Jessica Lee Smeltz

Works (7)

Updated: July 28th, 2023 21:15

2017 journal article

Cationic rhenium ((III)) complexes: synthesis, characterization, and reactivity for hydrosilylation of aldehydes

Dalton Transactions (Cambridge, England : 2003), 46(14), 4609–4616.

By: D. Perez n, J. Smeltz n, R. Sommer n , P. Boyle n & E. Ison n 

TL;DR: The catalytic efficiency for the hydrosilylation reaction of aldehydes using 4a has been demonstrated to be significantly more active than rhenium catalysts previously reported in the literature and the data suggest that electron-withdrawing substituents at the diamido amine ligand increase the catalysttic efficiency of the complexes. (via Semantic Scholar)
Sources: NC State University Libraries, NC State University Libraries
Added: August 6, 2018

2015 journal article

Synthesis and Reactivity of Oxorhenium(V) Methyl, Benzyl, and Phenyl Complexes with CO: Implications for a Unique Mechanism for Migratory Insertion

ORGANOMETALLICS, 34(13), 3152–3158.

By: L. Robbins n, C. Lilly n, J. Smeltz n, P. Boyle n & E. Ison n 

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Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2013 journal article

Mechanism of MTO-Catalyzed Deoxydehydration of Diols to Alkenes Using Sacrificial Alcohols

ORGANOMETALLICS, 32(11), 3210–3219.

By: S. Liu *, A. Senocak *, J. Smeltz n, L. Yang*, B. Wegenhart*, J. Yi *, H. Kenttaemaa, E. Ison n , M. Abu-Omar *

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6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2013 journal article

The Electronic Nature of Terminal Oxo Ligands in Transition-Metal Complexes: Ambiphilic Reactivity of Oxorhenium Species

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 135(25), 9433–9441.

By: J. Smeltz n, C. Lilly n, P. Boyle n & E. Ison n 

TL;DR: These are the first examples of mono-oxo d(2) metal complexes in which the oxo ligand exhibits ambiphilic reactivity, and it is shown that stoichiometric reactions between 3 and triarylphosphine (PAr3) result in the formation of triaryl phosphine oxide (OPAr3). (via Semantic Scholar)
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Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2012 journal article

Computational Investigation of the Mechanism for the Activation of CO by Oxorhenium Complexes

ORGANOMETALLICS, 31(10), 4055–4062.

By: J. Smeltz n, C. Webster * & E. Ison n 

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Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2012 journal article

Role of Low-Valent Rhenium Species in Catalytic Hydrosilylation Reactions with Oxorhenium Catalysts

ORGANOMETALLICS, 31(17), 5994–5997.

By: J. Smeltz n, P. Boyle n & E. Ison n 

Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2011 journal article

Mechanism for the Activation of Carbon Monoxide via Oxorhenium Complexes

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 133(34), 13288–13291.

By: J. Smeltz n, P. Boyle n & E. Ison n 

TL;DR: An unprecedented mechanism is proposed: CO is activated by theMetal oxo complex 1 and inserted into the rhenium-methyl bond to yield acyl complex 2, after which subsequent migration of the acyl ligand to the metal oxo ligand yields acetate complex 3. (via Semantic Scholar)
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Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

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