8008074

Shen, H., Brandt, A., Witting-Bissinger, B. E., Gunnoe, T. B., & Roe, R. M. (2009). Novel insecticide polymer chemistry to reduce the enzymatic digestion of a protein pesticide, trypsin modulating oostatic factor (TMOF). PESTICIDE BIOCHEMISTRY AND PHYSIOLOGY, 93(3), 144–152. https://doi.org/10.1016/j.pestbp.2009.02.004

Foley, N. A., Gunnoe, T. B., Cundari, T. R., Boyle, P. D., & Petersen, J. L. (2008). Activation of sp(3) carbon-hydrogen bonds complex and subsequent metal-mediated formation. Angewandte Chemie [International Edition in English], 47(4), 726–730.

Munro-Leighton, C., Delp, S. A., Alsop, N. M., Blue, E. D., & Gunnoe, T. B. (2008). Anti-Markovnikov hydroamination and hydrothiolation of electron-deficient vinylarenes catalyzed by well-defined monomeric copper(I) amido and thiolate complexes. CHEMICAL COMMUNICATIONS, (1), 111–113. https://doi.org/10.1039/b715507g

Foley, N. A., Ke, Z., Gunnoe, T. B., Cundari, T. R., & Petersen, J. L. (2008). Aromatic C-H activation and catalytic hydrophenylation of ethylene by TpRu{P(OCH2)(3)CEt}(NCMe)Ph. ORGANOMETALLICS, 27(13), 3007–3017. https://doi.org/10.1021/om800275b

Lail, M., Pittard, K. A., & Gunnoe, T. B. (2008). [Review of Chemistry surrounding Group 7 complexes that possess Poly(pyrazolyl)borate ligands]. Organotransition metal chemistry of poly(pyrazolyl)borates, pt 1, 56, 95–153.

McKeown, B. A., Foley, N. A., Lee, J. P., & Gunnoe, T. B. (2008). Hydroarylation of unactivated olefins catalyzed by platinum(II) complexes. ORGANOMETALLICS, 27(16), 4031–4033. https://doi.org/10.1021/om8006008

Munro-Leighton, C., Feng, Y., Zhang, J., Alsop, N. M., Gunnoe, T. B., Boyle, P. D., & Petersen, J. L. (2008). Preparation and reactivity of a monomeric octahedral platinum(IV) amido complex. Inorganic Chemistry, 47(14), 6124–6126. https://doi.org/10.1021/icS00843b

Sumiyoshi, T., Gunnoe, T. B., Petersen, J. L., & Boyle, P. D. (2008). Ruthenium(II) complexes possessing the eta(6)-p-cymene ligand. INORGANICA CHIMICA ACTA, 361(11), 3254–3262. https://doi.org/10.1016/j.ica.2007.10.012

Cundari, T. R., Grimes, T. V., & Gunnoe, T. B. (2007). [Review of Activation of carbon-hydrogen bonds via 1,2-addition across M-X (X = OH or NH2) bonds of d(6) transition metals as a potential key step in hydrocarbon functionalization: A computational study]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 129(43), 13172–13182. https://doi.org/10.1021/ja074125g

Munro-Leighton, C., Delp, S. A., Blue, E. D., & Gunnoe, T. B. (2007). Addition of N-H and O-H bonds of amines and alcohols to electron-deficient olefins catalyzed by monomeric copper(I) systems: Reaction scope, mechanistic details, and comparison of catalyst efficiency. ORGANOMETALLICS, 26(6), 1483–1493. https://doi.org/10.1021/om061133h

Delp, S. A., Munro-Leighton, C., Goj, L. A., Ramirez, M. A., Gunnoe, T. B., Petersen, J. L., & Boyle, P. D. (2007). Addition of s-h bonds across electron-deficient olefins catalyzed by well-defined copper(I) thiolate complexes. INORGANIC CHEMISTRY, 46(7), 2365–2367. https://doi.org/10.1021/ic070268s

DeYonker, N. J., Foley, N. A., Cundari, T. R., Gunnoe, T. B., & Petersen, J. L. (2007). Combined experimental and computational studies on the nature of aromatic C-H activation by octahedral ruthenium(II) complexes: Evidence for sigma-bond metathesis from Hammett studies. ORGANOMETALLICS, 26(26), 6604–6611. https://doi.org/10.1021/om7009057

Foley, N. A., Lail, M., Gunnoe, T. B., Cundari, T. R., Boyle, P. D., & Petersen, J. L. (2007). Combined experimental and computational study of TpRu{P(pyr)(3)}(NCMe)Me (pyr = N-pyrrolyl): Inter- and intramolecular activation of C-H bonds and the impact of sterics on catalytic hydroarylation of olefins. ORGANOMETALLICS, 26(23), 5507–5516. https://doi.org/10.1021/om700666y

Foley, N. A., Lail, M., Lee, J. P., Gunnoe, T. B., Cundari, T. R., & Petersen, J. L. (2007). Comparative reactivity of TpRu(L)(NCMe)Ph (L = CO or PMe3): Impact of ancillary ligand L on activation of carbon-hydrogen bonds including catalytic hydroarylation and hydrovinylation/oligomerization of ethylene. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 129(21), 6765–6781. https://doi.org/10.1021/ja068542p

Lee, J. P., Jimenez-Halla, O. C., Cundari, T. R., & Gunnoe, T. B. (2007). Reactivity of TpRu(L)(NCMe)R (L = CO, PMe3; R = Me, Ph) systems with isonitriles: Experimental and computational studies toward the intra- and intermolecular hydroarylation of isonitriles. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 692(11), 2175–2186. https://doi.org/10.1016/j.jorganchem.2007.01.037

Gunnoe, T. B. (2007). [Review of Reactivity of ruthenium(II) and copper(I) complexes that possess anionic heteroatomic ligands: Synthetic exploitation of nucleophilicity and basicity of amido, hydroxo, alkoxo, and aryloxo ligands for the activation of substrates that possess polar...]. European Journal of Inorganic Chemistry, (9), 1185–1203.

Munro-Leighton, C., Blue, E. D., & Gunnoe, T. B. (2006). Anti-Markovnikov N-H and O-H additions to electron-deficient olefins catalyzed by well-defined Cu(I) anilido, ethoxide, and phenoxide systems. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 128(5), 1446–1447. https://doi.org/10.1021/ja057622a

Goj, L. A., Blue, E. D., Delp, S. A., Gunnoe, T. B., Cundari, T. R., Pierpont, A. W., … Boyle, P. D. (2006). Chemistry surrounding monomeric copper(I) methyl, phenyl, anilido, ethoxide, and phenoxide complexes supported by N-heterocyclic carbene ligands: Reactivity consistent with both early and late transition metal systems. Inorganic Chemistry, 45(22), 9032–9045. https://doi.org/10.1021/ic0611995

Feng, Y., Lail, M., Foley, N. A., Gunnoe, T. B., Barakat, K. A., Cundari, T. R., & Petersen, J. L. (2006). Hydrogen-deuterium exchange between TpRu( PMe3)(L)X (L) = PMe3 and X = OH, OPh, Me, Ph, or NHPh; L = NCMe and X = Ph) and deuterated arene solvents: Evidence for metal-mediated processes. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 128(24), 7982–7994. https://doi.org/10.1021/ja0615775

Feng, Y., Gunnoe, T. B., Grimes, T. V., & Cundari, T. R. (2006). Octahedral [TpRu(PMe3)(2)OR](n+) complexes (Tp = hydridotris(pyrazolyl) borate; R = H or Ph; n=0 or 1): Reactions at Ru(II) and Ru(III) oxidation states with substrates that possess carbon-hydrogen bonds. ORGANOMETALLICS, 25(22), 5456–5465. https://doi.org/10.1021/om0606385

Blue, E. D., Gunnoe, T. B., Petersen, J. L., & Boyle, P. D. (2006). Protonation of N-heterocyclic carbene ligand coordinated to copper(I): Coordination mode of imidazolium cation as a function of counterion as determined by solid-state structures. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 691(26), 5988–5993. https://doi.org/10.1016/j.jorganchem.2006.09.051

Goj, L. A., Lail, M., Pittard, K. A., Riley, K. C., Gunnoe, T. B., & Petersen, J. L. (2006). Reactions of TpRu(CO)(NCMe)(Ph) with electron-rich olefins: examples of stoichiometric C-S, C-O and C-H bond cleavage. Chemical Communications (Cambridge, England), (9), 982–984.

Lee, J. P., Pittard, K. A., DeYonker, N. J., Cundari, T. R., Gunnoe, T. B., & Petersen, J. L. (2006). Reactions of a Ru(II) phenyl complex with substrates that possess C-N or C-O multiple bonds: C-C bond formation, N-H bond cleavage, and decarbonylation reactions. ORGANOMETALLICS, 25(6), 1500–1510. https://doi.org/10.1021/om050967h

Goj, L. A., Blue, E. D., Delp, S. A., Gunnoe, T. B., Cundari, T. R., & Petersen, J. L. (2006). Single-electron oxidation of monomeric copper(I) alkyl complexes: Evidence for reductive elimination through bimolecular formation of Alkanes. ORGANOMETALLICS, 25(17), 4097–4104. https://doi.org/10.1021/om060409i

Goj, L. A., Blue, E. D., Munro-Leighton, C., Gunnoe, T. B., & Petersen, J. L. (2005). Cleavage of X-H bonds (X = N, O, or C) by copper(I) alkyl complexes to form monomeric two-coordinate copper(I) systems. INORGANIC CHEMISTRY, 44(24), 8647–8649. https://doi.org/10.1021/ic0517624

Lail, M., Gunnoe, T. B., Barakat, K. A., & Cundari, T. R. (2005). Conversions of ruthenium(III) alkyl complexes to ruthenium(II) through Ru-C-alkyl bond homolysis. ORGANOMETALLICS, 24(6), 1301–1305. https://doi.org/10.1021/om049145v

Goj, L. A., & Gunnoe, T. B. (2005). Developments in catalytic aromatic C-H transformations: Promising tools for organic synthesis. CURRENT ORGANIC CHEMISTRY, 9(7), 671–685. https://doi.org/10.2174/1385272053765051

Feng, Y., Lail, M., Barakat, K. A., Cundari, T. R., Gunnoe, T. B., & Petersen, J. L. (2005). Evidence for the net addition of arene C-H bonds across a Ru(II)-hydroxide bond. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 127(41), 14174–14175. https://doi.org/10.1021/ja054101e

Zhang, J. B., Gunnoe, T. B., & Peterson, J. L. (2005). Reactions of (PCP)Ru(CO)(NHPh)(PMe3) (PCP=2,6-((CH2PBu2)-Bu-t)(2)C6H3) with substrates that possess polar bonds. INORGANIC CHEMISTRY, 44(8), 2895–2907. https://doi.org/10.1021/ic0483592

Pittard, K. A., Cundari, T. R., Gunnoe, T. B., Day, C. S., & Petersen, J. L. (2005). Ruthenium(II)-mediated carbon-carbon bond formation between acetonitrile and pyrrole: Combined experimental and computational study. ORGANOMETALLICS, 24(21), 5015–5024. https://doi.org/10.1021/om0506668

Zhang, J. B., Barakat, K. A., Cundari, T. R., Gunnoe, T. B., Boyle, P. D., Petersen, J. L., & Day, C. S. (2005). Synthesis of the five-coordinate ruthenium(II) Complexes [(PCP)Ru(CO)(L)][BAr'(4)] {PCP=2,6-((CH2PBu2)-Bu-t)(2)C6H3, BAr'(4) 3,5-(CF3)(2)C6H3, L = eta(1)-ClCH2Cl, eta-N-2, or mu-Cl-Ru(PCP)(CO)}: Reactions with phenyldiazomethane and phenylacetylene. Inorganic Chemistry, 44(23), 8379–8390. https://doi.org/10.1012/ic051074k

Lail, M., Bell, C. M., Conner, D., Cundari, T. R., Gunnoe, T. B., & Petersen, J. L. (2004). Experimental and computational studies of ruthenium(II)-catalyzed addition of arene C-H bonds to olefins. ORGANOMETALLICS, 23(21), 5007–5020. https://doi.org/10.1021/om049404g

Pittard, K. A., Lee, J. P., Cundari, T. R., Gunnoe, T. B., & Petersen, J. L. (2004). Reactions of TpRu(CO)(NCMe)(Me) (Tp = hydridotris(pyrazolyl)borate) with heteroaromatic substrates: Stoichiometric and catalytic C-H activation. ORGANOMETALLICS, 23(23), 5514–5523. https://doi.org/10.1021/om049508r

Zhang, J., Gunnoe, T. B., & Boyle, P. D. (2004). Ruthenium(II) anilido complex containing a bisphosphine pincer ligand: Reversible formation of amidinate ligands via intramolecular C-N bond formation. ORGANOMETALLICS, 23(13), 3094–3097. https://doi.org/10.1021/om0497543

Conner, D., Jayaprakash, K. N., Cundari, T. R., & Gunnoe, T. B. (2004). Synthesis and reactivity of a coordinatively unsaturated ruthenium(II) parent amido complex: Studies of X-H activation (X = H or C). ORGANOMETALLICS, 23(11), 2724–2733. https://doi.org/10.1021/om049836r

Lail, M., Arrowood, B. N., & Gunnoe, T. B. (2003). Addition of arenes to ethylene and propene catalyzed by ruthenium. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 125(25), 7506–7507. https://doi.org/10.1021/ja035076k

Bergman, R. G., Cundari, T. R., Gillespie, A. M., Gunnoe, T. B., Harman, W. D., Klinckman, T. R., … White, D. P. (2003). Computational study of methane activation by TpRe(CO)(2) and CpRe(CO)(2) with a stereoelectronic comparison of cyclopentadienyl and scorpionate ligands. ORGANOMETALLICS, 22(11), 2331–2337. https://doi.org/10.1021/om021048j

Conner, D., Jayaprakash, K. N., Wells, M. B., Manzer, S., Gunnoe, T. B., & Boyle, P. D. (2003). Octahedral Ru(II) amido complexes TpRu(L)(L ')(NHR) (Tp = hydridotris(pyrazolyl)borate; L = L ' = P(OMe)(3) or PMe3 or L = CO and L ' = PPh3; R = H, Ph, or Bu-t): Synthesis, characterization, and reactions with weakly acidic C-H bonds. INORGANIC CHEMISTRY, 42(15), 4759–4772. https://doi.org/10.1021/ic034410a

Arrowood, B. N., Lail, M., Gunnoe, T. B., & Boyle, P. D. (2003). Radical polymerization of styrene and methyl methacrylate with Ruthenium(II) complexes. ORGANOMETALLICS, 22(23), 4692–4698. https://doi.org/10.1021/om020871c

Zhang, J. B., & Gunnoe, T. B. (2003). Reactions of ruthenium benzylidene complexes with cyclic and acyclic imines: Oligomerization of 1-pyrroline and metathesis via tautomerism. ORGANOMETALLICS, 22(11), 2291–2297. https://doi.org/10.1021/om0301029

Conner, D., Jayaprakash, K. N., Gunnoe, T. B., & Boyle, P. D. (2002). Influence of filled d pi-manifold and L/L ' ligands on the structure, basicity, and bond rotations of the octahedral and d(6) amido complexes TpRu(L)(L ')(NHPh) (Tp = hydridotris(pyrazolyl)borate; L= L ' = PMe3 or P(OMe)(3), or L = CO and L ' = PPh3): Solid-state structures of [TpRu(PMe3)(2)(NH2Ph)][OTf], [TpRu{P(OMe)(3)}(2)(NH2Ph)][OTf], and TpRu{P(OMe)(3)}(2)(NHPh). INORGANIC CHEMISTRY, 41(11), 3042–3049. https://doi.org/10.1021/ic020163j

Conner, D., Jayaprakash, K. N., Gunnoe, T. B., & Boyle, P. D. (2002). Ruthenium(II) anilido complexes TpRuL(2)(NHPh): Oxidative 4,4 '-aryl coupling reactions (Tp = hydridotris(pyrazolylborate); L = PMe3, P(OMe)(3), or CO). ORGANOMETALLICS, 21(24), 5265–5271. https://doi.org/10.1021/om0206406

Jayaprakash, K. N., Gillepsie, A. M., Gunnoe, T. B., & White, D. P. (2002). Synthesis of the Ru-IV amido complex [TpRu(CO)(PPh3)(NHPh)][OTf](2) (Tp = hydridotris(pyrazolyl)borate; OTf = trifluoromethanesulfonate) and deprotonation to form an octahedral and d(4) imido complex: computational study of Ru-IV-imido bonding. Chemical Communications (Cambridge, England), (4), 372–373. https://doi.org/10.1039/b110999e

Blue, E. D., Gunnoe, T. B., & Brooks, N. R. (2002). Synthesis, spectroscopy, and solid-state structural characterization of the hexanuclear copper macrocycle [Cu6Cl6(mu-PCHP)(6)]. Angewandte Chemie [International Edition in English], 41(14), 2571-.

Jayaprakash, K. N., Gunnoe, T. B., & Boyle, P. D. (2001). Preparation of the octahedral d(6) amido complex TpRu(CO)(PPh3)(NHPh) (Tp = hydridotris(pyrazolyl)borate): Solid-state structural characterization and reactivity. INORGANIC CHEMISTRY, 40(25), 6481–6486. https://doi.org/10.1021/ic010785p

Jayaprakash, K. N., Conner, D., & Gunnoe, T. B. (2001). Synthesis and reactivity of the octahedral d(6) parent amido complexes TpRu(L)(L ')(NH2) (Tp = hydridotris(pyrazolyl)borate; L = L ' PMe3, P(OMe)(3); L = CO, L ' PPh3) and [TpRu(PPh3)(NH2)(2)][Li]. ORGANOMETALLICS, 20(25), 5254–5256. https://doi.org/10.1021/om010739x

Tellers, D. M., Skoog, S. J., Bergman, R. G., Gunnoe, T. B., & Harman, W. D. (2000, June 26). Comparison of the relative electron-donating abilities of hydridotris(pyrazolyl)borate and cyclopentadienyl ligands: Different interactions with different transition metals. https://doi.org/10.1021/om000043o