Works (7)
Updated: July 28th, 2023 21:15
2017 journal article
Cationic rhenium ((III)) complexes: synthesis, characterization, and reactivity for hydrosilylation of aldehydes
Dalton Transactions (Cambridge, England : 2003), 46(14), 4609–4616.
TL;DR:
The catalytic efficiency for the hydrosilylation reaction of aldehydes using 4a has been demonstrated to be significantly more active than rhenium catalysts previously reported in the literature and the data suggest that electron-withdrawing substituents at the diamido amine ligand increase the catalysttic efficiency of the complexes.
(via Semantic Scholar)
Sources: NC State University Libraries, NC State University Libraries
Added: August 6, 2018
2015 journal article
Synthesis and Reactivity of Oxorhenium(V) Methyl, Benzyl, and Phenyl Complexes with CO: Implications for a Unique Mechanism for Migratory Insertion
ORGANOMETALLICS, 34(13), 3152–3158.
UN Sustainable Development Goal Categories
12. Responsible Consumption and Production
(Web of Science)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018
2013 journal article
Mechanism of MTO-Catalyzed Deoxydehydration of Diols to Alkenes Using Sacrificial Alcohols
ORGANOMETALLICS, 32(11), 3210–3219.
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation
(OpenAlex)
12. Responsible Consumption and Production
(Web of Science)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018
2013 journal article
The Electronic Nature of Terminal Oxo Ligands in Transition-Metal Complexes: Ambiphilic Reactivity of Oxorhenium Species
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 135(25), 9433–9441.
TL;DR:
These are the first examples of mono-oxo d(2) metal complexes in which the oxo ligand exhibits ambiphilic reactivity, and it is shown that stoichiometric reactions between 3 and triarylphosphine (PAr3) result in the formation of triaryl phosphine oxide (OPAr3).
(via Semantic Scholar)
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy
(Web of Science)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018
2012 journal article
Computational Investigation of the Mechanism for the Activation of CO by Oxorhenium Complexes
ORGANOMETALLICS, 31(10), 4055–4062.
UN Sustainable Development Goal Categories
12. Responsible Consumption and Production
(Web of Science)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018
2012 journal article
Role of Low-Valent Rhenium Species in Catalytic Hydrosilylation Reactions with Oxorhenium Catalysts
ORGANOMETALLICS, 31(17), 5994–5997.
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018
2011 journal article
Mechanism for the Activation of Carbon Monoxide via Oxorhenium Complexes
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 133(34), 13288–13291.
TL;DR:
An unprecedented mechanism is proposed: CO is activated by theMetal oxo complex 1 and inserted into the rhenium-methyl bond to yield acyl complex 2, after which subsequent migration of the acyl ligand to the metal oxo ligand yields acetate complex 3.
(via Semantic Scholar)
UN Sustainable Development Goal Categories
12. Responsible Consumption and Production
(Web of Science)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018
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