Chemical and Biomolecular Engineering

Works Published in 2013

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Displaying works 81 - 100 of 245 in total

Sorted by most recent date added to the index first, which may not be the same as publication date order.

2013 article

Educational Practice and Educational Research in Engineering: Partners, Antagonists, or Ships Passing in the Night?

Felder, R. M., & Hadgraft, R. G. (2013, July). JOURNAL OF ENGINEERING EDUCATION, Vol. 102, pp. 339–345.

UN Sustainable Development Goal Categories
4. Quality Education (Web of Science; OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2013 journal article

Crossing the divide between homogeneous and heterogeneous catalysis in water oxidation

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 110(52), 20918–20922.

Contributors: A. Vannucci*, L. Alibabaei*, M. Losego n, J. Concepcion*, B. Kalanyan n, G. Parsons n, T. Meyer*

author keywords: electrocatalysis; surface stabilization
MeSH headings : Catalysis; Electrochemical Techniques; Electrodes; Hydrogen-Ion Concentration; Models, Chemical; Molecular Structure; Nanostructures / chemistry; Oxidation-Reduction; Surface Properties; Tin Compounds / chemistry; Titanium / chemistry; Water / chemistry
TL;DR: Enhanced surface binding stability of a phosphonate-derivatized water oxidation catalyst over a wide pH range (1–12) by atomic layer deposition of an overlayer of TiO2 provides a hybrid approach to heterogeneous catalysis. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2013 journal article

Bioactive Cellulose Nanofibrils for Specific Human IgG Binding

BIOMACROMOLECULES, 14(12), 4161–4168.

MeSH headings : Adsorption; Biosensing Techniques; Cellulose / chemistry; Cellulose / ultrastructure; Chromatography, Affinity; Humans; Immobilized Proteins; Immunoglobulin G / chemistry; Immunoglobulin G / isolation & purification; Kinetics; Microscopy, Atomic Force; Nanofibers / chemistry; Nanofibers / ultrastructure; Peptide Fragments / chemistry; Polymerization; Polymethacrylic Acids / chemistry; Protein Binding; Quartz Crystal Microbalance Techniques; Signal-To-Noise Ratio; Surface Properties
TL;DR: The effects of initiator concentration and thickness of poly(AMA-co-HEMA) layer on hIgG adsorption were investigated in the developed systems, which exhibited high signal-to-noise response. (via Semantic Scholar)
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2013 journal article

Activated carbon from biochar: Influence of its physicochemical properties on the sorption characteristics of phenanthrene

BIORESOURCE TECHNOLOGY, 149, 383–389.

author keywords: Biochar; Solid-state NMR; Activation Activated biochar; Phenanthrene adsorption
TL;DR: The relationship between physicochemical properties of biochar-based activated carbons and its adsorption was investigated using an aromatic model compound, phenanthrene, and solid-state (13)C NMR analysis indicated more condensed aromatic structures when pyrolysis temperature increased or after activation process induced. (via Semantic Scholar)
UN Sustainable Development Goal Categories
2. Zero Hunger (Web of Science)
6. Clean Water and Sanitation (OpenAlex)
13. Climate Action (Web of Science)
Source: Web Of Science
Added: August 6, 2018

2013 journal article

Thermomechanical Properties of Lignin-Based Electrospun Nanofibers and Films Reinforced with Cellulose Nanocrystals: A Dynamic Mechanical and Nanoindentation Study

ACS APPLIED MATERIALS & INTERFACES, 5(22), 11768–11776.

author keywords: cellulose nanocrystals; lignin; nanofibers; electrospinning; dynamic mechanical analysis; nanoindentation; thermomechanical properties; lignin films
MeSH headings : Cellulose / chemistry; Lignin / chemistry; Membranes, Artificial; Nanofibers / chemistry; Nanoparticles / chemistry; Polyvinyl Alcohol / chemistry
TL;DR: The thermomechanical performance of the lignin-based electrospun fibers and the spin-coated thin films was improved when they were embedded with CNCs, and insight was provided into the effect of addition of C NCs on the microphysical processes controlling the yield behavior in the composites. (via Semantic Scholar)
Source: Web Of Science
Added: August 6, 2018

2013 journal article

Solar water splitting in a molecular photoelectrochemical cell

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 110(50), 20008–20013.

Contributors: L. Alibabaei*, M. Brennaman*, M. Norris*, B. Kalanyan n, W. Song*, M. Losego n, J. Concepcion*, R. Binstead*, G. Parsons n, T. Meyer*

MeSH headings : Catalysis; Electrochemical Techniques / methods; Light; Models, Chemical; Photochemical Processes; Solar Energy; Time Factors; Titanium / chemistry; Water / chemistry
TL;DR: A hybrid strategy for solar water splitting based on a dye sensitized photoelectrosynthesis cell using a derivatized, core–shell nanostructured photoanode with the core a high surface area conductive metal oxide film––indium tin oxide or antimony tin oxide––coated with a thin outer shell of TiO2 formed by atomic layer deposition. (via Semantic Scholar)
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (Web of Science; OpenAlex)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2013 journal article

Scalable Manufacture of Built-to-Order Nanomedicine: Spray-Assisted Layer-by-Layer Functionalization of PRINT Nanoparticles

ADVANCED MATERIALS, 25(34), 4707–4713.

By: S. Morton*, K. Herlihy*, K. Shopsowitz*, Z. Deng*, K. Chu*, C. Bowerman*, J. DeSimone n, P. Hammond*

author keywords: core; shell nanoparticles; thin films; nanoimprinting; nanomedicine
MeSH headings : Carbocyanines / chemistry; Cell Line, Tumor; Drug Carriers / chemistry; Humans; Lactic Acid / chemistry; Microscopy, Atomic Force; Microscopy, Confocal; Nanomedicine; Nanoparticles / chemistry; Polyglycolic Acid / chemistry; Polylactic Acid-Polyglycolic Acid Copolymer; Polylysine / chemistry; Polyvinyl Alcohol / chemistry
TL;DR: A modular and tunable approach towards design of built-to-order nanoparticle systems, spray coating on PRINT particles is demonstrated to achieve technologies capable of targeted interactions with cancer cells for applications in drug delivery. (via Semantic Scholar)
UN Sustainable Development Goal Categories
3. Good Health and Well-being (Web of Science; OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2013 journal article

Rapidly-Dissolvable Microneedle Patches Via a Highly Scalable and Reproducible Soft Lithography Approach

ADVANCED MATERIALS, 25(36), 5060–5066.

By: K. Moga*, L. Bickford*, R. Geil*, S. Dunn*, A. Pandya*, Y. Wang*, J. Fain*, C. Archuleta*, . Adrian T. O'Neill*, J. DeSimone n

author keywords: microneedles; microprojections; PRINT; soft lithography; drug delivery
TL;DR: Biocompatible microneedles (made by using a soft lithography process known as PRINT) showed efficacy in piercing both murine and human skin samples and delivering a fluorescent drug surrogate to the tissue. (via Semantic Scholar)
Source: Web Of Science
Added: August 6, 2018

2013 journal article

Influence of solvent on ion aggregation and transport in PY15TFSI ionic liquid-aprotic solvent mixtures

Journal of Physical Chemistry. B, Condensed Matter, Materials, Surfaces, Interfaces & Biophysical, 117(36), 10581–10588.

By: O. Borodin, W. Henderson, E. Fox, M. Berman, M. Gobet & S. Greenbaum

Source: NC State University Libraries
Added: August 6, 2018

2013 journal article

Genetically encoded light-activated transcription for spatiotemporal control of gene expression and gene silencing in mammalian cells

Journal of the American Chemical Society, 135(36), 13433–13439.

MeSH headings : Activating Transcription Factors / genetics; Activating Transcription Factors / metabolism; DNA-Directed RNA Polymerases / genetics; DNA-Directed RNA Polymerases / metabolism; Gene Expression Regulation, Enzymologic / genetics; Gene Silencing; Green Fluorescent Proteins / genetics; Green Fluorescent Proteins / metabolism; HEK293 Cells; Humans; Light; Luciferases / genetics; Luciferases / metabolism; Models, Molecular; Molecular Structure; Photochemical Processes; Protein Engineering; Viral Proteins / genetics; Viral Proteins / metabolism
TL;DR: The photocaging of a synthetic gene network using unnatural amino acid mutagenesis in mammalian cells was demonstrated with an engineered bacteriophage RNA polymerase, demonstrating tight spatial and temporal control. (via Semantic Scholar)
Source: NC State University Libraries
Added: August 6, 2018

2013 journal article

Controllable atomistic graphene oxide model and its application in hydrogen sulfide removal

The Journal of Chemical Physics, 139(19), 194707.

By: L. Huang n, M. Seredych*, T. Bandosz*, A. van Duin*, X. Lu* & K. Gubbins n

TL;DR: This work combines temperature-programmed molecular dynamics simulation techniques and the ReaxFF reactive force field to generate realistic atomistic graphene oxide structures with different functional groups and defects. (via Semantic Scholar)
Sources: Web Of Science, Crossref, NC State University Libraries
Added: August 6, 2018

2013 journal article

Aligned Carbon Nanotube-Silicon Sheets: A Novel Nano-architecture for Flexible Lithium Ion Battery Electrodes

ADVANCED MATERIALS, 25(36), 5109–5114.

By: K. Fu n, O. Yildiz n, H. Bhanushali n, Y. Wang n, K. Stano n, L. Xue n, X. Zhang n, P. Bradford n

Contributors: P. Bradford n, X. Zhang n, L. Xue n, K. Stano n, Y. Wang n, H. Bhanushali n, O. Yildiz n, K. Fu n

author keywords: silicon; carbon nanotube; super-aligned; anode; lithium ion batteries
MeSH headings : Electric Power Supplies; Electrochemical Techniques; Electrodes; Ions / chemistry; Lithium / chemistry; Nanostructures / chemistry; Nanotubes, Carbon / chemistry; Silicon / chemistry
TL;DR: Aligned carbon nanotube sheets provide an engineered scaffold for the deposition of a silicon active material for lithium ion battery anodes, allowing uniform deposition of silicon thin films while the alignment allows unconstrained volumetric expansion of the silicon, facilitating stable cycling performance. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2013 journal article

A simple method to encapsulate SnSb nanoparticles into hollow carbon nanofibers with superior lithium-ion storage capability

JOURNAL OF MATERIALS CHEMISTRY A, 1(44), 13807–13813.

Contributors: L. Xue n, X. Xia n, T. Tucker*, K. Fu n, S. Zhang n, S. Li n, X. Zhang n

UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2013 journal article

3D Printing of Free Standing Liquid Metal Microstructures

ADVANCED MATERIALS, 25(36), 5081–5085.

By: C. Ladd n, J. So n, J. Muth n & M. Dickey n

author keywords: direct-write; 3D printing; liquid metal; egain; stretchable electronics
TL;DR: This paper describes a method to direct-write 3D liquid metal microcomponents at room temperature capable of printing wires, arrays of spheres, arches, and interconnects. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2013 journal article

Three-dimensional self-assembled photonic crystals with high temperature stability for thermal emission modification

NATURE COMMUNICATIONS, 4.

By: K. Arpin*, M. Losego n, A. Cloud*, H. Ning*, J. Mallek*, N. Sergeant*, L. Zhu*, Z. Yu* ...

Contributors: K. Arpin*, M. Losego n, A. Cloud*, H. Ning*, J. Mallek*, N. Sergeant*, L. Zhu*, Z. Yu* ...

TL;DR: Self-assembled templates are utilized to fabricate high-quality tungsten photonic crystals that demonstrate unprecedented thermal stability up to at least 1,400 °C and modified thermal emission at solar thermophotovoltaic operating temperatures, and comparable thermal and optical results are obtained using a photonic crystal comprising a previously unstudied material, hafnium diboride. (via Semantic Scholar)
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (Web of Science; OpenAlex)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2013 journal article

The Regulatory Implications of Hydroquinone for the Multifunctional Enzyme Dehaloperoxidase-Hemoglobin from Amphitrite ornata

JOURNAL OF PHYSICAL CHEMISTRY B, 117(47), 14615–14624.

By: J. Zhao n, J. Zhao n & S. Franzen n

MeSH headings : Animals; Chlorophenols / metabolism; Hemoglobins / chemistry; Hemoglobins / metabolism; Hydrogen Peroxide / metabolism; Hydroquinones / metabolism; Models, Molecular; Multifunctional Enzymes / chemistry; Multifunctional Enzymes / metabolism; Oxidation-Reduction; Peroxidases / chemistry; Peroxidases / metabolism; Phenols / metabolism; Polychaeta / chemistry; Polychaeta / enzymology; Polychaeta / metabolism
TL;DR: Light is shed on understanding the difference between substrate and inhibitor binding sites and regulatory implication for the peroxidase and oxygen-transporter functions in DHP, and the reversible reactions between ferric/oxyferrous DHP A and H2Q/1,4-BQ are shown to involve a proton-coupled electron transfer (PCET) mechanism. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2013 journal article

Stabilizing molecular sensitizers in aqueous environs

Nano Energy, 2(5), 1067–1069.

By: M. Losego & K. Hanson

Source: NC State University Libraries
Added: August 6, 2018

2013 journal article

Solid Electrolyte Interphase on Lithium-Ion Carbon Nanofiber Electrodes by Atomic and Molecular Layer Deposition

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 160(11), A1971–A1978.

By: A. Loebl n, C. Oldham n, C. Devine n, B. Gong n, S. Atanasov n, G. Parsons n, P. Fedkiw n

Contributors: A. Loebl n, C. Oldham n, C. Devine n, B. Gong n, S. Atanasov n, G. Parsons n, P. Fedkiw n

UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2013 journal article

Reversible cyclic peptide libraries for the discovery of affinity ligands

Analytical Chemistry, 85(19), 9229–9237.

By: S. Menegatti n, K. Ward n, A. Naik n, W. Kish n, R. Blackburn n & R. Carbonell n

MeSH headings : Ligands; Molecular Structure; Peptide Library; Peptides, Cyclic / analysis; Tandem Mass Spectrometry
TL;DR: A method is shown for synthesis of the irreversible cyclic peptide corresponding to the proposed depsipeptide structure, to make the ligand stable to the aqueous acid and alkaline conditions encountered in affinity chromatographic applications. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2013 personal communication

Reply to Perkin et al.: Experimental observations demonstrate that ionic liquids form both bound (Stern) and diffuse electric double layers

By: M. Gebbie, M. Valtiner, X. Banquy, W. Henderson & J. Israelachvili

Source: NC State University Libraries
Added: August 6, 2018

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