Jessica Lee Smeltz

Works (7)

Updated: April 23rd, 2025 21:48

2017 article

Cationic rhenium(iii) complexes: synthesis, characterization, and reactivity for hydrosilylation of aldehydes

Pérez, D. E., Smeltz, J. L., Sommer, R. D., Boyle, P. D., & Ison, E. A. (2017, January 1). Dalton Transactions, Vol. 46, pp. 4609–4616.

By: D. Pérez n, J. Smeltz n, R. Sommer n , P. Boyle n & E. Ison n 

topics (OpenAlex): Organoboron and organosilicon chemistry; Asymmetric Hydrogenation and Catalysis; Catalytic Cross-Coupling Reactions
TL;DR: The catalytic efficiency for the hydrosilylation reaction of aldehydes using 4a has been demonstrated to be significantly more active than rhenium catalysts previously reported in the literature and the data suggest that electron-withdrawing substituents at the diamido amine ligand increase the catalysttic efficiency of the complexes. (via Semantic Scholar)
Sources: NC State University Libraries, NC State University Libraries, ORCID
Added: August 6, 2018

2015 article

Synthesis and Reactivity of Oxorhenium(V) Methyl, Benzyl, and Phenyl Complexes with CO: Implications for a Unique Mechanism for Migratory Insertion

Robbins, L. K., Lilly, C. P., Smeltz, J. L., Boyle, P. D., & Ison, E. A. (2015, July 1). Organometallics, Vol. 34, pp. 3152–3158.

By: L. Robbins n, C. Lilly n , J. Smeltz n, P. Boyle n & E. Ison n 

topics (OpenAlex): CO2 Reduction Techniques and Catalysts; Organometallic Complex Synthesis and Catalysis; Radiopharmaceutical Chemistry and Applications
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Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2013 article

Mechanism of MTO-Catalyzed Deoxydehydration of Diols to Alkenes Using Sacrificial Alcohols

Liu, S., Senocak, A., Smeltz, J. L., Yang, L., Wegenhart, B., Yi, J., … Abu-Omar, M. M. (2013, May 21). Organometallics, Vol. 32, pp. 3210–3219.

By: S. Liu *, A. Senocak *, J. Smeltz n, L. Yang*, B. Wegenhart*, J. Yi *, H. Kenttämaa *, E. Ison n , M. Abu-Omar *

topics (OpenAlex): Catalysis for Biomass Conversion; Asymmetric Hydrogenation and Catalysis; Carbon dioxide utilization in catalysis
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6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2013 article

The Electronic Nature of Terminal Oxo Ligands in Transition-Metal Complexes: Ambiphilic Reactivity of Oxorhenium Species

Smeltz, J. L., Lilly, C. P., Boyle, P. D., & Ison, E. A. (2013, May 31). Journal of the American Chemical Society, Vol. 135, pp. 9433–9441.

By: J. Smeltz n, C. Lilly n , P. Boyle n & E. Ison n 

MeSH headings : Electrons; Ligands; Models, Molecular; Molecular Conformation; Organometallic Compounds / chemical synthesis; Organometallic Compounds / chemistry; Quantum Theory; Rhenium / chemistry
topics (OpenAlex): Metal-Catalyzed Oxygenation Mechanisms; Metalloenzymes and iron-sulfur proteins; Polyoxometalates: Synthesis and Applications
TL;DR: These are the first examples of mono-oxo d(2) metal complexes in which the oxo ligand exhibits ambiphilic reactivity, and it is shown that stoichiometric reactions between 3 and triarylphosphine (PAr3) result in the formation of triaryl phosphine oxide (OPAr3). (via Semantic Scholar)
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Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2012 article

Computational Investigation of the Mechanism for the Activation of CO by Oxorhenium Complexes

Smeltz, J. L., Webster, C. E., & Ison, E. A. (2012, May 11). Organometallics, Vol. 31, pp. 4055–4062.

By: J. Smeltz n, C. Webster * & E. Ison n 

topics (OpenAlex): Carbon dioxide utilization in catalysis; CO2 Reduction Techniques and Catalysts; Organometallic Complex Synthesis and Catalysis
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Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2012 article

Role of Low-Valent Rhenium Species in Catalytic Hydrosilylation Reactions with Oxorhenium Catalysts

Smeltz, J. L., Boyle, P. D., & Ison, E. A. (2012, August 23). Organometallics, Vol. 31, pp. 5994–5997.

By: J. Smeltz n, P. Boyle n & E. Ison n 

topics (OpenAlex): Organoboron and organosilicon chemistry; Organometallic Complex Synthesis and Catalysis; Asymmetric Hydrogenation and Catalysis
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2011 article

Mechanism for the Activation of Carbon Monoxide via Oxorhenium Complexes

Smeltz, J. L., Boyle, P. D., & Ison, E. A. (2011, August 2). Journal of the American Chemical Society, Vol. 133, pp. 13288–13291.

By: J. Smeltz n, P. Boyle n & E. Ison n 

topics (OpenAlex): Carbon dioxide utilization in catalysis; CO2 Reduction Techniques and Catalysts; Catalysis and Oxidation Reactions
TL;DR: An unprecedented mechanism is proposed: CO is activated by theMetal oxo complex 1 and inserted into the rhenium-methyl bond to yield acyl complex 2, after which subsequent migration of the acyl ligand to the metal oxo ligand yields acetate complex 3. (via Semantic Scholar)
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Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

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