Han-Je Kim

Works (14)

Updated: July 5th, 2023 15:59

2017 journal article

Synthesis of tailored hydrodipyrrins and their examination in directed routes to bacteriochlorins and tetradehydrocorrins

New Journal of Chemistry, 41(19), 11170–11189.

By: S. Zhang n, M. Reddy n, O. Mass n, H. Kim n, G. Hu n & J. Lindsey n 

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Sources: NC State University Libraries, NC State University Libraries
Added: August 6, 2018

2016 article

Synthesis and photophysical characteristics of 2,3,12,13-tetraalkylbacteriochlorins

Zhang, S., Kim, H.-J., Tang, Q., Yang, E., Bocian, D. F., Holten, D., & Lindsey, J. S. (2016, July 1). NEW JOURNAL OF CHEMISTRY, Vol. 40, pp. 5942–5956.

By: S. Zhang n, H. Kim n, Q. Tang *, E. Yang*, D. Bocian *, D. Holten *, J. Lindsey n 

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Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2011 journal article

Facile synthesis of a B,D-tetradehydrocorrin and rearrangement to bacteriochlorins

New Journal of Chemistry, 35(7), 1376–1384.

By: K. Aravindu, M. Krayer, H. Kim & J. Lindsey 

Source: NC State University Libraries
Added: August 6, 2018

2011 journal article

Photophysical Properties and Electronic Structure of Stable, Tunable Synthetic Bacteriochlorins: Extending the Features of Native Photosynthetic Pigments

JOURNAL OF PHYSICAL CHEMISTRY B, 115(37), 10801–10816.

By: E. Yang*, C. Kirmaier *, M. Krayer n, M. Taniguchi n , H. Kim n, J. Diers*, D. Bocian *, J. Lindsey n , D. Holten *

Contributors: E. Yang*, C. Kirmaier *, M. Krayer n, M. Taniguchi n , H. Kim n, J. Diers*, D. Bocian *, J. Lindsey n , D. Holten *

MeSH headings : Bacteriochlorophylls / chemistry; Electrons; Pheophytins / chemistry; Photosynthesis; Porphyrins / chemical synthesis; Porphyrins / chemistry; Quantum Theory; Spectroscopy, Near-Infrared
TL;DR: The studies show how the palette of synthetic bacteriochlorins extends the properties of the native photosynthetic pigments (bacteriochlorophylls) and elucidated design principles for tuning the spectral and photophysical characteristics as required for a wide variety of photochemical applications. (via Semantic Scholar)
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Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2011 journal article

Synthesis and Photophysical Characterization of Stable Indium Bacteriochlorins

INORGANIC CHEMISTRY, 50(10), 4607–4618.

By: M. Krayer n, E. Yang*, H. Kim n, H. Kee*, R. Deans n, C. Sluder n, J. Diers*, C. Kirmaier * ...

MeSH headings : Acids / chemistry; Bacteria; Bacteriochlorophylls / chemistry; Bacteriochlorophylls / metabolism; Catalysis; Coordination Complexes / chemical synthesis; Coordination Complexes / metabolism; Electrons; Fluorescence; Indium / chemistry; Indium / metabolism; Kinetics; Light; Magnetic Resonance Spectroscopy; Molecular Conformation / radiation effects; Molecular Mimicry; Photochemistry / methods; Photochemotherapy; Porphyrins / chemical synthesis; Porphyrins / metabolism; Pyrroles / chemistry; Quantum Theory
TL;DR: The trends in optical properties of the indium bacteriochlorins versus free base analogues, and the effects of 5-OMe versus 5-H substituents, correlate well with frontier molecular-orbital energies and energy gaps derived from density functional theory calculations. (via Semantic Scholar)
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Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2010 journal article

Expanded Scope of Synthetic Bacteriochlorins via Improved Acid Catalysis Conditions and Diverse Dihydrodipyrrin-Acetals

JOURNAL OF ORGANIC CHEMISTRY, 75(4), 1016–1039.

By: M. Krayer n, M. Ptaszek n, H. Kim n, K. Meneely n, D. Fan n, K. Secor n, J. Lindsey n 

MeSH headings : Acetals / chemistry; Acids / chemistry; Catalysis; Crystallography, X-Ray; Metalloporphyrins / chemical synthesis; Metalloporphyrins / chemistry; Models, Molecular; Molecular Structure; Photochemistry; Porphyrins / chemical synthesis; Porphyrins / chemistry; Pyrroles / chemistry; Spectroscopy, Near-Infrared
TL;DR: Four promising acid catalysis conditions are identified and 15 new bacteriochlorins prepared herein exhibit a long-wavelength absorption band in the range 707-759 nm, providing tunable access to the near-infrared region, which expands the scope of available bacterio chlorins for fundamental studies and diverse applications. (via Semantic Scholar)
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Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2009 patent

De novo synthesis of bacteriochlorins

By: H. Kim & J. Lindsey 

Source: NC State University Libraries
Added: August 6, 2018

2007 review

Sparsely substituted chlorins as core constructs in chlorophyll analogue chemistry. Part 1: Synthesis

[Review of ]. TETRAHEDRON, 63(18), 3826–3839.

By: M. Ptaszek n, B. McDowell n, M. Taniguchi n , H. Kim n & J. Lindsey n 

Contributors: M. Ptaszek n, B. McDowell n, M. Taniguchi n , H. Kim n & J. Lindsey n 

author keywords: chlorin; hydroporphyrin; hydrodipyrrin; dipyrromethane
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Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2007 journal article

Synthesis and photophysical characterization of porphyrin, chlorin and bacteriochlorin molecules bearing tethers for surface attachment

PHOTOCHEMISTRY AND PHOTOBIOLOGY, 83(6), 1513–1528.

By: C. Muthiah n, M. Taniguchi n , H. Kim n, I. Schmidt n, H. Kee*, D. Holten *, D. Bocian *, J. Lindsey n 

Contributors: C. Muthiah n, M. Taniguchi n , H. Kim n, I. Schmidt n, H. Kee*, D. Holten *, D. Bocian *, J. Lindsey n 

MeSH headings : Molecular Structure; Photochemistry; Porphyrins / chemical synthesis; Porphyrins / chemistry; Spectrophotometry; Surface Properties
TL;DR: The synthesis and characterization of the tetrapyrrole compounds underpin their use as sensitizers in molecular‐based solar cells and hold promise for diverse studies in artificial photosynthesis. (via Semantic Scholar)
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Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2006 journal article

Synthesis of hydrodipyrrins tailored for reactivity at the 1- and 9-positions

TETRAHEDRON, 63(1), 37–55.

By: H. Kim n, D. Dogutan n, M. Ptaszek n & J. Lindsey n 

author keywords: hydrodipyrrin; 1-pyrroline; pyrrole; hydroporphyrin
TL;DR: Straightforward access to various hydrodipyrrins should facilitate development of syntheses of diverse hydroporphyrins. (via Semantic Scholar)
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Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2005 journal article

De novo synthesis of stable tetrahydroporphyrinic macrocycles: Bacteriochlorins and a tetradehydrocorrin

JOURNAL OF ORGANIC CHEMISTRY, 70(14), 5475–5486.

By: H. Kim n & J. Lindsey n 

MeSH headings : Bacteriochlorophyll A / metabolism; Catalysis; Hydrogenation; Macrocyclic Compounds / chemical synthesis; Molecular Structure; Photochemistry; Pigments, Biological / chemical synthesis; Porphyrins / chemical synthesis; Spectrum Analysis
TL;DR: A simple entry to stable bacteriochlorins and tetradehydrocorrins should facilitate a wide variety of applications and is stable to routine handling in light and air. (via Semantic Scholar)
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Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2005 journal article

Refined synthesis of 2,3,4,5-tetrahydro-1,3,3-trimethyidipyrrin, a deceptively simple precursor to hydroporphyrins

ORGANIC PROCESS RESEARCH & DEVELOPMENT, 9(5), 651–659.

By: M. Ptaszek n, J. Bhaumik n, H. Kim n, M. Taniguchi n  & J. Lindsey n 

Contributors: M. Ptaszek n, J. Bhaumik n, H. Kim n, M. Taniguchi n  & J. Lindsey n 

TL;DR: The prior 5-step synthesis of 1 from pyrrole-2-carboxaldehyde employed relatively simple and well-known reactions yet suffered from several drawbacks, including limited scale and lessened reliance on chromatography. (via Semantic Scholar)
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Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2004 patent

Regioisomerically pure oxochlorins and methods of synthesis

Washington, DC: U.S. Patent and Trademark Office.

By: J. Lindsey , M. Taniguchi , S. Prathapan, M. Kim & H. Kim

Source: NC State University Libraries
Added: August 6, 2018

2002 journal article

Synthesis and electronic properties of regioisomerically pure oxochlorins

JOURNAL OF ORGANIC CHEMISTRY, 67(21), 7329–7342.

By: M. Taniguchi n , H. Kim n, D. Ra n, J. Schwartz n, C. Kirmaier  n, E. Hindin n, . Diers n, S. Prathapan n ...

Contributors: M. Taniguchi n , D. Holten  n, J. Lindsey n , H. Kim n, D. Ra n, J. Schwartz n, C. Kirmaier  n, E. Hindin n ...

MeSH headings : Indicators and Reagents; Models, Molecular; Molecular Conformation; Molecular Structure; Oxidation-Reduction; Porphyrins / chemical synthesis; Porphyrins / chemistry; Spectrophotometry; Stereoisomerism
TL;DR: Collectively, the fluorescence yields, excited-state lifetimes, oxidation potentials, and various spectral characteristics of the chlorin and oxochlorin building blocks provide the foundation for studies of photochemical processes in larger architectures based on these chromophores. (via Semantic Scholar)
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Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

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